Hydrogen Embrittlement in Metallic Materials

A special issue of Metals (ISSN 2075-4701). This special issue belongs to the section "Metal Failure Analysis".

Deadline for manuscript submissions: closed (31 December 2021) | Viewed by 9273

Special Issue Editors

Department of Microstructure Physics and Alloy Design, Max Planck Institute for Iron Research GmbH, Düsseldorf, Germany
Interests: hydrogen embrittlement; advanced steels; fracture mechanics; microstructure physics; physical metallurgy

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Guest Editor
Department of Mechanical Engineering, University of New Brunswick, Fredericton, NB E3B 5A3, Canada
Interests: thermomechanical processing; development of novel alloys; mechanical properties and deformation behavior of materials; phase transformation in metal alloys; static and dynamic materials testing; high-strain rate deformation; static and dynamic recrystallization; materials characterization; texture and anisotropy of materials; thermodynamics of materials; additive manufacturing of metallic materials
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School of Materials Science and Engineering, Dalian University of Technology, Dalian, China
Interests: structural metallic materials (steels and non-ferrous alloys); microstructures of materials; grain refinement; hydrogen embrittlement; mechanical metallurgy

Special Issue Information

Dear Colleagues,

Hydrogen embrittlement (HE), which corresponds to the abrupt loss of a material’s load-bearing capacity in presence of H, is often responsible for catastrophic and unpredictable failure of large-scale engineering structures (e.g., bridges, pipelines, vessels and chemical infrastructures). This embrittlement phenomenon occurs in many metallic materials including steels, titanium alloys, nickel-, cobalt- and iron-based superalloys, aluminum alloys and etc. High-strength alloys are particularly prone to H embrittlement, due to (a) H is the smallest atom with an ubiquitous nature, thus its ingress into a material is normally difficult to avoid and (b) an amount of H even below 1 wt ppm can result in a serious embrittlement effect in these materials. Therefore, H embrittlement basically threatens any industries (e.g., automotive and aerospace) that aim to use high-strength alloys to make lightweight structural components, and with that, may set an abrupt halt to some of the pending infrastructures needed for a hydrogen economy. It is thus crucial to understand the mechanisms as well as to explore solutions for improving materials’ resistance to H.

This Research Topic aims to cover all experimental and modeling studies associated with H embrittlement, with particular focuses on three aspects. (a) Fundamental investigations towards the understanding of H embrittlement mechanisms. This includes H trapping, interaction between H and lattice defects (e.g., dislocations, interfaces and vacancies), and H-induced or assisted damage mechanisms. (b) Characterization of H diffusion and H embrittlement phenomenon in various types of metallic materials. The latter includes but is not limited to H-induced degradation of mechanical properties, H-induced microstructure change, H-induced damages and the resulting fractography. (c) Novel technical, alloying and microstructural concepts against H embrittlement. The state-of-the-art research, development, and current challenges in the field of H embrittlement will be highlighted in this Research Topic, which is helpful to guide future research efforts.

Dr. Binhan Sun
Prof. Clodualdo Aranas
Dr. Yu Bai
Guest Editors

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Keywords

  • hydrogen embrittlement
  • hydrogen diffusion and trapping
  • fracture mechanics
  • steels
  • microstructure
  • damage
  • characterization
  • mechanical property

Published Papers (3 papers)

