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14 pages, 2177 KiB  
Article
Study on the Regulation Mechanism of Silane Coupling Agents’ Molecular Structure on the Rheological Properties of Fe3O4/CNT Silicone Oil-Based Magnetic Liquids
by Wenyi Li, Xiaotong Zeng, Shiyu Yang, Bingxue Wang, Xiangju Tian and Weihao Shen
J. Compos. Sci. 2025, 9(8), 423; https://doi.org/10.3390/jcs9080423 - 7 Aug 2025
Abstract
Silicone oil-based magnetic liquids containing carbon nanotubes (CNTs) were prepared using an in situ chemical coprecipitation method. The surface modification of Fe3O4/CNT composite particles was carried out by using three silane coupling agents: γ-aminopropyltriethoxysilane (550), γ-methacryloxypropyltrimethoxysilane (570), and phenyltrimethoxysilane [...] Read more.
Silicone oil-based magnetic liquids containing carbon nanotubes (CNTs) were prepared using an in situ chemical coprecipitation method. The surface modification of Fe3O4/CNT composite particles was carried out by using three silane coupling agents: γ-aminopropyltriethoxysilane (550), γ-methacryloxypropyltrimethoxysilane (570), and phenyltrimethoxysilane (7030). Infrared Spectroscopy (IR), Transmission Electron Microscopy (TEM), and X-ray Diffraction (XRD) were used to confirm the successful doping of CNTs and the effective coating of the coupling agents. The rheological behavior of the magnetic liquids was systematically studied using an Anton Paar Rheometer. The results show that viscosity decreases exponentially with increasing temperature (fitting the Arrhenius equation), increases and tends to saturate with rising magnetic field intensity, and exhibits shear-thinning characteristics with increasing shear rate. Among the samples, Fe3O4@7030 has the best visco-thermal performance due to the benzene ring structure, which reduces the symmetry of the molecular chains. In contrast, Fe3O4@570 shows the most significant magneto-viscous effect (viscosity variation of 161.4%) as a result of the long-chain structure enhancing the steric hindrance of the magnetic dipoles. Full article
(This article belongs to the Section Composites Modelling and Characterization)
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26 pages, 15885 KiB  
Article
Comparative Analysis of Fully Floating and Semi-Floating Ring Bearings in High-Speed Turbocharger Rotordynamics
by Kyuman Kim and Keun Ryu
Lubricants 2025, 13(8), 338; https://doi.org/10.3390/lubricants13080338 - 31 Jul 2025
Viewed by 215
Abstract
This study presents a detailed experimental comparison of the rotordynamic and thermal performance of automotive turbochargers supported by two distinct hydrodynamic bearing configurations: fully floating ring bearings (FFRBs) and semi-floating ring bearings (SFRBs). While both designs are widely used in commercial turbochargers, they [...] Read more.
This study presents a detailed experimental comparison of the rotordynamic and thermal performance of automotive turbochargers supported by two distinct hydrodynamic bearing configurations: fully floating ring bearings (FFRBs) and semi-floating ring bearings (SFRBs). While both designs are widely used in commercial turbochargers, they exhibit significantly different dynamic behaviors due to differences in ring motion and fluid film interaction. A cold air-driven test rig was employed to assess vibration and temperature characteristics across a range of controlled lubricant conditions. The test matrix included oil supply pressures from 2 bar (g) to 4 bar (g) and temperatures between 30 °C and 70 °C. Rotor speeds reached up to 200 krpm (thousands of revolutions per minute), and data were collected using a high-speed data acquisition system, triaxial accelerometers, and infrared (IR) thermal imaging. Rotor vibration was characterized through waterfall and Bode plots, while jump speeds and thermal profiles were analyzed to evaluate the onset and severity of instability. The results demonstrate that the FFRB configuration