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Institute of Chemistry, St. Petersburg State University, 199034 St. Petersburg, Russia
Author to whom correspondence should be addressed.
Academic Editor: Hidenori Tanaka
Molbank 2021, 2021(3), M1245;
Received: 8 June 2021 / Revised: 15 June 2021 / Accepted: 16 June 2021 / Published: 3 July 2021
(This article belongs to the Section Organic Synthesis)
Salen-type complexes with transition metals and corresponding polymers attract great scientific interest due to their high electrochemical properties and potential for use as part of next generation organic energy storage devices. Because of their good conductivity but relatively low capacity, energy-intensive additives such as quinones or TEMPO fragments can significantly enhance the capacitive characteristics of the electrode materials. Herein, we report a preparation of precursor for a modified Salen-type complex, the substituted 2,3-Dihydroxybenzaldehyde by butoxy linkers with TEMPO fragment using alkylation reaction. The resulting product was characterized by the 1H and 13C, COSY, HMBC, HSQC nuclear magnetic resonance (NMR), ESI–high resolution mass spectrometry (ESI–HRMS), and Fourier-transform infrared spectroscopy (FTIR). The reported approach opens the way for easy modification of Salen-type complexes in order to increase their specific characteristics. View Full-Text
Keywords: TEMPO; linkers; Salen precursor; alkylation TEMPO; linkers; Salen precursor; alkylation
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MDPI and ACS Style

Vereshchagin, A.A.; Novoselova, J.V.; Kalnin, A.Y.; Lukyanov, D.A. 2-Hydroxy-3-(4-oxy(2,2,6,6-tetramethylpiperidin-1-oxyl)butoxy)benzaldehyde. Molbank 2021, 2021, M1245.

AMA Style

Vereshchagin AA, Novoselova JV, Kalnin AY, Lukyanov DA. 2-Hydroxy-3-(4-oxy(2,2,6,6-tetramethylpiperidin-1-oxyl)butoxy)benzaldehyde. Molbank. 2021; 2021(3):M1245.

Chicago/Turabian Style

Vereshchagin, Anatoliy A., Julia V. Novoselova, Arseniy Y. Kalnin, and Daniil A. Lukyanov 2021. "2-Hydroxy-3-(4-oxy(2,2,6,6-tetramethylpiperidin-1-oxyl)butoxy)benzaldehyde" Molbank 2021, no. 3: M1245.

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