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Air

Air is an international, peer-reviewed, open access journal on all aspects of air research, including air science, air technology, air management and governance, published quarterly online by MDPI.

All Articles (81)

Limonene: A Resource or a Danger

  • Ivan Notardonato,
  • Mario Lovrić and
  • Pasquale Avino

Limonene is one of the most abundant, natural, bio-based monoterpenes. In recent years, it has attracted growing attention in both industrial and scientific communities due to its versatile physicochemical properties and wide spectrum of biological activities, including antimicrobial, antioxidant, and anti-inflammatory effects. Its renewable origin and biodegradability make limonene an ideal candidate for sustainable development and as a key building block in green chemistry. The industrial relevance of limonene spans multiple sectors, ranging from its use as a solvent and flavoring agent to its application in pharmaceuticals, cosmetics, polymers, and renewable fuels. Nevertheless, despite its numerous advantages, certain limitations and safety concerns have emerged. Prolonged or high-level exposure may result in sensitization, irritant reactions, or secondary oxidation products that pose potential health risks. Moreover, its oxidative instability can lead to the formation of reactive compounds under specific environmental conditions that influence indoor air quality and may contribute to secondary organic aerosol formation. Current research focuses on several key challenges: improving extraction and purification yields through biotechnological and enzymatic pathways; enhancing oxidative stability via encapsulation or chemical modification; and standardizing toxicological assessment protocols for both occupational and clinical settings. In this review, we analyze and discuss studies published predominantly in the last five years that explore the dual nature of limonene, its valuable industrial applications and its potential environmental and health-related challenges.

4 February 2026

(a) (R)-(+)-limonene, D-limonene; (b) (S)-(−)-limonene, L-Limonene.

Spatiotemporal Graph Neural Networks for PM2.5 Concentration Forecasting

  • Vongani Chabalala,
  • Craig Rudolph and
  • Bruce Mellado
  • + 10 authors

Air pollution, particularly fine particulate matter (PM2.5), poses significant public health and environmental risks. This study explores the effectiveness of spatiotemporal graph neural networks (ST-GNNs) in forecasting PM2.5 concentrations by integrating remote-sensing hyperspectral indices with traditional meteorological and pollutant data. The model was evaluated using data from Switzerland and the Gauteng province in South Africa, with datasets spanning from January 2016 to December 2021. Key performance metrics, including root mean squared error (RMSE), mean absolute error (MAE), probability of detection (POD), critical success index (CSI), and false alarm rate (FAR), were employed to assess model accuracy. For Switzerland, the integration of spectral indices improved RMSE from 1.4660 to 1.4591, MAE from 1.1147 to 1.1053, CSI from 0.8345 to 0.8387, POD from 0.8961 to 0.8972, and reduced FAR from 0.0760 to 0.0719. In Gauteng, RMSE decreased from 6.3486 to 6.2319, MAE from 4.4891 to 4.4066, CSI from 0.9555 to 0.9560, and POD from 0.9699 to 0.9732, while FAR slightly increased from 0.0154 to 0.0181. Error analysis revealed that while the initial one-day ahead forecast without spectral indices had a marginally lower error, the dataset with spectral indices outperformed from the two-day ahead mark onwards. The error for Swiss monitoring stations stabilized over longer prediction lengths, indicating the robustness of the spectral indices for extended forecasts. The study faced limitations, including the exclusion of the Planetary Boundary Layer (PBL) height and K-index, lack of terrain data for South Africa, and significant missing data in remote sensing indices. Despite these challenges, the results demonstrate that ST-GNNs, enhanced with hyperspectral data, provide a more accurate and reliable tool for PM2.5 forecasting. Future work will focus on expanding the dataset to include additional regions and further refining the model by incorporating additional environmental variables. This approach holds promise for improving air quality management and mitigating health risks associated with air pollution.

13 January 2026

Switzerland measurement stations’ locations and types.

Road dust resuspension is widely recognized as a major contributor to traffic-related particulate matter (PM) in urban environments. Nevertheless, reported emission factors exhibit substantial variability. These discrepancies stem not only from the intrinsic complexity of the resuspension process but also from limitations in measurement techniques, which often fail to adequately control or characterize the influencing parameters. As a result, the contribution of each parameter remains difficult to isolate, leading to inconsistencies across studies. This study presents an experimental protocol developed to quantify PM10 and PM2.5 emission factors associated with vehicle-induced road dust resuspension. Experiments were conducted on a dedicated test track seeded with alumina particles of controlled mass and size distribution to simulate road dust. A network of microsensors was strategically deployed at multiple upwind and downwind locations to continuously monitor particle concentration variations during vehicle passages. Emission factors were derived through time integration of the mass flow rate of resuspended dust measured by the sensor network. The estimated PM10 emission factor showed excellent agreement, within 2.5%, with predictions from a literature-based formulation, thereby validating the accuracy and external relevance of the proposed protocol. In contrast, comparisons with U.S. EPA formulas and other empirical equations revealed substantially larger discrepancies, particularly for PM2.5, highlighting the persistent limitations of current modeling approaches.

7 January 2026

Experimental setup on the TEQMO flat area.

Fine particulate matter (PM2.5) poses substantial urban health risks that vary across space, time, and population vulnerability. We integrate a spatio-temporal INLA–SPDE PM2.5 field with an agent-based model (ABM) of 10,000 daily home–work commuters in Indianapolis’s Pleasant Run airshed (50 weeks; 250 m grid). The PM2.5 surface fuses 23 corrected PurpleAir PA-II-SD sensors with meteorology, land use, road proximity, and MODIS AOD. Validation indicated strong agreement (leave-one-out R2 = 0.79, RMSE = 3.5 μg/m3; EPA monitor comparison R2 = 0.81, RMSE = 3.1 μg/m3). We model a spatial-equity counterfactual by assigning susceptibility independently of residence and workplace, isolating vulnerability from residential segregation. Under this design, annual PM2.5 exposure was statistically indistinguishable across groups (16.22–16.29 μg/m3; max difference 0.07 μg/m3, <0.5%), yet VWDI differed by ~10× (High vs. Very Low). Route-level maps reveal recurrent micro-corridors (>20 μg/m3) near industrial zones and arterials that increase within-group variability without creating between-group exposure gaps. These findings quantify a policy-relevant “floor effect” in environmental justice: even with perfect spatial equity, substantial health disparities remain driven by susceptibility. Effective mitigation, therefore, requires dual strategies—place-based emissions and mobility interventions to reduce exposure for all, paired with vulnerability-targeted health supports (screening, access to care, indoor air quality) to address irreducible risk. The data and code framework provides a reproducible baseline against which real-world segregation and mobility constraints can be assessed in future, stratified scenarios.

4 December 2025

Location and land cover of the Pleasant Run Airshed (PRAS). Points (black dot inside white circle) are locations where PA-II-SD sensors were placed.

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Air - ISSN 2813-4168