Search Results (9,050)

In indoor thermal analyses, the effect of humid air as a radiatively participating medium that absorbs and emits energy is often neglected. This simplification can underestimate important values in the results. This study presents a numerical investigation of the humid air that participates radiatively in the conjugate heat and mass transfer convection into a room modeled as a two-dimensional square cavity with a semitransparent wall (glass). The governing equations for mass, momentum, energy, species transport, turbulence, and radiative heat transfer were solved using the Finite Volume Method and coupled with the SIMPLEC algorithm. Two scenarios were analyzed: a radiatively participating medium (RPM) and a non-participating medium (NPM), under two climatic conditions (hot and cold). Results show that considering the radiatively participating medium breaks the symmetric patterns observed in the case of NPM. The energy absorbed by humid air enhances turbulent viscosity, buoyant forces, and indoor temperature. Humid air absorbs approximately 30–32% of the incident energy entering the enclosure. Finally, a correlation for the average temperature is proposed. The results provide insight into the influence of radiatively participating humid air on indoor-like thermal behavior. The study focuses on the analysis of fundamental transport mechanisms. Full article

Given the depletion of conventional oil and gas resources, oil shale represents a promising alternative source of hydrocarbons that can be recovered through pyrolysis. This study examines the thermal decomposition of raw oil shale from the Tarfaya deposit and its decarbonized concentrate, studied by thermogravimetric analysis at different heating rates (5, 10, 20 and 40 °C/min). Pretreatment with acetic acid enabled the selective removal of calcite, confirmed by elemental, XRF, and XRD analyses, which revealed a relative enrichment in silica and dolomite in the oil shale concentrate. Pyrolysis of the raw shale occurs primarily between 300 and 500 °C, with a conversion rate of approximately 30%. In contrast, for the oil shale concentrate, the pyrolysis process begins at a relatively low temperature, within a wider temperature range (260–520 °C). Kinetic analysis based on Flynn–Wall–Ozawa (FWO) and Kissinger–Akahira–Sunose (KAS) methods shows that at a conversion rate of 60%, the activation energy achieves 14.09 kJ/mol and 10.78 kJ/mol, respectively. The results indicate that the selective removal of calcite by acetic acid treatment facilitates kerogen pyrolysis by reducing mineral–organic interactions. Indeed, calcite dilutes the reactive organic fraction and can act as a physical barrier limiting heat and mass transfer within the oil shale. Its removal improves, on the one hand, the accessibility of kerogen to thermal cracking and promotes its decomposition, and on the other hand, reduces the amount of residue after pyrolysis. In addition, the kinetic analysis based on Criado master curves reveals changes in the reaction mechanism after decarbonation treatment depending on the heating rate (β). A shift from a two-dimensional Avrami–Erofeev model (A2) to a three-dimensional model (A3) was observed at a low heating rate (β = 5 °C/min), suggesting a change in nucleation and growth dynamics during kerogen decomposition. At high heating rates (10, 20 and 40 °C/min), the thermal decomposition of kerogen combines several reaction mechanisms depending on the temperature range considered. Full article

The high-temperature corrosion (HTC) caused by H₂S poses a critical threat to the water-wall of unity boilers. To address this challenge, the present work develops a predictive corrosion depth model that integrates two critical determinants: the local concentration of H₂S and the temperature of the water-wall metal. The proposed methodology is applied to evaluate HTC risks under three distinct thermal loads: boiler maximum continuous rating (BMCR), 75% turbine heat acceptance (THA) and 50% THA. Furthermore, the protective effect of near-wall air (NWA) ratio injection using recirculated flue gas (RFG) was numerically investigated, to quantify their influence on both HTC mitigation and in-furnace combustion characteristics. Key findings indicate that at BMCR load, elevated sidewall temperatures combined with H₂S enrichment produce a peak corrosion depth of 33.7 μm. At 50% THA, the peak H₂S concentration drops sharply to 150 ppm, and the corresponding corrosion depth falls to only 7 μm. Consequently, it is recommended that NWA protection measures be implemented whenever the boiler load exceeds 50% THA. Even at a 7% NWA ratio, the impact on the furnace temperature field remains negligible. Meanwhile, it significantly reduces the corroded area and halves the peak corrosion depth, confirming that RFG-based NWA offers a flexible and effective engineering solution for mitigating HTC in coal-fired utility boilers. Full article

