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Authors = Ning Li

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18 pages, 2161 KiB  
Article
Performance Degradation Behavior and Service Life Prediction of Hydraulic Asphalt Concrete Under Long-Term Water Immersion
by Xinhe Cai, Feng Li, Kangping Li, Zhiyuan Ning and Jing Dong
Materials 2025, 18(15), 3706; https://doi.org/10.3390/ma18153706 (registering DOI) - 7 Aug 2025
Abstract
Hydraulic asphalt concrete (HAC) is susceptible to performance deterioration under long-term water immersion. This study conducted compressive, tensile, and bending tests on HAC under various immersion times (0–96 h), established a multidimensional performance evaluation method, and developed a service-life prediction model for long-term [...] Read more.
Hydraulic asphalt concrete (HAC) is susceptible to performance deterioration under long-term water immersion. This study conducted compressive, tensile, and bending tests on HAC under various immersion times (0–96 h), established a multidimensional performance evaluation method, and developed a service-life prediction model for long-term water immersion. The average relative error between test values and predicted values was less than 5%, validating the model’s effectiveness and applicability. Results indicate that the rate of mechanical property degradation exhibits stage-dependent characteristics with immersion time, and the water damage resistance of alkaline aggregate is significantly superior to that of acidic aggregate. The predictive model shows that after 192 h of immersion, the retention rate of key mechanical properties for the alkaline aggregate reaches 92.71%, while that for acidic aggregate was only 73.85%. This study establishes a predictive model that provides a theoretical basis for assessing the lifespan of HAC under long-term immersion conditions. Full article
(This article belongs to the Special Issue Advances in Material Characterization and Pavement Modeling)
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18 pages, 8000 KiB  
Article
Phenology-Aware Machine Learning Framework for Chlorophyll Estimation in Cotton Using Hyperspectral Reflectance
by Chunbo Jiang, Yi Cheng, Yongfu Li, Lei Peng, Gangshang Dong, Ning Lai and Qinglong Geng
Remote Sens. 2025, 17(15), 2713; https://doi.org/10.3390/rs17152713 - 6 Aug 2025
Abstract
Accurate and non-destructive monitoring of leaf chlorophyll content (LCC) is essential for assessing crop photosynthetic activity and nitrogen status in precision agriculture. This study introduces a phenology-aware machine learning framework that combines hyperspectral reflectance data with various regression models to estimate leaf chlorophyll [...] Read more.
Accurate and non-destructive monitoring of leaf chlorophyll content (LCC) is essential for assessing crop photosynthetic activity and nitrogen status in precision agriculture. This study introduces a phenology-aware machine learning framework that combines hyperspectral reflectance data with various regression models to estimate leaf chlorophyll content (LCC) in cotton at six key reproductive stages. Field experiments utilized synchronized spectral and SPAD measurements, incorporating spectral transformations—such as vegetation indices (VIs), first-order derivatives, and trilateration edge parameters (TEPs, a new set of geometric metrics for red-edge characterization)—for evaluation. Five regression approaches were evaluated, including univariate and multivariate linear models, along with three machine learning algorithms: Random Forest, K-Nearest Neighbor, and Support Vector Regression. Random Forest consistently outperformed the other models, achieving the highest R2 (0.85) and the lowest RMSE (4.1) during the bud stage. Notably, the optimal prediction accuracy was achieved with fewer than five spectral features. The proposed framework demonstrates the potential for scalable, stage-specific monitoring of chlorophyll dynamics and offers valuable insights for large-scale crop management applications. Full article
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16 pages, 4442 KiB  
Article
Faulted-Pole Discrimination in Shipboard DC Microgrids Using S-Transformation and Convolutional Neural Networks
by Yayu Yang, Zhenxing Wang, Ning Gao, Kangan Wang, Binjie Jin, Hao Chen and Bo Li
J. Mar. Sci. Eng. 2025, 13(8), 1510; https://doi.org/10.3390/jmse13081510 - 5 Aug 2025
Abstract
The complex topology of shipboard DC microgrids and the strong coupling between positive and negative poles during faults pose significant challenges for faulted-pole identification, especially under high-resistance conditions. To address these issues, this paper proposes a novel faulted-pole identification method based on S-Transformation [...] Read more.
