Search Results (13,467)

Growing concern over the environmental impact of conventional plastics has driven the development of biodegradable alternatives. In this context, natural polymers such as starch have emerged as sustainable options. Commercial montmorillonite, implemented as a reference nanomaterial, allows for the enhancement of the properties of biodegradable materials. In this study, commercial cassava starch powder plasticized with water and 35% glycerol, along with commercial nanoclay at concentrations of 0%, 2%, and 4%, was used as film reinforcement. The manufacturing process employed extrusion to evaluate the effectiveness of the nanomaterial in improving the mechanical and functional characteristics of the films. Films with varying concentrations of glycerol and nanoclay were produced to determine the optimal formulation by assessing their rheological, thermal, and mechanical properties. These films were subjected to comprehensive analysis using internationally standardised techniques, including Thermogravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC), Fourier Transform Infrared Spectroscopy (FTIR), and morphological characterisation via Scanning Electron Microscopy (SEM). Among the properties evaluated, water vapour permeability (WVTR) was of particular interest. Results showed that higher nanoclay content improved moisture retention, thus enhancing the films’ water barrier properties. Mechanical testing indicated that the film with the highest nanoclay concentration, F-g35-NC4, displayed tensile strength values of 0.23 ± 0.02 MPa and elongation of 66.90% ± 4.85, whereas F-g35-NC0 and F-g35-NC2 exhibited lower values. Conversely, the highest tear resistance was also recorded for F-g35-NC4, reaching 0.740 ± 0.009 kg. Contact angle measurements revealed a hydrophilic tendency, with values of 89.93° ± 8.78°. Finally, WVTR analysis confirmed that increased nanoclay content enhanced moisture retention and improved the water barrier performance, with a value of 0.030 ± 0.011 g/m²·day, supporting potential applications in the packaging sector. Full article

With the fast development of the 5G technology and IoV, a vehicle has become a smart device with communication, computing, and storage capabilities. However, the limited on-board storage and computing resources often cause large latency for task processing and result in degradation of system QoS as well as user QoE. In the meantime, to build the environmentally harmonious transportation system and green city, the energy consumption of data processing has become a new concern in vehicles. Moreover, due to the fast movement of IoV, traditional GSI-based methods face the dilemma of information uncertainty and are no longer applicable. To address these challenges, we propose a T2VC model. To deal with information uncertainty and dynamic offloading due to the mobility of vehicles, we propose a MAB-based QEVA-UCB solution to minimize the system cost expressed as the sum of weighted latency and power consumption. QEVA-UCB takes into account several related factors such as the task property, task arrival queue, offloading decision as well as the vehicle mobility, and selects the optimal location for offloading tasks to minimize the system cost with latency energy awareness and conflict awareness. Extensive simulations verify that, compared with other benchmark methods, our approach can learn and make the task offloading decision faster and more accurately for both latency-sensitive and energy-sensitive vehicle users. Moreover, it has superior performance in terms of system cost and learning regret. Full article

Greenwashing by unvalidated environmental labelling is increasingly common and highly problematic due to the potential to mislead consumers. This is especially concerning for products that pose health risks, including alcohol. As environmental sustainability becomes more important to consumers, it is vital to assess changes in the use of potentially misleading claims over time. Among the first studies of its kind globally, this study aimed to (i) develop a typology of environmental claims displayed on alcohol products in Australia, (ii) examine the prevalence of these claims to establish baseline data for ongoing tracking, and (iii) assess the provision of recycling information. Four claim categories were identified: sustainability, planet friendly, bio-related and carbon-related. Claims featured on 8% of the 5982 sampled products, with considerable variation between alcohol categories. Sustainability claims were the most prevalent (5%). Recycling information appeared on 72% of products. The results suggest ambiguous environmental claims are present although not yet widespread. In contrast, recycling information is much more common although not universal. These findings highlight the need to consider restrictions on unsubstantiated environmental claims on alcohol products that can mislead consumers. Further, a nationally standardised mandatory recycling label should be introduced to assist consumers in reducing their environmental impacts. Full article