is highly sensitive to oil supply parameters, exhibiting strong subsynchronous instabilities and hysteresis during acceleration–deceleration cycles. In contrast, the SFRB configuration consistently provided superior vibrational stability and reduced sensitivity to lubricant conditions. Changes in lubricant supply conditions induced a jump speed variation in floating ring bearing (FRB) turbochargers that was approximately 3.47 times larger than that experienced by semi-floating ring bearing (SFRB) turbochargers. Furthermore, IR images and oil outlet temperature data confirm that the FFRB system experiences greater heat generation and thermal gradients, consistent with higher energy dissipation through viscous shear. This study provides a comprehensive assessment of both bearing types under realistic high-speed conditions and highlights the advantages of the SFRB configuration in improving turbocharger reliability, thermal performance, and noise suppression. The findings support the application of SFRBs in high-performance automotive systems where mechanical stability and reduced frictional losses are critical. Full article
(This article belongs to the Collection Rising Stars in Tribological Research)
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20 pages, 3407 KiB  
Article
Impact of Adverse Mobility Ratio on Oil Mobilization by Polymer Flooding
by Abdulmajeed Murad, Arne Skauge, Behruz Shaker Shiran, Tormod Skauge, Alexandra Klimenko, Enric Santanach-Carreras and Stephane Jouenne
Polymers 2025, 17(15), 2033; https://doi.org/10.3390/polym17152033 - 25 Jul 2025
Viewed by 211
Abstract
Polymer flooding is a widely used enhanced oil recovery (EOR) method for improving energy efficiency and reducing the carbon footprint of oil production. Optimizing polymer concentration is critical for maximizing recovery while minimizing economic and environmental costs. Here, we present a systematic experimental [...] Read more.
Polymer flooding is a widely used enhanced oil recovery (EOR) method for improving energy efficiency and reducing the carbon footprint of oil production. Optimizing polymer concentration is critical for maximizing recovery while minimizing economic and environmental costs. Here, we present a systematic experimental study which shows that even very low concentrations of polymers yield relatively high recovery rates at adverse mobility ratios (230 cP oil). A series of core flood experiments were conducted on Bentheimer sandstone rock, with polymer concentrations ranging from 40 ppm (1.35 cP) to 600 ppm (10.0 cP). Beyond a mobility ratio threshold, increasing polymer concentration did not significantly enhance recovery. This plateau in performance was attributed to the persistence of viscous fingering and oil crossflow into pre-established water channels. The study suggests that low concentrations of polymer may mobilize oil at high mobility ratios by making use of the pre-established water channels as transport paths for the oil and that the rheology of the polymer enhances this effect. These findings enable reductions in the polymer concentration in fields with adverse mobility ratios, leading to substantial reductions in chemical usage, energy consumption, and environmental impact of the extraction process. Full article
(This article belongs to the Section Polymer Applications)
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13 pages, 4246 KiB  
Article
Study on the Characteristics of CO2 Displacing Non-Newtonian Fluids
by Yu-Ting Wu, Sung-Ki Lyu, Zhen Qin, Yanjun Qin, Hua Qiao and Bing Li
Lubricants 2025, 13(7), 300; https://doi.org/10.3390/lubricants13070300 - 8 Jul 2025
Viewed by 328
Abstract
CO2 displacement is a key technique that was examined through numerical methods in a 3D Hele–Shaw cell, with CO2 as the displacing phase and shear-thinning fluids as the displaced phase. Without interfacial tension effects, the displacement shows branching patterns forming two [...] Read more.
