Development, Application, and Characterization of New Electrode Materials for Advanced Batteries

A special issue of Batteries (ISSN 2313-0105). This special issue belongs to the section "Battery Mechanisms and Fundamental Electrochemistry Aspects".

Deadline for manuscript submissions: 10 June 2024 | Viewed by 920

Special Issue Editors


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Guest Editor
Department of Industrial Chemistry, University of Bologna, Bologna, Italy
Interests: cathode and anode materials for advanced batteries; advanced electrodes for energy application; characterization of electrode materials; post-mortem analysis; core level spectroscopies; X-ray methods; metal hexacyanoferrates; post lithium batteries; aqueous batteries; synchrotron studies; data analysis
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Guest Editor
Elettra-Sincrotrone Trieste, Strada Statale 14 km, km 163.5 in AREA Science Park, 34149 Trieste, Italy
Interests: structural characterization of advanced materials for energy storage; structural characterization of matter under extreme pressure and temperature conditions
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

The purpose of this Special Issue is to provide an overview of new electrode materials for advanced batteries, by taking into account both developments and applications. Synthesis strategies and applications for different chemistries including sodium ion and multivalent technologies are welcome.

This Special Issue also provides responses to scientific questions by adopting the most suitable technique for battery characterization using the peculiar characteristics of X-rays. Both conventional laboratory-based methods and large-scale facilities such as synchrotrons will be covered. The selectivity characteristic of the X-ray range—in both soft and hard domains—permits us to check, for instance, the electronic structure of selected atomic species; the local and the average structure of the electrode materials can be explored by using absorption techniques. Scattering of the X-rays is widely used to give details on the crystal structure modification upon cycling in operando modality, for instance, in layered NMC and LMFP cathodes. X-ray microscopy is also used to explore the surface conditions and inhomogeneities of the metal oxidation state in aged electrodes.

Researchers working in these fields are strongly encouraged to submit a contribution.

  • LIBs, SIBs, multivalent chemistries;
  • Synthesis and characterization;
  • Electrode/electrolyte interface;
  • Electrode intercalation mechanism and secondary reactions;
  • X-ray diffraction, SAXS, WAXS;
  • EXAFS, XANES, X-Ray Microscopy;
  • Operando and ex situ experiments;
  • Photoelectron Spectroscopy.

Dr. Marco Giorgetti
Dr. Giuliana Aquilanti
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Batteries is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • electrode mechanism
  • electronic and structural modifications
  • interface and interphase analysis
  • SEI
  • CEI
  • degradation mechanism
  • oxidation state
  • Jahn–Teller effects

Published Papers (1 paper)

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Research

15 pages, 4934 KiB  
Article
Aging Mechanism of Mn-Based Prussian Blue Cathode Material by Synchrotron 2D X-ray Fluorescence
by Mariam Maisuradze, Min Li, Ilaria Carlomagno, Mattia Gaboardi, Giuliana Aquilanti, Jasper Rikkert Plaisier and Marco Giorgetti
Batteries 2024, 10(4), 123; https://doi.org/10.3390/batteries10040123 - 05 Apr 2024
Viewed by 545
Abstract
The aging mechanism of 10% and 30% nickel-substituted manganese hexacyanoferrate cathode material in aqueous zinc-ion batteries has been explored through the advanced synchrotron-based two-dimensional X-ray fluorescence technique. Thanks to the two-dimension modality, not only were the metal concentration dynamics throughout the entire electrodes [...] Read more.
The aging mechanism of 10% and 30% nickel-substituted manganese hexacyanoferrate cathode material in aqueous zinc-ion batteries has been explored through the advanced synchrotron-based two-dimensional X-ray fluorescence technique. Thanks to the two-dimension modality, not only were the metal concentration dynamics throughout the entire electrodes followed during the aging process, but their spatial distribution was also revealed, suggesting the route of the material transformation. The dissolution of Mn and Ni, as well as the penetration of Zn inside the framework were detected, while the Mn aggregations were found outside the hexacyanoferrate framework. Additionally, the possibility of conducting X-ray absorption spectroscopy measurements on the regions of interest made it possible to explore the chemical state of each metal, and furthermore, synchrotron-based powder X-ray diffraction demonstrated the gradual structural modification in 30% Ni-containing sample series in terms of the different phase formation. Full article
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