Coordination Cluster Compounds

Dear Colleagues,

Coordination clusters represent one of the most intriguing areas of inorganic chemistry because it encompasses polynuclear species of very diverse nature such as polyoxometalates, metal-organic polyhedra, and metal-chalcogenide/halide clusters. Their rich solution equilibria, together with a remarkable structural variety that allows systematic compositional variations, have resulted in molecular entities with a wide range of properties (e.g., acidity, outstanding redox behavior, magnetism, optics, catalytic and/or biological activity) arising from the combination of both inorganic metal cations and non-metallic ligands. In some specific cases, the possibility of generating vacant metallic sites in a controlled way allows their use as ligands towards additional electrophilic moieties or organic functions (e.g., transition-metal cations, rare earths, p-block organoderivatives, etc.), thus paving the way for providing the clusters with tailored additional properties

This Special Issue aims to emphasize the latest advances in the chemistry of such type of inorganic clusters by covering topics from fundamental aspects (synthesis, reactivity, spectroscopy, structure, solution studies) to functional materials that incorporate these molecular units (organic polymers, functional surfaces, inorganic matrixes, nanoparticles), as well as their potential applications in fields like catalysis, photo- and electrochemistry, electronics, optics, bio-medicine, energy storage, sorption and environmental remediation.

Dr. Beñat Artetxe
Dr. Santiago Reinoso
Guest Editors

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