CO2 displacement is a key technique that was examined through numerical methods in a 3D Hele–Shaw cell, with CO2 as the displacing phase and shear-thinning fluids as the displaced phase. Without interfacial tension effects, the displacement shows branching patterns forming two vertically symmetric fingers, regardless of whether the displacing fluid is air or CO2. Under CO2 displacement, viscous fingering propagates farther and achieves higher displacement efficiency than air. Compared with air displacement, the finger advancing distance increases by 0.0035 m, and the displacement efficiency is 15.2% higher than that of air displacement. Shear-thinning behavior significantly influences the process; stronger shear thinning enhances interfacial stability and suppresses fingering. As the power-law index n increases (reducing shear thinning), the fingering length extends. Variations in interfacial tension reveal it notably affects fingering initiation and velocity in CO2 displacement of non-Newtonian fluids, but has a weaker impact on fingering formation. Interfacial tension suppresses short-wavelength perturbations, critical to interface stability, jet breakup, and flows, informing applications like foam-assisted oil recovery and microfluidics. Full article
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15 pages, 1225 KiB  
Article
Physicochemical and Perceived Olfactory Changes in Black Soldier Fly (Hermetia illucens) Larvae Oil Under Domestic Cooking Temperatures
by Kian Aun Chang, Sze Ying Leong, Lye Yee Chew, Ching Qi Lim, Meng Jack Lim, Zongwei Ong and Sook Wah Chan
Foods 2025, 14(13), 2333; https://doi.org/10.3390/foods14132333 - 30 Jun 2025
Viewed by 373
Abstract
The rapid growth and sustainable production of black soldier fly larvae (BSFL) contribute positively to the circular economy. This study profiled the fatty acid composition of crude BSFL oil, followed by an evaluation of its physicochemical properties under domestic cooking temperatures (up to [...] Read more.
The rapid growth and sustainable production of black soldier fly larvae (BSFL) contribute positively to the circular economy. This study profiled the fatty acid composition of crude BSFL oil, followed by an evaluation of its physicochemical properties under domestic cooking temperatures (up to 180 °C, 30 min). Odour evaluation of the BSFL oil was also performed using 10 trained panellists for attributes such as fishy, nutty, oily, meaty/savoury, roasted, and pungent. The results indicated that BSFL oil contains palmitic (23.69%), oleic (30.90%), and linoleic (21.81%) acids in relatively similar proportions, representing a mix of saturated, monounsaturated, and polyunsaturated fatty acids. Heating caused BSFL oil to be darker and more viscous. The peroxide and free fatty acid values also increased significantly (p < 0.05) with rising temperatures, indicating limited oxidative stability and reduced suitability of BSFL oil for cooking purposes. The perceived intensity of odour attributes, particularly fishy and oily notes, increased concomitantly with higher cooking temperatures. Refining processes and antioxidants may assist in improving the thermal stability of BSFL oil for culinary applications. Full article
(This article belongs to the Special Issue Food Bioactives: Innovations, Mechanisms, and Future Applications)
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19 pages, 4761 KiB  
Article
An Open-Type Crossflow Microfluidic Chip for Deformable Droplet Separation Driven by a Centrifugal Field
by Zekun Li, Yongchao Cai, Xiangfu Wei, Cuimin Sun, Wenshen Luo and Hui You
Micromachines 2025, 16(7), 774; https://doi.org/10.3390/mi16070774 - 30 Jun 2025
Viewed by 307
Abstract
This study presents an innovative wedge-shaped inlet weir-type microfluidic chip designed to address common issues of clogging and inefficiency in microfiltration processes. Driven solely by centrifugal force, the chip integrates a crossflow separation mechanism and enables selective droplet sorting based on size, without [...] Read more.
This study presents an innovative wedge-shaped inlet weir-type microfluidic chip designed to address common issues of clogging and inefficiency in microfiltration processes. Driven solely by centrifugal force, the chip integrates a crossflow separation mechanism and enables selective droplet sorting based on size, without the need for external pumps. Fabricated from PMMA, the device features a central elliptical chamber, a wedge-shaped inlet, and spiral microchannels. These structures leverage shear stress and Dean vortices under centrifugal fields to achieve high-throughput separation of droplets with different diameters. Using water-in-oil emulsions as a model system, we systematically investigated the effects of geometric parameters and rotational speed on separation performance. A theoretical model was developed to derive the critical droplet size based on force balance, accounting for centrifugal force, viscous drag, pressure differentials, and surface tension. Experimental results demonstrate that the chip can effectively separate droplets ranging from 0 to 400 μm in diameter at 200 rpm, achieving a sorting efficiency of up to 72% and a separation threshold (cutoff accuracy) of 98.2%. Fluorescence analysis confirmed the absence of cross-contamination during single-chip operation. This work offers a structure-guided, efficient, and contamination-free droplet sorting strategy with broad potential applications in biomedical diagnostics and drug screening. Full article
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24 pages, 11727 KiB  
Article
Experimental Evaluation of Residual Oil Saturation in Solvent-Assisted SAGD Using Single-Component Solvents
by Fernando Rengifo Barbosa, Amin Kordestany and Brij Maini
Energies 2025, 18(13), 3362; https://doi.org/10.3390/en18133362 - 26 Jun 2025
Viewed by 321
Abstract
The massive heavy oil reserves in the Athabasca region of northern Alberta depend on steam-assisted gravity drainage (SAGD) for their economic exploitation. Even though SAGD has been successful in highly viscous oil recovery, it is still a costly technology because of the large [...] Read more.
