Search Results (619)

This paper investigates co-continuous structures in immiscible polymer blends through three-dimensional (3D) computational calculations based on a multiphase phase-field equation for fluid flow. The mathematical model describes phase separation with the Cahn–Hilliard (CH) equation and fluid motion with the incompressible Navier–Stokes (NS) equations. Both polymers are treated as Newtonian viscous fluids, and the model includes surface tension, viscosity, and volume fraction effects. A semi-implicit finite difference method (FDM) solves the CH equation, and a projection method maintains the incompressibility of the flow field. Multigrid techniques solve the nonlinear systems efficiently. In addition, a connectivity-based detection algorithm determines whether a phase forms a connected structure that reaches all boundaries of the numerical domain. The numerical results show that the morphology changes from a droplet–matrix structure to a co-continuous structure as the volume fraction increases. The interfacial area per unit volume reaches a local maximum near the transition between these two regimes. Full article

To address the surface wear issues of tungsten alloys in die-casting mold applications—where low hardness coupled with severe service conditions involving high-pressure impact from molten metal, thermal cycling, and component counter-friction—this study employed three techniques: laser cladding, plasma spraying, and vacuum surface carburization. Three distinct strengthening coatings were prepared on a tungsten heavy alloy (WHA) substrate. X-ray diffraction (XRD), scanning electron microscopy (SEM), a Vickers hardness tester, and block-on-ring friction and wear tests were employed to characterize the phase composition, microstructure, hardness, and wear resistance of the coatings. The results indicate that all three coatings significantly enhanced the hardness of the substrate, albeit through different strengthening mechanisms. The hardness increase in the laser-clad coating is attributed to the combined strengthening effect of rapid solidification-induced fine grains and dispersed WC particles. The enhanced hardness of the plasma-sprayed coating is due to the intrinsic hardness of WC and its dense layered structure. The carburized layer exhibits the highest hardness, resulting from the continuous WC phase formed via in situ reaction and an interface-free gradient transition with the substrate, which eliminates interfacial weak zones. Under loads of 50 N and 100 N, the plasma-sprayed coating demonstrated the best wear resistance, with wear volumes of 0.16% and 0.18% of that of the substrate, and wear depths of 4.57% and 3.50% of that of the substrate, respectively. It also exhibited the optimal load adaptability, making it a preferred solution for surface strengthening of tungsten alloy die-casting molds. Full article

Galactic cosmic rays (CRs) are a fundamental non-thermal component of the interstellar medium (ISM). Understanding the transport of super-high-energy particles is essential for interpreting observations of Galactic PeVatrons. Classical diffusion models assuming a homogeneous and isothermal medium oversimplify the multiphase ISM. We utilize high-resolution three-dimensional magnetohydrodynamic simulations to self-consistently generate a multiphase ISM—comprising the warm (WNM), unstable (UNM), and cold neutral medium (CNM)—and investigate 1.5–15 PeV particle transport using a test-particle approach. We find that thermal phase transitions induce steep magnetic field strength gradients at phase boundaries, creating localized magnetic fluctuations that act as efficient sites for adiabatic mirror reflections and non-adiabatic pitch-angle scattering, strongly enhancing cross-field transport at these interfaces. However, because phase boundaries occupy only a small volume fraction and particles spend most of their trajectory in the weakly scattering WNM and UNM, the global pitch-angle scattering coefficient in the multiphase ISM is smaller than in an equivalent isothermal medium. This locally strong scattering nevertheless drives both parallel and perpendicular spatial diffusion coefficients to ∼${10}^{30}$ cm² s⁻¹ at 1.5 PeV, with the perpendicular component exceeding its isothermal counterpart (∼${10}^{28}$ cm² s⁻¹) by two orders of magnitude. Using a phase–phase diffusion matrix decomposition, we show that global CR transport is governed by the volume-filling, trans-Alfvénic WNM and UNM, where particles stream along stochastically wandering field lines. Cross-phase displacement correlations are universally positive, indicating cooperative transport between thermal phases. In contrast, the super-Alfvénic CNM acts as an efficient confinement that substantially suppresses local diffusion. Full article

