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Advances in Titanium Matrix Composites

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Advanced Composites".

Deadline for manuscript submissions: closed (20 February 2025) | Viewed by 1843

Special Issue Editors

School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
Interests: metal matrix composites; material characterization; microstructures; mechanical properties; laser additive manufacturing; strengthening mechanisms
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Guest Editor
Hubei Key Laboratory of Advanced Technology for Automotive Components, Wuhan University of Technology, Wuhan 430070, China
Interests: titanium alloys; titanium matrix composites; additive manufacturing; surface treatment
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Guest Editor
School of Materials Science and Engineering, Northwestern Polytechnical University, Xi’an 710072, China
Interests: metal matrix composites; laser additive manufacturing; microstructure–property relationship; strengthening mechanisms

Special Issue Information

Dear Colleagues,

This Special Issue is devoted to the current state of the art in titanium matrix composites (TMCs). As one of the most important metal matrix composites (MMCs), TMCs exhibit high specific strength, elastic modulus, temperature durability, wear resistance, and formability. Recent innovative research has shown that tailoring a reinforcement network distribution that is completely different from the conventional homogeneous distribution can not only improve the strengthening effect but can also resolve the issue of poor tensile ductility in TMCs. Based on the network architecture, for example, a multi-scale architecture, two-scale and laminate network microstructures can further inspire superior strength, creep, and oxidation resistance at elevated temperatures. In addition to microstructural tailoring, advanced fabrication methods have also been developed to produce TMCs with high mechanical performance, for instance, laser additive manufacturing and spark plasma sintering. Furthermore, the hot deformation and post-heat treatment of TMCs have been investigated and have shown great potential in regulating the reinforcement distribution, optimizing the interface structure, and adjusting the grain morphology of Ti alloy matrices. As a result, the mechanical properties of TMCs have been effectively improved, and the trade-off between strength and ductility has been resolved. In this regard, the high performance of advanced TMCs can meet the urgent demands for lightweight application-worthy structural materials and potentially replace nickel-based superalloys at 600-800oC while reducing weight by 45%.

This Special Issue particularly welcomes work related to the fabrication, hot processing, microstructure design and evolution, mechanical behavior, simulation, heat treatment, advanced characterization, and atomic-scale interface study of TMCs. We hope that the high-quality research papers presented in this Special Issue will play a positive role in promoting the rapid development of TMCs.

It is our pleasure to invite you to submit your work to this Special Issue. Research papers, reviews, and communications are welcome.

Dr. Qi An
Prof. Dr. Lechun Xie
Dr. Lian Li
Guest Editors

Manuscript Submission Information

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Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • titanium matrix composites
  • fabrication method
  • multi-scale microstructure
  • interface
  • mechanical property
  • simulation
  • hot processing
  • post-heattreatment
  • strengthening mechanism

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Published Papers (3 papers)

