Determination of Critical Micellar Concentration of Homologous 2-Alkoxyphenylcarbamoyloxyethyl-Morpholinium Chlorides
Abstract
1. Introduction
2. Results
3. Materials and Methods
3.1. Chemistry
3.2. Preparation of Pyrene Stock Solution
3.3. Absorbance Measurements
3.4. pH Measurements
4. Conclusions
Author Contributions
Acknowledgments
Conflicts of Interest
References
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Sample Availability: Samples of compounds 1–7 are available from author F. Andriamainty and J. Čižmárik. |
Comp. | R | nc | z | x0 | Δx | x0/Δx | r2 | χ2 | cmc1 [M] | cmc2 [M] | cmc [M] | MV * [cm3] | ST * [dyne/cm] |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | C2H5 | 2 | 28 | 0.0760 | 2.17 × 10−2 | 3.50 | 0.998 | 8.19 × 10−6 | 7.60 × 10−2 | 1.19 × 10−1 | 7.60 × 10−2 | 47.29 | 46.40 |
2 | C4H9 | 4 | 42 | 0.0476 | 7.90 × 10−3 | 6.03 | 0.995 | 2.89 × 10−6 | 4.76 × 10−2 | 6.34 × 10−2 | 4.76 × 10−2 | 80.31 | 44.91 |
3 | C5H11 | 5 | 69 | 0.0397 | 2.76 × 10−2 | 1.44 | 0.998 | 3.33 × 10−5 | 3.97 × 10−2 | 9.49 × 10−2 | 3.97 × 10−2 | 96.81 | 44.30 |
4 | C6H13 | 6 | 42 | 0.0172 | 6.29 × 10−3 | 2.73 | 0.998 | 2.63 × 10−5 | 1.72 × 10−2 | 2.98 × 10−2 | 1.72 × 10−2 | 113.32 | 43.76 |
5 | C7H15 | 7 | 28 | 0.0115 | 3.26 × 10−3 | 3.52 | 0.998 | 2.26 × 10−4 | 1.15 × 10−2 | 1.80 × 10−2 | 1.15 × 10−2 | 129.83 | 43.27 |
6 | C8H17 | 8 | 29 | 3.17 × 10−4 | 7.10 × 10−5 | 4.46 | 0.999 | 2.59 × 10−6 | 3.17 × 10−4 | 4.59 × 10−4 | 3.17 × 10−4 | 146.33 | 42.84 |
7 | C9H19 | 9 | 21 | 9.47 × 10−5 | 2.80 × 10−5 | 3.38 | 0.995 | 1.40 × 10−5 | 9.47 × 10−5 | 1.51 × 10−4 | 9.47 × 10−5 | 162.84 | 42.45 |
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Stopková, L.; Gališinová, J.; Šuchtová, Z.; Čižmárik, J.; Andriamainty, F. Determination of Critical Micellar Concentration of Homologous 2-Alkoxyphenylcarbamoyloxyethyl-Morpholinium Chlorides. Molecules 2018, 23, 1064. https://doi.org/10.3390/molecules23051064
Stopková L, Gališinová J, Šuchtová Z, Čižmárik J, Andriamainty F. Determination of Critical Micellar Concentration of Homologous 2-Alkoxyphenylcarbamoyloxyethyl-Morpholinium Chlorides. Molecules. 2018; 23(5):1064. https://doi.org/10.3390/molecules23051064
Chicago/Turabian StyleStopková, Lenka, Jana Gališinová, Zuzana Šuchtová, Jozef Čižmárik, and Fils Andriamainty. 2018. "Determination of Critical Micellar Concentration of Homologous 2-Alkoxyphenylcarbamoyloxyethyl-Morpholinium Chlorides" Molecules 23, no. 5: 1064. https://doi.org/10.3390/molecules23051064
APA StyleStopková, L., Gališinová, J., Šuchtová, Z., Čižmárik, J., & Andriamainty, F. (2018). Determination of Critical Micellar Concentration of Homologous 2-Alkoxyphenylcarbamoyloxyethyl-Morpholinium Chlorides. Molecules, 23(5), 1064. https://doi.org/10.3390/molecules23051064