Background: Drug delivery against ciprofloxacin-resistant microbial strains is one of the most challenging areas of research in the pharmaceutical industry. The broad-spectrum antibiotic ciprofloxacin often faces challenges due to its poor bioavailability; thus, the activity of this drug is generally compromised against resistant strains. Traditional drug delivery systems, such as liposomes, are utilized to address this issue; however, niosomes have surfaced as a promising successor to their liposomal counterparts due to their superior attributes, such as enhanced stability and reduced toxicity. However, owing to environmental and toxicological concerns over commonly used chemical surfactants in niosomes, there is a pressing need to explore greener and safer alternatives. This study is focused on the application of sophorolipids (SLs), a biosurfactant that is synthesized by the yeast Starmerella bombicola, as a vesicular assembly for ciprofloxacin encapsulation. Methods: The SL-based niosomal formulation was characterized for particle size, zeta potential, and polydispersity index (PDI), while transmission electron microscopy (TEM) was employed to determine the morphology of niosomes. Agar well diffusion, broth dilution, and biofilm inhibition assays were performed to assess efficacy. Results: The niosomal formulations were successfully prepared; among them, the (+)vely charged formulation exhibited a more organized morphology, and their size and zeta potential values were found to be around ~371 nm and 63 mV for the blank niosomes (without the loaded drug) and ~269 nm and 51 mV for the ciprofloxacin-loaded niosomes. The minimum inhibitory concentration and biofilm inhibitory concentration against the MRSA strain were 5 µg/mL and 25 µg/mL, respectively, for the ciprofloxacin-loaded, (+)vely charged SL niosomes—for free ciprofloxacin these values were 40 µg/mL and 100 µg/mL—presenting remarkable potential for biofilm inhibition. Conclusion: This study highlights the promising therapeutic potential of SL-based ciprofloxacin-loaded niosomes against the emerging health threat of the MRSA strain. Full article

This article presents a conceptual framework linking responsible leadership competencies to organizational processes relevant for sustainability transformation. A leader’s personal impact is conceptualized as indirect through organizational governance, prioritization, collaboration, and innovation. The article provides a conceptual mapping approach that systematically connects individual leadership competencies with strategic organizational impact areas. The framework builds on the Competency Assessment for Responsible Leadership (CARL) and the Positive Impact Organization (PIO) concept to relate leadership capabilities to organizational transformation requirements. Five responsible leadership competencies—ethics and values, self-awareness, stakeholder relations, change and innovation, and systems thinking—are mapped to five organizational impact areas: governance alignment, sustainability culture, external stakeholder validation, purpose-driven product and service innovation, and transformative sustainability. The article identifies how specific leadership competencies align with distinct organizational leverage points, clarifying the mechanisms through which leaders shape structures, decision processes, cultural norms, and innovation pathways associated with sustainability transformation. By specifying these relationships, the framework distinguishes leadership impact at the organizational level and provides a structured basis for analyzing how leadership competencies contribute to an organization’s capacity for societal and environmental contribution. The framework is applicable to research on responsible leadership and business sustainability and informs leadership development and management education concerned with sustainability-oriented organizational change. Full article

Sustainability concerns over the management and handling of the growing volume of waste tires have necessitated the exploration of potential applications for the reuse and recycling of this resource, as they are categorized as hazardous wastes and are typically incinerated through thermal processing or dumped in landfills, resulting in significant environmental issues. The recycled steel and textile fibers from tires can be incorporated in concrete to assist in mitigating this impending environmental calamity, primarily by enhancing the efficacy of concrete. The present study aims to investigate the effect of using recycled tire steel fibers (RTSF) and recycled tire textile fibers (RTTF) in concrete, as economically viable and environmentally friendly alternatives to commercially available fibers. Although literature on the use of recycled fibers in concrete is available, the research is very limited in terms of their hybrid use and with minimal environmental analysis. Consequently, to address the gaps, this research concentrates on the use of RTSF and RTTF as a hybrid mix in concrete with life cycle assessment (LCA) to balance the mechanical performance and environmental sustainability. The experimental work is formulated to suggest an optimum dose of RTSF and RTTF, as a hybrid mix form, to be incorporated in concrete that imparts sufficient strength and workability. The fibers were integrated with dosages of 0.75%, 1%, and 1.25% for RTSF and 0.25%, 0.5%, and 0.75% for RTTF, respectively, by volume in non-hybrid form, while in hybrid form, they were reinforced as four different combinations (1%:0.5%, 0.75%, 0.75%, 0.5%, 0.5%:0.5%, and 0.75%:0.25%) by volume of RTSF and RTTF, respectively. Fresh and hardened properties of concrete were tested according to the ASTM standards. The results showed that concrete with hybrid fibers outperformed the concrete with normal individual fibers in both fresh and hardened states tests. The mechanical strength results showed that the synergistic use of RTSF and RTTF can enhance the strength, toughness, ductility, and crack resistance of the concrete. The hybrid mix H1 comprising 1% RTSF and 0.5% RTTF was ascertained as the optimal mix showing the highest mechanical performance with embodied CO₂ and energy values only slightly higher than the control mix, while offering the significant sustainability benefit of utilizing recycled fibers. Full article

