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Keywords = waste GFRP

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20 pages, 6178 KiB  
Article
General Evaluation of the Recyclability of Polyester-Glass Laminates Used to Reinforce Steel Tanks
by Sławomir Stelmach, Dawid Gacki, Mateusz Szul, Kamil Słowiński, Tomasz Radko and Małgorzata Wojtaszek-Kalaitzidi
Sustainability 2025, 17(9), 4199; https://doi.org/10.3390/su17094199 - 6 May 2025
Viewed by 395
Abstract
Polyester-glass laminates are widely used to reinforce underground steel fuel tanks due to their excellent corrosion resistance and mechanical performance. However, the management of these composites at the end of their service life poses significant challenges, particularly in terms of material recovery and [...] Read more.
Polyester-glass laminates are widely used to reinforce underground steel fuel tanks due to their excellent corrosion resistance and mechanical performance. However, the management of these composites at the end of their service life poses significant challenges, particularly in terms of material recovery and environmental impact. This study investigates both the structural benefits and recyclability of polyester-glass laminates. Numerical simulations confirmed that reinforcing corroded steel tank shells with a 5 mm GFRP (Glass Fiber Reinforced Polymer) coating reduced the maximum equivalent stress by nearly 50%, significantly improving mechanical integrity. In parallel, thermogravimetric and microscopic analyses were conducted on waste GFRP samples subjected to pyrolysis, gasification, and combustion. Among the methods tested, pyrolysis proved to be the most favorable, allowing substantial organic degradation while preserving the structural integrity of the glass fiber fraction. However, microscopy revealed that the fibers were embedded in a dense char matrix, requiring additional separation processes. Although combustion leaves the fibers physically loose, pyrolysis is favored due to better preservation of fiber mechanical properties. Combustion resulted in loose and morphologically intact fibers but exposed them to high temperatures, which, according to the literature, may reduce their mechanical strength. Gasification showed intermediate performance in terms of energy recovery and fiber preservation. The findings suggest that pyrolysis offers the best trade-off between environmental performance and fiber recovery potential, provided that appropriate post-treatment is applied. This work supports the use of pyrolysis as a technically and environmentally viable strategy for recycling polyester-glass laminates and encourages further development of closed-loop composite waste management. Full article
(This article belongs to the Special Issue Solid Waste Management and Recycling for a Sustainable World)
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42 pages, 4134 KiB  
Review
Solvent-Based Recycling as a Waste Management Strategy for Fibre-Reinforced Polymers: Current State of the Art
by Matthew J. Keith, Bushra Al-Duri, Tom O. McDonald and Gary A. Leeke
Polymers 2025, 17(7), 843; https://doi.org/10.3390/polym17070843 - 21 Mar 2025
Viewed by 1426
Abstract
The growing use of fibre-reinforced polymers (FRPs) is driving a demand for the development of sustainable end-of-life strategies. Solvolysis, a chemical recycling method using solvents to decompose the polymer matrix, has emerged as a promising approach for reclaiming both fibres and organic compounds [...] Read more.