Toxoplasma gondii (T. gondi) is a widespread zoonotic parasite that poses a significant threat to global public health, yet effective therapeutic options remain limited. In this study, we found that the flavonoid compound myricetin (MYR) can significantly inhibit the proliferation of T. gondii. This effect is associated with the inhibition of dihydroorotase (TgDHO) activity in the de novo pyrimidine biosynthesis pathway, and this inhibition can be partially reversed by exogenous supplementation with uracil. Further studies revealed that MYR treatment can induce cell cycle arrest in tachyzoites and impair bradyzoite proliferation, concurrently disrupting the UDP-GlcNAc glycosylation of the cyst wall. In mouse models, MYR demonstrated significant efficacy, achieving an 80% survival rate in acute infection and inducing morphological abnormalities in intracerebral cysts during chronic infection. Collectively, these findings elucidate the anti-Toxoplasma activity and multifaceted mechanisms of MYR, providing valuable insights for developing novel therapeutics against toxoplasmosis. Full article

Floods are among the most frequent and destructive natural hazards, causing significant socio-economic losses worldwide. This paper presents a comprehensive review of floodwall technologies, focusing on the integration of ultra-high-performance fibre-reinforced concrete (UHPFRC) to enhance structural and hydraulic performance. Flood protection systems are categorized into permanent, demountable, and temporary, and are evaluated based on parameters such as activation time, seepage resistance, and lifecycle cost. This review examines key structural applications, including floodwall barriers, wave-energy floaters, and retaining walls, in which UHPFRC provides significant advantages such as reduced material consumption, improved impact resistance, and increased durability in harsh environmental conditions. Additionally, recent advancements in floodwall systems are critically assessed through experimental investigations, numerical modelling, and hydraulic performance under varied loading and flow conditions. The analysis reveals that while UHPFRC systems can reduce material volumes by up to 73% and carbon emissions by 49% compared to conventional reinforced concrete, their adoption is currently limited by a lack of dedicated design standards. Based on a synthesis of peer-reviewed studies (2010–2026), findings indicate that autonomous, buoyancy-driven UHPFRC barriers offer the highest reliability in high-risk zones, whereas manual modular systems remain limited by human-factor vulnerabilities during rapid deployment. Critical research gaps are identified—specifically the need for standardized constitutive models for UHPFRC in hydrostatic environments and extensive long-term field validation—to support the transition toward resilient, smart urban flood defence infrastructure. Full article

This paper presents an effective approach to reducing noise and vibration levels in ultra-high-voltage (UHV) shunt reactors based on structural optimization and damping techniques. The main sources of vibration are associated with magnetostriction of electrical steel and electromagnetic forces in the magnetic system, which induce structural excitation of the reactor tank. A combined numerical and experimental methodology is employed, including finite element modeling (FEM) of the reactor tank and field measurements of vibration displacement and acoustic noise. In contrast to previous studies focused primarily on material properties, this work emphasizes the role of structural modifications in controlling vibration transmission. The proposed solutions include the use of nitrile butadiene rubber (NBR) damping elements, optimization of the magnetic system geometry, and reinforcement of the tank structure using vertical and horizontal stiffeners. The FEM analysis in the frequency range of 50–150 Hz shows that the maximum displacement amplitude reaches 16.2 μm at the tank bottom and 10.5 μm at the tank walls. Experimental results confirm a reduction in vibration levels to 13 μm and a sound power level of 88 dBA, which meets regulatory requirements. The proposed approach improves the vibroacoustic performance and operational reliability of UHV reactors and can be effectively applied in the design of modern high-voltage power equipment. Full article

