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19 pages, 5407 KB  
Article
A Study on Reducing Loss in PCB Motor Stator Using Multi-Via Structure
by Su-Bin Jeon, Do-Hyeon Choi, Hyung-Sub Han, Yun-Ha Song and Won-Ho Kim
Actuators 2025, 14(9), 424; https://doi.org/10.3390/act14090424 - 29 Aug 2025
Abstract
This study proposes a multi-via structure as a loss-reduction design technique to mitigate current crowding in a slotless axial flux permanent magnet motor (AFPM) equipped with printed circuit board (PCB) stators. The PCB stator enables high current density operation through parallel copper-foil stacking [...] Read more.
This study proposes a multi-via structure as a loss-reduction design technique to mitigate current crowding in a slotless axial flux permanent magnet motor (AFPM) equipped with printed circuit board (PCB) stators. The PCB stator enables high current density operation through parallel copper-foil stacking and supports an ultra-compact structural configuration. However, current concentration in the via regions can increase copper loss and phase resistance. In this work, the via position and diameter were defined as design variables to perform a sensitivity analysis of current distribution and phase resistance variation. The effects of current density dispersion and the potential for copper loss reduction were evaluated using three-dimensional finite-element analysis (FEA). The results confirm that adopting a multi-via structure improves current path uniformity and reduces electrical losses, thereby enhancing overall efficiency. Furthermore, the analysis shows that excessive via enlargement or overuse does not necessarily yield optimal results and, in certain cases, may lead to localized current peaks. These findings demonstrate that the multi-via structure is an effective and appropriate design strategy for PCB stators and highlight the importance of optimized via placement tailored to each stator configuration. Full article
(This article belongs to the Special Issue Recent Developments in Precision Actuation Technologies)
34 pages, 945 KB  
Review
Artificial Intelligence in Ocular Transcriptomics: Applications of Unsupervised and Supervised Learning
by Catherine Lalman, Yimin Yang and Janice L. Walker
Cells 2025, 14(17), 1315; https://doi.org/10.3390/cells14171315 - 26 Aug 2025
Viewed by 294
Abstract
Transcriptomic profiling is a powerful tool for dissecting the cellular and molecular complexity of ocular tissues, providing insights into retinal development, corneal disease, macular degeneration, and glaucoma. With the expansion of microarray, bulk RNA sequencing (RNA-seq), and single-cell RNA-seq technologies, artificial intelligence (AI) [...] Read more.
Transcriptomic profiling is a powerful tool for dissecting the cellular and molecular complexity of ocular tissues, providing insights into retinal development, corneal disease, macular degeneration, and glaucoma. With the expansion of microarray, bulk RNA sequencing (RNA-seq), and single-cell RNA-seq technologies, artificial intelligence (AI) has emerged as a key strategy for analyzing high-dimensional gene expression data. This review synthesizes AI-enabled transcriptomic studies in ophthalmology from 2019 to 2025, highlighting how supervised and unsupervised machine learning (ML) methods have advanced biomarker discovery, cell type classification, and eye development and ocular disease modeling. Here, we discuss unsupervised techniques, such as principal component analysis (PCA), t-distributed stochastic neighbor embedding (t-SNE), uniform manifold approximation and projection (UMAP), and weighted gene co-expression network analysis (WGCNA), now the standard in single-cell workflows. Supervised approaches are also discussed, including the least absolute shrinkage and selection operator (LASSO), support vector machines (SVMs), and random forests (RFs), and their utility in identifying diagnostic and prognostic markers in age-related macular degeneration (AMD), diabetic retinopathy (DR), glaucoma, keratoconus, thyroid eye disease, and posterior capsule opacification (PCO), as well as deep learning frameworks, such as variational autoencoders and neural networks that support multi-omics integration. Despite challenges in interpretability and standardization, explainable AI and multimodal approaches offer promising avenues for advancing precision ophthalmology. Full article
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16 pages, 14897 KB  
Article
Model Insights into the Role of Bed Topography on Wetland Performance
by Andrea Bottacin-Busolin, Gianfranco Santovito and Andrea Marion
Water 2025, 17(17), 2528; https://doi.org/10.3390/w17172528 - 25 Aug 2025
Viewed by 388
Abstract
Free water surface constructed wetlands can be effective systems for contaminant removal, but their performance is sensitive to interactions among flow dynamics, vegetation, and bed topography. This study presents a numerical investigation into how heterogeneous bed topographies influence hydraulic and contaminant transport behavior [...] Read more.