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Research

15 pages, 14836 KiB  
Article
Influence of Nb Addition on the Microstructure and Mechanical Properties of Laser Powder Bed Fusion-Fabricated Ti6Al4V Alloy
by Bo Zhang, Min Wan, Na Gao, Hao Jiang, Tuokuan Chen, Peng Zhao, Zhenzhen Liu, Qingyuan Jiao, Baoguo Lv, Quanquan Han and Xiebin Wang
Materials 2025, 18(8), 1803; https://doi.org/10.3390/ma18081803 - 15 Apr 2025
Viewed by 282
Abstract
Additive manufacturing of Ti6Al4V alloys via laser powder bed fusion (L-PBF) has demonstrated superior tensile strength compared to conventional methods. However, challenges remain in enhancing ductility and tailoring mechanical properties for specific applications. In this work, we show a feasible method to regulate [...] Read more.
Additive manufacturing of Ti6Al4V alloys via laser powder bed fusion (L-PBF) has demonstrated superior tensile strength compared to conventional methods. However, challenges remain in enhancing ductility and tailoring mechanical properties for specific applications. In this work, we show a feasible method to regulate the mechanical properties of additively manufacturing Ti alloys. Ti6Al4V alloys with different Nb content (1, 3, and 10 wt.%) were fabricated through laser powder bed fusion (L-PBF) in situ alloying using the mixture of Ti6Al4V and Nb powders. The powder mixture shows good printability, and dense Ti6Al4V-xNb alloys are obtained. Although the distribution of Nb is highly heterogeneous, no solidification cracks or secondary intermetallics were detected in both the Nb-rich and Nb-lean regions. The microstructure is gradually refined with the increase in Nb addition, mainly due to the heterogeneous nucleation caused by the partially melted Nb particles. The L-PBF-fabricated T6Al4V-xNb alloys are mainly in α’ martensite phase, even with the addition of 10 wt.% Nb, due to the low content of Nb solute in the matrix. The presence of β phase is suggested around the Nb particles, since a small region with graded Nb content is formed around the Nb particles. The ultimate tensile strength increases from 1050 to 1181 MPa with the addition of 3 wt.% Nb, and the total elongation increases slightly from 8.8% to 10.5%. With the addition of 10 wt.% Nb, the total elongation increases largely to 15.6%, while maintaining a high strength of 1135 MPa. Moreover, the elastic modulus decreases from 105 to 80 GPa with the increase in Nb content to 10 wt.%. The results of this work suggest that L-PBF in situ alloying is a promising approach to optimize the mechanical performance of Ti6Al4V alloys. Full article
(This article belongs to the Special Issue Advances in Titanium Matrix Composites)
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12 pages, 9084 KiB  
Article
Preparation of Laminated Titanium Matrix Composites with High Strength and Plasticity via Regulating Heat Treatment Processes
by Xiong Zou, Yu Yang, Junliang Liu, Tingting Sun and Fuqin Zhang
Materials 2025, 18(7), 1429; https://doi.org/10.3390/ma18071429 - 24 Mar 2025
Viewed by 366
Abstract
In order to achieve a balance between the strength and ductility of titanium matrix composites (TMCs), a spray deposition method was employed to deposit carbon nanotubes (CNTs) onto the surface of Ti foil. Subsequently, spark plasma sintering (SPS) at 850 °C and an [...] Read more.
In order to achieve a balance between the strength and ductility of titanium matrix composites (TMCs), a spray deposition method was employed to deposit carbon nanotubes (CNTs) onto the surface of Ti foil. Subsequently, spark plasma sintering (SPS) at 850 °C and an additional 1 h heat treatment at 880 °C were utilized to fabricate two laminated composites of different composition, namely, CNTs/Ti (SPS) and in situ TiC/Ti (SPS+HT). The microstructure evolution, mechanical properties, and strengthening and fracture mechanisms of laminated composites were systematically studied. The results revealed that after sintering at 850 °C, the reaction between CNTs and the titanium matrix was limited. However, after a 1 h heat treatment at 880 °C, CNTs were completely transformed into TiC, while the titanium matrix remained α phase without undergoing phase transformation. Through rolling and annealing, TiC particles were refined to 500 nm and exhibited a flattened shape. The in situ TiC/Ti layered composite material exhibited a tensile strength (UTS) of 491.51 MPa, which was a 29.63% improvement compared to pure titanium (379.16 MPa), and significantly higher than the UTS of CNTs/Ti samples (419.65 MPa). The primary strengthening mechanism was load transfer strengthening. The elongation (EL) remained at 26.59%, slightly lower than pure titanium (29.15%) and CNTs/Ti samples (27.51%). This can be attributed to the increased connectivity of the matrix achieved through rolling, which enhanced the ability to passivate cracks and prolonged the crack propagation path. This study presents a method for preparing laminated titanium matrix composites with both strength and ductility by controlling the heat treatment process. Full article
(This article belongs to the Special Issue Advances in Titanium Matrix Composites)
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16 pages, 10453 KiB  
Article
Effect of Temperature and Stress on Creep Behavior of (TiB + TiC + Y2O3)/α-Ti Composite
by Xicheng Wang, Yunfei Zheng, Shiwei Han, Shulong Xiao, Jing Tian and Lijuan Xu
Materials 2025, 18(1), 110; https://doi.org/10.3390/ma18010110 - 30 Dec 2024
Viewed by 791
Abstract
In this study, a (TiB + TiC + Y2O3)/α-Ti composite was prepared by induction skull melting to investigate its creep behavior and microstructure evolution under different temperatures and stresses. The results show that the microstructure of the composite in [...] Read more.
In this study, a (TiB + TiC + Y2O3)/α-Ti composite was prepared by induction skull melting to investigate its creep behavior and microstructure evolution under different temperatures and stresses. The results show that the microstructure of the composite in the as-cast state is a basket-weave structure, and the main phase composition is α lamella, containing a small amount of β phase and equiaxed α phase. The creep life of the composite decreases significantly when the temperature is increased from 650 °C to 700 °C, and the steady-state creep rate is increased by 1 to 2 orders of magnitude. The creep stress exponent at 650 °C and 700 °C is 2.92 and 2.96, respectively, and the creep mechanism of the titanium matrix composite is dominated by dislocation movement. TiB and TiC exhibit synergistic strengthening effects, and Y2O3 remains stable during creep. The reinforcements strengthen the composite by impeding the dislocation movement. The accelerated dissolution of β phase is one of the major reasons for the decrease of creep properties of composite with increasing temperature and stress. Silicide precipitation was observed near the reinforcements and dissolved β-Ti, mainly in elliptical or short rod shapes, which pins dislocations and improves the creep performance of the composite. The results of this study can provide theoretical guidance and practical reference for the subsequent development and application of hybrid reinforced titanium matrix composites. Full article
(This article belongs to the Special Issue Advances in Titanium Matrix Composites)
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