Solid Electrolyte Interphase Layer Formation on the Si-Based Electrodes with and without Binder Studied by XPS and ToF-SIMS Analysis
Abstract
:1. Introduction
2. Experimental Part
2.1. Si-Based Electrodes
2.2. Galvanostatic Tests
2.3. Morphology Characterizations
2.4. XPS and ToF-SIMS Characterizations
2.4.1. XPS and ToF-SIMS Experimental Conditions
2.4.2. Sample Preparation for XPS and ToF-SIMS
- -
- -
- -
- -
- point 4 (3.0 V) corresponding to the full delithiated state of the electrode.
3. Results and Discussion
3.1. Morphological Characterization of Electrodes by SEM
3.2. Galvanostatic Tests
3.3. Surface Characterizations
3.3.1. XPS Surface Characterizations of the Si-XG-AB Electrode
3.3.2. XPS Surface Characterizations of the Si@C-Network Electrode
3.4. ToF-SIMS Surface and Bulk Characterizations
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Wu, Z.-Y.; Deng, L.; Li, J.-T.; Zanna, S.; Seyeux, A.; Huang, L.; Sun, S.-G.; Marcus, P.; Światowska, J. Solid Electrolyte Interphase Layer Formation on the Si-Based Electrodes with and without Binder Studied by XPS and ToF-SIMS Analysis. Batteries 2022, 8, 271. https://doi.org/10.3390/batteries8120271
Wu Z-Y, Deng L, Li J-T, Zanna S, Seyeux A, Huang L, Sun S-G, Marcus P, Światowska J. Solid Electrolyte Interphase Layer Formation on the Si-Based Electrodes with and without Binder Studied by XPS and ToF-SIMS Analysis. Batteries. 2022; 8(12):271. https://doi.org/10.3390/batteries8120271
Chicago/Turabian StyleWu, Zhan-Yu, Li Deng, Jun-Tao Li, Sandrine Zanna, Antoine Seyeux, Ling Huang, Shi-Gang Sun, Philippe Marcus, and Jolanta Światowska. 2022. "Solid Electrolyte Interphase Layer Formation on the Si-Based Electrodes with and without Binder Studied by XPS and ToF-SIMS Analysis" Batteries 8, no. 12: 271. https://doi.org/10.3390/batteries8120271