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Polymers, Volume 9, Issue 3

March 2017 - 38 articles

Cover Story: Successful gene therapy relies on the development of efficient and biocompatible delivery vectors. Cationic polymers hold tremendous potential in this regard due to their low cytotoxicity and rapid complexation with negatively-charged nucleic acids. With a multitude of structures available, the challenge has become fine tuning macromolecular composition to probe detailed structure–property relationships. In this issue, Campos and co-workers explore the gene delivery capacities of polymers based on the aromatic trisaminocyclopropenium ion. Modifying the degree of substituent chain branching, the authors found a significant dependence on substituent identity while highlighting the importance of precise control over polymer structure. By Luis M. Campos. View the paper
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Articles (38)

  • Article
  • Open Access
32 Citations
6,535 Views
18 Pages

22 March 2017

Three dithienylpyrroles (1-(4-(methylthio)phenyl)-2,5-di(thiophen-2-yl)-pyrrole (MPS), 1-(4-methoxyphenyl)-2,5-di(thiophen-2-yl)-pyrrole (MPO), and 4-(2,5-di(thiophen-2-yl)-pyrrol-1-yl)benzonitrile (ANIL)) were synthesized and their corresponding pol...

  • Article
  • Open Access
10 Citations
7,258 Views
13 Pages

22 March 2017

A mathematical model for the reaction-diffusion equation is developed to describe the nutrient release profiles and degradation of poly(lactic acid) (PLA)-coated controlled-release fertilizer. A multi-diffusion model that consists of coupled partial...

  • Article
  • Open Access
49 Citations
8,751 Views
19 Pages

Epoxy-Based Shape-Memory Actuators Obtained via Dual-Curing of Off-Stoichiometric “Thiol–Epoxy” Mixtures

  • Alberto Belmonte,
  • Claudio Russo,
  • Veronica Ambrogi,
  • Xavier Fernández-Francos and
  • Silvia De la Flor

21 March 2017

In this work, epoxy-based shape-memory actuators have been developed by taking advantage of the sequential dual-curing of off-stoichiometric “thiol–epoxy” systems. Bent-shaped designs for flexural actuation were obtained thanks to the easy processing...

  • Review
  • Open Access
31 Citations
13,220 Views
40 Pages

Self-Assembled Organic Materials for Photovoltaic Application

  • Tanwistha Ghosh,
  • Jayanthy S. Panicker and
  • Vijayakumar C. Nair

21 March 2017

Organic photovoltaic cells based on bulk-heterojunction architecture have been a topic of intense research for the past two decades. Recent reports on power conversion efficiency surpassing 10% suggest these devices are a viable low-cost choice for a...

  • Article
  • Open Access
59 Citations
8,074 Views
12 Pages

17 March 2017

In this work, a blending strategy based on compounding the hydrophilic titanium dioxide (TiO2) particles with the host polypropylene (PP) pellets, followed by the common membrane manufacture process of melt extruding/annealing/stretching, was used to...

  • Article
  • Open Access
14 Citations
9,024 Views
12 Pages

17 March 2017

1,3-dimethylurea (DMU) was used to mimic urea and to model melamine-urea-formaldehyde (MUF) co-condensation reactions. The products of 1,3-dimethylurea-formaldehyde (DMUF), melamine-formaldehyde (MF), and melamine-1,3-dimethylurea-formaldehyde (MDMUF...

  • Article
  • Open Access
12 Citations
7,101 Views
13 Pages

17 March 2017

Chiral MnIII (salen) complex supported on modified ZPS-PVPA (zirconium poly(styrene-phenylvinylphosphonate)) and ZPS-IPPA (zirconium poly(styrene-isopropenyl phosphonate)) were prepared using –CH2Cl as a reactive surface modifier by a covalent grafti...

  • Article
  • Open Access
19 Citations
8,070 Views
10 Pages

16 March 2017

The nickel(II) catalyst has manifested higher catalytic activity compared to that of other late transition metal catalysts for norbornene polymerization. Therefore, several structurally similar trans-nickel(II) compounds of N,O-chelate bidentate liga...

  • Article
  • Open Access
21 Citations
8,422 Views
20 Pages

15 March 2017

In this study, we synthesized an unusual 2-aminobutyl maleimide isobutyl polyhedral oligomeric silsesquioxane (MIPOSS-NHBu) monomer lacking conventional fluorescent groups. We then prepared poly(styrene-alt-2-aminobutyl maleimide isobutyl POSS) [poly...

  • Article
  • Open Access
10 Citations
6,912 Views
15 Pages

15 March 2017

The presence of N-phenyl-p-phenylenediamine (PPDA: a dimer of aniline) during microwave (MW) irradiation can significantly improve Pt-loading on the XC72 carbon matrix as a catalyst support of proton exchange membrane fuel cells (PEMFCs). PPDA is con...

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Polymers - ISSN 2073-4360