Background and Objectives: Lung cancer in never-smokers (LCINS) has become a major global health concern, ranking as the fifth leading cause of cancer-related mortality. Unlike smoking-related lung cancer, LCINS arises from complex interactions between environmental carcinogens and distinct genomic alterations. This review summarizes current evidence on environmental risks, molecular features, and therapeutic progress shaping lung cancer management. Methods: A narrative review was conducted to examine risk factors for lung cancer in non-smokers. Studies reporting driver mutations in never-smokers and smokers were identified across major lung cancer histological subtypes, including small-cell lung cancer (SCLC), lung adenocarcinoma (LUAD), squamous cell carcinoma (SCC), and large-cell carcinoma (LCC). In addition, PubMed was searched for phase III trials and studies on targeted therapies related to driver mutations published between 2016 and 2025. Results: Environmental factors such as cooking oil fumes, radon, asbestos, arsenic, and fine particulate matter (PM_2.5) are strongly associated with LCINS through oxidative stress, DNA damage, and chronic inflammation. EGFR, PIK3CA, OS9, MET, and STK11 mutations are characteristic of never-smokers, in contrast to TP53 mutations, which are more common in smokers. Recent advances in targeted therapy and immunotherapy have improved survival and quality of life, emphasizing the importance of molecular profiling for treatment selection. Conclusions: LCINS represents a distinct clinical and molecular entity shaped by complex interactions between environmental exposures and genetic susceptibility. Genetic alterations promote tumor immune evasion, facilitating cancer development and progression. Continued advances in air quality control, molecular diagnostics, and precision therapies are essential for prevention, early detection, and reduction of the global disease burden. Full article

Availability of irrigation water during growing seasons in the Republic of South Africa (RSA) remains a significant concern. Persistent droughts and unpredictable rainfall patterns attributed to climate change, coupled with an increasing population, have exacerbated irrigation water scarcity. Globally, treated wastewater has been utilised as an irrigation water source; however, despite global advances in the usage of treated wastewater, its suitability for irrigation in RSA remains a contentious issue. Considering this uncertainty, this review article aims to unravel the South African scenario on the suitability of treated wastewater for irrigation purposes and highlights the potential environmental impacts and public health risks. The review synthesised literature in the last two decades (2000–present) using Web of Science, ScienceDirect, ResearchGate, and Google Scholar databases. Findings reveal that treated wastewater can serve as a viable irrigation source in the country, enhancing various soil parameters, including nutritional pool, organic carbon, and fertility status. However, elevated levels of salts, heavy metals, and microplastics in treated wastewater resulting from insufficient treatment of wastewater processes may present significant challenges. These contaminants might induce saline conditions and increase heavy metals and microplastics in soil systems and water bodies, thereby posing a threat to public health and potentially causing ecological risks. Based on the reviewed literature, irrigation with treated wastewater should be implemented on a localised and pilot basis. This review aims to influence policy-making decisions regarding wastewater treatment plant structure and management. Stricter monitoring and compliance policies, revision of irrigation water standards to include emerging contaminants such as microplastics, and intensive investment in wastewater treatment plants in the country are recommended. With improved policies, management, and treatment efficiency, treated wastewater can be a dependable, sustainable, and practical irrigation water source in the country with minimal public health risks. Full article

Filtration of emulsions is an important operation in multiple processes of chemical, environmental, and petroleum engineering. The primary concern of the present study is cleaning of water produced from a petroleum reservoir. The produced water is filtered from the oil droplets before being dumped into the sea or reinjected into the reservoir. Efficiency of filtration is determined, in particular, by the droplet size distribution and interfacial properties. We have developed a new population balance model of emulsion filtration, based on the Boltzmann–Smoluchowski approach. The model accounts for the droplet size distribution, as well as for the different mechanisms of the droplet capture: attachment to the surface and straining in the pore constrictions. The model can not only be applied to filtering of the produced water, but also to more general emulsion processing. It is capable of reproducing experimental data on the droplet production history and dynamic permeability decline. The sensitivity study indicates low sensitivity of the permeability decline curves to the model parameters. The production histories or other kinds of experimental data are necessary to discriminate between the different parametrizations of the model. Full article