The complex topology of shipboard DC microgrids and the strong coupling between positive and negative poles during faults pose significant challenges for faulted-pole identification, especially under high-resistance conditions. To address these issues, this paper proposes a novel faulted-pole identification method based on S-Transformation and convolutional neural networks (CNNs). Single-ended voltage and current measurements from the generator side are used to generate time–frequency spectrograms via S-Transformation, which are then processed by a CNN trained to classify the faulted pole. This approach avoids reliance on complex threshold settings. Simulation results on a representative shipboard DC microgrid demonstrate that the proposed method achieves high accuracy, fast response, and strong robustness, even under high-resistance fault scenarios. The method significantly enhances the selectivity and reliability of fault protection, offering a promising solution for advanced marine DC power systems. Compared to conventional fault-diagnosis techniques, the proposed model achieves notable improvements in classification accuracy and computational efficiency for line-fault detection. Full article
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17 pages, 2283 KiB  
Article
A Remote Strawberry Health Monitoring System Performed with Multiple Sensors Approach
by Xiao Du, Jun Steed Huang, Qian Shi, Tongge Li, Yanfei Wang, Haodong Liu, Zhaoyuan Zhang, Ni Yu and Ning Yang
Agriculture 2025, 15(15), 1690; https://doi.org/10.3390/agriculture15151690 - 5 Aug 2025
Abstract
Temperature is a key physiological indicator of plant health, influenced by factors including water status, disease and developmental stage. Monitoring changes in multiple factors is helpful for early diagnosis of plant growth. However, there are a variety of complex light interference phenomena in [...] Read more.
Temperature is a key physiological indicator of plant health, influenced by factors including water status, disease and developmental stage. Monitoring changes in multiple factors is helpful for early diagnosis of plant growth. However, there are a variety of complex light interference phenomena in the greenhouse, so traditional detection methods cannot meet effective online monitoring of strawberry health status without manual intervention. Therefore, this paper proposes a leaf soft-sensing method based on a thermal infrared imaging sensor and adaptive image screening Internet of Things system, with additional sensors to realize indirect and rapid monitoring of the health status of a large range of strawberries. Firstly, a fuzzy comprehensive evaluation model is established by analyzing the environmental interference terms from the other sensors. Secondly, through the relationship between plant physiological metabolism and canopy temperature, a growth model is established to predict the growth period of strawberries based on canopy temperature. Finally, by deploying environmental sensors and solar height sensors, the image acquisition node is activated when the environmental interference is less than the specified value and the acquisition is completed. The results showed that the accuracy of this multiple sensors system was 86.9%, which is 30% higher than the traditional model and 4.28% higher than the latest advanced model. It makes it possible to quickly and accurately assess the health status of plants by a single factor without in-person manual intervention, and provides an important indication of the early, undetectable state of strawberry disease, based on remote operation. Full article
(This article belongs to the Section Artificial Intelligence and Digital Agriculture)
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3 pages, 132 KiB  
Editorial
Sensor and Sensorless Technology with Renewable Energy and Flexible Load Participation in Active Distribution Network
by Ning Li, Jie Yan, Su Su, Jakub Jurasz and Rongsheng Chen
Sensors 2025, 25(15), 4815; https://doi.org/10.3390/s25154815 - 5 Aug 2025
Abstract
With the rapid growth of active distribution networks, the demand for intelligent and flexible operation has increased significantly [...] Full article
13 pages, 3474 KiB  
Article
Energy Dispersion Relationship and Hofstadter Butterfly of Triangle and Rectangular Moiré Patterns in Tight Binding States
by Ziheng Li, Jiangwei Liu, Xiaoxiao Zheng, Yu Sun, Nan Han, Liang Wang, Muyang Li, Lei Han, Safia Khan, S. Hassan M. Jafri, Klaus Leifer, Yafei Ning and Hu Li
Physics 2025, 7(3), 34; https://doi.org/10.3390/physics7030034 - 5 Aug 2025
Abstract
Herein, the energy dispersion relationship and the density of states of triangular and rectangular moiré patterns are investigated using a tight binding model. Their characteristics of Hofstadter butterflies under different magnetic fields are also examined. The results indicate that, by analyzing different moiré [...] Read more.