Composite hydrogen storage vessels exhibit pronounced anisotropy, multilayered winding architectures, and strong ultrasonic attenuation, which severely degrade the focusing accuracy and defect visibility of the conventional isotropic total focusing method (TFM). To address these challenges, this study proposes an enhanced TFM framework for defect inspection in composite hydrogen storage vessels by integrating anisotropic delay correction, Gray-code coded excitation, and coherence-weighted reconstruction. First, an anisotropic propagation delay model is established using forward ray tracing to compensate for beam deviation and focusing mismatch induced by the anisotropic winding structure. Then, Gray-code excitation and pulse compression are introduced to improve signal energy and echo detectability under high-attenuation conditions. Finally, coherence-weighted imaging is applied to suppress incoherent background noise and structural artifacts, thereby enhancing defect contrast and image readability. The proposed method is validated on hydrogen storage vessel specimens containing artificial defects, with CT results used as references. Experimental results show that, compared with conventional isotropic TFM, the proposed collaborative approach significantly improves defect imaging quality for defects of different sizes and depths. The signal-to-noise ratio is increased from 7.2, 12.8, 14.8, and 7.4 dB for isotropic TFM to 32.5, 29.9, 52.6, and 42.7 dB, respectively, for the combined anisotropic, coded-excitation, and coherence-weighted TFM. In addition, the defect depth estimation remains stable and agrees well with the CT references, yielding approximately 9.0–9.6 mm for shallow defects and 18.7–19.3 mm for deeper defects. These results demonstrate that the proposed method can effectively improve defect detectability, image contrast, and depth characterization for embedded delamination-like artificial defects in composite hydrogen storage vessels, providing a promising ultrasonic imaging strategy for thick-walled anisotropic composite pressure structures. Full article

Both developed and developing countries are striving to reduce building energy consumption. Heating still accounts for an important share of the total energy used in buildings. Many studies compare different heating modes, but few take into account that, first of all, in heated rooms, similar operative temperatures should be provided. In this study, operative temperatures in different locations of a heated room have been analysed, assuming two different heating systems. In addition, the operative temperature distribution can be further disturbed by the room geometry (one or more external walls, or family house) and the room’s position in the building (ground floor, intermediate floor, or top floor). The operative temperature distribution was analysed at nine locations across 525 different room models for radiator and floor heating. The conducted research proved that, at the p = 0.05 significance level, the differences in operative temperatures across locations in a radiator-heated room are significant. Differences in operative temperatures across locations in a floor-heated room are significant and the number of external walls (one, two, or three) also have a significant effect on operative temperatures in a heated room. The differences in operative temperatures at the same location in a heated room with different dimensions can be significant. The differences between the mean operative temperatures in a room (radiator-heated or floor-heated) are not significant if the room has different positions in a multilevel building (ground floor, intermediate level, or top level). To compare two heating systems energetically, a complex analysis should be conducted, and efforts should be made to ensure similar operative temperatures at the most critical locations. Full article

Hybrid stepper (HB) motors are widely used in precision actuation systems such as cryogenic refrigerator robotic arms. Under cryogenic working conditions, the core loss characteristics of magnetic materials change significantly, while conventional core loss models calibrated at room temperature can hardly provide reliable prediction accuracy. In this work, the electromagnetic properties of 35SW1900 non-oriented silicon steel were measured from 25 °C − 100 °C using a BROCKHAUS Epstein frame system. Variations in permeability, core loss and coercivity with magnetic flux density, temperature and frequency were obtained. An improved core loss model was developed by introducing a flux-dependent exponent and dual temperature correction coefficients for hysteresis and eddy current losses. Experiments place the prediction error of the proposed model within 4% under cryogenic conditions. Compared with the classical Bertotti model, the proposed model effectively reduces high-frequency deviation caused by the temperature-dependent material properties and skin effect. The core loss of silicon steel increases by 15–30% at −100 °C compared with room temperature, which is mainly attributed to the decrease in resistivity and the strengthening of domain wall pinning. This paper provides an accurate loss prediction method and design references for HB motors applied in ultralow temperature working conditions. Full article