The massive heavy oil reserves in the Athabasca region of northern Alberta depend on steam-assisted gravity drainage (SAGD) for their economic exploitation. Even though SAGD has been successful in highly viscous oil recovery, it is still a costly technology because of the large energy input requirement. Large water and natural gas quantities needed for steam generation imply sizable greenhouse gas (GHG) emissions and extensive post-production water treatment. Several methods to make SAGD more energy-efficient and environmentally sustainable have been attempted. Their main goal is to reduce steam consumption whilst maintaining favourable oil production rates and ultimate oil recovery. Oil saturation within the steam chamber plays a critical role in determining both the economic viability and resource efficiency of SAGD operations. However, accurately quantifying the residual oil saturation left behind by SAGD remains a challenge. In this experimental research, sand pack Expanding Solvent SAGD (ES-SAGD) coinjection experiments are reported in which Pentane -C5H12, and Hexane -C6H14 were utilised as an additive to steam to produce Long Lake bitumen. Each solvent is assessed at three different constant concentrations through time using experiments simulating SAGD to quantify their impact. The benefits of single-component solvent coinjection gradually diminish as the SAGD process approaches its later stages. ES-SAGD pentane coinjection offers a smaller improvement in recovery factor (RF) (4% approx.) compared to hexane (8% approx.). Between these two single-component solvents, 15 vol% hexane offered the fastest recovery. The obtained data in this research provided compelling evidence that the coinjection of solvent under carefully controlled operating conditions, reduced overall steam requirement, energy consumption, and residual oil saturation allowing proper adjustment of oil and water relative permeability curve endpoints for field pilot reservoir simulations. Full article
(This article belongs to the Special Issue Enhanced Oil Recovery: Numerical Simulation and Deep Machine Learning)
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14 pages, 1902 KiB  
Article
An Experimental Investigation of the Effect of Pressure and Salinity on IFT in Live Oil/Brine Systems
by Deniz M. Paker, Birol Dindoruk, Swati Sagar, Leslie Baksmaty, Ram R. Ratnakar, Hanin Samara and Philip Jaeger
Processes 2025, 13(6), 1843; https://doi.org/10.3390/pr13061843 - 11 Jun 2025
Viewed by 463
Abstract
Residual oil saturation in reservoirs is primarily influenced by viscous and capillary forces, with interfacial tension (IFT) being a critical factor in fluid distribution due to capillary pressure. Adjusting IFT is essential for enhancing oil recovery, particularly in waterflooding, which is the most [...] Read more.
