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Magnetochemistry, Volume 8, Issue 4

April 2022 - 11 articles

Cover Story: We synthesized a CoII complex with two terpyridine ligands, one of which has a paramagnetic nitroxide group at its terminus. As CoII is paramagnetic, we measured the distance between CoII and nitroxide using relaxation-induced dipolar modulation enhancement (RIDME) and double-electron-electron resonance (DEER) pulse sequences at 34 GHz. Our complex’s structure can be seen on the top of the cover, with the red arrow indicating the distance between the paramagnetic centers we sought to measure. On the bottom left are the6-pulse RIDME experimental data, and on the bottom right is the CoII–nitroxide distance of 2.6 nm found with our experiment. View this paper
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Articles (11)

  • Article
  • Open Access
3 Citations
2,791 Views
9 Pages

Enhanced Coercivity of Low-Density Barium Hexaferrite Magnets from Paste-Injection Molding

  • Wannisa Thongsamrit,
  • Pongsakorn Jantaratana,
  • Thanida Charoensuk and
  • Chitnarong Sirisathitkul

Ceramic–polymer paste-injection molding is demonstrated as a facile fabrication route for barium hexaferrite magnets. Interestingly, these low-density (1.90–2.35 g/cm3) magnets exhibit substantial coercivity of 3868–4002 Oe. When ce...

  • Article
  • Open Access
4 Citations
2,533 Views
7 Pages

Simple Realistic Model of Spin Reorientation in 4f-3d Compounds

  • Alexander Moskvin,
  • Evgenii Vasinovich and
  • Anton Shadrin

This is a simple but realistic microscopic theory of spontaneous spin reorientation in rare-earth perovskites, orthoferrites RFeO3 and orthochromites RCrO3, induced by the 4f-3d interaction, namely, the interaction of the well-isolated ground-state K...

  • Article
  • Open Access
2 Citations
3,937 Views
14 Pages

A Low-Spin CoII/Nitroxide Complex for Distance Measurements at Q-Band Frequencies

  • Angeliki Giannoulis,
  • David B. Cordes,
  • Alexandra M. Z. Slawin and
  • Bela E. Bode

Pulse dipolar electron paramagnetic resonance spectroscopy (PDS) is continuously furthering the understanding of chemical and biological assemblies through distance measurements in the nanometer range. New paramagnets and pulse sequences can provide...

  • Article
  • Open Access
1 Citations
3,065 Views
12 Pages

A quantum-chemical analysis of the effect of a constant magnetic field on radical formation in the processes of chain oxidation of organic compounds by molecular oxygen is presented. The calculation of the total electronic energies and thermodynamic...

  • Review
  • Open Access
17 Citations
7,419 Views
14 Pages

Magnetic force microscopy (MFM) enables to characterize magnetic properties with submicron (nanoscale) resolution and without much demand on sample surface preparation. MFM can operate in a wide range of temperatures and environmental conditions, tha...

  • Article
  • Open Access
2 Citations
5,225 Views
14 Pages

Graphene-Coated Iron Nitride Streptavidin Magnetic Beads: Preparation and Application in SARS-CoV-2 Enrichment

  • Jianxing Li,
  • Minglian Wang,
  • Runqing Jia,
  • Zhuang Ma,
  • Xiaoxu Zhang,
  • Jintao Li,
  • Xiangqian Xiao,
  • Yunzhi Zhou and
  • Qun Wang

In this study, we prepared a streptavidin magnetic bead based on graphene-coated iron nitride magnetic beads (G@FeN-MB) and tried to use it for the enrichment of severe acute respiratory syndrome coronavirus-2 (SARS-CoV-2). The outer shell of our mag...

  • Feature Paper
  • Article
  • Open Access
1 Citations
3,691 Views
10 Pages

Use of Time Domain Nuclear Magnetic Resonance Relaxometry to Monitor the Effect of Magnetic Field on the Copper Corrosion Rate in Real Time

  • Cirlei Igreja Nascimento Mitre,
  • Bruna Ferreira Gomes,
  • Elaine Paris,
  • Carlos Manuel Silva Lobo,
  • Christina Roth and
  • Luiz Alberto Colnago

The corrosion of metals is a major problem of modern societies, demanding new technologies and studies to understand and minimize it. Here we evaluated the effect of a magnetic field (B) on the corrosion of copper in aqueous HCl solution under open c...

  • Article
  • Open Access
3 Citations
3,148 Views
12 Pages

Giant Rotational Magnetocaloric Effect in Ni(en)(H2O)4·2H2O: Experiment and Theory

  • Petro Danylchenko,
  • Róbert Tarasenko,
  • Erik Čižmár,
  • Vladimír Tkáč,
  • Alexander Feher,
  • Alžbeta Orendáčová and
  • Martin Orendáč

An experimental study of the rotational magnetocaloric effect in Ni(en)(H2O)4SO4∙2H2O (en = ethylenediamine) single crystal is presented. The study was carried out at temperatures above 2 K and was associated with adiabatic crystal rotation bet...

  • Review
  • Open Access
36 Citations
5,156 Views
18 Pages

Recent Advances of Magnetic Gold Hybrids and Nanocomposites, and Their Potential Biological Applications

  • Gul Rehman Elmi,
  • Kalsoom Saleem,
  • Mirza Muhammad Faran Ashraf Baig,
  • Muhammad Naeem Aamir,
  • Minglian Wang,
  • Xiuli Gao,
  • Muhammad Abbas and
  • Masood Ur Rehman

Magnetic gold nanoparticles (mGNP) have become a great interest of research for nanomaterial scientists because of their significant magnetic and plasmonic properties applicable in biomedical applications. Various synthetic approaches and surface mod...

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Magnetochemistry - ISSN 2312-7481