Search Results (490)

The scarcity of natural aggregates and the accumulation of oil sludge in desert regions pose critical challenges for highway construction. Although aeolian sand and oil sludge pyrolysis residue have been studied individually as construction materials, their combined use in foamed lightweight soil remains unexplored. This study addresses this gap by developing a novel foamed lightweight soil termed SOFS, which is created through the synergistic modification of aeolian sand and oil sludge pyrolysis residue. A six-factor, five-level orthogonal array (L25) was employed to systematically investigate the effects of residue content, sand content, foam-to-slurry ratio, foaming agent dilution, water-to-solid ratio, and mixing time. The evaluated properties included physical properties (fluidity and wet density), mechanical properties (compressive, splitting tensile, and flexural strength), and durability (wet–dry and freeze–thaw resistance). Scanning electron microscopy was used to examine the microstructural mechanisms. Variance and range analysis identified the optimal mixture, designated H14, which achieved 28-day compressive, splitting tensile, and flexural strengths of 3.75 MPa, 2.21 MPa, and 0.9 MPa, respectively, thereby meeting desert roadbed requirements. Compared with conventional materials, H14 exhibited superior durability, with strength losses of only 16.3% in compressive strength and 19.1% in splitting tensile strength after 25 cycles. Microstructural analysis revealed a dense C-S-H gel network encapsulating the solid waste particles, with nanoscale Al- and Cl-rich crystalline phases observed at interfacial pores—a phenomenon that has rarely been documented in previous studies. These findings provide a theoretical and technical foundation for solid waste valorization and the development of sustainable desert infrastructure. Full article

This paper develops foamed mixture lightweight soil (FMLS) using dredged soil for ecological floating landscapes applications, focusing on key performance indices including dry density, compressive strength, splitting tensile strength, water absorption, and fluidity. Orthogonal experiments determined the optimal mix ratio, while CaO expansion agent, MgO expansion agent, polypropylene fiber (PPF), and basalt fiber (BF) were employed to modify material properties. The microstructural mechanisms of FMLS before and after modification were characterized by scanning electron microscopy (SEM). The results show that FMLS achieves optimal comprehensive performance at a cement-to-sand ratio of 0.4, foam content of 10%, and water-to-sand ratio of 0.35, with all parameters conforming to technical specifications. The optimal dosage for both CaO and MgO expansion agents is 5%, PPF is 0.3% and BF is 0.5%, respectively. MgO expansion agent and PPF demonstrate superior suitability for floating landscapes due to enhanced pore-filling efficiency and crack-bridging effects by SEM. Finally, correlation analysis further indicates that the water–binder ratio critically governs the strength characteristics of FMLS. This paper not only provides a new direction to promote the effective use of dredged soil resources, but also provides new ideas for carrier materials for ecological floating landscapes. Full article

Opal glass, known for its mechanical strength, hygiene, and aesthetic appeal, contains fluorides that hinder recycling and often lead to landfilling. This study investigates the use of discarded opal glass for the production of sustainable alkali-activated materials (AAMs), contributing to waste valorization and reduced raw material consumption. By optimizing the activation process, dense products with high compressive strength, comparable to conventional concretes, were obtained using low-molarity alkaline solutions and low-temperature curing (60 °C). In addition, lightweight porous structures with porosity exceeding 80% were successfully produced through direct foaming and salt templating. The developed materials exhibited good chemical stability under aggressive conditions. Preliminary biological tests indicated antimicrobial activity and low toxicity, supporting their potential use in applications where hygiene and durability are important. The results highlight the versatility of mild alkali activation for transforming waste opal glass into dense and porous materials with tunable properties. Full article