Prestress loss and bi-directional prestress effects are critical design parameters that determine the bearing capacity of large-span U-shaped aqueducts. Based on a 42 m span simply supported U-shaped aqueduct, the pipeline friction coefficients were tested through least-squares fitting and validated against a finite element analysis model. The results revealed pipeline friction induced 4.82–5.08% longitudinal and 35.84–39.23% circumferential prestress loss, with 12-month post-tensioning monitoring showing 9.84% (longitudinal) and 3.15% (circumferential) long-term loss. Maximum concrete compressive stresses reached 5.83 MPa (inner wall) and 7.14 MPa (outer wall) under empty groove conditions. Six prestress tensioning sequences were numerically compared to identify the optimal “both ends to center” circumferential tensioning scheme. The prestressed tendon layout was optimized by increasing circumferential tendon spacing from 40 cm to 60 cm while maintaining global compression. This research provides a systematic framework for prestress optimization in curved concrete structures. Full article

The post-tensioned cross-laminated timber (CLT) rocking wall is a recently developed resilient CLT lateral force-resisting system with a self-centering feature. The structural responses of the systems with different designs need to be determined and evaluated efficiently to promote the development and standardization of industrial applications. This study developed a computationally efficient, component-assembled numerical model for post-tensioned cross-laminated timber (PT CLT) rocking walls that captures decompression, post-tension self-centering, and energy dissipation within a framework. The single wall model was assembled using nonlinear zero-length springs for the compression at the CLT bottom, truss bar element for the PT tendon, and elastic shell element for the CLT panel deformation. The energy dissipation device, the UFP, was modeled with nonlinear one-dimensional springs between the wall panels in the coupled wall model. The wall models were separately calibrated considering the wall designs of single-panel walls and coupled walls. Both single and coupled wall models predicted the initial stiffness, decompression, yielding, post-yield stiffness, and reloading/unloading stiffness. The residual drift and nonlinear unloading captured with the PT model were also validated with the test data. A two-story platform structure model was established based on the NHERI Tallwood project, assembled with the coupled wall model and CLT slab in shell elements and columns in Euler beam elements. With recorded ground acceleration signals from the test, the platform structure’s peak story displacement and inter-story drift were simulated with less than 30% differences for most cases. Unlike existing detailed contact-based models, the proposed approach balances local damage fidelity and computational efficiency. The validated model provides a framework for evaluating PT CLT wall design parameters considering their influence on full structures. Full article

Background/Objectives: This study presents the development of an activated carbon/sodium alginate-based gastric-retentive delivery system aimed at enhancing the gastroprotective efficacy of eugenol (Eug) in simulated body fluids. Methods: Hybrid hydrogel beads were fabricated using tea waste-derived activated carbon (AC) as a core material and sodium alginate as a wall material. Results: The system achieved a loading capacity of 3.37 ± 0.11 mg Eug/g hydrogel beads, and in vitro assays revealed a controlled release profile, with cumulative release reaching 0.694 ± 0.006 mg/g hydrogel beads in simulated gastric fluid (SGF) and 0.198 ± 0.002 mg Eug/g hydrogel beads in simulated intestinal fluid (SIF). Conclusions: Kinetic modeling confirmed a predominantly diffusion-controlled process with non-Fickian transport mechanism, indicating combined diffusion and matrix relaxation. By maintaining local therapeutic concentrations in the gastric mucosa, this pH-responsive Alg/Eug@AC system offers a sustainable strategy to overcome Eug’s low bioavailability and provide effective gastroprotection against oxidative damage. Full article