The growing use of fibre-reinforced polymers (FRPs) is driving a demand for the development of sustainable end-of-life strategies. Solvolysis, a chemical recycling method using solvents to decompose the polymer matrix, has emerged as a promising approach for reclaiming both fibres and organic compounds from FRP waste. This work provides a comprehensive overview of solvolysis techniques by discussing the environmental benefits and economic opportunities of this technology, summarising the process conditions, and evaluating the characteristics of the recovered products. The economic viability of solvolysis lies in recovering high-value components; predominantly carbon fibres from CFRPs and organic products from GFRPs, which are suitable for reuse or as a feedstock for new composites. Solvolysis can operate under low temperature and pressure (LTP) or high temperature and pressure (HTP) conditions. The choice of solvent, catalyst, reaction time, and temperature is crucial to achieving high resin decomposition while preserving fibre properties. To achieve an economically viable and environmentally beneficial process, it will be essential to optimise these parameters. A key challenge is maintaining the strength and surface properties of the recovered fibres, as degradation in their performance can limit their suitability for high-performance applications. The implication of this is that, without careful consideration of the recycling process, FRPs cannot be fully circular. They will be continuously downgraded into low-value applications and ultimately incinerated or landfilled. This review further explores the diversity of organic products obtained, which can range from monomers to oligomers to complex mixtures. Efficient separation and upgrading techniques, such as distillation and liquid–liquid extraction, are essential to maximise the value of the recovered organics. These additional processing steps are likely to result in greater financial and resource costs within a commercial recycling system. This review concludes with a summary of commercial solvent-based recycling ventures and an outlook on future research directions, which includes the need to develop processes capable of recovering high-value, long carbon fibres. Successful development of such a process would represent a step-change in the value proposition of a carbon fibre recycling industry. Full article
(This article belongs to the Special Issue New Polymer Fibers: Production and Applications)
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9 pages, 3998 KiB  
Proceeding Paper
Automatic Detection of Defects Using Active Thermography
by Miguel Gómez and David Castro
Eng. Proc. 2025, 90(1), 29; https://doi.org/10.3390/engproc2025090029 - 12 Mar 2025
Viewed by 592
Abstract
The increase in composite material waste from the aviation and wind energy sectors will become a significant environmental challenge in the near future. This escalation is attributed to the enhanced use of new, advanced composite materials, such as Glass Fiber Reinforced Polymer (GFRP). [...] Read more.
The increase in composite material waste from the aviation and wind energy sectors will become a significant environmental challenge in the near future. This escalation is attributed to the enhanced use of new, advanced composite materials, such as Glass Fiber Reinforced Polymer (GFRP). Despite their benefits, the disposal of these materials at their end-of-life poses considerable environmental and logistical challenges. Assessing the condition of these materials is thus pivotal to develop sustainable strategies for their recycling, reusing, or repurposing. This study investigates the use of Non-Destructive Testing (NDT) techniques, with a focus on Active Thermography, to evaluate GFRP components’ suitability for sustainable management without compromising the material integrity. This research highlights the use of Active Thermography for extensive, non-invasive inspections, due to its capability to inspect a large area quickly using external energy heating. It delves into Pulse Phase Thermography (PPT) and Principal Component Thermography (PCT), two advanced signal post-processing techniques, tested on GFRP materials with purposefully induced defects. Finally, an automated method based on the Signal-to-Noise Ratio (SNR) value is implemented for defect detection, with which defects of a 5 mm diameter and a 3 mm depth can be detected. The document elaborates on the theoretical principle of NDT, PPT, and PCT, details the experimental methodology and specimens, and analyzes the outcomes of employing these techniques, drawing comparisons between them. Full article
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22 pages, 7879 KiB  
Article
Mechanical Properties of Concrete Mixes with Selectively Crushed Wind Turbine Blade: Comparison with Raw-Crushing
by Víctor Revilla-Cuesta, Ana B. Espinosa, Roberto Serrano-López, Marta Skaf and Juan M. Manso
Materials 2024, 17(24), 6299; https://doi.org/10.3390/ma17246299 - 23 Dec 2024
Cited by 3 | Viewed by 879
Abstract
The glass fiber-reinforced polymer (GFRP) materials of wind turbine blades can be recovered and recycled by crushing, thereby solving one of the most perplexing problems facing the wind energy sector. This process yields selectively crushed wind turbine blade (SCWTB), a novel waste that [...] Read more.
