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Crystals, Volume 6, Issue 11

2016 November - 20 articles

Cover Story: Within our research on the metal binding patterns of acyclovir (acv), we report the crystal structure of (H3O)2[Cu(N7–acv)2(H2O)2(SO4)2]·2H2O which has also been modeled by high-level DFT (left) and molecular electrostatic potential surface calculations (right). Our results highlight the role of the two H-bonding interactions between the hydronium ions, the guanine acv-moiety on the electronic properties of the novel Cu(II) complex and the depleted proton affinity of the N3-acv atom.View this paper.
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Articles (20)

  • Article
  • Open Access
12 Citations
6,868 Views
10 Pages

23 November 2016

A hierarchical zeolite CaA with microporous, mesoporous and macroporous structure was hydrothermally synthesized by a ”Bond-Blocking” method using organo-functionalized mesoporous silica (MS) as a silica source. The characterization by XRD, SEM/TEM a...

  • Review
  • Open Access
88 Citations
18,060 Views
26 Pages

Topological Insulator Film Growth by Molecular Beam Epitaxy: A Review

  • Theresa P. Ginley,
  • Yong Wang and
  • Stephanie Law

23 November 2016

In this article, we will review recent progress in the growth of topological insulator (TI) thin films by molecular beam epitaxy (MBE). The materials we focus on are the V2-VI3 family of TIs. These materials are ideally bulk insulating with surface s...

  • Article
  • Open Access
4 Citations
7,285 Views
13 Pages

23 November 2016

Starting from Ni-Co-Mn carbonate nanoparticles prepared by microreaction technology, uniform spherical particles of Ni1/3Co1/3Mn1/3CO3 with a size of 3–4 μm were obtained by a controllable hydrothermal conversion with the addition of (NH4)2CO3. Based...

  • Technical Note
  • Open Access
6 Citations
8,609 Views
8 Pages

Synthesis and Crystallographic Characterization of a Maleimide Derivative of Tryptamine

  • Jean Dubois,
  • Melwin Colaço,
  • Grégoire Rondelet and
  • Johan Wouters

21 November 2016

While mechanosynthesis of the target compound, 1-[2-(1H-indol-3-yl)-ethyl]-pyrrole-2,5-dione, C14 H12 N2 O2, did not yield the desired product, it instead resulted in an open intermediate. On the other hand, synthesis starting from the activated male...

  • Article
  • Open Access
20 Citations
13,224 Views
9 Pages

E’’ Raman Mode in Thermal Strain-Fractured CVD-MoS2

  • Di Wu,
  • Han Huang,
  • Xupeng Zhu,
  • Yanwei He,
  • Qiliang Xie,
  • Xiaoliu Chen,
  • Xiaoming Zheng,
  • Huigao Duan and
  • Yongli Gao

18 November 2016

Molybdenum disulfide (MoS2) has recently attracted considerable interests due to its unique properties and potential applications. Chemical vapor deposition (CVD) method is used widely to grow large-area and high-quality MoS2 single crystals. Here, w...

  • Article
  • Open Access
3 Citations
6,305 Views
7 Pages

Temperature-Dependent X-ray Diffraction Measurements of Infrared Superlattices Grown by MBE

  • Charles J. Reyner,
  • Arnold M. Kiefer,
  • Gamini Ariyawansa,
  • Joshua M. Duran and
  • John E. Scheihing

17 November 2016

Strained-layer superlattices (SLSs) are an active research topic in the molecular beam epitaxy (MBE) and infrared focal plane array communities. These structures undergo a >500 K temperature change between deposition and operation. As a result, th...

  • Review
  • Open Access
102 Citations
13,296 Views
19 Pages

16 November 2016

Semiconductor photocatalysis provides potential solutions for many energy and environmental-related issues. Recently, various semiconductors with hierarchical nanostructures have been fabricated to achieve efficient photocatalysts owing to their mult...

  • Article
  • Open Access
10 Citations
8,320 Views
10 Pages

Structural and Quantitative Investigation of Perovskite Pore Filling in Mesoporous Metal Oxides

  • Shany Gamliel,
  • Inna Popov,
  • Bat-El Cohen,
  • Vladimir Uvarov and
  • Lioz Etgar

16 November 2016

In recent years, hybrid organic–inorganic perovskite light absorbers have attracted much attention in the field of solar cells due to their optoelectronic characteristics that enable high power conversion efficiencies. Perovskite-based solar cells’ e...