Herein, the energy dispersion relationship and the density of states of triangular and rectangular moiré patterns are investigated using a tight binding model. Their characteristics of Hofstadter butterflies under different magnetic fields are also examined. The results indicate that, by analyzing different moiré superlattices, Hofstadter butterflies arising from different moiré pattern structures are obtained, exhibiting considerable fractal characteristics and self-similarities. Moreover, it is also observed that under an alternating magnetic field, the redistribution of electronic states leads to a significant change in the density of states curve, and the Van Hove peak changes with the increase in magnetic field intensity. This study enriches the understanding of the electronic behavior of moiré systems, but it also provides multiple potential application directions for future technological development. Full article
(This article belongs to the Section Statistical Physics and Nonlinear Phenomena)
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12 pages, 617 KiB  
Review
Developments in the Study of Inert Gas Biological Effects and the Underlying Molecular Mechanisms
by Mei-Ning Tong, Xia Li, Jie Cheng and Zheng-Lin Jiang
Int. J. Mol. Sci. 2025, 26(15), 7551; https://doi.org/10.3390/ijms26157551 - 5 Aug 2025
Viewed by 37
Abstract
It has long been accepted that breathing gases that are physiologically inert include helium (He), neon (Ne), nitrogen (N2), argon (Ar), krypton (Kr), xenon (Xe), and hydrogen (H2). The term “inert gas” has been used to describe them due [...] Read more.
It has long been accepted that breathing gases that are physiologically inert include helium (He), neon (Ne), nitrogen (N2), argon (Ar), krypton (Kr), xenon (Xe), and hydrogen (H2). The term “inert gas” has been used to describe them due to their unusually high chemical stability. However, as investigations have advanced, many have shown that inert gas can have specific biological impacts when exposed to high pressure or atmospheric pressure. Additionally, different inert gases have different effects on intracellular signal transduction, ion channels, and cell membrane receptors, which are linked to their anesthetic and cell protection effects in normal or pathological processes. Through a selective analysis of the representative literature, this study offers a concise overview of the state of research on the biological impacts of inert gas and their molecular mechanisms. Full article
(This article belongs to the Section Molecular Biophysics)
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16 pages, 1921 KiB  
Article
A Bivalent mRNA Vaccine Efficiently Prevents Gammaherpesvirus Latent Infection
by Yannan Yin, Jinkai Zang, Huichun Shi, Zhuang Wang, Linlin Kuang, Shuxia Wang, Haikun Wang, Ning Li, Xiaozhen Liang and Zhong Huang
Vaccines 2025, 13(8), 830; https://doi.org/10.3390/vaccines13080830 - 4 Aug 2025
Viewed by 170
Abstract
Background: It is still challenging to develop effective vaccines against tumorigenic human gammaherpesviruses such as Epstein–Barr virus (EBV). A major obstacle is the lack of a small animal model that reproduces the natural infection course of human gammaherpesviruses to allow for proper [...] Read more.