The glass fiber-reinforced polymer (GFRP) materials of wind turbine blades can be recovered and recycled by crushing, thereby solving one of the most perplexing problems facing the wind energy sector. This process yields selectively crushed wind turbine blade (SCWTB), a novel waste that is almost exclusively composed of GFRP composite fibers that can be revalued in terms of their use as a raw material in concrete production. In this research, the fresh and mechanical performance of concrete made with 1.5%, 3.0%, 4.5%, and 6.0% SCWTB is studied. Once incorporated into concrete mixes, SCWTB waste slightly reduced slumps due to the large specific surface area of the fibers, and the stitching effect of the fibers on mechanical behavior was generally adequate, as scanning electron microscopy demonstrated good fiber adhesion within the cementitious matrix. Thus, despite the increase in the content of water and plasticizers when adding this waste to preserve workability, the compressive strength only decreased in the long term with the addition of 6.0% SCWTB, a value of 45 MPa always being reached at 28 days; Poisson’s coefficient remained constant from 3.0% SCWTB; splitting tensile strength was maintained at around 4.7 MPa up to additions of 3.0% SCWTB; and the flexural strength of mixes containing 6.0% and 1.5% SCWTB was statistically equal, with a value near 6.1 MPa. Furthermore, all mechanical properties of the concrete except for flexural strength were improved with additions of SCWTB compared to raw crushed wind turbine blade, which apart from GFRP composite fibers contains approximately spherical polymer and balsa wood particles. Flexural strength was conditioned by the proportion of fibers, their dimensions, and their strength, which were almost identical for both waste types. SCWTB would be preferable for applications in which compression stresses predominate. Full article
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24 pages, 11911 KiB  
Article
Development of a Modular Sandwich Panel with a Composite Core of Recycled Material for Application in Sustainable Building
by Juan José Valenzuela Expósito, Elena Picazo Camilo and Francisco Antonio Corpas Iglesias
Polymers 2024, 16(24), 3604; https://doi.org/10.3390/polym16243604 - 23 Dec 2024
Cited by 6 | Viewed by 1722
Abstract
In recent years, the construction industry has faced challenges related to rising material costs, labor shortages and environmental sustainability, resulting in an increased interest in modular construction cores composed of recycled materials, such as XPS, PUR, PLW and GFRP, from waste from the [...] Read more.
In recent years, the construction industry has faced challenges related to rising material costs, labor shortages and environmental sustainability, resulting in an increased interest in modular construction cores composed of recycled materials, such as XPS, PUR, PLW and GFRP, from waste from the truck body industry. Two resins, PUR and polyester, were used to bond these recycled composites. Physical, chemical and mechanical analyses showed that the panels formed with PUR resin had superior workability due to the higher open time of the resin, 11.3% better thermal conductivity than the commercial PLW panel (SP-PLW) and reduced porosity compared to those using polyester resin. The mechanical performance of the panels improved with higher structural reinforcement content (PLW and GFRP). Compared to a commercial panel (SP-PLW), the SP-RCM1 recycled panel showed 4% higher performance, demonstrating its potential for sustainable building applications. Thermal and microscopic characterizations showed good adhesion of the materials in the best performing formulations related to higher thermal stability. Therefore, this research aims to demonstrate the feasibility of using waste from the car industry in the manufacture of sandwich panels for modular construction to address these issues. Full article
(This article belongs to the Section Circular and Green Sustainable Polymer Science)
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23 pages, 12740 KiB  
Article
Initial Approach to Self-Compacting Concrete with Raw-Crushed Wind-Turbine Blade: Fresh, CFD and Mechanical Analysis
by Manuel Hernando-Revenga, Víctor Revilla-Cuesta, José A. Chica, Vanesa Ortega-López and Juan M. Manso
Appl. Sci. 2024, 14(21), 9946; https://doi.org/10.3390/app14219946 - 30 Oct 2024
Cited by 1 | Viewed by 979
Abstract
The production of raw-crushed wind-turbine blade (RCWTB) and its addition to conventionally designed self-compacting Concrete (SCC) enable us to provide a second life to wind-turbine blades. However, SCC containing RCWTB must show proper fresh behavior, an aspect evaluated in this paper both experimentally [...] Read more.
