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Open AccessArticle

Crystal Structures of Two 1,4-Diamino-1,2,4-triazolium Salts

1
Faculty of Chemistry and Pharmacy, University of Innsbruck, 6020 Innsbruck, Austria
2
Institute of Mineralogy and Petrography, University of Innsbruck, 6020 Innsbruck, Austria
*
Author to whom correspondence should be addressed.
Academic Editor: Helmut Cölfen
Crystals 2016, 6(1), 13; https://doi.org/10.3390/cryst6010013
Received: 30 December 2015 / Revised: 13 January 2016 / Accepted: 18 January 2016 / Published: 20 January 2016
(This article belongs to the Special Issue Nitrogen-Rich Salts)
Bis(1,4-diamino-1,2,4-triazolium) sulfate (1) was obtained from the corresponding chloride by ion metathesis using Ag2SO4. Further metathesis with barium 5,5′-azotetrazolate yielded bis(1,4-diamino-1,2,4-triazolium) 5,5′-azotetrazolate (2). Numerous NH···N and NH···O interactions were identified in the crystal structures of 1 and 2. Both compounds undergo exothermal decomposition upon heating. View Full-Text
Keywords: azotetrazolate; hydrogen bond; sulfate; thermoanalysis; triazolium azotetrazolate; hydrogen bond; sulfate; thermoanalysis; triazolium
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MDPI and ACS Style

Laus, G.; Wurst, K.; Kahlenberg, V.; Schottenberger, H. Crystal Structures of Two 1,4-Diamino-1,2,4-triazolium Salts. Crystals 2016, 6, 13.

AMA Style

Laus G, Wurst K, Kahlenberg V, Schottenberger H. Crystal Structures of Two 1,4-Diamino-1,2,4-triazolium Salts. Crystals. 2016; 6(1):13.

Chicago/Turabian Style

Laus, Gerhard; Wurst, Klaus; Kahlenberg, Volker; Schottenberger, Herwig. 2016. "Crystal Structures of Two 1,4-Diamino-1,2,4-triazolium Salts" Crystals 6, no. 1: 13.

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