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Crystals, Volume 6, Issue 10

October 2016 - 17 articles

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Cover Story: We investigated a self-assembly of metal organic frameworks (MOFs) based on zinc(II) or cadmium(II), terephthalate ions and flexible bis-imidazolyl ligands. Three out of four products possess an interpenetrated diamond topology. The MOF with bis(imidazol-1-yl)hexane and cadmium(II) ions formed a very rare eight-connected self-penetrated net. The influence of the chemical composition of MOFs on their photoluminescent properties is investigated and discussed in detail. View this paper.

Articles (17)

  • Article
  • Open Access
17 Citations
5,763 Views
13 Pages

Stable Photocatalytic Paints Prepared from Hybrid Core-Shell Fluorinated/Acrylic/TiO2 Waterborne Dispersions

  • Audrey Bonnefond,
  • Edurne González,
  • José M. Asua,
  • Jose Ramon Leiza,
  • Eliana Ieva,
  • Giulio Brinati,
  • Serena Carella,
  • Alessio Marrani,
  • Alessandro Veneroni and
  • John Kiwi
  • + 2 authors

24 October 2016

The contamination of air and water is one of the major concerns towards the development of a sustainable world in the 21st century. In this context many efforts are devoted to the design of photocatalytic paints able to degrade chemical and biologica...

  • Article
  • Open Access
6 Citations
6,199 Views
15 Pages

ZnO Micro- and Nanostructures Obtained by Thermal Oxidation: Microstructure, Morphogenesis, Optical, and Photoluminescence Properties

  • Alejandro Escobedo-Morales,
  • Rubén J. Aranda-García,
  • Ernesto Chigo-Anota,
  • Armando Pérez-Centeno,
  • Antonio Méndez-Blas and
  • Carlos G. Arana-Toro

20 October 2016

ZnO micro- and nanostructures were obtained through thermal oxidation of Zn powders at high temperature under air atmosphere. A detailed study of the microstructure, morphology, optical, and photoluminescence properties of the generated products at d...

  • Article
  • Open Access
7 Citations
4,879 Views
10 Pages

19 October 2016

Still looking at the development of new materials with unique properties and taking advantage of the nucleophilic properties of amines to form stable azomethines, dinitrophenylhydrazine was reacted with 4-ethyl-5-methyl-2-phenyl-pyrazol-3-one and the...

  • Article
  • Open Access
2 Citations
4,420 Views
7 Pages

18 October 2016

A heterobimetallic 2-D coordination polymer, [Na2(Cu2I2(2pyCOO)4)(H2O)4]n (1) (2pyCOO=picolinate) was synthesized and characterized. The complex was also structurally characterized using single X-ray diffraction studies that revealed the complex 1 ha...

  • Article
  • Open Access
8 Citations
4,391 Views
7 Pages

18 October 2016

Two new oxaspirocyclic compounds, 8-(4-(dimethylamino)benzylidene)-6,10-dioxaspiro[4.5]decane-7,9-dione (1) and 8-(4-hydroxybenzylidene)-6,10-dioxaspiro[4.5]decane-7,9-dione (2) have been synthesized and their structures determined by single crystal...

  • Article
  • Open Access
7 Citations
7,339 Views
15 Pages

Water-Soluble CdTe/CdS Core/Shell Semiconductor Nanocrystals: How Their Optical Properties Depend on the Synthesis Methods

  • Brener R. C. Vale,
  • Fernanda O. Silva,
  • Melissa S. Carvalho,
  • Ellen Raphael,
  • Jefferson L. Ferrari and
  • Marco A. Schiavon

15 October 2016

We conducted a comparative synthesis of water-soluble CdTe/CdS colloidal nanocrystalline semiconductors of the core/shell type. We prepared the CdS shell using two different methods: a one-pot approach and successive ionic layer adsorption and reacti...

  • Communication
  • Open Access
16 Citations
5,116 Views
8 Pages

13 October 2016

We synthesized new Fe(II) compounds consisting of [Fe(L)2] (HL: 2-Acetylpyridine isonicotinoylhydrazone) and dicarboxylic acids. Single crystal analysis shows that short hydrogen bonds are formed between [Fe(L)2] and dicarboxylic acids. The hydrogen...

  • Article
  • Open Access
23 Citations
6,879 Views
15 Pages

13 October 2016

New metal-organic frameworks (MOFs) based on zinc and cadmium ions, terephthalic acid, and flexible ligands 1,5-bis(imidazol-1-yl)pentane or 1,6-bis(imidazol-1-yl)hexane were prepared and characterized by X-ray diffraction, thermorgavimetric analysis...

  • Article
  • Open Access
3 Citations
4,790 Views
8 Pages

12 October 2016

Directionally solidified multicrystalline silicon (mc-Si)-based solar cells have dominated the global photovoltaic market in recent years. The photovoltaic performance of mc-Si solar cells is strongly influenced by their crystalline defects. The occu...

  • Letter
  • Open Access
3 Citations
4,748 Views
9 Pages

Dynamic Tuning and Memory Switching of Defect Modes in a Hybrid Photonic Structure

  • Hsiao-Tsung Wang,
  • Po-Chang Wu,
  • Ivan V. Timofeev,
  • Victor Ya. Zyryanov and
  • Wei Lee

10 October 2016

We propose a memorable and electrically tunable photonic device by infiltrating a dual-mode chiral-doped dual-frequency liquid crystal (LC) as the central defect layer in a one-dimensional photonic crystal (PC). According to the transmission properti...

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