The production of raw-crushed wind-turbine blade (RCWTB) and its addition to conventionally designed self-compacting Concrete (SCC) enable us to provide a second life to wind-turbine blades. However, SCC containing RCWTB must show proper fresh behavior, an aspect evaluated in this paper both experimentally and through simulations based on computational fluid dynamics (CFD) for RCWTB additions up to 3.0% by volume. In experimental terms, RCWTB reduced the flowability and passing ability of SCC, and slowed SCC flow, although the performance of SCC with 1.5% RCWTB was adequate under free-flow conditions. In terms of modeling, RCWTB did not impact yield stress and increased plastic viscosity. CFD modeling under free flow, regardless of the presence or not of obstacles simulating concrete reinforcement, was successful, especially in the long term. Nevertheless, the modeling of the passing ability was not accurate; precision could be improved by simulating the effect of the individual GFRP fibers within the SCC flow. Finally, the mechanical properties of SCC were negatively impacted by RCWTB, the stitching effect of the GFRP fibers not being effective in an SCC with a conventional design. A specific SCC design when adding RCWTB is therefore needed to advance in the use of this waste in this concrete type. Full article
(This article belongs to the Section Materials Science and Engineering)
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28 pages, 7910 KiB  
Article
Study on the Bonding Properties of Reinforced Reef Limestone Concrete and Its Influencing Factors
by Jinxin Huang, Kun Xu, Wenjun Xiao, Wei Nie, Jun Zhou, Jiang Luo, Mengchen Zhang and Xiqi Liu
Buildings 2024, 14(7), 2133; https://doi.org/10.3390/buildings14072133 - 11 Jul 2024
Cited by 3 | Viewed by 877
Abstract
Reinforced concrete structures play a pivotal role in island and reef engineering projects. Given the resource constraints typical of island regions, substituting traditional manufactured sand aggregate with reef limestone not only reduces reliance on river sand but also addresses the issue of disposing [...] Read more.
Reinforced concrete structures play a pivotal role in island and reef engineering projects. Given the resource constraints typical of island regions, substituting traditional manufactured sand aggregate with reef limestone not only reduces reliance on river sand but also addresses the issue of disposing of waste reef limestone slag generated during excavation. However, the performance characteristics of reef limestone concrete, particularly its bond strength with reinforcing steel, warrant further investigation. This is particularly true for the bond–slip behavior of the reinforcement. This study aims to elucidate the effects of various parameters on the bond performance between steel and reef limestone concrete through central pullout tests. These parameters include the type and diameter of the reinforcement, bond length, and loading rate. The investigation encompasses the analysis of load–slip curves, bond failure modes, and variations in bond stress. Additionally, using the Abaqus software, a numerical simulation was conducted to analyze the mesoscopic stress characteristics, thereby revealing the mechanisms of bond formation and failure modes between steel reinforcement and reef limestone concrete. The results indicate that the bond–slip curve for reef limestone concrete reinforced with ribbed rebars and Glass Fiber-Reinforced Polymer (GFRP) rebars can be broadly categorized into four phases: minor slip, slip, decline, and residual, with the residual phase exhibiting a wave-like pattern. The predominant failure modes in reef limestone concrete are either pulling out or splitting. The bond stress in reef limestone concrete decreases with an increase in rebar diameter and bond length; conversely, it increases with the loading rate, although the ultimate slip decreases. The mesoscopic failure characteristics of reinforced reef limestone concrete, as simulated in Abaqus, are consistent with the experimental outcomes. Full article
(This article belongs to the Special Issue Low-Carbon Material Engineering in Construction)
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16 pages, 3657 KiB  
Article
The Effects of Replacing Sand with Glass Fiber-Reinforced Polymer (GFRP) Waste on the Mechanical Properties of Cement Mortars
by Youssef El Bitouri, Bouagui Fofana, Romain Léger, Didier Perrin and Patrick Ienny
Eng 2024, 5(1), 266-281; https://doi.org/10.3390/eng5010014 - 29 Jan 2024
Cited by 9 | Viewed by 2284
Abstract
The aim of this study is to examine the effect of the partial replacement of sand by Glass Fiber-Reinforced Polymer (GFRP) waste on the mechanical properties of cement mortars. Compressive and flexural tests were carried out on mortars containing 0, 3, 5, 10, [...] Read more.
