Photoredox Catalysis 2021

A special issue of Photochem (ISSN 2673-7256).

Deadline for manuscript submissions: closed (31 December 2021) | Viewed by 9067

Special Issue Editor


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Guest Editor
Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Fukui, Fukui 910-8507, Japan
Interests: organic photochemistry (synthetic); photoredox catalysis; photoinduced electron transfer; photoinduced decarboxylation
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Special Issue Information

Dear Colleagues,

Photoredox catalysis is the most exciting topic in organic chemistry today, because photoredox catalysts can provide unique and environmentally friendly processes for organic synthesis. Therefore, this Special Issue aims to illustrate recent developments on photoinduced reactions with photoredox catalysts. Contributions will focus on a broad range of organic reactions by effective photoredox catalysts.

Prof. Dr. Yasuharu Yoshimi
Guest Editor

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Keywords

  • Photoredox reaction
  • Photoredox catalyst
  • Photoinduced electron transfer
  • Dual catalysis
  • Organic photochemical reaction

Published Papers (3 papers)

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Editorial

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2 pages, 171 KiB  
Editorial
Renaissance of “Photoredox Catalysis” for Organic Molecules
by Yasuharu Yoshimi
Photochem 2021, 1(3), 458-459; https://doi.org/10.3390/photochem1030028 - 4 Nov 2021
Cited by 1 | Viewed by 1771
Abstract
The concept of “Photoredox Catalysis” for organic molecules was reported by Sakurai and Pac in 1977 [...] Full article
(This article belongs to the Special Issue Photoredox Catalysis 2021)

Research

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10 pages, 1189 KiB  
Article
Transition-Metal-Free Access to 2-Subsituted Indolines from Indoles via Dearomative Nucleophilic Addition Using Two-Molecule Organic Photoredox Catalysts
by Yosuke Tanaka, Takumi Ikeda, Yasuhiro Nachi, Taisei Mizuno, Kousuke Maeda, Chisato Sakamoto, Mugen Yamawaki, Toshio Morita and Yasuharu Yoshimi
Photochem 2021, 1(3), 448-457; https://doi.org/10.3390/photochem1030027 - 1 Nov 2021
Cited by 2 | Viewed by 2498
Abstract
A Photoinduced dearomative nucleophilic addition to N-Boc indoles mediated by two-molecule organic photoredox catalysts such as phenanthrene and 1,4-dicyanobenzene with UV irradiation furnished 2-substituted indolines in moderate to quantitative yields. Hydroxide, alkoxide, and cyanide ions can be used as a nucleophile to [...] Read more.
A Photoinduced dearomative nucleophilic addition to N-Boc indoles mediated by two-molecule organic photoredox catalysts such as phenanthrene and 1,4-dicyanobenzene with UV irradiation furnished 2-substituted indolines in moderate to quantitative yields. Hydroxide, alkoxide, and cyanide ions can be used as a nucleophile to provide 2-hydroxy, 2-alkoxy, and 2-cyanoindolines, respectively. Both electron-rich and -deficient indoles, including tryptophan derivatives, can be employed in the photoreaction to provide various indolines. This method provides transition-metal-free access to 2-subsituted indolines from indoles using organic photoredox catalysts under mild conditions. Full article
(This article belongs to the Special Issue Photoredox Catalysis 2021)
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Review

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10 pages, 3418 KiB  
Review
Recent Advances of Dicyanopyrazine (DPZ) in Photoredox Catalysis
by Vishal Srivastava, Pravin K. Singh, Arjita Srivastava, Surabhi Sinha and Praveen P. Singh
Photochem 2021, 1(2), 237-246; https://doi.org/10.3390/photochem1020014 - 2 Sep 2021
Cited by 21 | Viewed by 4045
Abstract
Visible light organophotoredox catalysis has emerged as an invaluable tool for organic synthetic transformations since it works brilliantly in tandem with organic substrates and has been known to create unique chemical environment for organic transformations. Dicyanopyrazine (DPZ), a relatively lesser researched organophotoredox catalyst, [...] Read more.
Visible light organophotoredox catalysis has emerged as an invaluable tool for organic synthetic transformations since it works brilliantly in tandem with organic substrates and has been known to create unique chemical environment for organic transformations. Dicyanopyrazine (DPZ), a relatively lesser researched organophotoredox catalyst, has shown great potential through its catalytic activity in organic synthesis and necessitates attention of synthetic community. Full article
(This article belongs to the Special Issue Photoredox Catalysis 2021)
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