Magnesium hydroxide is attracting growing interest as a versatile, halogen-free flame retardant, and this review surveys its production routes, structure–property relationships and use in polymer systems from commodity polyolefins to advanced bio-based materials. Industrial Mg(OH)₂ is still predominantly obtained from mining or hydration of MgO, but increasing attention is being devoted to recovery from seawater and saltwork brines, where precipitation from Mg²⁺-rich streams followed by controlled rehydration or direct precipitation yields fine, high-purity powders suitable for flame retardant use and simultaneously valorizes saline wastes. In parallel, hydrothermal synthesis has been extensively explored to tailor particle size and morphology by adjusting the precursor, solvent, temperature and time, enabling high-surface-area Mg(OH)₂ or MgO with narrow size distributions that are attractive for high-performance composites also evaluated via ball milling, crushing and refining. More recently, process intensification strategies such as microwaves and ultrasounds have been proposed to shorten reaction times, lower temperatures and better control nucleation and growth, opening paths toward energy efficient production of structured Mg(OH)₂ from both conventional and brine-derived precursors. The second part of the review analyzes how the intrinsic endothermic decomposition and basic character of Mg(OH)₂ can be utilized across a broad range of polymer matrices and how surface functionalization strategies extend its applicability. In addition to “as received” powders, stearic acid and other fatty acids, metal soaps and various organic coupling agents are widely used to render the surface more hydrophobic, enhance dispersion and interfacial adhesion, and in some cases introduce additional char-forming or barrier functionality. In terms of the application, the review methodically synthesizes and contrasts fire and mechanical data for Mg(OH)₂-containing polyolefins (HDPE, LLDPE, PP and EVA) utilized in cables and building products, expandable polymers and foams, biopolymers (PLA and PBS), and elastomers. The review places particular emphasis on the balance between loading level, processability, flame performance and mechanical integrity. This review aims to provide a comprehensive framework for designing next-generation Mg(OH)₂-based flame-retardant systems for both conventional and emerging polymer technologies. To this end, it integrates advances in sustainable feedstocks, controlled synthesis and surface engineering with the rapidly expanding application space. Full article

Microplastic contamination in wetland ecosystems is an escalating environmental threat, compromising ecosystem services, biogeochemical cycling and biodiversity conservation. This study assessed the occurrence, distribution and physicochemical characteristics of microplastics in the Ramsar-designated Pallikaranai wetland, southern India. Six representative subsamples were collected from spatially distinct locations and analyzed using density separation, followed by polymer identification via Raman spectroscopy and energy-dispersive X-ray spectroscopy (EDS). Microplastics were ubiquitously detected across both sediment and water matrices, with significantly higher abundances in sediments, indicating their role as a major sink. The dominant polymer types, polyethylene (PE), polypropylene (PP) and polystyrene (PS), along with prevalent morphotypes such as fragments, fibers, beads and foams, reflect diverse and persistent anthropogenic inputs. The compositional profile strongly implicates mismanaged domestic and urban waste as the primary source. The widespread presence and accumulation of microplastics in this ecologically sensitive wetland raise concerns over potential impacts on trophic interactions, habitat quality and long-term ecosystem resilience. These findings underscore the urgent need for targeted waste management strategies, pollution mitigation frameworks and continuous monitoring to safeguard the ecological integrity of the Pallikaranai wetland and similar Ramsar-listed ecosystems. Full article

This study presents a green-intensified system for the production of bio-based polyurethane foam using waste cooking oil (WCO) as the primary polyol source. The experimental setup was specifically designed to apply the concept of green intensification by integrating cavitation energy generated through ultrasonic irradiation with a high-shear mixing system. This hybrid approach facilitates the effective mixing of WCO-based bio-polyol with isocyanate, enhancing the reaction during foam formation. An ultrasonic atomizer was employed to convert water into a fine mist, which was then introduced into the reaction mixture using a controlled air blower. The misted water serves as an eco-friendly blowing agent, improving its dispersion within the polyol matrix. The results indicate that this method prolongs gel time, suggesting a more controlled and gradual blowing reaction. Furthermore, the combined use of ultrasonic irradiation and high-shear mixing significantly reduced foam density and produced a finer, more uniform cellular structure. These findings demonstrate that ultrasonic-assisted misting and emulsification not only enhance process efficiency but also contribute to the environmentally sustainable synthesis of bio-polyurethane foam. Full article