Residual oil saturation in reservoirs is primarily influenced by viscous and capillary forces, with interfacial tension (IFT) being a critical factor in fluid distribution due to capillary pressure. Adjusting IFT is essential for enhancing oil recovery, particularly in waterflooding, which is the most common secondary recovery technique after primary production. The salinity of injected water directly affects the IFT between crude oil and brine, making it a crucial factor in optimizing recovery. However, limited studies have examined IFT using live oil samples under actual reservoir conditions. In this study, a high-pressure, high-temperature (HPHT) drop shape analyzer was used to measure the IFT between live oil and brine under reservoir conditions. Five live oil samples and two sodium chloride (NaCl) brine concentrations (30,000 and 100,000 ppm) were tested at a reservoir temperature of 180 °F. Measurements were conducted above the bubble points of the oils, replicating undersaturated reservoir conditions. The results revealed that the impact of pressure on IFT was more complex than that of salinity. IFT generally decreased with increasing pressure but showed mixed behavior across different samples. Conversely, IFT consistently increased with higher salinity. These findings enhance the understanding of IFT behavior under reservoir conditions, supporting improved reservoir simulations and oil recovery strategies. Full article
(This article belongs to the Special Issue Phase Equilibrium in Chemical Processes: Experiments and Modeling)
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16 pages, 719 KiB  
Article
The Issue of Hydrodynamic Friction in the Context of the Operational Properties of Ring-Shaped Torsional Vibration Dampers
by Aleksander Mazurkow, Andrzej Chmielowiec and Wojciech Homik
Appl. Sci. 2025, 15(12), 6528; https://doi.org/10.3390/app15126528 - 10 Jun 2025
Cited by 1 | Viewed by 325
Abstract
Improving the reliability and durability of internal combustion engines in marine vessels is a complex issue. The vibrations generated in these engines significantly affect their proper operation. One of the current research challenges is identifying effective methods to reduce, among other things, torsional [...] Read more.
Improving the reliability and durability of internal combustion engines in marine vessels is a complex issue. The vibrations generated in these engines significantly affect their proper operation. One of the current research challenges is identifying effective methods to reduce, among other things, torsional vibrations generated within the crank–piston system. To mitigate these vibrations, viscous dampers are commonly used. The selection of a viscous damper for a high-power multi-cylinder engine, such as those in marine power plants, requires a thorough understanding of the thermo-hydrodynamic properties of oil films formed in the spaces between the damper housing and the inertial mass. The description of the phenomena involved is complicated by the variable positioning of the inertial mass center relative to the housing during operation. Most previous studies assume a concentric alignment between these components. The main novelty of this work lies in highlighting the combined effect of the eccentric motion of the inertial ring on both hydrodynamic resistance and thermal characteristics, which has not been fully addressed in existing studies. This article defines the oil flow resistance coefficients and develops static characteristics of the dampers. Additionally, it evaluates the impact of the size of the frontal and cylindrical surfaces of the damper on its heat dissipation capacity. The presented characteristics can be utilized to assess the performance parameters of this type of damper. Full article
(This article belongs to the Special Issue Modern Internal Combustion Engines: Design, Testing, and Application)
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18 pages, 3901 KiB  
Article
Influence of Talc Substitution with Starches from Different Botanical Origins on Rheological and Absorption Properties of Stiff Zinc Oxide Paste Formulations
by Dragana Zaklan, Nikola Davidović, Jovana Milutinov, Dejan Ćirin, Veljko Krstonošić and Nebojša Pavlović
Pharmaceutics 2025, 17(5), 627; https://doi.org/10.3390/pharmaceutics17050627 - 8 May 2025
Viewed by 483
Abstract
Background: Zinc oxide paste is traditionally compounded and applied in the therapy of various skin conditions. However, prolonged use of talc, usually present in zinc oxide pastes, may pose health risks due to potential contamination with asbestos and quartz, highlighting the need for [...] Read more.