  • Article
  • Open Access
17 Citations
5,247 Views
12 Pages

15 November 2016

In order to match the growth of the decentered square and the evolution of the interface cell in a two-dimensional cellular automaton-finite volume method (CA-FVM) model with decentered square algorithm, the present work first alters the determinatio...

  • Article
  • Open Access
20 Citations
8,593 Views
11 Pages

12 November 2016

High quality stoichiometric brownmillerite-type oxide single crystals have been successfully grown by the floating zone method using a mirror furnace. We report here on the growth conditions and structural characterization of two model compounds: Ca2...

  • Article
  • Open Access
5 Citations
6,453 Views
9 Pages

Shear-Thinning Characteristics of Nematic Liquid Crystals Doped with Nanoparticles

  • Munehiro Kimura,
  • Zur Ain Binti Hanafi,
  • Tatsuya Takagi,
  • Ryosuke Sawara and
  • Shuji Fujii

12 November 2016

This work investigated changes in the physical properties of nematic liquid crystals (NLCs) upon doping with nanoparticles. Shear viscosity measurements demonstrated the shear-thinning of typical NLCs following the addition of small amounts of nanopa...

  • Article
  • Open Access
9 Citations
7,094 Views
9 Pages

Interplay Effect of Excitation and Temperature on Carrier Transfer between Vertically Aligned InAs/GaAs Quantum Dot Pairs

  • Yao Liu,
  • Ying Wang,
  • Baolai Liang,
  • Qinglin Guo,
  • Shufang Wang,
  • Guangsheng Fu,
  • Yuriy I. Mazur,
  • Morgan E. Ware and
  • Gregory J. Salamo

10 November 2016

Carrier transfer in vertically-coupled InAs/GaAs quantum dot (QD) pairs is investigated. Photoluminescence (PL) and PL excitation spectra measured at low temperature indicate that the PL peak intensity ratio between the emission from the two sets of...

  • Review
  • Open Access
49 Citations
19,111 Views
13 Pages

10 November 2016

The 2D outlook of graphene and similar layers has initiated a number of theoretical considerations of electronic structure that are both interesting and exciting, but applying these ideas to real layered systems, in terms of a model 2D system, must b...

  • Article
  • Open Access
3 Citations
7,003 Views
7 Pages

9 November 2016

A sequence of structural/magnetic transitions on cooling is reported in the literature for hole-doped iron-based superconductor (Ba1 − xKx)Fe2As2 with x = 0.24. By using polarized light microscopy, we directly observe the formation of orthorhombic do...

  • Article
  • Open Access
4 Citations
9,320 Views
19 Pages

3 November 2016

We present a novel method to determine the projected atomic potential of a specimen directly from transmission electron microscopy coherent electron nano-diffraction patterns, overcoming common limitations encountered so far due to the dynamical natu...

  • Article
  • Open Access
14 Citations
5,707 Views
12 Pages

31 October 2016

3D hierarchical Bi2S3 architectures have been successfully synthesized via a simple and effective hydrothermal process. The as-prepared Bi2S3 samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission elec...

  • Article
  • Open Access
19 Citations
6,826 Views
12 Pages

29 October 2016

Two new linear silver(I) nitrate coordination polymers with bitopic ligand 1,1,2,2-tetra(pyrazol-1-yl)ethane were synthesized. Synthesized compounds were characterized by IR spectroscopy, elemental analysis, powder X-ray diffraction and thermal analy...

  • Communication
  • Open Access
6 Citations
7,075 Views
19 Pages

Structural and Theoretical Evidence of the Depleted Proton Affinity of the N3-Atom in Acyclovir

  • Esther Vílchez-Rodríguez,
  • Inmaculada Pérez-Toro,
  • Antonio Bauzá and
  • Antonio Matilla-Hernández

29 October 2016

The hydronium salt (H3O)2[Cu(N7–acv)2(H2O)2(SO4)2]·2H2O (1, acv = acyclovir) has been synthesized and characterized by single-crystal X-ray diffraction and spectral methods. Solvated Cu(OH)2 is a by-product of the synthesis. In the all-trans centrosy...

  • Review
  • Open Access
6 Citations
13,555 Views
16 Pages

Quasicrystals and Other Aperiodic Structures in Mineralogy

  • Carlos M. Pina and
  • Victoria López-Acevedo

27 October 2016

In this article, we first present and discuss eighteenth-century descriptions of minerals that contributed decisively to the development of crystallography. Remarkably, these old crystallographic descriptions included morphologies with symmetries inc...

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Crystals - ISSN 2073-4352