This study evaluates the feasibility of using waste Bakelite thermoset as a slag foaming and iron oxide reduction agent in electric arc furnace (EAF) steelmaking. Bakelite was blended with metallurgical coke at three ratios (10–30 wt% Bakelite), designated as Blend#1 to Blend#3. All carbon samples were heat-treated at 1000 °C under an argon atmosphere to produce char and were subsequently assessed for carbon–slag interactions at 1550 °C, with emphasis on slag foaming behavior and FeO reduction. The incorporation of Bakelite increased the total carbon content and significantly altered coke ash chemistry, marked by reduced SiO₂ and Al₂O₃ and increased CaO contents. Structural analysis revealed enhanced carbon graphitization with increasing Bakelite proportion. Among all samples, Blend#3 exhibited the most stable and pronounced slag foaming, achieving a maximum volume ratio of approximately 1.7 and forming uniformly distributed, multi-sized gas bubbles within the slag. FeO reduction improved with Bakelite addition, with metallization degrees of 77.30, 81.65, 80.56, and 84.41% for coke, Blend#1, Blend#2, and Blend#3, respectively. Blend#3 produced the lowest total gas emission (186,000 ppm), approximately 30% lower than that of pure coke. These findings demonstrate that waste Bakelite thermoset is an effective low-carbon alternative carbon source for EAF steelmaking, enhancing FeO reduction, slag foaming stability, and overall environmental performance. Full article

Promoting construction waste utilization, this study explores using 30% mass fraction recycled micro powder (brick/concrete/hybrid) to replace cement in A03 foam concrete, as well as microbial foaming agents for insulation boards. The results show that hybrid micro powder foam concrete achieved higher compressive strength (0.7 MPa, 0.65 MPa) than pure brick (0.54 MPa) and concrete powder (0.61 MPa). For 30% hybrid micro powder insulation boards (brick:concrete ratios 2:8–8:2), when the ratio is 4:6, their performance meets JC/T 2200-2013 standards. At this point, the compressive strength is 0.43 MPa, the drying shrinkage is 0.29 mm, and the thermal conductivity 0.062 is W/(m·K). As the proportion of recycled brick powder increases, the material properties first improve and then decline, indicating that the proportion of recycled brick powder has a significant impact on the material’s overall performance; within an appropriate range, optimal performance can be achieved. Full article

This study presents a novel, rapidly synthesized geopolymer foam fabricated from granite industrial waste using microwave sintering, reducing the demolding time from 7 days to 3 min and the overall processing time to 24 h, while enhancing mechanical performance. Five sample compositions (G1–G5) were prepared with varying granite powder and alkaline solution ratios, cured in a microwave for 3 min, and sintered for an additional 3 min. X-ray fluorescence (XRF), compressive strength tests, water absorption, thermogravimetric analysis (TGA), differential thermal analysis (DTA), and Fourier transform infrared spectroscopy (FTIR) were used for thorough characterization. The compressive strength increased progressively from 13 MPa (G1) to 20 MPa (G5), the total porosity decreased from 33.33% to 18.58%, the water absorption reached a minimum of 2.02% (G5), and the bulk density rose from 1.143 to 1.49 g/cm³. XRF analysis confirmed Si/Al molar ratios of 6.5–11.4, indicating enhanced aluminosilicate network development. FTIR confirmed progressive geopolymerization, with integrated Si-O-T band areas increasing from 41,900 a.u. (G1) to 44,680 a.u. (G5). The microwave sintering approach consumed over 90% less active energy than conventional thermal curing, significantly reducing associated CO₂ emissions and thereby supporting SDG 7, SDG 12, and SDG 13. These results position granite-waste-derived geopolymer foam as a high-performance, energy-efficient alternative to conventional fired bricks and cement-based construction materials. Full article