Background: It is still challenging to develop effective vaccines against tumorigenic human gammaherpesviruses such as Epstein–Barr virus (EBV). A major obstacle is the lack of a small animal model that reproduces the natural infection course of human gammaherpesviruses to allow for proper assessment of vaccine efficacy. Murine gammaherpesvirus 68 (MHV68) is a natural pathogen of wild rodents and laboratory mice and therefore can be used as a surrogate for human gammaherpesviruses to evaluate vaccination strategies. Methods: In this study, two mRNA vaccine candidates were generated, one encoding a fusion protein of the MHV68 gH with the gL (gHgL-mRNA) and the other expressing the MHV68 gB protein (gB-mRNA). The immunogenicity and protective efficacy of the mRNA vaccine candidates were evaluated in a mouse model of MHV68 infection. Results: The gHgL-mRNA but not the gB-mRNA candidate vaccine was able to induce neutralizing antibodies in mice, whereas both vaccines could elicit antigen-specific T-cell responses. Following MHV68 intranasal inoculation, complete blocking of the establishment of viral latency was observed in some mice immunized with individual gHgL-mRNA or gB-mRNA vaccines. Notably, co-immunization with the two mRNA vaccines appeared to be more effective than individual vaccines, achieving sterile immunity in 50% of the vaccinated mice. Conclusions: This study demonstrates that immunization with mRNA platform-based subunit vaccines is indeed capable of preventing MHV68 latent infection, thus validating a safe and efficacious vaccination strategy that may be applicable to human gammaherpesviruses. Full article
(This article belongs to the Special Issue The Development of mRNA Vaccines)
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17 pages, 2085 KiB  
Article
Identification Method of Weak Nodes in Distributed Photovoltaic Distribution Networks for Electric Vehicle Charging Station Planning
by Xiaoxing Lu, Xiaolong Xiao, Jian Liu, Ning Guo, Lu Liang and Jiacheng Li
World Electr. Veh. J. 2025, 16(8), 433; https://doi.org/10.3390/wevj16080433 - 2 Aug 2025
Viewed by 252
Abstract
With the large-scale integration of high-penetration distributed photovoltaic (DPV) into distribution networks, its output volatility and reverse power flow characteristics are prone to causing voltage violations, necessitating the accurate identification of weak nodes to enhance operational reliability. This paper investigates the definition, quantification [...] Read more.
With the large-scale integration of high-penetration distributed photovoltaic (DPV) into distribution networks, its output volatility and reverse power flow characteristics are prone to causing voltage violations, necessitating the accurate identification of weak nodes to enhance operational reliability. This paper investigates the definition, quantification criteria, and multi-indicator comprehensive determination methods for weak nodes in distribution networks. A multi-criteria assessment method integrating voltage deviation rate, sensitivity analysis, and power margin has been proposed. This method quantifies the node disturbance resistance and comprehensively evaluates the vulnerability of voltage stability. Simulation validation based on the IEEE 33-node system demonstrates that the proposed method can effectively identify the distribution patterns of weak nodes under different penetration levels (20~80%) and varying numbers of DPV access points (single-point to multi-point distributed access scenarios). The study reveals the impact of increased penetration and dispersed access locations on the migration characteristics of weak nodes. The research findings provide a theoretical basis for the planning of distribution networks with high-penetration DPV, offering valuable insights for optimizing the siting of volatile loads such as electric vehicle (EV) charging stations while considering both grid safety and the demand for distributed energy accommodation. Full article
(This article belongs to the Special Issue Fast-Charging Station for Electric Vehicles: Challenges and Issues)
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16 pages, 10446 KiB  
Article
Transient Vortex Dynamics in Tip Clearance Flow of a Novel Dishwasher Pump
by Chao Ning, Yalin Li, Haichao Sun, Yue Wang and Fan Meng
Machines 2025, 13(8), 681; https://doi.org/10.3390/machines13080681 - 2 Aug 2025
Viewed by 189
Abstract
Blade tip leakage vortex (TLV) is a critical phenomenon in hydraulic machinery, which can significantly affect the internal flow characteristics and deteriorate the hydraulic performance. In this paper, the blade tip leakage flow and TLV characteristics in a novel dishwasher pump were investigated. [...] Read more.
Blade tip leakage vortex (TLV) is a critical phenomenon in hydraulic machinery, which can significantly affect the internal flow characteristics and deteriorate the hydraulic performance. In this paper, the blade tip leakage flow and TLV characteristics in a novel dishwasher pump were investigated. The correlation between the vorticity distribution in various directions and the leakage vortices was established within a rotating coordinate system. The results show that the TLV in a composite impeller can be categorized into initial and secondary leakage vortices. The initial leakage vortex originates from the evolution of two corner vortices that initially form at different locations within the blade tip clearance. This vortex induces pressure fluctuations at the impeller inlet; its shedding is identified as the primary contributor to localized energy loss within the flow passage. These findings provide insights into TLVs in complex pump geometries and provide solutions for future pump optimization strategies. Full article
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15 pages, 2440 KiB  
Article
An Ultra-Robust, Highly Compressible Silk/Silver Nanowire Sponge-Based Wearable Pressure Sensor for Health Monitoring
by Zijie Li, Ning Yu, Martin C. Hartel, Reihaneh Haghniaz, Sam Emaminejad and Yangzhi Zhu
Biosensors 2025, 15(8), 498; https://doi.org/10.3390/bios15080498 - 1 Aug 2025
Viewed by 134
Abstract
Wearable pressure sensors have emerged as vital tools in personalized monitoring, promising transformative advances in patient care and diagnostics. Nevertheless, conventional devices frequently suffer from limited sensitivity, inadequate flexibility, and concerns regarding biocompatibility. Herein, we introduce silk fibroin, a naturally occurring protein extracted [...] Read more.
