Recycling and Recovery of Rare Earth Metals

A special issue of Metals (ISSN 2075-4701). This special issue belongs to the section "Extractive Metallurgy".

Deadline for manuscript submissions: closed (30 September 2021) | Viewed by 4296

Special Issue Editor


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Guest Editor
UC Berkeley, Department of Materials Science and Engineering, Berkeley, United States
Interests: application of chemical thermodynamics; chemical and electrochemical kinetics; transport phenomena; colloid and interfacial science to develop a fundamental mechanistic understanding of minerals and materials processing operations and material–solution interactions, with the goal of developing a foundation for ensuring sustainability and economic competitiveness in the supply of resources and energy

Special Issue Information

Dear Colleagues,

Rare earth metals and their compounds have unique chemical, catalytic, electrical, magnetic, and optical properties. In addition to their traditional use in sectors such as metallurgy, petroleum refinement, textiles, and agriculture, rare earth metals are critical to burgeoning applications such as batteries, hybrid cars, wind turbines, flat-screen televisions, and defense technologies. The global mine production in 2019 was 210,000 tonnes of rare-earth-oxide equivalent, an 11% increase over 2018 [1]. Although the term “rare” earth is a misnomer, these relatively abundant elements seldom occur in concentrated mineral deposits from which rare earth metals can be extracted economically. Moreover, the mining, processing, and separation of these elements are capital- and energy-intensive, and may require the removal and disposal of chemically similar radioactive actinides. Hence, there is significant interest in improving the processes used to recover rare earth metals from minerals, such as bastnaesite, monazite, and xenotime, and ion-adsorption rare earth deposits, along with recovering rare earth metals from non-conventional sources such as wastes from coal production. There is also significant interest in recycling rare earth metals, either from their compounds or alloys. This presents logistical challenges in terms of collecting rare-earth-rich components, along with the technical issues associated with economically processing such sources.

This Special Issue of Metals will include reviews and research articles on any topic related to the recovery and recycling of rare earth metals, including economic and life cycle analyses.  Authors with questions about whether their work would lie within the scope of this Special Issue are invited to submit an abstract before preparing a full manuscript.

Prof. Dr. Fiona M. Doyle
Guest Editor

Reference

  1. USGS Mineral Commodity Summaries 2020 Available online: https://www.usgs.gov/centers/nmic/mineral-commodity-summaries (accessed on 2 July 2020)


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Keywords

  • leaching of rare earth minerals
  • novel primary rare earth resources
  • solvent extraction and separation of rare earths
  • novel separation methods for rare earths
  • thorium and uranium removal from rare earth resources
  • collection of rare-earth-bearing wastes
  • treatment processes for secondary rare earth sources
  • economics of rare earth recycling and recovery
  • life cycle analysis of rare earth processing and recycling.

Published Papers (1 paper)

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Research

24 pages, 7625 KiB  
Article
Application of Eh-pH Diagrams on Acid Leaching Systems for the Recovery of REEs from Bastnaesite, Monazite and Xenotime
by Peijia Lin, Xinbo Yang, Joshua M. Werner and Rick Q. Honaker
Metals 2021, 11(5), 734; https://doi.org/10.3390/met11050734 - 29 Apr 2021
Cited by 10 | Viewed by 3415
Abstract
Bastnaesite, monazite and xenotime are rare earth minerals (REMs) that are typical sources for rare earth elements (REEs). To advance the understanding of their leaching and precipitation behavior in different hydrometallurgical processes, Eh-pH diagrams were constructed and modified using the HSC 9.9 software. [...] Read more.
Bastnaesite, monazite and xenotime are rare earth minerals (REMs) that are typical sources for rare earth elements (REEs). To advance the understanding of their leaching and precipitation behavior in different hydrometallurgical processes, Eh-pH diagrams were constructed and modified using the HSC 9.9 software. The aqueous stability of rare earth elements in H2O and acid leaching systems, i.e., the REE-Ligands-H2O systems, were depicted and studied based on the Eh-pH diagrams. This study considers the most relevant lixiviants, their resulting equilibrium states and the importance in the hydrometallurgical recovery of rare earth elements (REMs). A literature review was performed summarizing relevant Eh-pH diagrams and associated thermodynamic data. Shifting stability regions for REEs were discovered with additions of acid ligands and a narrow stability region for soluble REE-(SO4/Cl/NO3) complexes under highly acidic conditions. As such, the recovery of REEs can be enhanced by adjusting pH and Eh values. In addition, the Eh-pH diagrams of the major contaminants (i.e., Fe, Ca and Al) in leaching systems were studied. The resulting Eh-pH diagrams provide possible insights into potential passivation on the particle surfaces due to the formation of an insoluble product layer. Full article
(This article belongs to the Special Issue Recycling and Recovery of Rare Earth Metals)
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