Background: Zinc oxide paste is traditionally compounded and applied in the therapy of various skin conditions. However, prolonged use of talc, usually present in zinc oxide pastes, may pose health risks due to potential contamination with asbestos and quartz, highlighting the need for alternative excipients. This study aimed to examine the effects of starches from various botanical sources and their particle size on the rheological and absorption properties of zinc oxide paste. Methods: Eight zinc oxide paste formulations were prepared, containing 25% zinc oxide and 25% indifferent excipient (talc, tapioca, rice, or maize starch) in two particle sizes. Rheological properties were assessed using amplitude and frequency sweep tests, and water- and oil-absorption capacities were determined using a centrifugation-based method. Results: Amplitude sweep tests confirmed the predominant solid-like nature of zinc oxide pastes, with the elastic modulus (G′) exceeding the viscous modulus (G″) in all formulations. Tapioca starch-based pastes exhibited the highest G′ and G″ values, while talc-based pastes exhibited the lowest. Frequency sweep tests showed that pastes were resistant to structural changes under stress, with G′ consistently dominating over G″ across the entire frequency range. Tapioca starch-based formulations exhibited the highest water-absorption capacity, while the talc-based formulations had the highest oil-absorption capacity. Reducing particle size improved both water- and oil-absorption capacities. Conclusions: Starches may be considered as alternatives to talc in zinc oxide pastes, due to their ability to modify the absorption and rheological properties of pastes. Future studies should assess the impact of starch substitution on sensory characteristics, shelf-life stability, and patient satisfaction. Full article
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27 pages, 7362 KiB  
Article
Preparation and Properties of a Novel Multi-Functional Viscous Friction Reducer Suspension for Fracturing in Unconventional Reservoirs
by Shenglong Shi, Jinsheng Sun, Shanbo Mu, Kaihe Lv, Yingrui Bai and Jian Li
Gels 2025, 11(5), 344; https://doi.org/10.3390/gels11050344 - 6 May 2025
Viewed by 403
Abstract
Aiming at the problem that conventional friction reducers used in fracturing cannot simultaneously possess properties such as temperature resistance, salt resistance, shear resistance, rapid dissolution, and low damage. Under the design concept of “medium-low molecular weight, salt-resistant functional monomer, supramolecular physical crosslinking aggregation, [...] Read more.
Aiming at the problem that conventional friction reducers used in fracturing cannot simultaneously possess properties such as temperature resistance, salt resistance, shear resistance, rapid dissolution, and low damage. Under the design concept of “medium-low molecular weight, salt-resistant functional monomer, supramolecular physical crosslinking aggregation, and enhanced chain mechanical strength”, acrylamide, sulfonic acid salt-resistant monomer 2-acrylamide-2-methylpropanesulfonic acid, hydrophobic association monomer, and rigid skeleton functional monomer acryloyl morpholine were introduced into the friction reducer molecular chain by free radical polymerization, and combined with the compound suspension technology to develop a new type of multi-functional viscous friction reducer suspension (SAMD), the comprehensive performance of SAMD was investigated. The results indicated that the critical micelle concentration of SAMD was 0.33 wt%, SAMD could be dissolved in 80,000 mg/L brine within 3.0 min, and the viscosity loss of 0.5 wt% SAMD solution was 24.1% after 10 min of dissolution in 80,000 mg/L brine compared with that in deionized water, the drag reduction rate of 0.1 wt% SAMD solution could exceed 70% at 120 °C and still maintained good drag reduction performance in brine with a salinity of 100,000 mg/L. After three cycles of 170 s−1 and 1022 s−1 variable shear, the SAMD solution restored viscosity quickly and exhibited good shear resistance. The Tan δ (a parameter characterizing the viscoelasticity of the system) of 1.0 wt% SAMD solution was 0.52, which showed a good sand-carrying capacity, and the proppant settling velocity in it could be as low as 0.147 mm/s at 120 °C, achieving the function of high drag reduction at low concentrations and strong sand transportation at high concentrations. The viscosity of 1.4 wt% SAMD was 95.5 mPa s after shearing for 120 min at 140 °C and at 170 s−1. After breaking a gel, the SAMD solution system had a core permeability harm rate of less than 15%, while the SAMD solution also possessed the performance of enhancing oil recovery. Compared with common friction reducers, SAMD simultaneously possessed the properties of temperature resistance, salt resistance, shear resistance, rapid dissolution, low damage, and enhanced oil recovery. Therefore, the use of this multi-effect friction reducer is suitable for the development of unconventional oil reservoirs with a temperature lower than 140 °C and a salinity of less than 100,000 mg/L. Full article
(This article belongs to the Special Issue Chemical and Gels for Oil Drilling and Enhanced Recovery)
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29 pages, 1122 KiB  
Review
Trends in Lubrication Research on Tapered Roller Bearings: A Review by Bearing Type and Size, Lubricant, and Study Approach
by Muhammad Ishaq Khan, Lorenzo Maccioni and Franco Concli
Lubricants 2025, 13(5), 204; https://doi.org/10.3390/lubricants13050204 - 6 May 2025
Cited by 1 | Viewed by 891
Abstract
A tapered roller bearing (TRB) is a specialized type of bearing with a high load-to-volume ratio, designed to support both radial and axial loads. Lubrication plays a crucial role in TRB operation by reducing friction and dissipating heat generated during rotation. However, it [...] Read more.
