Catalytic Pyrolysis of Biomass and Waste

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Biomass Catalysis".

Deadline for manuscript submissions: closed (31 December 2020) | Viewed by 4974

Special Issue Editors


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Guest Editor
Department of Chemical Engineering, University of the Basque Country UPV/EHU, Campus Bizkaia, Bilbao, Spain
Interests: pyrolysis; spouted bed; catalysts; waste plastics; biomass; pyrolysis reforming
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Special Issue Information

Dear Colleagues,

The need to reduce the current dependence on fossil fuels has promoted the development of alternative sources for the production of fuels and chemicals. In this scenario, the valorization of biomass and waste is gaining increasing attention. Amongst the existing valorization routes, chemical approaches have the best perspectives for large-scale implementation. Pyrolysis is an efficient and eco-friendly process that makes it possible to produce fuels and chemicals from biomass and waste. The incorporation of suitable catalysts for pyrolysis is an interesting alternative to improve the selectivity and quality of key products. A wide range of catalysts have been proposed in the literature for biomass and waste valorization. Thus, the use of cracking catalysts—mainly of acid nature—represents a suitable option for the production of fuels and valuable chemicals such as BTX or light olefins. More recently, hydrogen production by combining pyrolysis and in-line catalytic steam reforming over metallic catalysts has demonstrated great potential. Moreover, from a technical point of view, different strategies have also been proposed as the use of the catalyst in a single step (in situ catalytic pyrolysis) or in two-step processes (thermal pyrolysis and the in-line catalytic transformation of pyrolysis volatiles). Therefore, this Special Issue aims to gather the most novel and relevant catalytic pyrolysis studies of different types of biomass and solid waste.

Dr. Gartzen Lopez
Dr. Maite Artetxe
Guest Editors

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Keywords

  • cracking
  • steam reforming
  • biomass
  • waste plastics
  • waste tires
  • fuels
  • hydrogen
  • bio-oil
  • pyrolysis-reforming
  • deactivation

Published Papers (1 paper)

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Research

16 pages, 1026 KiB  
Article
Catalytic Pyrolysis of a Residual Plastic Waste Using Zeolites Produced by Coal Fly Ash
by Marco Cocchi, Doina De Angelis, Leone Mazzeo, Piergianni Nardozi, Vincenzo Piemonte, Riccardo Tuffi and Stefano Vecchio Ciprioti
Catalysts 2020, 10(10), 1113; https://doi.org/10.3390/catal10101113 - 25 Sep 2020
Cited by 27 | Viewed by 4420
Abstract
The plastic film residue (PFR) of a plastic waste recycling process was selected as pyrolysis feed. Both thermal and catalytic pyrolysis experiments were performed and coal fly ash (CFA) and X zeolites synthesized from CFA (X/CFA) were used as pyrolysis catalysts. The main [...] Read more.
The plastic film residue (PFR) of a plastic waste recycling process was selected as pyrolysis feed. Both thermal and catalytic pyrolysis experiments were performed and coal fly ash (CFA) and X zeolites synthesized from CFA (X/CFA) were used as pyrolysis catalysts. The main goal is to study the effect of low-cost catalysts on yields and quality of pyrolysis oils. NaX/CFA, obtained using the fusion/hydrothermal method, underwent ion exchange followed by calcination in order to produce HX/CFA. Firstly, thermogravimetry and differential scanning calorimetry (TG and DSC, respectively) analyses evaluated the effect of catalysts on the PFR degradation temperature and the process energy demand. Subsequently, pyrolysis was carried out in a bench scale reactor adopting the liquid-phase contact mode. HX/CFA and NaX/CFA reduced the degradation temperature of PFR from 753 to 680 and 744 K, respectively, while the degradation energy from 2.27 to 1.47 and 2.07 MJkg−1, respectively. Pyrolysis runs showed that the highest oil yield (44 wt %) was obtained by HX/CFA, while the main products obtained by thermal pyrolysis were wax and tar. Furthermore, up to 70% of HX/CFA oil was composed by gasoline range hydrocarbons. Finally, the produced gases showed a combustion energy up to 8 times higher than the pyrolysis energy needs. Full article
(This article belongs to the Special Issue Catalytic Pyrolysis of Biomass and Waste)
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