The aim of this study is to examine the effect of the partial replacement of sand by Glass Fiber-Reinforced Polymer (GFRP) waste on the mechanical properties of cement mortars. Compressive and flexural tests were carried out on mortars containing 0, 3, 5, 10, and 15% (by volume) of GFRP waste. It appears that the incorporation of 3% GFRP waste did not significantly affect the mechanical strength. However, further increasing the GFRP waste content led to a reduction in the mechanical strength. The flexural strength seemed less affected than the compressive strength, since the decrease in flexural strength at a 10% replacement was only 37%, while it was 54% for the compressive strength. However, an improvement in the toughness of the mortar with an increase in the substitution rate was observed. The reference sample displayed a flexural toughness of 0.351 N·m, while the mortar incorporating 15% of GFRP exhibited a flexural toughness of 0.642 N·m. The reuse of GFRP waste in cementitious materials, therefore, constitutes an interesting recycling solution. Full article
(This article belongs to the Section Materials Engineering)
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18 pages, 12103 KiB  
Article
Effect of Glass Fiber-Reinforced Plastic Waste on the Mechanical Properties of Concrete and Evaluation of Its Feasibility for Reuse in Concrete Applications
by Tianhao Zhao, Yong Lv, Jianzhong Chen, Pengfei Song, Mingqing Sun, Xiaoyu Zhang and Li Huang
Materials 2023, 16(20), 6772; https://doi.org/10.3390/ma16206772 - 19 Oct 2023
Cited by 7 | Viewed by 2613
Abstract
The disposal of glass fiber-reinforced plastic (GFRP) waste has become an urgent issue in both the engineering and environmental fields. In this study, the feasibility of reusing mechanically recycled GFRP in concrete was evaluated. Secondary screening of the recycled material was conducted to [...] Read more.
The disposal of glass fiber-reinforced plastic (GFRP) waste has become an urgent issue in both the engineering and environmental fields. In this study, the feasibility of reusing mechanically recycled GFRP in concrete was evaluated. Secondary screening of the recycled material was conducted to obtain different types of products, and the recycled GFRP (rGFRP) was characterized. Subsequently, the effect of rGFRP on concrete performance was evaluated using different dosages (0%, 1%, 3%, 5%) of rGFRP powder and rGFRP cluster (with different sizes and fiber contents) to replace fine aggregate in concrete preparation. The experimental results indicated that the addition of rGFRP powder has no significant impact on the mechanical properties of concrete, while the addition of a small amount of rGFRP cluster slightly improves the compressive strength and splitting tensile strength of concrete. Additionally, the short fibers in rGFRP improve the failure mode of concrete, and increased fiber content and longer fiber length demonstrate a more pronounced reinforcing effect. The challenges and potential directions for future research in the realm of reusing rGFRP in concrete are discussed at the end. A systematic process for reusing GFRP waste in concrete is proposed to address the primary challenges and provide guidance for its practical engineering application. Full article
(This article belongs to the Special Issue Recycled Materials in Civil Engineering Application)
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16 pages, 3363 KiB  
Article
Study on the Utilization of Waste Thermoset Glass Fiber-Reinforced Polymer in Normal Strength Concrete and Controlled Low Strength Material
by Yeou-Fong Li, Yi-Wei Hsu, Jin-Yuan Syu, Bian-Yu Chen and Bo Song
Materials 2023, 16(9), 3552; https://doi.org/10.3390/ma16093552 - 5 May 2023
Cited by 8 | Viewed by 2405
Abstract
Thermoset glass fiber-reinforced polymers (GFRP) have been widely used in manufacturing and construction for nearly half a century, but the large amount of waste produced by this material is difficult to dispose of. In an effort to address this issue, this research investigates [...] Read more.