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Research

11 pages, 2981 KiB  
Article
Hydrogen-Related Fracture Behavior under Constant Loading Tensile Test in As-Quenched Low-Carbon Martensitic Steel
by Akinobu Shibata, Yasunari Takeda, Yuuji Kimura and Nobuhiro Tsuji
Metals 2022, 12(3), 440; https://doi.org/10.3390/met12030440 - 03 Mar 2022
Cited by 6 | Viewed by 2637
Abstract
This study investigated the hydrogen-related fracture behavior in as-quenched low-carbon martensitic steel under a constant loading tensile test with various applied stresses. We found that the fracture time in the constant loading tensile test decreased as the applied stress and hydrogen content increased. [...] Read more.
This study investigated the hydrogen-related fracture behavior in as-quenched low-carbon martensitic steel under a constant loading tensile test with various applied stresses. We found that the fracture time in the constant loading tensile test decreased as the applied stress and hydrogen content increased. The fracture surface topography analysis revealed that when the applied stress was low, the intergranular fracture was initiated around the side surface of the specimen and gradually propagated into the inner part of the specimen. In contrast, several intergranular fractures were separately initiated inside the specimen when the applied stress was high. The mode of hydrogen-related fracture was controlled by the fracture stress and not by the global hydrogen content inside the specimen. Increasing the global hydrogen content caused a decrease in the duration required for the accumulation of critical local hydrogen concentration at the fracture initiation site (prior austenite grain boundary). Accordingly, we propose that the local state at the crack initiation site is constant under a given applied stress, even when the global hydrogen content is different. Full article
(This article belongs to the Special Issue Hydrogen Embrittlement in Metallic Materials)
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14 pages, 29607 KiB  
Article
Influence of Specimen Surface Roughness on Hydrogen Embrittlement Induced in Austenitic Steels during In-Situ Small Punch Testing in High-Pressure Hydrogen Environments
by Hyung-Seop Shin, Juho Yeo and Un-Bong Baek
Metals 2021, 11(10), 1579; https://doi.org/10.3390/met11101579 - 04 Oct 2021
Cited by 11 | Viewed by 2349
Abstract
An in-situ small punch (SP) test method has recently been developed as a simple screening technique for evaluating the properties of metallic materials used in high-pressure hydrogen environments. With this method, the test conditions including temperature and gas pressure can easily be adjusted [...] Read more.
An in-situ small punch (SP) test method has recently been developed as a simple screening technique for evaluating the properties of metallic materials used in high-pressure hydrogen environments. With this method, the test conditions including temperature and gas pressure can easily be adjusted to those used in practice. In this study, specimens of STS316L steel and 18 wt% Mn steel were prepared at two different surface roughness, fabricated using wire-cutting and mechanical polishing. Their effects on hydrogen embrittlement (HE) were evaluated using in-situ SP testing at both room temperature and a lower temperature where HE was shown to occur under 10 MPa hydrogen. Both steels were evaluated using two variables obtained from in-situ SP testing, the SP energy, and the relative reduction of thickness (RRT), to quantitatively determine the effect of specimen surface roughness on HE susceptibility. Their fracture characteristics due to HE under 10 MPa hydrogen showed little difference with surface finish. Surface roughness had a negligible influence on these quantitative factors describing HE, indicating that it is not a dominant factor to be considered in in-situ SP testing when it is used to screen for HE compatibility in steels used in high-pressure hydrogen environments. Full article
(This article belongs to the Special Issue Hydrogen Embrittlement in Metallic Materials)
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18 pages, 20593 KiB  
Article
Hydrogen-Assisted Cracking in GMA Welding of High-Strength Structural Steel—A New Look into This Issue at Narrow Groove
by Thomas Schaupp, Nina Schroeder, Dirk Schroepfer and Thomas Kannengiesser
Metals 2021, 11(6), 904; https://doi.org/10.3390/met11060904 - 01 Jun 2021
Cited by 5 | Viewed by 3289
Abstract
Modern arc processes, such as the modified spray arc (Mod. SA), have been developed for gas metal arc welding of high-strength structural steels with which even narrow weld seams can be welded. High-strength joints are subjected to increasingly stringent requirements in terms of [...] Read more.
Modern arc processes, such as the modified spray arc (Mod. SA), have been developed for gas metal arc welding of high-strength structural steels with which even narrow weld seams can be welded. High-strength joints are subjected to increasingly stringent requirements in terms of welding processing and the resulting component performance. In the present work, this challenge is to be met by clarifying the influences on hydrogen-assisted cracking (HAC) in a high-strength structural steel S960QL. Adapted samples analogous to the self-restraint TEKKEN test are used and analyzed with respect to crack formation, microstructure, diffusible hydrogen concentration and residual stresses. The variation of the seam opening angle of the test seams is between 30° and 60°. To prevent HAC, the effectiveness of a dehydrogenation heat treatment (DHT) from the welding heat is investigated. As a result, the weld metals produced at reduced weld opening angle show slightly higher hydrogen concentrations on average. In addition, increased micro- as well as macro-crack formation can be observed on these weld metal samples. On all samples without DHT, cracks in the root notch occur due to HAC, which can be prevented by DHT immediately after welding. Full article
(This article belongs to the Special Issue Hydrogen Embrittlement in Metallic Materials)
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