The growing reliance on virgin resources in construction, alongside accelerated urban development and the significant volumes of waste generated at the end-of-life phase of buildings, has intensified environmental impacts across the built environment. These challenges highlight the urgent need to transition towards a circular economy (CE) in the construction sector. At the same time, the sector’s ongoing digital transformation presents opportunities to enhance stakeholder collaboration and improve construction and demolition waste management (CDWM) practices. This paper aims to develop a conceptual framework for a Digital Information Management System (DIMS) to support CE implementation in construction through improved CDWM. Following the Design Science Research methodology, this paper addresses the first two stages: problem identification and solution proposition. A questionnaire survey with industry experts was conducted to validate the problem areas identified in the literature and assess the applicability of the proposed conceptual framework. The findings confirm critical gaps in CDWM, including limited stakeholder collaboration, fragmented processes, and the absence of lifecycle-spanning information systems, and validate the proposed conceptual framework solution, particularly the integration of BIM and IoT to support material and product flow tracking throughout the project lifecycle, supported by clearly defined stakeholder roles and engagements. However, respondents expressed reservations regarding Blockchain due to concerns about energy consumption and long-term data storage. Overall, the validated conceptual framework for DIMS provides a robust foundation for future studies, to focus on co-creating and developing a detailed conceptual model for DIMS for future real-world implementation. Full article

The feasibility of using brittle δ-Nb₃Al as the reinforcement phase in powder metallurgy nickel-based superalloys depends on both the preparation of near-spherical particles and their phase stability during hot isostatic pressing (HIP). In this study, irregular δ-Nb₃Al particles were converted into near-spherical reinforcement particles by controlled ball milling. The optimized milling condition for obtaining high-sphericity δ-Nb₃Al particles was 200 r/min for 20 h. The morphological evolution during ball milling clarifies a particle-rounding mechanism governed by edge elimination, fine-fragment adhesion, surface consolidation, and re-fragmentation. During subsequent HIP consolidation to introduce the particles into a nickel-based superalloy, extensive interdiffusion occurred between δ-Nb₃Al and the surrounding matrix, resulting in the formation of multilayer interfacial reaction zones and multiple Nb-rich secondary phases, including Laves-(Ni, Cr)₂Nb, Ni₆Nb₇, Nb solid solution, and Ni₃Nb. Quantitative analysis indicates that the retained volume fraction of δ-Nb3Al after HIP is only about 9.85%, much lower than the initial addition level. Combined with thermodynamic analysis based on the effective heat of formation model, the results show that the final phase constitution is governed by the coupled effects of diffusion kinetics and thermodynamic driving force. These findings clarify the intrinsic processing–microstructure–phase transition relationship in δ-Nb₃Al-reinforced powder metallurgy nickel-based superalloys, showing that ball milling controls the powder-state evolution of δ-Nb₃Al, whereas diffusion-driven interfacial reactions during HIP govern its retention and final phase constitution. Full article

As solid waste generated from shield tunnel construction, shield muck is characterized by its massive volume, high water content, and poor engineering properties. Large-scale stockpiling not only occupies precious land resources but also poses potential environmental risks. This has become one of the key bottlenecks hindering the green, low-carbon, and sustainable development of rail transit construction. Efficient dewatering is a key prerequisite for its subsequent disposal or reutilization. Lime, cement, phosphogypsum, nano-SiO₂, and ground granulated blast furnace slag were employed in this research as composite conditioning agents to dewater shield tunnel muck. A range of water content, pH, and total organic carbon analyses tests were conducted to explore the roles of lime, cement, phosphogypsum, nano-SiO₂, and ground granulated blast furnace slag on the dewatering effect of shield tunnel muck. Furthermore, microstructures and elemental distribution of typical mixes were analyzed by scanning electron microscopy and energy-dispersive X-ray spectroscopy tests. Results indicate that a composite agent consisting of 3.5% lime, 4% cement, 1% phosphogypsum, 0.2% nano-SiO₂, and 4% ground granulated blast furnace slag exhibits optimal performance, reducing water content from 50% to 29.8% within 24 h. Phosphogypsum significantly decreased pH and reduced TOC to below 1 g/kg after 15 days, effectively mitigating the environmental hazards associated with muck disposal. The formation of cementitious products, including calcium aluminate hydrate, calcium aluminosilicate hydrate gels, and calcium silicate hydrate, effectively bonds soil particles. Additionally, ettringite crystals produced by the reaction between phosphogypsum and calcium aluminate phases filled interparticle voids. These processes were identified as the primary mechanisms for water reduction. Although nano-SiO₂ exerted a limited direct influence on water content, it acted as a pozzolanic catalyst that accelerated hydration reactions of lime and cement, rapidly reducing muck fluidity. The synergistic effect of the composite dewatering agent components establishes a multi-mechanism dewatering system characterized by “hydration gel + AFt filling + nano-catalysis.” The dewatering system developed in this study achieves both high efficiency and environmental friendliness for shield tunnel muck. This provides technical support for subsequent resource utilization, such as subgrade filling, while promoting the recycling of industrial solid wastes like phosphogypsum and blast furnace slag, ultimately contributing to green, low-carbon, and sustainable development. Full article

