Lithofacies Identification and Multivariate Analysis of Groundwater Chemistry in Coastal Aquifers in Koko Area of the Western Niger Delta

Understanding aquifer lithofacies and depth of occurrence, and what factors influence its quality and chemistry are of paramount importance to the management of groundwater resource. Subsurface lithofacies distribution was characterized by resistivity and validated with available subsurface geology. Resistivity values varied from less than 100 Ωm to above 1000 Ωm. Lithofacies identified includes clay, clayey sand, sand and peat. Shallow unconfined and confined aquifers occurred at depths ranging from 0 to 12 m and 18 to 63 m, respectively. Geochemistry and multivariate statistical analysis consisting of principal component analysis (PCA) and cluster analysis (CA) were used for the determination of quality and groundwater evolution. Groundwater types depicted by Piper plots were Ca³⁺, Cl⁻ and Na⁺, Cl⁻, which was characterized by low dissolved ions, slightly acidic and Fe²⁺. The dominant variables influencing groundwater quality as returned by PCA were organic pollution resulting from swampy depositional environment, anthropogenic effects resulting from septic and leachates from haphazard dumpsites mixing with groundwater from diffuse sources. In addition, the weathering and dissolution of aquifer sediments rich in feldspar and clay minerals have considerable impact on groundwater quality. CA depicted two distinct types of groundwater that are significantly comparable to those obtained from Piper plots.