Gravelly soil is widely used in western China but suffers from poor gradation, low water stability, and weak freeze–thaw resistance. Traditional cementitious stabilizers involve high energy and carbon emissions. To address these issues, a novel, eco-friendly gravelly soil stabilizer was prepared from waste foamed concrete (WFC) via crushing, ball milling, and high-temperature calcination. This study systematically evaluated stabilization performance and mechanisms. Results indicate that the WFC stabilizer significantly enhances soil properties. At the optimal 30% dosage, the 28-day unconfined compressive strength (UCS) reached 6.5 MPa (a 333% increase), and water stability was significantly improved. Under freeze–thaw conditions, the 30% dosage yielded a mere 2% mass loss after five cycles, with the UCS reaching 9.56 MPa (a 437% increase). Microstructural analyses (XRD, SEM) revealed that hydration generates calcium silicate hydrate (C-S-H) gel and katoite (Ca₃Al₂(SiO₄)_3−x(OH)_4x). These products effectively fill soil pores and the spaces of the particles, optimizing the microstructure. This study provides a sustainable pathway for WFC recycling and offers a relatively lower energy consumption, low-carbon and high-performance stabilizer for reinforcing gravelly soil subgrades in cold regions. Full article

Sulfur–soybean oil polymers with tunable thermal insulation properties were synthesized via inverse vulcanization of elemental sulfur and soybean oil and reinforced with biochar (BC) derived from spent barley biomass. Biopolymer films (F-BPs) with sulfur contents ranging from 20 to 80 wt% were prepared, and biochar-filled biocomposites (F-BP-Cs) were obtained using different filler loadings and processing routes. Their structural, morphological, thermal, mechanical, and surface properties were systematically analyzed to establish structure–property relationships, with particular focus on thermal transport behavior. Differential scanning calorimetry (DSC) revealed that sulfur contents ≤ 50 wt% favored the chemical incorporation of elemental sulfur into the polymer network via covalent bonding, significantly reducing the presence of free crystalline sulfur in the material. SEM images and porosity analysis revealed that BC incorporation and processing conditions significantly affected microstructural connectivity and air-filled porosity. As a result, F-BP-C materials exhibited low thermal conductivities, reaching values of ~0.033–0.039 W/(m·K), comparable to commercial insulating materials such as cork and polymeric foams. This reduction was attributed to increased structural disorder, high interfacial density, and enhanced phonon scattering within the heterogeneous polymer–BC–air system. These findings demonstrate the potential of these biocomposites as sustainable thermal insulating materials derived from industrial and agricultural waste. Full article

Red mud, as a by-product of alkaline regeneration of alumina, has limited application due to its strong alkalinity, fine particle size, and complex composition. In this work, red mud porous ceramics with uniform pore size distribution and high mechanical strength were prepared using a foam-gel casting method. The effects of solid loading and sintering temperature on the microstructure of porous ceramics were systematically investigated. The porosity of red mud-based porousceramics sintered at 1150 °C with a solid content of 60.4% was 33.7%, and the maximum compressive strength was 54.70 MPa, while the porousceramics prepared with a solid loading of 34.1% and sintered at 1050 °C achieved a maximum porosity of 79.7% and a compressive strength of 2.36 MPa. Increasing the solid loading reduced porosity and enhanced compressive strength, allowing for the tailoring of mechanical properties to meet specific application requirements. Higher sintering temperature promoted the formation of the liquid phase, enhanced particle bonding, and further improved the compressive strength. Additionally, toxicity leaching tests confirmed that the ceramics are environmentally safe, with leachate levels well within regulated limits. These results demonstrate the potential of foam-gel casting as an effective route for transforming red mud into value-added porous ceramics, thereby contributing to sustainable waste utilization and broadening the application prospects of red mud-based materials. Full article

