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Research on Zeolites and Zeolite-Like Materials: Synthesis, Structure, Properties and Application

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Porous Materials".

Deadline for manuscript submissions: 20 October 2025 | Viewed by 1304

Special Issue Editors

Dr. Beata Anwajler

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Guest Editor
Department of Energy Conversion Engineering, Faculty of Mechanical and Power Engineering, Wroclaw University of Science and Technology, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw, Poland
Interests: porous materials; material characterization; composites
Special Issues, Collections and Topics in MDPI journals
Dr. Daniel Smykowski

E-Mail Website
Guest Editor
Department of Energy Conversion Engineering, Faculty of Mechanical and Power Engineering, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27 St., 50-370 Wrocław, Poland
Interests: sorption and thermochemical heat storage; numerical modelling; sustainable energy
Dr. Piotr Szulc

E-Mail Website
Guest Editor
Department of Energy Conversion Engineering, Faculty of Mechanical and Power Engineering, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27 St., 50-370 Wrocław, Poland
Interests: energy storage; thermal engineering; renewable energy technologies; heat exchangers
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

This new Special Issue, entitled “Research on Zeolites and Zeolite-Like Materials: Synthesis, Structure, Properties and Application”, is dedicated to zeolites and their use in the production of new materials, structures, and for use in appliances. Zeolites have played a major role in many fields in recent decades and have become a focus of interest for scientists and material engineers. A research intensification into zeolites has been recorded over the last fifty years; about 200 different structures have been synthesised or discovered and have found practical applications to a greater or lesser extent. In this Special Issue, we aim to review the latest developments in the science and engineering of zeolites, which are attracting increasing attention due to their potential technological applications. The main objective is to link performance and functionality to the fundamental properties, chemistry, and physics of these materials, as well as to the process characteristics, in order to provide a multidisciplinary perspective and deeper understanding of this topic.

This Special Issue aims to provide an interdisciplinary forum to discuss the latest research developments in the field of materials and structures and to provide a vision for future research.

We look forward to receiving your contributions.

Dr. Beata Anwajler
Dr. Daniel Smykowski
Dr. Piotr Szulc
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • zeolites
  • zeolite-like materials
  • synthesis
  • structure
  • properties
  • application

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Published Papers (2 papers)

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Research

17 pages, 2516 KiB  
Article
Seed-Assisted Crystallization in the Hydrothermal Synthesis of FAU Zeolite from Acid-Treated Residue Glass Powder
by Paulla B. F. Sousa, Lindiane Bieseki and Sibele B. C. Pergher
Materials 2025, 18(7), 1393; https://doi.org/10.3390/ma18071393 - 21 Mar 2025
Viewed by 315
Abstract
A simple and low-cost synthesis assisted by seed crystals has been proposed to convert residual colorless glass powder into a Na-X zeolite. For this purpose, the optimal parameters for acid leaching of glass powder were studied to remove impurities that could interfere with [...] Read more.
A simple and low-cost synthesis assisted by seed crystals has been proposed to convert residual colorless glass powder into a Na-X zeolite. For this purpose, the optimal parameters for acid leaching of glass powder were studied to remove impurities that could interfere with the crystallization process. Then, the hydrothermal syntheses were supported by Na-X seed crystals (0% to 5%, wt.) to induce the growth of zeolite X, evaluating the crystallization time (12 h to 48 h) and the variation of the silicon source (acid-treated and untreated residues). The formation of the faujasite as the main phase, with a higher degree of structural order and microporosity, was observed with the previous treatment in the residue, a higher seed loading, and a shorter crystallization time. On the other hand, a phase competition between faujasite, gismondine, Linde type-A, and sodalite structures was observed in the zeolites synthesized from the untreated residue. In this case, the high seed loading and the longer synthesis time allowed the correct targeting of the faujasite structure with low structural order and micro/mesoporous properties. Furthermore, interzeolite transformations occur in all syntheses, where the framework type synthesized was influenced by the presence of a specific ion as a mineralizing agent. Full article
(This article belongs to the Special Issue Research on Zeolites and Zeolite-Like Materials: Synthesis, Structure, Properties and Application)
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11 pages, 2994 KiB  
Article
How the Pretreatment Temperature of Zeolitic Catalysts Can Affect the Reaction Temperature of Methanol to Olefins and Gasoline Processes
by Simón Yunes, Abel Gaspar Rosas and Antonio Gil
Materials 2025, 18(6), 1370; https://doi.org/10.3390/ma18061370 - 20 Mar 2025
Viewed by 353
Abstract
The dehydration of methanol to produce light olefins and gasoline, known as MTO (methanol-to-olefins) process requires acidic catalysts that maintain their acidity at reaction temperatures. Zeolites, such as SAPOs and ZSM-5, are commonly used for this purpose due to their acidic centers. The [...] Read more.
The dehydration of methanol to produce light olefins and gasoline, known as MTO (methanol-to-olefins) process requires acidic catalysts that maintain their acidity at reaction temperatures. Zeolites, such as SAPOs and ZSM-5, are commonly used for this purpose due to their acidic centers. The initial step in these experiments involves the activation or pretreatment of these solids to remove physically adsorbed water from their pores. Inadequate pretreatment can lead to the destruction of the existing Brönsted sites through the dihydroxylation of surface -OH groups. Therefore, it is crucial to pretreat the zeolites properly to preserve the Brönsted sites. One method is to subject the fresh catalyst to programmed dehydration, which involves desorption at a controlled temperature while monitoring the appearance of water that results from Brönsted site dihydroxylation. The temperature at which the dehydration peak appears determines the optimal reaction temperature. The results presented in this work will demonstrate the progressive deactivation of the catalysts when the reaction temperature exceeds 400 °C. Full article
(This article belongs to the Special Issue Research on Zeolites and Zeolite-Like Materials: Synthesis, Structure, Properties and Application)
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