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Catalysts, Volume 9, Issue 7

July 2019 - 66 articles

Cover Story: The cover illustrates a metal–semiconductor/polyaniline nanocomposite with spectacular catalytic properties. The nanocomposites catalyze the decomposition of methyl orange (MO) in darkness. Indeed, the RuO2–TiO2 mixed oxide is an excellent photocatalyst under visible light, while the nanocomposite RuO2–TiO2/aryl/polyaniline exhibits unique, fast catalytic performance in the dark. Total discoloration of MO was noted without any spectral evidence for organic products, thus suggesting complete mineralization of the dye. This activity does not only depend on the components that constitute these materials but also on the subtle interface chemical composition which is driven by diazonium modification of RuO2–TiO2. View this paper.
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Articles (66)

  • Article
  • Open Access
9 Citations
5,234 Views
16 Pages

Hierarchical H-MOR Zeolite Supported Vanadium Oxide for Dimethyl Ether Direct Oxidation

  • Wenfeng Wang,
  • Xiujuan Gao,
  • Ru Feng,
  • Qi Yang,
  • Tao Zhang,
  • Junfeng Zhang,
  • Qingde Zhang,
  • Yizhuo Han and
  • Yisheng Tan

23 July 2019

A series of hierarchical H-MOR zeolites with different pore structure were designed and synthesized by alkaline and alkaline-acid post-synthesis methods. The catalytic performance of hierarchical H-MOR zeolite-supported vanadium oxide was investigate...

  • Article
  • Open Access
63 Citations
9,823 Views
14 Pages

Identification and Characterization of New Laccase Biocatalysts from Pseudomonas Species Suitable for Degradation of Synthetic Textile Dyes

  • Mina Mandic,
  • Lidija Djokic,
  • Efstratios Nikolaivits,
  • Radivoje Prodanovic,
  • Kevin O’Connor,
  • Sanja Jeremic,
  • Evangelos Topakas and
  • Jasmina Nikodinovic-Runic

23 July 2019

Laccases are multicopper-oxidases with variety of biotechnological applications. While predominantly used, fungal laccases have limitations such as narrow pH and temperature range and their production via heterologous protein expression is more compl...

  • Review
  • Open Access
37 Citations
6,926 Views
21 Pages

Catalysis inside Supramolecular Capsules: Recent Developments

  • Andrea Pappalardo,
  • Roberta Puglisi and
  • Giuseppe Trusso Sfrazzetto

23 July 2019

In the last decades, supramolecular chemists have developed new molecular receptors able to include a wide range of guests. In addition, they have designed synthetic hosts able to form capsules having an internal volume of thousands of Å3. This...

  • Article
  • Open Access
39 Citations
6,415 Views
22 Pages

Pyrolysis Kinetics of Hydrochars Produced from Brewer’s Spent Grains

  • Maciej P. Olszewski,
  • Pablo J. Arauzo,
  • Przemyslaw A. Maziarka,
  • Frederik Ronsse and
  • Andrea Kruse

22 July 2019

The current market situation shows that large quantities of the brewer’s spent grains (BSG)—the leftovers from the beer productions—are not fully utilized as cattle feed. The untapped BSG is a promising feedstock for cheap and envir...

  • Article
  • Open Access
18 Citations
5,168 Views
14 Pages

Electromagnetic Effective Medium Modelling of Composites with Metal-Semiconductor Core-Shell Type Inclusions

  • Yael Gutiérrez,
  • Dolores Ortiz,
  • Rodrigo Alcaraz de la Osa,
  • José M. Saiz,
  • Francisco González and
  • Fernando Moreno

22 July 2019

The possibility of using light to drive chemical reactions has highlighted the role of photocatalysis as a key tool to address the environmental and energy issues faced by today’s society. Plasmonic photocatalysis, proposed to circumvent some of the...

  • Article
  • Open Access
17 Citations
5,644 Views
18 Pages

22 July 2019

A commercial carbon-modified titanium dioxide, KRONOClean 7000, was applied as a UV(A) and visible-light active photocatalyst to investigate the conversion of the antipsychotic pharmaceutical chlorpromazine in aqueous phase employing two monochromati...

  • Article
  • Open Access
8 Citations
4,468 Views
16 Pages

21 July 2019

Novel gene estBAS from Bacillus altitudinis, encoding a 216-amino acid esterase (EstBAS) with a signal peptide (SP), was expressed in Escherichia coli. EstBASΔSP showed the highest activity toward p-nitrophenyl hexanoate at 50 °C and pH 8.0 and had a...

  • Feature Paper
  • Article
  • Open Access
39 Citations
6,565 Views
24 Pages

The Effect of CeO2 Preparation Method on the Carbon Pathways in the Dry Reforming of Methane on Ni/CeO2 Studied by Transient Techniques

  • Constantinos M. Damaskinos,
  • Michalis A. Vasiliades,
  • Vassilis N. Stathopoulos and
  • Angelos M. Efstathiou

21 July 2019

The present work discusses the effect of CeO2 synthesis method (thermal decomposition (TD), precipitation (PT), hydrothermal (HT), and sol-gel (SG)) on the carbon pathways of dry reforming of methane with carbon dioxide (DRM) applied at 750 °C ov...

  • Feature Paper
  • Review
  • Open Access
44 Citations
11,859 Views
43 Pages

Dextran Aldehyde in Biocatalysis: More Than a Mere Immobilization System

  • Veymar G. Tacias-Pascacio,
  • Claudia Ortiz,
  • Nazzoly Rueda,
  • Ángel Berenguer-Murcia,
  • Niuris Acosta,
  • Inmaculada Aranaz,
  • Concepción Civera,
  • Roberto Fernandez-Lafuente and
  • Andrés R. Alcántara

21 July 2019

Dextran aldehyde (dexOx), resulting from the periodate oxidative cleavage of 1,2-diol moiety inside dextran, is a polymer that is very useful in many areas, including as a macromolecular carrier for drug delivery and other biomedical applications. In...

  • Article
  • Open Access
43 Citations
8,810 Views
9 Pages

Efficient Photocatalytic Hydrogen Peroxide Production over TiO2 Passivated by SnO2

  • Guifu Zuo,
  • Bingdong Li,
  • Zhaoliang Guo,
  • Liang Wang,
  • Fan Yang,
  • Weishu Hou,
  • Songtao Zhang,
  • Peixiao Zong,
  • Shanshan Liu and
  • Xianguang Meng
  • + 3 authors

21 July 2019

Photocatalysis provides an attractive strategy for synthesizing H2O2 at ambient condition. However, the photocatalytic synthesis of H2O2 is still limited due to the inefficiency of photocatalysts and decomposition of H2O2 during formation. Here, we r...

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Catalysts - ISSN 2073-4344