Wearable pressure sensors have emerged as vital tools in personalized monitoring, promising transformative advances in patient care and diagnostics. Nevertheless, conventional devices frequently suffer from limited sensitivity, inadequate flexibility, and concerns regarding biocompatibility. Herein, we introduce silk fibroin, a naturally occurring protein extracted from silkworm cocoons, as a promising material platform for next-generation wearable sensors. Owing to its remarkable biocompatibility, mechanical robustness, and structural tunability, silk fibroin serves as an ideal substrate for constructing capacitive pressure sensors tailored to medical applications. We engineered silk-derived capacitive architecture and evaluated its performance in real-time human motion and physiological signal detection. The resulting sensor exhibits a high sensitivity of 18.68 kPa−1 over a broad operational range of 0 to 2.4 kPa, enabling accurate tracking of subtle pressures associated with pulse, respiration, and joint articulation. Under extreme loading conditions, our silk fibroin sensor demonstrated superior stability and accuracy compared to a commercial resistive counterpart (FlexiForce™ A401). These findings establish silk fibroin as a versatile, practical candidate for wearable pressure sensing and pave the way for advanced biocompatible devices in healthcare monitoring. Full article
(This article belongs to the Special Issue Wearable Biosensors and Health Monitoring)
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29 pages, 6122 KiB  
Article
Lacticaseibacillus paracasei L21 and Its Postbiotics Ameliorate Ulcerative Colitis Through Gut Microbiota Modulation, Intestinal Barrier Restoration, and HIF1α/AhR-IL-22 Axis Activation: Combined In Vitro and In Vivo Evidence
by Jingru Chen, Linfang Zhang, Yuehua Jiao, Xuan Lu, Ning Zhang, Xinyi Li, Suo Zheng, Bailiang Li, Fei Liu and Peng Zuo
Nutrients 2025, 17(15), 2537; https://doi.org/10.3390/nu17152537 - 1 Aug 2025
Viewed by 455
Abstract
Background: Ulcerative colitis (UC), characterized by chronic intestinal inflammation, epithelial barrier dysfunction, and immune imbalance demands novel ameliorative strategies beyond conventional approaches. Methods: In this study, the probiotic properties of Lactobacillus paracaseiL21 (L. paracaseiL21) and its ability to ameliorate [...] Read more.
Background: Ulcerative colitis (UC), characterized by chronic intestinal inflammation, epithelial barrier dysfunction, and immune imbalance demands novel ameliorative strategies beyond conventional approaches. Methods: In this study, the probiotic properties of Lactobacillus paracaseiL21 (L. paracaseiL21) and its ability to ameliorate colitis were evaluated using an in vitro lipopolysaccharide (LPS)-induced intestinal crypt epithelial cell (IEC-6) model and an in vivo dextran sulfate sodium (DSS)-induced UC mouse model. Results: In vitro, L. paracaseiL21 decreased levels of pro-inflammatory cytokines (TNF-α, IL-1β, IL-8) while increasing anti-inflammatory IL-10 levels (p < 0.05) in LPS-induced IEC-6 cells, significantly enhancing the expression of tight junction proteins (ZO-1, occludin, claudin-1), thereby restoring the intestinal barrier. In vivo, both viable L. paracaseiL21 and its heat-inactivated postbiotic (H-L21) mitigated weight loss, colon shortening, and disease activity indices, concurrently reducing serum LPS and proinflammatory mediators. Interventions inhibited NF-κB signaling while activating HIF1α/AhR pathways, increasing IL-22 and mucin MUC2 to restore goblet cell populations. Gut microbiota analysis showed that