Urban underground construction in water-rich sandy strata produces large quantities of high-fluidity pipe-jacking spoil whose high water content, residual conditioning agents and heavy metal contaminants make conventional dewatering and landfilling increasingly unsustainable under carbon peaking and neutrality targets. This study explores a low-carbon route that converts such spoil into CO₂ foamed concrete through a coupled alkali activation–CO₂ foaming process. Ground granulated blast furnace slag and fly ash are used as geopolymer precursors, while a CO₂-based aqueous foam is introduced as both a pore-forming phase and carbon source. Single-factor tests and an L16(4⁴) orthogonal design are conducted to quantify the effects of CO₂ concentration, foam volume fraction, geopolymer dosage and alkali activator content on fluidity, setting time and compressive strength. Scanning electron microscopy (SEM) is employed to examine pore structure, gel morphology, carbonate precipitation and the interfacial transition zone around spoil particles. The results identify an optimum mix window (CO₂ 60–80%, foam 70–80%, geopolymer ≈ 20% and alkali activator ≈ 10% of solids) that delivers a fluidity above 210 mm, 28-day strength exceeding 3.0 MPa and a uniform closed-pore network. A multi-scale mechanism is proposed in which physical foaming, chemical carbonation and spoil particle immobilization act synergistically to form a dense gas–solid–soil composite suitable for in situ backfilling. Full article

The dominant pores governing methane adsorption in coal are micropores (pore size < 2 nm). Their spatial heterogeneity can be quantitatively characterized using multifractal theory; however, the evolution patterns and mechanisms of microporous structures across different coalification degrees remain unclear. This research selected a series of coal samples from different ranks and identified the coalification degree using the maximum vitrinite reflectance (Rₒ_,max). By comprehensively employing low-temperature CO₂ adsorption experiments and multifractal analysis, the evolution patterns of the microporous structures and their multifractal spectral parameters were systematically revealed, and the underlying control mechanisms were explored. Results indicate that micropore volume (PV) and specific surface area (SSA) first exhibit a decrease and then increase as Rₒ_,max increases, with the trough occurring during the second coalification jump at Rₒ_,max = 1.2–1.4%. The pore sizes exhibit bimodal distributions, with the primary peak occurring in the range of 0.45–0.65 nm and the secondary peak occurring in the range of 0.8–0.9 nm. All microporous structures possess pronounced multifractal characteristics. The generalized dimension spectrum width (ΔD) and singularity spectrum width (Δα) exhibit an increasing–decreasing–increasing trend with Rₒ_,max, whereas the Hurst exponent (H) follows an inverted parabolic curve, first increases then decreases. This contrasts with the trends in PV and SSA, indicating that the evolution of pore-space heterogeneity and connectivity is independent of and lags the changes in micropore quantity. These patterns are governed by a structural phase transition within the coal macromolecular network. Marked by the second coalification jump, the microporous system shifts from a flexible degradation–polycondensation paradigm to a rigid ordering–construction paradigm. This transition drives the asynchronous, synergistic evolutions of pore quantity, spatial heterogeneity (ΔD and Δα), and topological connectivity (H). This research provides a theoretical basis for quantitatively evaluating pore heterogeneity in coal reservoirs. Full article

Microcline is an important rock-forming mineral in the Earth’s crust, and characterizing its structural behavior under compression is essential for understanding the high-pressure response of feldspar minerals under geological conditions. In this study, the crystal structural evolution of microcline up to 12 GPa was investigated using first-principles calculations based on density functional theory. The results reveal an isosymmetric phase transition at approximately 6–7 GPa, accompanied by a ~7% volume collapse. Across this transition, the b-axis and unit-cell angles (α, β, γ) change abruptly, and the aluminum coordination transforms from fourfold to a distorted fivefold geometry intermediate between a trigonal bipyramid and a square pyramid. Analysis of bond lengths and angles indicates that compression in the low-pressure phase is primarily driven by shear deformation of tetrahedral Ring 1. Near the transition pressure, however, marked shear deformations of Ring 2 and Ring 3 induce a strong contraction of the b-axis and abrupt changes in the unit-cell angles. Comparison with the compression behavior of low albite reveals both similarities and distinct structural responses, highlighting the role of framework topology and extra-framework cations in controlling pressure-induced structural evolution in feldspar minerals. These results provide new insights into the high-pressure behavior of microcline and contribute to a better understanding of the structural stability of feldspar minerals in the Earth’s interior. Full article

