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Inorganics, Volume 10, Issue 1

2022 January - 14 articles

Cover Story: Rechargeable lithium-metal batteries (LMBs), which have high power and energy density, are very attractive to solve the intermittence problem of the energy supplied either by windmills or solar plants or to power electric vehicles. However, two failure modes limit the commercial use of LMBs, i.e., dendrite growth at the surface of Li metal and side reactions with the electrolyte. Different strategies are being accomplished to mitigate these drawbacks. including modification of the electrolyte (salt and solvents) to obtain a highly conductive solid–electrolyte interphase (SEI) layer, protection of the Li anode by in situ and ex situ coatings, use of three-dimensional porous skeletons, and anchoring Li on 3D current collectors. View this paper.
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Articles (14)

  • Review
  • Open Access
2 Citations
4,767 Views
24 Pages

The earliest forms of life (i.e., Archaea, Bacteria, and Eukarya) appeared on our planet about ten billion years after its formation. Although Archaea do not seem to possess the multiprotein machinery constituted by the NIF (Nitrogen Fixation), ISC (...

  • Article
  • Open Access
7 Citations
3,872 Views
19 Pages

Antioxidant and Anticancer Activities and Protein Interaction of the Oxidovanadium(IV) Naringin Complex

  • Andrés Gonzalo Restrepo-Guerrero,
  • Helen Goitia-Semenco,
  • Luciana G. Naso,
  • Marilin Rey,
  • Pablo J. Gonzalez,
  • Evelina G. Ferrer and
  • Patricia A. M. Williams

The complex of oxidovanadium(IV) with naringin (Narg) [VO(Narg)2] 8H2O (VONarg) was prepared according to the literature improving the synthetic procedure and physicochemical characterization. In addition, biological activities (cytotoxic, antioxidan...

  • Article
  • Open Access
4 Citations
3,502 Views
15 Pages

Bidimensional Polyiodide Netting Stabilized by a Cu(II) Macrocyclic Complex

  • Matteo Savastano,
  • Valeria Monini,
  • Carla Bazzicalupi and
  • Antonio Bianchi

Iodine-dense polyiodide phases are interesting materials for a number of potential uses, including batteries and solid-state conductors. The incorporation of transition metal cations is considered a promising way to enhance the stability, tune the pr...

  • Article
  • Open Access
10 Citations
5,135 Views
26 Pages

An attempt was made, using computational methods, to understand whether the intermolecular interactions in the dimers of molybdenum dichalcogenides MoCh2 (Ch = chalcogen, element of group 16, especially S, Se and Te) and similar mixed-chalcogenide de...

  • Article
  • Open Access
5 Citations
3,350 Views
13 Pages

The high voltage spinel material LiMn1.5Ni0.5O4 (LMNO) has the potential to increase the energy density of lithium batteries. However, its battery performance suffers from poor long-term cycling and high-temperature stability. In order to overcome th...

  • Article
  • Open Access
1 Citations
3,208 Views
11 Pages

Anisometric Ln(III) Complexes with Efficient Near-IR Luminescence

  • Andrey A. Knyazev,
  • Aleksandr S. Krupin and
  • Yuriy G. Galyametdinov

Recent studies in development of near-infrared luminophores focus on overcoming their disadvantages such as low quantum efficiency, limited emission power, and broad emission spectra. Rare earth (RE) elements are promising compounds in this respect a...

  • Article
  • Open Access
3 Citations
5,568 Views
30 Pages

Aqueous Solution Equilibria and Spectral Features of Copper Complexes with Tripeptides Containing Glycine or Sarcosine and Leucine or Phenylalanine

  • Giselle M. Vicatos,
  • Ahmed N. Hammouda,
  • Radwan Alnajjar,
  • Raffaele P. Bonomo,
  • Gabriele Valora,
  • Susan A. Bourne and
  • Graham E. Jackson

Copper(II) complexes of glycyl-L-leucyl-L-histidine (GLH), sarcosyl-L-leucyl-L-histidine (Sar-LH), glycyl-L-phenylalanyl-L-histidine (GFH) and sarcosyl-L-phenylalanyl-L-histidine (Sar-FH) have potential anti-inflammatory activity, which can help to a...

  • Article
  • Open Access
3 Citations
2,927 Views
13 Pages

Two new modifications of the pentafluoridoaluminate K2AlF5 were obtained from ammonothermal synthesis at 753 K, 224 MPa and 773 K, 220 MPa, respectively. Both crystallize in the orthorhombic space group type Pbcn, with close metric relations and feat...

  • Review
  • Open Access
11 Citations
5,559 Views
15 Pages

Alzheimer’s disease is a progressive neurodegenerative disorder that eventually leads the affected patients to die. The appearance of senile plaques in the brains of Alzheimer’s patients is known as a main symptom of this disease. The pla...

  • Review
  • Open Access
8 Citations
9,387 Views
51 Pages

Rechargeable lithium-metal batteries (LMBs), which have high power and energy density, are very attractive to solve the intermittence problem of the energy supplied either by wind mills or solar plants or to power electric vehicles. However, two fail...

  • Article
  • Open Access
4 Citations
3,655 Views
16 Pages

Phenanthroline Complexation Enhances the Cytotoxic Activity of the VO-Chrysin System

  • Agustin Actis Dato,
  • Luciana G. Naso,
  • Marilin Rey,
  • Pablo J. Gonzalez,
  • Evelina G. Ferrer and
  • Patricia A. M. Williams

Metal complexation in general improves the biological properties of ligands. We have previously measured the anticancer effects of the oxidovanadium(IV) cation with chrysin complex, VO(chrys)2. In the present study, we synthesized and characterized a...

  • Article
  • Open Access
10 Citations
6,983 Views
15 Pages

AlphaFold and RoseTTAFold are deep learning-based approaches that predict the structure of proteins from their amino acid sequences. Remarkable success has recently been achieved in the prediction accuracy of not only the fold of the target protein b...

  • Article
  • Open Access
4 Citations
4,253 Views
16 Pages

Synthesis and Characterization of Novel Copper(II)-Sunitinib Complex: Molecular Docking, DFT Studies, Hirshfeld Analysis and Cytotoxicity Studies

  • Facundo Tarasi,
  • Priscila Ailín Lanza,
  • Valeria Ferretti,
  • Gustavo Alberto Echeverría,
  • Oscar Enrique Piro,
  • Maximiliano Cacicedo,
  • Stephan Gehring,
  • Ignacio Esteban León and
  • María Soledad Islas

The main goal of this work was to report the synthesis, characterization, and cytotoxicity study of a novel copper(II)-sunitinib complex, CuSun. It has been synthesized and characterized in solid state and in solution by different methods (such as DF...

  • Article
  • Open Access
20 Citations
4,643 Views
14 Pages

Aluminium dross is a hazardous industrial waste generated during aluminium production. It contains metallic oxides of aluminium and magnesium, other phases (aluminum nitride), and residues of fluxes and salts from the melting process of aluminium. Di...

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Inorganics - ISSN 2304-6740