Free water surface constructed wetlands can be effective systems for contaminant removal, but their performance is sensitive to interactions among flow dynamics, vegetation, and bed topography. This study presents a numerical investigation into how heterogeneous bed topographies influence hydraulic and contaminant transport behavior in a rectangular wetland. Topographies were generated using a correlated pseudo-random pattern generator, and flow and solute transport were simulated with a two-dimensional, depth-averaged model. Residence time distributions and contaminant removal efficiencies were analyzed as functions of the variance and correlation length of the bed elevation. Results indicate that increasing the variability of bed elevation leads to greater dispersion in residence times, reducing hydraulic efficiency. Moreover, as the variability of bed elevation increases, so does the spread in hydraulic performance among wetlands with the same statistical topographic parameters, indicating a growing sensitivity of flow behavior to the specific spatial configurations of bed features. Larger spatial correlation lengths were found to reduce the residence time variance, as shorter correlation lengths promoted complex flow structures with lateral dead zones and internal islands. Contaminant removal efficiency, evaluated under the assumption of uniform vegetation, was influenced by bed topography, with variations becoming more pronounced under conditions of lower vegetation density. The results underscore the significant impact of bed topography on hydraulic behavior and contaminant removal performance, highlighting the importance of careful topographic design to ensure high wetland efficiency. Full article
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22 pages, 8222 KB  
Article
Structural Health Monitoring of Defective Carbon Fiber Reinforced Polymer Composites Based on Multi-Sensor Technology
by Wuyi Li, Heng Huang, Boli Wan, Xiwen Pang and Guang Yan
Sensors 2025, 25(17), 5259; https://doi.org/10.3390/s25175259 - 24 Aug 2025
Viewed by 475
Abstract
Carbon fiber reinforced polymer (CFRP) composites are prone to developing localized material loss defects during long-term service, which can severely degrade their mechanical properties and structural reliability. To address this issue, this study proposes a multi-sensor synchronous monitoring method combining embedded fiber Bragg [...] Read more.
Carbon fiber reinforced polymer (CFRP) composites are prone to developing localized material loss defects during long-term service, which can severely degrade their mechanical properties and structural reliability. To address this issue, this study proposes a multi-sensor synchronous monitoring method combining embedded fiber Bragg grating (FBG) sensors and surface-mounted electrical resistance strain gauges. First, finite element simulations based on the three-dimensional Hashin damage criterion were performed to simulate the damage initiation and propagation processes in CFRP laminates, revealing the complete damage evolution mechanism from initial defect formation to progressive failure. The simulations were also used to determine the optimal sensor placement strategy. Subsequently, tensile test specimens with prefabricated defects were prepared in accordance with ASTM D3039, and multi-sensor monitoring techniques were employed to capture multi-parameter, dynamic data throughout the damage evolution process. The experimental results indicate that embedded FBG sensors and surface-mounted strain gauges can effectively monitor localized material loss defects within composite laminate structures. Strain gauge measurements showed uniform strain distribution at all measuring points in intact specimens (with deviations less than 5%). In contrast, in defective specimens, strain values at measurement points near the notch edge were significantly higher than those in regions farther from the notch, indicating that the prefabricated defect disrupted fiber continuity and induced stress redistribution. The combined use of surface-mounted strain gauges and embedded FBG sensors was demonstrated to accurately and reliably track the damage evolution behavior of defective CFRP laminates. Full article
(This article belongs to the Section Sensor Materials)
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15 pages, 2690 KB  
Article
Analysis on Inner Flow Field and Hydrodynamic Force on Flexible Mining Pipeline Under Bending States
by Wen-Hua Wang, Lei Wang, Chuang Liu, Li-Jian Wang, Zi-Han Zhao, Lei-Lei Dong, Gang Liu, Ying-Ying Wang, Hai-Bo Sun and Kun Li
J. Mar. Sci. Eng. 2025, 13(8), 1599; https://doi.org/10.3390/jmse13081599 - 21 Aug 2025
Viewed by 309
Abstract
To investigate the internal flow characteristics of particles during hydraulic lifting in deep-sea mining risers, this study developed a three-dimensional curved riser multiphase flow model based on the Eulerian–Eulerian framework and the RNG k-ε turbulence model. The effects of particle distribution [...] Read more.