This study evaluates the performance of foamed geopolymer concrete (FGC) incorporating rigid polyurethane (PU) waste as a partial sand replacement and aluminum powder (AP, 1%) as a foaming agent. The mixtures were based on metakaolin, fly ash, and silica fume. Fresh and hardened properties were assessed, including workability, setting time, density, compressive strength, flexural strength, splitting tensile strength, elastic modulus, water absorption, porosity, gas permeability, and chloride ion penetration. Microstructural characteristics were examined using scanning electron microscopy (SEM). The results show that moderate PU incorporation significantly enhances mechanical performance. The optimal mixture (PU30) achieved a compressive strength of 47.25 MPa at 180 days, representing a 15.6% increase compared to the control. Flexural and splitting tensile strengths improved by 19.9% and 16.7%, respectively, while the elastic modulus increased by 33.8% to 0.95 GPa. These improvements are attributed to enhanced particle packing and more efficient stress transfer within the matrix. In contrast, higher PU contents (>30%) reduced mechanical performance due to increased total porosity and weakened interfacial bonding. Durability-related properties indicated that mixtures PU20–PU30 exhibited reduced permeability and optimized pore structure, characterized by lower pore connectivity. SEM observations confirmed a denser matrix with uniformly distributed pores at optimal PU levels. Additionally, the integration of Random Forest regression with GLCM-based texture analysis demonstrated strong capability in predicting mechanical properties from SEM images. Overall, the combined use of PU waste and AP enables the production of lightweight, structurally efficient, and sustainable FGC with improved mechanical and durability performance. Full article

The urgent global need for sustainable infrastructure drives the demand for high-value buildings and waste removal. This paper studies the feasibility of using recycled foam concrete aggregate (FCA) as a substitute for natural coarse aggregate (NCA) in concrete and studies its impact on rheology, mechanical degradation, shear resistance, and the full-range replacement ratio (0–100). The experimental results show that the monotonic change in the workability of fresh concrete determines the lubrication threshold at 60% replacement, which is driven by the volume proportion effect. Beyond this value, capillary suction dominates, and the viscosity rises rapidly. From a mechanical perspective, the porous structure of FCA is conducive to “internal curing” so that moisture is released from the drying interface, but it also becomes a source of defects that change the fault topology. Specifically, the critical transition of the shear failure mode shifts from the debonding of the interface to the crushing of the cross-particle aggregate. At this time, the shear capacity decreases substantially, experiencing a reduction of 71.8% when completely replaced. There is a strong correlation between ultrasonic pulse velocity (UPV), rebound number, and compressive strength, and a multivariate nonlinear regression model (R² > 0.85) with non-destructive strength prediction is ultimately obtained. Based on the balance between mechanical capacity and resource cyclability, an optimal alternative zone of 20% to 40% is proposed. This work not only provides a mechanism for multi-scale coupling between pore structure and structural properties but also provides a data-driven method for the safety assessment of lightweight recycled aggregate concrete (RAC). Full article

Construction industry remains a major driver of global resource use and waste generation, therefore, identifying sustainable material alternatives is increasingly important. Recycled-textile-based insulation presents a promising pathway to support circular economy principles by diverting post-consumer waste from landfills and reducing reliance on virgin petrochemical materials. This study conducts a cradle-to-gate life cycle assessment (LCA) using SimaPro to compare polyurethane (PU) foam and recycled denim (cotton fiber) insulation. The system boundary includes raw material extraction, transportation, and manufacturing. A functional unit of 1 m² of installed insulation with a thermal resistance of RSI = 1 m²·K/W at the factory gate ensures comparability, with mass-based results reported as secondary metrics. The results indicate that recycled denim exhibits higher embodied carbon per unit mass, despite lower production energy and lower cradle-to-gate impacts per installed area, reinforcing the need for a declared-unit-based comparison tied to thermal performance. Air leakage is evaluated separately as a complementary performance indicator influencing in-service energy behavior showing significantly lower air leakage for PU; but is not included in the cradle-to-gate normalization. However, it could be argued that materials with improved airtightness may enable the use of reduced insulation thickness while still achieving equivalent performance, thereby potentially lowering overall material demand. Nevertheless, recycled denim offers environmental advantages by reducing landfill waste and promoting resource conservation through material reuse. A transient coupled heat–moisture model in COMSOL Multiphysics, using climate data from Arizona and Florida, further reveals that denim absorbs more moisture than polyurethane. This leads to larger heat flux fluctuations, highlighting a trade-off between denim’s sustainability advantages and its reduced hygrothermal durability. Overall, these findings demonstrate the limitations of single-metric comparisons and emphasize the need for performance-based, multi-criteria assessments that integrate functional efficiency with circularity. Future research should incorporate occupant health and comfort to enable a more comprehensive evaluation of insulation sustainability. Full article