Bovine Respiratory Disease (BRD) represents one of the largest causes of economic loss and animal morbidity in the global cattle industry, second only to neonatal diarrhea. Its etiology is complex, originating from a multifactorial combination of host susceptibility, environmental stressors, viral infections, and secondary bacterial pathogens. Although viruses are often the initial cause of disease, suppressing the host’s respiratory defense mechanisms, most of the severe pneumonic damage and clinical signs can be attributed to bacterial infections. This review provides an overview of the primary bacterial agents identified within the BRD complex, including Mannheimia haemolytica, Pasteurella multocida, Histophilus somni, and Mycoplasma bovis. We discuss their role as commensals that then become opportunistic pathogens, and further how they interact in a synergistic relationship with a primary viral insult, leading to the resulting pathogenesis and the development of pneumonia. This manuscript discusses in further detail some of the challenges in BRD management, such as the limitations of current diagnostic methodologies, overreliance on antimicrobial therapy, and the growing concern of antimicrobial resistance. Lastly, the need for integrated approaches in management, better husbandry and biosecurity, coupled with the development of novel therapeutic alternatives, is underlined as a means of assuring a sustainable control of this serious syndrome. Full article

Introduction: Mpox virus (MpoxV), an emerging zoonotic pathogen, has recently caused global concern due to increasing outbreaks beyond its traditional endemic regions. While transmission primarily occurs via close contact, fomites are also suspected of contributing. This study aims to evaluate the effectiveness of UV-C irradiation on MpoxV-contaminated surfaces. Methods: the virucidal activity of UV-C (254 nm) irradiation on MpoxV applied to plastic, glass, and stainless-steel surfaces was assessed. Using a viral stock of 2.49 × 10⁵ TCID₅₀/mL, the samples were exposed to increasing UV-C doses. Viral titers were quantified through TCID₅₀ and plaque assays. Results: A UV-C dose of 6.34 mJ/cm² achieved a >2-log reduction of viral load, below the detection limit (31.6 TCID50/mL), on all tested surfaces. EC₉₀ values were determined as 3.33 mJ/cm² (plastic), 0.81 mJ/cm² (stainless steel), and 1.98 mJ/cm² (glass). No viable virus was detectable post-treatment at these doses on plastic and stainless steel while the titer was significantly reduced on glass. Conclusions: UV-C irradiation at low doses effectively inactivated MpoxV on various fomites. These findings support UV-C as a rapid and effective environmental disinfection strategy in healthcare and community settings to prevent indirect transmission of MpoxV. Full article

A global interest in the cultivation of Kalibaus (Labeo calbasu) has emerged due to decreasing natural stocks and a consistent rise in market value and demand. Given these concerns, understanding the species’ physiological responses to environmental changes is crucial. The present research aimed to assess the effect of varying environmental temperatures on metabolism, haemato-biochemical indices, hormonal concentrations and immune responses in L. calbasu. This study was conducted in triplicate using 100 L glass aquariums at four different temperatures: 22, 26, 30, and 34 °C. The highest weight and length gain were observed at 30 °C, while the lowest occurred at 22 °C. Notably, the best feed conversion ratio (FCR) of 1.51 ± 0.03 was also recorded at 30 °C. Although haematological and biochemical parameters remained within normal ranges, they varied with temperature changes. Indicators of cold and heat stress were evident through lower hematocrit levels and higher white blood cell (WBC) counts. Biochemical indicators such as serum albumin (1.84 ± 0.05 g dL⁻¹), serum globulin (1.64 ± 0.06 gdL⁻¹), HCO₃ (30.93 ± 0.62), Na⁺ (115.60 ± 3.72 mmolL⁻¹), alkaline phosphatase (93.33 ± 9.39 AP, IUL⁻¹), and AST/SGOT (21.00 ± 4.55 UL⁻¹) were significantly higher at 30 °C. Regarding hormonal responses, peak levels of growth hormone (GH), triiodothyronine (T3) (1.44 ± 0.07 ngmL⁻¹), and thyroxine (T4) were recorded at 30 °C. Meanwhile, serum cortisol (1.62 ± 0.06 µgdL⁻¹) and adrenocorticotropic hormone (ACTH) (18.01 ± 3.26 pgmL⁻¹) were highest at 34 °C. Immune responses were strongest between 26 and 30 °C. In conclusion, the results suggest that L. calbasu should ideally be cultured between 26 and 30 °C for optimum growth and health, making it ideal for commercial farming. Full article