both interventions increased the abundance of beneficial gut bacteria (Lactobacillus, Dubococcus, and Akkermansia) and improved faecal propanoic acid and butyric acid levels. H-L21 uniquely exerted an anti-inflammatory effect, marked by the regulation of Dubosiella, while L. paracaseiL21 marked by the Akkermansia. Conclusions: These results highlight the potential of L. paracaseiL21 as a candidate for the development of both probiotic and postbiotic formulations. It is expected to provide a theoretical basis for the management of UC and to drive the development of the next generation of UC therapies. Full article
(This article belongs to the Special Issue Probiotics, Postbiotics, Gut Microbiota and Gastrointestinal Health)
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14 pages, 2350 KiB  
Article
Temporal Deformation Characteristics of Hydraulic Asphalt Concrete Slope Flow Under Different Test Temperatures
by Xuexu An, Jingjing Li and Zhiyuan Ning
Materials 2025, 18(15), 3625; https://doi.org/10.3390/ma18153625 - 1 Aug 2025
Viewed by 217
Abstract
To investigate temporal deformation mechanisms of hydraulic asphalt concrete slope flow under evolving temperatures, this study developed a novel temperature-controlled slope flow intelligent test apparatus. Using this apparatus, slope flow tests were conducted at four temperature levels: 20 °C, 35 °C, 50 °C, [...] Read more.
To investigate temporal deformation mechanisms of hydraulic asphalt concrete slope flow under evolving temperatures, this study developed a novel temperature-controlled slope flow intelligent test apparatus. Using this apparatus, slope flow tests were conducted at four temperature levels: 20 °C, 35 °C, 50 °C, and 70 °C. By applying nonlinear dynamics theory, the temporal evolution of slope flow deformation and its nonlinear mechanical characteristics under varying temperatures were thoroughly analyzed. Results indicate that the thermal stability of hydraulic asphalt concrete is synergistically governed by the phase-transition behavior between asphalt binder and aggregates. Temporal evolution of slope flow exhibits a distinct three-stage pattern as follows: rapid growth (0~12 h), where sharp temperature rise disrupts the primary skeleton of coarse aggregates; decelerated growth (12~24 h), where an embryonic secondary skeleton forms and progressively resists deformation; stabilization (>24 h), where reorganization of coarse aggregates is completed, establishing structural equilibrium. The thermal stability temperature influence factor (δ) shows a nonlinear concave growth trend with increasing test temperature. Dynamically, this process transitions sequentially through critical stability, nonlinear stability, period-doubling oscillatory stability, and unsteady states. Full article
(This article belongs to the Special Issue Advances in Material Characterization and Pavement Modeling)
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44 pages, 58273 KiB  
Article
Geological Hazard Susceptibility Assessment Based on the Combined Weighting Method: A Case Study of Xi’an City, China
by Peng Li, Wei Sun, Chang-Rao Li, Ning Nan and Sheng-Rui Su
Geosciences 2025, 15(8), 290; https://doi.org/10.3390/geosciences15080290 - 1 Aug 2025
Viewed by 245
Abstract
Xi’an, China, has a complex geological environment, with geological hazards seriously hindering urban development and safety. This study analyzed the conditions leading to disaster formation and screened 12 evaluation factors (e.g., slope and slope direction) using Spearman’s correlation. Furthermore, it also introduced an [...] Read more.