Thermoset glass fiber-reinforced polymers (GFRP) have been widely used in manufacturing and construction for nearly half a century, but the large amount of waste produced by this material is difficult to dispose of. In an effort to address this issue, this research investigates the reuse of thermoset GFRP waste in normal strength concrete (NSC) and controlled low-strength materials (CLSM). The mechanical performance and workability of the resulting concrete were also evaluated. To prepare the concrete specimens, the thermoset GFRP waste was first pulverized into granular pieces, which were then mixed with cement, fly ash, and water to form cylindrical concrete specimens. The results showed that when the proportion of thermoset GFRP waste aggregate in the concrete increased, the compressive strengths of NSC and CLSM would decrease. However, when incorporating 5% GFRP waste into CLSM, the compressive strength was 7% higher than concrete without GFRP. However, the workability of CLSM could be improved to meet engineering standards by adding an appropriate amount of superplasticizer. This finding suggests that the use of various combinations of proportions in the mixture during production could allow for the production of CLSM with different compressive strength needs. In addition, the use of recycled thermoset GFRP waste as a new aggregate replacement for traditional aggregates in CLSM was found to be a more sustainable alternative to the current CLSM combinations used in the market. Full article
(This article belongs to the Special Issue Strengthening, Repair, and Retrofit of Reinforced Concrete)
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11 pages, 4326 KiB  
Article
Experimental Analysis of the Performance of Doweled Connections Reinforced with Glass-Fiber-Reinforced Polymer (GFRP) in Wood Pinus spp.
by Marcos Vinício de Camargo, André Luis Christoforo, Laisa Rebeca do Vale Barcarolo and Jorge Daniel de Melo Moura
Forests 2023, 14(5), 931; https://doi.org/10.3390/f14050931 - 30 Apr 2023
Cited by 2 | Viewed by 1891
Abstract
In line with technological advancements, the construction industry worldwide has sought more efficient building systems in relation to aspects such as increased productivity, reduced material waste and meeting the growing demand. The objective of this research was to use structural joints composed of [...] Read more.
In line with technological advancements, the construction industry worldwide has sought more efficient building systems in relation to aspects such as increased productivity, reduced material waste and meeting the growing demand. The objective of this research was to use structural joints composed of composite dowels in laminated wood beams as an alternative to connect pieces of wood. Composite materials are composed of a matrix phase and a reinforcement phase and, in civil engineering, are generally applied as reinforcements in concrete structures. This article presents the structural performance of laminated pine timber with composite dowels made of fiber-reinforced polymeric resin (epoxy resin, hardener and glass fiber) (glass-fiber-reinforced polymer, GFRP) with a diameter of 12.5 mm, which was subjected to tensile force in the direction of the connection. For this, an experimental program was carried out that included characterization of the GFRP dowel, characterization of the woods used to make the connection and a tensile test of the connections with the dowels reinforced with fiberglass through a prototype designed specifically for the test. Subsequently, the results were compared with those observed in the literature. In the comparisons, it was possible to conclude that the joints with FRP pins exhibited better performance in terms of shear strength per section than those such as common nails, helical nails (Ardox) and composite structural pins (half-lap, 90°), which were 3.8 mm, 3.4 mm and 6 mm in diameter, respectively. This indicates that this composite material has potential for application in these types of connections. As an original contribution, it proves the feasibility of using this material in dowel joints for wooden structures. Full article
(This article belongs to the Section Wood Science and Forest Products)
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19 pages, 5113 KiB  
Article
Mechanical and Thermal Insulation Properties of rGFRP Fiber-Reinforced Lightweight Fly-Ash-Slag-Based Geopolymer Mortar
by Mo Zhang, Xinxin Qiu, Si Shen, Ling Wang and Yongquan Zang
Sustainability 2023, 15(9), 7200; https://doi.org/10.3390/su15097200 - 26 Apr 2023
Cited by 10 | Viewed by 2125
Abstract
As a lightweight cementitious material for thermal insulation, the mechanical performance of foamed geopolymer is always compromised by its density reduction. In this study, recycled-glass-fiber-reinforced plastic (rGFRP) fiber was used to reinforce the fly ash-slag based foamed geopolymer, and vitrified micro bubbles (VMB) [...] Read more.
