Metal–Organic Framework Catalysts: Celebrating a Nobel Prize and Forging Future Developments and Applications

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalytic Materials".

Deadline for manuscript submissions: 31 December 2026 | Viewed by 1077

Special Issue Editors


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Guest Editor
Laboratory of Organometallics, Catalysis and Ordered Materials, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, China
Interests: organometallics; MOFs; POPs; catalysis; electrocatalysis; photocatalysis; carbon dioxide utilization; ROP; olefin metathesis; water splitting
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Guest Editor
Research Centre for Synthesis and Catalysis, Department of Chemical Sciences, University of Johannesburg, Johannesburg, South Africa
Interests: green chemistry; biorefinery; CO2 utilization; MOFs; organometallic chemistry; surface organometallics; porous materials

Special Issue Information

Dear Colleagues,

The awarding of the 2025 Nobel Prize in Chemistry to Professor Omar M. Yaghi for his pioneering work on metal–organic frameworks has highlighted the transformative impact of this class of materials in a spectacular manner. MOFs, with their extraordinary porosity, structural diversity, and tunable functionality, have cemented their role as a cornerstone of modern materials science and catalysis. This Special Issue seeks to celebrate this landmark achievement and showcase the dynamic future of MOFs as advanced catalysts.

Building on the foundational principles recognized by the Nobel Committee, this Special Issue will focus on the application and development of MOFs in heterogeneous catalysis. Their design allows for unparalleled control over active sites, leading to superior activity, selectivity, and stability in reactions ranging from organic transformations and polymerization to energy-conversion processes like photocatalysis and electrocatalysis. The recyclability and reduced environmental footprint of MOF catalysts further align with the pressing goals of sustainable chemistry.

We invite contributions that explore the following topics:

  • Novel design, synthesis, and post-synthetic modification of MOF catalysts;
  • Advanced characterization and mechanistic studies of catalysis in MOFs;
  • Applications in thermo-, photo-, and electrocatalysis for energy and sustainability;
  • MOF-derived materials (e.g., carbon composites, single-atom catalysts) for catalytic applications;
  • Asymmetric catalysis and enzyme–MOF hybrid systems;
  • Scale-up, stability, and industrial perspectives;
  • Further areas for development (perspectives).

Prof. Dr. Francis Verpoort
Dr. Banothile C. E. Makhubela
Guest Editors

Manuscript Submission Information

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Keywords

  • metal–organic frameworks (MOFs)
  • heterogeneous catalysis
  • sustainable chemistry
  • advanced characterization
  • energy conversion (covering photo-, electro-, and thermocatalysis)
  • industrial applications

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Published Papers (1 paper)

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Review

41 pages, 4060 KB  
Review
Reimagining Textile Effluent Treatment Using Metal–Organic Framework-Based Hybrid Catalysts: A Critical Review
by Hossam A. Nabwey and Maha A. Tony
Catalysts 2026, 16(4), 355; https://doi.org/10.3390/catal16040355 - 15 Apr 2026
Viewed by 769
Abstract
Textile wastewater remains one of the most challenging industrial effluents to remediate due to its intense and persistent coloration, high organic load, elevated salinity, and fluctuating pH and the presence of recalcitrant dye structures and auxiliary chemicals. Conventional physicochemical and biological treatments frequently [...] Read more.
Textile wastewater remains one of the most challenging industrial effluents to remediate due to its intense and persistent coloration, high organic load, elevated salinity, and fluctuating pH and the presence of recalcitrant dye structures and auxiliary chemicals. Conventional physicochemical and biological treatments frequently achieve incomplete removal, generate secondary wastes, or fail under high-salt and toxic dye matrices. Advanced oxidation processes (AOPs) provide molecular-level degradation via reactive oxygen species (ROS), yet their deployment is often constrained by narrow operating windows, catalyst instability, chemical/energy demand, and scale-up limitations. In this context, metal–organic frameworks (MOFs) have emerged as tunable porous catalytic platforms that integrate adsorption and oxidation within a single architecture through controllable metal nodes, functional linkers, and engineered pore environments. This critical review reimagines textile effluent treatment through the lens of MOF-based hybrid catalysts, synthesizing progress across Fenton/photo-Fenton catalysis, photocatalytic MOFs, persulfate activation, and MOF-derived/composite systems. Mechanistic pathways are discussed by linking pollutant enrichment, cyclic redox reactions, charge-transfer processes, and ROS-driven degradation toward mineralization, with emphasis on the distinction between rapid decolorization and true organic removal. A critical comparison highlights how hybridization improves charge transport, stability, and catalyst recovery, while persistent gaps remain in hydrolytic robustness, metal leaching control, intermediate toxicity assessment, real-wastewater validation, continuous-flow reactor integration, and techno-economic feasibility. Finally, the review outlines actionable research directions, including water-stable and defect-engineered MOFs, immobilized and structured catalysts, solar-driven operation, standardized performance metrics, and life-cycle-informed design, to accelerate translation toward scalable and sustainable textile wastewater remediation. By bridging material chemistry with reactor-level feasibility and sustainability assessment, this review provides an implementation-oriented perspective for next-generation textile wastewater treatment. Full article
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