Biodegradable nanocomposite materials possessing self-healing behavior are emerging as an attractive option of being used in advanced mechatronic systems. The current study is focused on a thorough examination of the micromechanical properties of graphene–reinforced polylactic acid (PLA)/polycaprolactone (PCL) composite samples, followed by estimation of their self-healing behavior upon heating. Polymer blend–based nanocomposite materials were prepared using the green and reliable in terms of good nanofiller dispersion melt extrusion method. 3D printed nanocomposite specimens with impeccable flatness were subjected to fine microscratch testing by applying a constant force experimental mode. The surface resistance of the three-component polymer materials against the lateral movement of the stylus fulfilling the scratch and the impact of the dual-phase PLA/PCL ratio on the nanocomposite mechanical performance were estimated by calculation of the coefficient of friction (COF = F_x/F_z). COF values in the range of 0.8–1.4 indicated excellent nanocomposite resilience against scratch. Creating a heterogeneous polymer system that combines phase-separated soft and hard domains with close melt and glass transition temperatures, respectively, may facilitate the physical flow of macromolecular chains into voids or free volume areas. This aspect can be critical in the achievement of thermally–induced self-healing properties of the composite material. Scanning electron microscopy (SEM) imaging of the microscratches, made before and after Joule heating of the polymer samples, revealed a significant degree of surface recovery and a sensible reduction in the width of the adjusted scratch grooves. Full article

The intermittent and variable nature of solar energy poses challenges for maintaining stable thermal performance in solar heating systems. One effective approach to mitigate this limitation is to store surplus thermal energy during periods of high solar irradiance and release it when solar input is insufficient. Phase change materials (PCMs) are particularly suitable for this purpose due to their ability to absorb and release large amounts of latent heat during phase transition. The aim of this work is to develop a mathematical model of a flow-through tank containing a phase change material in the form of a spherical packed bed. Including longitudinal dispersion in the model equations allows for a more accurate description of the heat transfer process in a tank containing PCM elements. Simulation calculations based on the model were carried out to demonstrate its potential applicability to practical problems. The influence of the following parameters on the process was investigated: tank volume, water flow rate, phase change temperature, process duration, dispersion coefficient during water flow, radius of the packed-bed elements, and cyclic variations of the inlet water temperature. A significant influence of the axial dispersion coefficient in the tank containing PCM on the outlet water temperature profile was demonstrated. It was found that the internal heat transfer coefficient within the packing elements containing PCM falls within the range of 58–145 W/(m²K). Full article

Phase-change materials (PCMs) are capable of storing or releasing a substantial amount of thermal energy within a small volume through the latent heat of fusion during phase transitions of melting and solidification, i.e., from solid to liquid or vice versa, in a near isothermal process. However, commonly used organic PCMs, such as paraffin wax, exhibit very low thermal conductivity, contributing to an adverse increase in overall thermal resistance and, thus, a slow thermal response. This limitation often becomes a bottleneck for the system from a thermal performance standpoint. To mitigate this issue, the present work explores the fabrication of heat sinks incorporating nano-structured graphitic foams, including carbon foam (CF) and expanded graphite (EG), as well as micro-structured metal foams such as open-cell copper foam (OCCF), all impregnated with a paraffin-based PCM with a melting temperature near 37 °C. This study focuses on applying passive thermal management strategies to design efficient heat sinks capable of maintaining the temperatures of battery modules and electronic circuits within an acceptable thermal safety threshold for small satellites and spacecrafts, exemplified by the OPTIMUS and Pumpkin battery modules designed for CubeSats with a nominal cross-sectional area of almost 4″ × 4″. Temperature responses and average overall thermal resistances for fabricated heat sinks are accordingly assessed and compared in a vacuum chamber to simulate space conditions. Furthermore, the impact of operating pressure on the thermal performances of various heat sinks will be investigated by executing the same tests in both atmospheric and vacuum conditions. The findings demonstrate a superior thermal performance of composite heat sinks integrating carbon foam and copper foam into the paraffin PCM compared to the baseline PCM heat sink under both vacuum and atmospheric operating pressure conditions. Full article