As a lightweight cementitious material for thermal insulation, the mechanical performance of foamed geopolymer is always compromised by its density reduction. In this study, recycled-glass-fiber-reinforced plastic (rGFRP) fiber was used to reinforce the fly ash-slag based foamed geopolymer, and vitrified micro bubbles (VMB) were applied to further decrease the thermal conductivity and modify the resistance of the lightweight mortar against drying shrinkage. The results revealed that the density, compressive strength, and thermal conductivity of the foamed geopolymer with/without VMB decreased with the increase in foaming agent content. By adding 2~6% of rGFRP fiber, the compressive strength was increased by 25~165%, and the drying shrinkage was reduced the most, by 55%. After the addition of 10% of VMB, the density, thermal conductivity, and drying shrinkage of foamed geopolymer mortar were further decreased, with the highest reductions of 8%, 26%, and 64%, respectively, due to the reduced pore volume and increase proportion of closed pores. With 6% of rGFRP fiber and 25% of foaming agent, the lightweight geopolymer mortar had the optimum performance, with compressive strength of 1.343 MPa, thermal conductivity of 0.134 W/(m·K), and drying shrinkage of 0.095%. This study developed a sustainable lightweight mortar with multiple types of industrial by-products, which benefit both the development of thermal insulation materials and reuse of solid wastes. Full article
(This article belongs to the Special Issue Life Cycle and Sustainability of Building Materials)
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14 pages, 2920 KiB  
Article
The Effect of GFRP Powder on the High and Low-Temperature Properties of Asphalt Mastic
by Tao Zhen, Pinxue Zhao, Xing Zhang, Wei Si and Tianqing Ling
Materials 2023, 16(7), 2662; https://doi.org/10.3390/ma16072662 - 27 Mar 2023
Cited by 8 | Viewed by 1886
Abstract
Glass fiber reinforced polymer (GFRP) is the main composite material used in wind turbine blades. In recent years, zero-carbon energy sources such as wind power have been widely used to reduce carbon emissions, resulting in a large amount of waste GFRP, and causing [...] Read more.
Glass fiber reinforced polymer (GFRP) is the main composite material used in wind turbine blades. In recent years, zero-carbon energy sources such as wind power have been widely used to reduce carbon emissions, resulting in a large amount of waste GFRP, and causing serious environmental problems. To explore efficient ways to recycle waste GFRP, this study explores the impact of adding GFRP powder (nominal maximum particle size ≤ 0.075 mm) on the high and low temperature properties of asphalt mastic. Samples of GFRP asphalt mastics were prepared with filler-asphalt mass ratios of 0.01:1, 0.1:1, 0.8:1, and 1:1, as well as two control samples of limestone filler asphalt mastics with filler-asphalt mass ratios of 0.8:1 and 1:1. The study analyzed the effect of GFRP on the asphalt mastic’s performance using temperature sweep, MSCR, and BBR tests. Results showed that the presence of GFRP improved the high-temperature resistance and recovery of asphalt mastic but led to decreased low-temperature crack resistance. The results suggest that GFRP has the potential to be used as a filler in asphalt mastic, with a recommended filler-asphalt mass ratio range of less than 0.8:1 for optimal low-temperature performance. However, further research is necessary to determine the optimal content of GFRP in asphalt mastic and to study its impact on other road performance metrics. Full article
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17 pages, 5533 KiB  
Article
Development of Cellulose-Reinforced Polyurethane Coatings: A Novel Eco-Friendly Approach for Wind Turbine Blade Protection
by Shrirang M. Pathak, V. Praveen Kumar, Venkataramana Bonu, Leon Mishnaevsky, R. V. Lakshmi, Parthasarathi Bera and Harish C. Barshilia
Energies 2023, 16(4), 1730; https://doi.org/10.3390/en16041730 - 9 Feb 2023
Cited by 15 | Viewed by 3345
Abstract
Wind energy is considered a clean energy source and is predicted to be one of the primary sources of electricity. However, leading-edge erosion of wind turbine blades due to impacts from rain drops, solid particles, hailstones, bird fouling, ice, etc., is a major [...] Read more.