Xi’an, China, has a complex geological environment, with geological hazards seriously hindering urban development and safety. This study analyzed the conditions leading to disaster formation and screened 12 evaluation factors (e.g., slope and slope direction) using Spearman’s correlation. Furthermore, it also introduced an innovative combined weighting method, integrating subjective weights from the hierarchical analysis method and objective weights from the entropy method, as well as an information value model for susceptibility assessment. The main results are as follows: (1) There are 787 hazard points—landslides/collapses are concentrated in loess areas and Qinling foothills, while subsidence/fissures are concentrated in plains. (2) The combined weighting method effectively overcame the limitations of single methods. (3) Validation using hazard density and ROC curves showed that the combined weighting information value model achieved the highest accuracy (AUC = 0.872). (4) The model was applied to classify the disaster susceptibility of Xi’an into high (12.31%), medium (18.68%), low (7.88%), and non-susceptible (61.14%) zones. The results are consistent with the actual distribution of disasters, thus providing a scientific basis for disaster prevention. Full article
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26 pages, 8845 KiB  
Article
Occurrence State and Genesis of Large Particle Marcasite in a Thick Coal Seam of the Zhundong Coalfield in Xinjiang
by Xue Wu, Ning Lü, Shuo Feng, Wenfeng Wang, Jijun Tian, Xin Li and Hayerhan Xadethan
Minerals 2025, 15(8), 816; https://doi.org/10.3390/min15080816 - 31 Jul 2025
Viewed by 194
Abstract
The Junggar Basin contains a large amount of coal resources and is an important coal production base in China. The coal seam in Zhundong coalfield has a large single-layer thickness and high content of inertinite, but large particle Fe-sulphide minerals are associated with [...] Read more.
The Junggar Basin contains a large amount of coal resources and is an important coal production base in China. The coal seam in Zhundong coalfield has a large single-layer thickness and high content of inertinite, but large particle Fe-sulphide minerals are associated with coal seams in some mining areas. A series of economic and environmental problems caused by the combustion of large-grained Fe-sulphide minerals in coal have seriously affected the economic, clean and efficient utilization of coal. In this paper, the ultra-thick coal seam of the Xishanyao formation in the Yihua open-pit mine of the Zhundong coalfield is taken as the research object. Through the analysis of coal quality, X-ray fluorescence spectrometer test of major elements in coal, inductively coupled plasma mass spectrometry test of trace elements, SEM-Raman identification of Fe-sulphide minerals in coal and LA-MC-ICP-MS test of sulfur isotope of marcasite, the coal quality characteristics, main and trace element characteristics, macro and micro occurrence characteristics of Fe-sulphide minerals and sulfur isotope characteristics of marcasite in the ultra-thick coal seam of the Xishanyao formation are tested. On this basis, the occurrence state and genesis of large particle Fe-sulphide minerals in the ultra-thick coal seam of the Xishanyao formation are clarified. The main results and understandings are as follows: (1) the occurrence state of Fe-sulphide minerals in extremely thick coal seams is clarified. The Fe-sulphide minerals in the extremely thick coal seam are mainly marcasite, and concentrated in the YH-2, YH-3, YH-8, YH-9, YH-14, YH-15 and YH-16 horizons. Macroscopically, Fe-sulphide minerals mainly occur in three forms: thin film Fe-sulphide minerals, nodular Fe-sulphide minerals, and disseminated Fe-sulphide minerals. Microscopically, they mainly occur in four forms: flake, block, spearhead, and crack filling. (2) The difference in sulfur isotope of marcasite was discussed, and the formation period of marcasite was preliminarily divided. The overall variation range of the δ34S value of marcasite is wide, and the extreme values are quite different. The polyflake marcasite was formed in the early stage of diagenesis and the δ34S value was negative, while the fissure filling marcasite was formed in the late stage of diagenesis and the δ34S value was positive. (3) The coal quality characteristics of the thick coal seam were analyzed. The organic components in the thick coal seam are mainly inertinite, and the inorganic components are mainly clay minerals and marcasite. (4) The difference between the element content in the thick coal seam of the Zhundong coalfield and the average element content of Chinese coal was compared. The major element oxides in the thick coal seam are mainly CaO and MgO, followed by SiO2, Al2O3, Fe2O3 and Na2O. Li, Ga, Ba, U and Th are enriched in trace elements. (5) The coal-accumulating environment characteristics of the extremely thick coal seam are revealed. The whole thick coal seam is formed in an acidic oxidation environment, and the horizon with Fe-sulphide minerals is in an acidic reduction environment. The acidic reduction environment is conducive to the formation of marcasite and is not conducive to the formation of pyrite. (6) There are many matrix vitrinite, inertinite content, clay content, and terrigenous debris in the extremely thick coal seam. The good supply of peat swamp, suitable reduction environment and pH value, as well as groundwater leaching and infiltration, together cause the occurrence of large-grained Fe-sulphide minerals in the extremely thick coal seam of the Xishanyao formation in the Zhundong coalfield. Full article
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