Stimuli-responsive hydrogels, also referred to as “smart” hydrogels, have emerged as versatile platforms for a wide range of biological and biomedical applications owing to their tunable physical, chemical, and biocompatible properties. Their adaptability arises from both their ability to undergo reversible swelling–deswelling and volume phase transitions in response to specific physicochemical or biological stimuli and the diversity of synthesis strategies that enable precise tailoring of material properties to meet distinct biomedical demands. Recent advances have led to the development of novel hydrogel designs with improved swelling–deswelling behavior, enhanced stimulus sensitivity, and superior biocompatibility, thereby expanding their applicability in complex biological environments. Despite this progress, challenges such as precise control over hydrogel size and relatively slow response kinetics remain critical barriers to broader biomedical and clinical translation. Addressing these limitations requires strategies, including reducing hydrogel particle dimensions to accelerate response rates and engineering heterogeneous or highly porous gel architectures to increase functional surface area. This review provides a comprehensive classification of stimuli-responsive hydrogels based on their physical properties and response mechanisms, and summarizes recent innovations in their design, synthesis, and biomedical applications. Furthermore, it discusses emerging approaches to enhance the clinical applicability of smart hydrogels in controlled drug release, targeted gene delivery, biosensor development, and tissue engineering. Overall, continued optimization of swelling–deswelling characteristics and material design will be essential to fully realize the potential of stimuli-responsive hydrogels in precision medicine and advanced therapeutic applications. Full article

The annual soccer training cycle consists of preparatory, competitive, and transition periods. The transition phase is usually characterized by a decrease in training volume, which may lead to detraining and declines in physical fitness. The aim of this study was to examine the effects of a structured transitional training program on anthropometric characteristics, aerobic capacity, and jumping performance in young soccer players. Twenty-three under-17 players participated in the study and, following a two-week period of training cessation, completed a three-week program that included aerobic training three times per week (continuous and interval running sessions) and strength progressive resistance training twice per week. Pre- and post-intervention measurements were analyzed using paired-samples t-tests, with statistical significance set at p < 0.05. The results revealed significant reductions in body fat percentage (p = 0.016, d = 0.547), body fat mass (p = 0.018, d = 0.535), and resting systolic blood pressure (p = 0.024, d = 0.507). Additionally, time to reach the anaerobic threshold (p = 0.022, d = −0.515) and movement speed at the anaerobic threshold (p = 0.029, d = −0.487) significantly increased. No significant changes were observed in the remaining variables. These findings indicate that a three-week transition-period training program combining structured aerobic running drills with progressive resistance training can induce favorable adaptations in selected anthropometric and physiological parameters in youth soccer players. However, the lack of a control group should be considered when interpreting the magnitude of the program’s effects. Full article

To investigate the influence of a second-phase mineral on the rheology of mantle peridotite, we conducted high-temperature deformation experiments on dry olivine–clinopyroxene (Ol-Cpx) aggregates. Cylindrical samples were manufactured using hot-isostatic pressing techniques, with Ol as the matrix phase and Cpx added at volume fractions of f_Cpx = 0.1, 0.3, and 0.5. Deformation experiments were performed in a Paterson gas-medium apparatus at a confining pressure of ~300 MPa, temperatures ranging from 1423 to 1523 K, and strain rates of ~5 × 10⁻⁶ s⁻¹, ~1 × 10⁻⁵ s⁻¹, ~2 × 10⁻⁵ s⁻¹, and ~5 × 10⁻⁵ s⁻¹. The stress exponents (n = 3.4–4.3) for two-phase aggregates are comparable to those reported for both pure Ol and pure Cpx, indicating that dislocation creep remains the dominant deformation mechanism. Increasing Cpx content does not induce a transition of dominant mechanism but leads to a slight decrease in activation energy, consistent with predictions from two-phase rheological models and reflecting the increasing contribution of Cpx to bulk deformation. Normalized flow stresses fall between the Ol and Cpx end-members within the Taylor–Sachs bounds, indicating moderate strain partitioning between phases. Aggregates with f_Cpx = 0.5 show slightly reduced strength and lower effective stress exponents. This is attributed to enhanced dynamic recrystallization, which triggers grain-size reduction and thereby increases the contribution of diffusion-assisted deformation, even though dislocation creep remains the dominant mechanism. These results suggest that under dry conditions, Cpx primarily modulates the rheology of olivine-rich aggregates through microstructural evolution and strain partitioning rather than by altering the dominant deformation mechanism. Full article