Although austenitic steels have been implemented in direct liquid hydrogen (LH₂) contact for decades, detailed microstructural and mechanical studies are still rare at a temperature of 20 K and inexistent for long-term exposure in LH₂. Therefore, austenitic stainless-steel parts, which were in direct contact with LH₂, from a container for LH₂ transport from the company Linde GmbH that has been in service for over 30 years, was chosen as a material model system for this investigation. In the present work, the possible influence of cryogenic gaseous and liquid H₂ (GH₂ and LH₂) on the micro- and macroscopic as well as mechanical properties of the container was investigated. Monitoring the properties after long-term GH₂ and LH₂-exposed material assesses the durability and the failure characteristics of these austenitic steels. A mean content of 2.5 ppm H was detected in the container walls after the long-term exposure. The microhardness of the long-term GH₂ and LH₂ are similar to an H₂ non-exposed sample. Based on the SEM investigations, no microstructural change could be detected in the material after long-term H₂ exposure and the residual tensile properties are still similar to those of ‘fresh’ non-exposed material. The hydrogen embrittlement (HE) occurred in the container material only after additional thermal H-charging, where the ductility reduced to about 50% at 200 K. Full article

Botrytis cinerea is a major phytopathogen responsible for significant postharvest losses in plant-derived foods. The increasing resistance to synthetic fungicides has driven the search for sustainable alternatives, including enzyme-based biofungicides. In this study, the proteolytic fraction P1G10 from Vasconcellea pubescens latex was encapsulated in an alginate–chitosan (ALG-CS) matrix to improve its stability and antifungal performance. The encapsulated formulation (ALG-CS-P1G10) retained ~95% enzymatic activity after 8 h under stress conditions (37 °C, 1350 lux), compared with 67% for the free enzyme. In vitro assays demonstrated a dose-dependent inhibition of B. cinerea growth, with an IC₅₀ value of ~11 mg/mL determined using a logistic model. At this concentration, the formulation reduced fungal adhesion by more than 80% and increased sensitivity to cell wall-disrupting agents (Congo Red and Calcofluor White), pointing to alterations in cell wall integrity. Importantly, the encapsulated system provided a more stable and sustained antifungal effect, consistent with a controlled-release mechanism. These results demonstrate that coupling enzyme stabilization with controlled release can improve the functional performance of protease-based antifungal systems, offering a promising strategy for the development of biofungicides in postharvest applications. Full article

Water structures play a vital role in regulating irrigation water within open-channel networks by controlling discharge, water levels, flow direction, and velocity. Despite their importance, these structures act as hydraulic obstructions that induce flow disturbances, which may reduce hydraulic efficiency and threaten structural integrity. One of the most critical consequences is localized erosion downstream, posing serious risks to structural safety and long-term performance. From a sustainability perspective, maintaining structural stability and hydraulic efficiency is essential to ensure reliable water delivery, minimize maintenance costs, and extend the service life of irrigation structures. Therefore, mitigating such adverse hydraulic effects is a key component of sustainable water resources management. This study aims to investigate the mechanisms responsible for this phenomenon and propose engineering solutions to reduce its impacts. The geometry of upstream wing walls significantly influences flow behavior both through and downstream of the structure. Additionally, irrigation canals are constructed with varying side slopes depending on soil conditions, which further affect flow characteristics. However, the combined effect of different upstream wing wall configurations and canal inside slopes has not been sufficiently addressed. Accordingly, this research evaluates their integrated impact to support the development of more efficient, resilient, and sustainable irrigation structures. A total of 435 laboratory experiments were conducted using a physical model under varying discharge conditions. Common canal inside slopes were tested with four widely used wing wall types. Scour hole geometry, including depth, length, and shape, was measured and analyzed. Results indicate that the splayed wing wall configuration outperforms the box type, reducing maximum scour depth and length by approximately 22.74% and 23.61%, respectively, when combined with a 1:1 canal inside slope. Additionally, new dimensionless empirical equations were developed to predict downstream scour behavior, providing practical tools for selecting optimal wing wall configurations under different canal conditions. Full article