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Open AccessArticle

Portable Power Generation for Remote Areas Using Hydrogen Generated via Maleic Acid-Promoted Hydrolysis of Ammonia Borane

1
School of Mechanical Engineering, Purdue University, West Lafayette, IN 47906, USA
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School of Aeronautics and Astronautics, Purdue University, West Lafayette, IN 47906, USA
*
Author to whom correspondence should be addressed.
Academic Editor: Ewa C. E. Rönnebro
Molecules 2019, 24(22), 4045; https://doi.org/10.3390/molecules24224045
Received: 8 October 2019 / Revised: 30 October 2019 / Accepted: 6 November 2019 / Published: 8 November 2019
(This article belongs to the Special Issue Advances in Hydrogen Storage Materials for Energy Utilization)
A significant drawback to ammonia borane as a hydrogen storage material is the production of ammonia gas during hydrolysis. As a possible solution, maleic acid is shown to be capable of fully promoting hydrolysis of ammonia borane while also preventing ammonia release in excess of single digit parts per million. The reaction is shown to be relatively insensitive towards common water contaminants, with seawater, puddle water, and synthetic urine resulting in hydrogen evolution comparable to that observed when using highly pure deionized water. A common cola beverage was also investigated as a potential water source, with results deviating from those observed when using the other water sources. The ability to use low quality water sources presents the option of acquiring water at the point of use, greatly increasing the energy density of the system during transportation. For each of the water sources being used, concentrations of ammonia in the gas products of maleic acid-promoted hydrolysis were found to be less than the lower detection limits of the employed analysis methods. Based on this reaction, a portable hydrogen reactor is reported and shown to be capable of on-demand hydrogen generation sufficient to power a proton exchange membrane fuel cell at varying loads without significant changes in system pressure. The overall power production system has substantial value in scenarios where electrical power is required but there is no access to an established electrical utility, with prime examples including disaster relief and expeditionary military operations. View Full-Text
Keywords: hydrogen fuel cells; portable power production; ammonia borane hydrolysis; acid-promoted hydrolysis hydrogen fuel cells; portable power production; ammonia borane hydrolysis; acid-promoted hydrolysis
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Groom, T.B.; Gabl, J.R.; Pourpoint, T.L. Portable Power Generation for Remote Areas Using Hydrogen Generated via Maleic Acid-Promoted Hydrolysis of Ammonia Borane. Molecules 2019, 24, 4045.

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