A tapered roller bearing (TRB) is a specialized type of bearing with a high load-to-volume ratio, designed to support both radial and axial loads. Lubrication plays a crucial role in TRB operation by reducing friction and dissipating heat generated during rotation. However, it can also negatively impact TRB performance due to the viscous and inertial effects of the lubricant. Extensive research has been conducted to examine the role of lubrication in TRB performance. Lubrication primarily influences the frictional characteristics, thermal behavior, hydraulic losses, dynamic stability, and contact mechanics of TRBs. This paper aims to collect and classify the scientific literature on TRB lubrication based on these key aspects. Specifically, it explores the scope of research on the use of Newtonian and non-Newtonian lubricants in TRBs. Furthermore, this study analyzes research based on TRB size and type, considering both oil and grease as lubricants. The findings indicate that both numerical and experimental studies have been conducted to investigate Newtonian and non-Newtonian lubricants across various TRB sizes and types. However, the results highlight that limited research has focused on non-Newtonian lubricants in TRBs with an Outer Diameter (OD) exceeding 300 mm, i.e., those typically used in wind turbines, industrial gearboxes, and railways. Full article
(This article belongs to the Special Issue Tribological Characteristics of Bearing System, 3rd Edition)
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19 pages, 6017 KiB  
Article
Construction of a Covalent Crosslinked Membrane Exhibiting Superhydrophilicity and Underwater Superoleophobicity for the Efficient Separation of High-Viscosity Oil–Water Emulsion Under Gravity
by Mengxi Zhou, Peiqing Yuan, Xinru Xu and Jingyi Yang
Molecules 2025, 30(8), 1840; https://doi.org/10.3390/molecules30081840 - 19 Apr 2025
Cited by 1 | Viewed by 471
Abstract
The separation of high-viscosity oil–water emulsions remains a global challenge due to ultra-stable interfaces and severe membrane fouling. In this paper, SiO2 micro–nanoparticles coated with polyethyleneimine (PEI) were initially loaded onto a stainless steel substrate. This dual-functional design simultaneously modifies surface roughness [...] Read more.
The separation of high-viscosity oil–water emulsions remains a global challenge due to ultra-stable interfaces and severe membrane fouling. In this paper, SiO2 micro–nanoparticles coated with polyethyleneimine (PEI) were initially loaded onto a stainless steel substrate. This dual-functional design simultaneously modifies surface roughness and wettability. Furthermore, a covalent crosslinking network was created through the Schiff base reaction between PEI and glutaraldehyde (GA) to enhance the stability of the membrane. The membrane exhibits extreme wettability, superhydrophilicity (WCA = 0°), and underwater superoleophobicity (UWOCA = 156.9°), enabling a gravity-driven separation of pump oil emulsions with 99.9% efficiency and a flux of 1006 L·m−2·h−1. Moreover, molecular dynamics (MD) simulations demonstrate that the SiO2-PEI-GA-modified membrane promotes the formation of a stable hydration layer, reduces the oil–layer interaction energy by 85.54%, and exhibits superior underwater oleophobicity compared to the unmodified SSM. Efficiency is maintained at 99.8% after 10 cycles. This study provides a scalable strategy that combines covalent crosslinking with hydrophilic particle modification, effectively addressing the trade-off between separation performance and membrane longevity in the treatment of viscous emulsions. Full article
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18 pages, 1976 KiB  
Review
Progress in Wax Deposition Characteristics and Prediction Methods for High Pour Point and Viscous Crude Oil Water System
by Jiangbo Wen, Yuzhang Jia, Yongrui Lu, Haijun Luo, Zhenwei Huang, Chuanlin You, Zizhe He and Xu Xiao
Processes 2025, 13(4), 1115; https://doi.org/10.3390/pr13041115 - 8 Apr 2025
Viewed by 848
Abstract
With the continuous growth of global energy demand, the exploitation of deepwater oil and gas resources has become an important part of national energy strategies. The high-viscosity crude oil in deepwater areas such as the South China Sea poses severe challenges to oil [...] Read more.