Drought stress and insecticide exposure are two significant environmental factors that can impact the physiology and behaviour of aphids, a major agricultural pest. An understanding of the mechanisms of green peach aphids’ response to insecticides under drought stress is a critical area of research that needs urgent attention. In view of this, we conducted this study to determine the impact of drought and insecticides on the activity of detoxification enzymes in green peach aphid. A 2 × 2 × 3 factorial experiment involving two levels of water treatments (drought and no drought), two levels of aphids infestation (aphids and no aphids), and three levels of pesticides applications (thiacloprid, flonicamid and no pesticide) was conducted. The treatments were arranged in a randomized complete block design with three replications. The results showed that there was a significant (p < 0.01) interaction effect of drought × insecticides on the green peach aphid performance under drought or no drought conditions. Generally, the highest aphids host acceptance, survival rate, colonization success, and average daily reproduction under drought and well-watered conditions occurred on flonicamid-treated plants, whereas thiacloprid-treated plants had the least. However, the thiacloprid-treated plants had higher photosynthetic rate, water use efficiency, lower stomatal conductance, and decreased transpiration rate. Moreover, flonicamid treatment increased the accumulation of glutathione–S-transferase, acetylcholinesterase, butyrylcholinesterase, 1-napthyle acetate, and 1-napthyle butyrate activities in aphids, compared to the thiacloprid treatments. The thiacloprid pesticide, which demonstrated higher efficacy against green peach aphid, can be used in areas where green peach aphids and drought stress are major concerns. Full article

The escalating global water crisis demands the development of cost-effective and environmentally sustainable treatment technologies. Among various advanced oxidation processes (AOPs), peracetic acid (PAA) has emerged as a promising oxidant, owing to its high redox potential, chemical stability, and potent disinfection capability. Nevertheless, the lack of highly efficient catalysts remains a major obstacle to achieving the effective degradation of contaminants of emerging concern in wastewater. Heterogeneous catalysis has proven to be a viable strategy for enhancing PAA activation, highlighting the urgent need for catalysts with superior activity, stability, and recyclability. Metal–organic frameworks (MOFs), with their large surface areas, tunable porosity, and structural diversity, provide versatile platforms for catalyst design. Recently, MOF-derived materials have attracted increasing attention for PAA activation, offering a new frontier in advanced oxidation technologies for efficient and sustainable wastewater remediation. This review systematically examines the role of MOFs in PAA activation, from pristine frameworks to MOF-based composites and MOF-derived catalysts. Mechanistic insights into PAA activation are highlighted, strategies for engineering MOF-based composites with synergistic catalytic properties are discussed, and the transformation of MOFs into robust derivatives with improved stability and reactivity is explored. Special attention is given to the identification and quantification of reactive species generated in PAA systems, providing a critical understanding of reaction pathways and catalytic performance. Finally, current challenges and future directions are outlined for designing highly efficient, recyclable, and environmentally compatible MOF-based catalysts, emphasizing their potential to significantly advance PAA-based AOPs. Full article

Digital twin technology is widely promoted as a transformative step for precision livestock farming, yet no fully realized, engineering-grade digital twins are deployed in commercial dairy or poultry systems today. This work establishes the current state of knowledge on dairy and poultry digital twins by synthesizing evidence through systematic database searches, thematic evidence mapping and critical analysis of validation gaps, carbon accounting and adoption barriers. Existing platforms are better described as near-digital-twin systems with partial sensing and modelling, digital-twin-inspired prototypes, simulation frameworks or decision-support tools that are often labelled as twins despite lacking continuous synchronization and closed-loop control. This distinction matters because the empirical foundation supporting many claims remains limited. Three critical gaps emerge: life-cycle carbon impacts of digital infrastructures are rarely quantified even as sustainability benefits are frequently asserted; field-validated improvements in feed efficiency, particularly in poultry feed conversion ratios, are scarce and inconsistent; and systematic reporting of failure rates, downtime and technology abandonment is almost absent, leaving uncertainties about long-term reliability. Adoption barriers persist across technical, economic and social dimensions, including rural connectivity limitations, sensor durability challenges, capital and operating costs, and farmer concerns regarding data rights, transparency and trust. Progress for cows and chickens will require rigorous validation in commercial environments, integration of mechanistic and statistical modelling, open and modular architectures and governance structures that support biological, economic and environmental accountability whilst ensuring that system intelligence is worth its material and energy cost. Full article