Wind energy is considered a clean energy source and is predicted to be one of the primary sources of electricity. However, leading-edge erosion of wind turbine blades due to impacts from rain drops, solid particles, hailstones, bird fouling, ice, etc., is a major concern for the wind energy sector that reduces annual energy production. Therefore, leading-edge protection of turbine blades has been an important topic of research and development in the last 20 years. Further, there are critical issues related to the amount of waste produced, including glass fiber, carbon fiber, and various harmful volatile organic compounds in turbine fabrication and their end-of-life phases. Hence, it is vital to use eco-friendly, solvent-free materials and to extend blade life to make wind energy a perfect clean energy source. In this study, cellulose microparticles (CMP) and cellulose microfibers (CMF) have been used as fillers to reinforce water-based polyurethane (PU) coatings developed on glass fiber reinforced polymer (GFRP) substrates by a simple spray method for the first time. Field emission scanning electron microscopy images show the agglomerated particles of CMP and fiber-like morphology of CMF. Fourier transform infrared spectra of CMP, CMF, and related coatings exhibit associated C–H, C=O, and N–H absorption bands of cellulose and polyurethane. Thermal gravimetric analysis shows that CMP is stable up to 285 °C, whereas CMF degradation is observed at 243 °C. X-ray photoelectron spectroscopy of C 1s and O 1s core levels of CMP, CMF and related coatings show C–C/C–H, C–O, C–OH, and O–C=O bonds associated with cellulose structure. The solid particle erosion resistance properties of the coatings have been evaluated with different concentrations of CMP and CMF at impact angles of 30° and 90°, and all of the coatings are observed to outperform the PU and bare GFRP substrates. Three-dimensional (3D) profiles of erosion scans confirm the shape of erosion scars, and 2D profiles have been used to calculate volume loss due to erosion. CMP-reinforced PU coating with 5 wt.% filler concentration and CMF-reinforced PU coating with 2 wt.% concentration are found to be the best-performing coatings against solid particle erosion. Nanoindentation studies have been performed to establish a relation between H3/E2 and the average erosion rate of the coatings. Full article
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22 pages, 2255 KiB  
Review
A Review of Recycling Methods for Fibre Reinforced Polymer Composites
by Jawed Qureshi
Sustainability 2022, 14(24), 16855; https://doi.org/10.3390/su142416855 - 15 Dec 2022
Cited by 67 | Viewed by 13862
Abstract
This paper presents a review of waste disposal methods for fibre reinforced polymer (FRP) materials. The methods range from waste minimisation, repurposing, reusing, recycling, incineration, and co-processing in a cement plant to dumping in a landfill. Their strength, limitations, and key points of [...] Read more.
This paper presents a review of waste disposal methods for fibre reinforced polymer (FRP) materials. The methods range from waste minimisation, repurposing, reusing, recycling, incineration, and co-processing in a cement plant to dumping in a landfill. Their strength, limitations, and key points of attention are discussed. Both glass and carbon fibre reinforced polymer (GFRP and CFRP) waste management strategies are critically reviewed. The energy demand and cost of FRP waste disposal routes are also discussed. Landfill and co-incineration are the most common and cheapest techniques to discard FRP scrap. Three main recycling pathways, including mechanical, thermal, and chemical recycling, are reviewed. Chemical recycling is the most energy-intensive and costly route. Mechanical recycling is only suitable for GFRP waste, and it has actually been used at an industrial scale by GFRP manufacturers. Chemical and thermal recycling routes are more appropriate for reclaiming carbon fibres from CFRP, where the value of reclaimed fibres is more than the cost of the recycling process. Discarding FRP waste in a sustainable manner presents a major challenge in a circular economy. With strict legislation on landfill and other environmental limits, recycling, reusing, and repurposing FRP composites will be at the forefront of sustainable waste-management strategies in the future. Full article
(This article belongs to the Collection Sustainability and Engineering Design)
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