With the continuous growth of global energy demand, the exploitation of deepwater oil and gas resources has become an important part of national energy strategies. The high-viscosity crude oil in deepwater areas such as the South China Sea poses severe challenges to oil and gas pipeline transportation due to its high pour point and high viscosity characteristics. Wax deposition, particularly significant under low temperature and high viscosity conditions, can lead to reduced pipeline flow rates, decreased transportation efficiency, and even potential safety hazards. Therefore, in-depth research on the wax deposition characteristics and mechanisms in high-viscosity systems holds significant theoretical and engineering application value. Current research primarily focuses on the influencing factors of wax deposition, deposition mechanisms, and the establishment of prediction models. Studies have shown that external factors such as temperature, shear intensity, operating time, and water content have significant effects on the wax deposition process. Specifically, increased temperature differences accelerate the deposition of wax molecules, while the presence of the aqueous phase inhibits wax crystallization and deposition. Furthermore, the formation mechanisms of wax deposition mainly include molecular diffusion, shear stripping, and aging effects. Researchers have explored the dynamic changes and influencing laws of wax deposition by establishing mathematical models combined with experimental data. In summary, although some progress has been made in studying the wax deposition characteristics in high-viscosity systems, research on wax deposition characteristics in mixtures, especially under the combined action of pour point depressants and flow improvers, is still inadequate. Future research should strengthen the systematic exploration of wax deposition mechanisms, quantify the effects of different external factors, and develop wax deposition prediction models suitable for practical engineering to ensure the safe and stable operation of deepwater oil and gas pipelines. Through in depth theoretical and experimental research, robust technical support can be provided for the efficient development of deepwater oil and gas resources. Full article
(This article belongs to the Section Energy Systems)
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22 pages, 2888 KiB  
Article
Filtration Experiments for Assessing EOR Efficiency in High-Viscosity Oil Reservoirs: A Case Study of the East Moldabek Field, Kazakhstan
by Karlygash Soltanbekova, Gaukhar Ramazanova, Uzak Zhapbasbayev and Zhenis Kuatov
Processes 2025, 13(4), 1069; https://doi.org/10.3390/pr13041069 - 3 Apr 2025
Viewed by 457
Abstract
This study is dedicated to fundamental research on evaluating the effectiveness of enhanced oil recovery (EOR) methods for high-viscosity oil reservoirs. This paper presents the results of filtration experiments assessing the application of thermal, chemical, and gas-based EOR techniques to reservoir cores of [...] Read more.
This study is dedicated to fundamental research on evaluating the effectiveness of enhanced oil recovery (EOR) methods for high-viscosity oil reservoirs. This paper presents the results of filtration experiments assessing the application of thermal, chemical, and gas-based EOR techniques to reservoir cores of high-viscosity oil, using the East Moldabek field in Kazakhstan as a case study. Experimental studies were conducted on the Cretaceous horizons M-II and M-III as well as the Jurassic horizon J-IV. The obtained production data from the East Moldabek wells indicated the low efficiency of conventional recovery methods. The objective of this study was to identify the most effective EOR method in terms of displacement efficiency. The investigated recovery techniques included base case conventional waterflooding (displacement using formation water), thermal EOR (hot-water flooding), chemical EOR (polymer flooding and ASP flooding), and gas EOR (nitrogen and CO2 flooding). The filtration experiments were conducted at different times using various filtration systems. The results indicated that the most effective EOR methods for the highly viscous oil in the East Moldabek field were the chemical and thermal EOR techniques. The chemical EOR included ASP flooding, polymer flooding, and surfactant solution injection. ASP flooding achieved the highest increase in displacement efficiency, reaching 19%, making it the most effective method among all of the others. Full article
(This article belongs to the Section Chemical Processes and Systems)
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