To investigate the internal flow characteristics of particles during hydraulic lifting in deep-sea mining risers, this study developed a three-dimensional curved riser multiphase flow model based on the Eulerian–Eulerian framework and the RNG k-ε turbulence model. The effects of particle distribution and pressure loss in the curved section, as well as the influence of curvature radius, were analyzed. Results indicate that particle distributions take concave circular or crescent-shaped patterns, becoming more uniform with larger curvature radii. Pressure on the extrados is consistently greater than on the intrados, with pressure loss increasing in the bend and peaking at the midpoint. A larger curvature radius leads to greater total pressure loss but lower frictional loss. Additionally, the bend experiences a restoring force toward the vertical position, which increases as the curvature radius decreases. Full article
(This article belongs to the Section Ocean Engineering)
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38 pages, 24625 KB  
Article
Field Calibration of the Optical Properties of Pedestrian Targets in Autonomous Emergency Braking Tests Using a Three-Dimensional Multi-Faceted Standard Body
by Weijie Wang, Chundi Zheng, Houping Wu, Guojin Feng, Ruoduan Sun, Tao Liang, Xikuai Xie, Qiaoxiang Zhang, Yingwei He and Haiyong Gan
Sensors 2025, 25(16), 5145; https://doi.org/10.3390/s25165145 - 19 Aug 2025
Viewed by 309
Abstract
To address the growing need for field calibration of the optical properties of pedestrian targets used in autonomous emergency braking (AEB) tests, a novel three-dimensional multi-faceted standard body (TDMFSB) was developed. A camera-based analytical algorithm was proposed to evaluate the bidirectional reflectance distribution [...] Read more.
To address the growing need for field calibration of the optical properties of pedestrian targets used in autonomous emergency braking (AEB) tests, a novel three-dimensional multi-faceted standard body (TDMFSB) was developed. A camera-based analytical algorithm was proposed to evaluate the bidirectional reflectance distribution function (BRDF) characteristics of pedestrian targets. Additionally, a field calibration method applied in AEB testing scenarios (CPFAO and CPLA protocols) on one new and one aged typical pedestrian target of the same type revealed a 21% decrease in the BRDF uniformity of the aged target compared to the new one, confirming optical degradation due to repeated “crash–scatter–reassembly” cycles. The surface wear of the aged target on the side facing the vehicle produced a smoother surface, increasing its BRDF magnitude by 25% compared to the new target and making it easily detectable by the vehicle’s perception system. This led to “reverse scoring,” a safety risk in performance evaluation, necessitating timely calibration of AEB pedestrian targets to ensure reliable test results. The findings provide valuable insights into the development of regulatory techniques, evaluation standards, and technical specifications for test targets and offer a practical path toward full-life-cycle traceability and quality control. Full article
(This article belongs to the Section Optical Sensors)
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22 pages, 5275 KB  
Article
Effect of Pressure Gradient on Flow and Heat Transfer over Surface-Mounted Heated Blocks in a Narrow Channel
by Dildar Gürses and Erhan Pulat
Appl. Sci. 2025, 15(16), 9099; https://doi.org/10.3390/app15169099 - 18 Aug 2025
Viewed by 248
Abstract
In this study, pressure gradient effects on heat transfer from block-like electronic chips are investigated computationally. The pressure gradient is provided by the slope given to the upper plate and starts just before the first block. Tilt angles of −2°, 0°, 2°, 4° [...] Read more.
In this study, pressure gradient effects on heat transfer from block-like electronic chips are investigated computationally. The pressure gradient is provided by the slope given to the upper plate and starts just before the first block. Tilt angles of −2°, 0°, 2°, 4° and 6° have been used. Air is used as the fluid, and it enters the duct at a constant speed with a uniform velocity profile. Calculations were made for Re numbers (Re = 6000, 9015, and 11,993) defined according to the channel height. For this purpose, conservation and SST k-ω turbulence model equations are solved by using ANSYS-Fluent 20.1 software for two-dimensional, incompressible, and turbulent flow conditions. Velocity, temperature, pressure, and turbulence kinetic energy distributions were obtained and compared for the considered slope angles. The effects of all changing conditions on heat transfer were discussed by calculating local and average Nusselt values, the reattachment lengths after the last block were calculated by plotting, and a comparison was made by plotting the pressure values on the block in the middle of the channel and at the top of the channel. Full article
(This article belongs to the Section Applied Thermal Engineering)
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18 pages, 19901 KB  
Article
A Novel Polysilicon-Fill-Strengthened Etch-Through 3D Trench Electrode Detector: Fabrication Methods and Electrical Property Simulations
by Xuran Zhu, Zheng Li, Zhiyu Liu, Tao Long, Jun Zhao, Xinqing Li, Manwen Liu and Meishan Wang
Micromachines 2025, 16(8), 912; https://doi.org/10.3390/mi16080912 - 6 Aug 2025
Viewed by 349
Abstract
Three-dimensional trench electrode silicon detectors play an important role in particle physics research, nuclear radiation detection, and other fields. A novel polysilicon-fill-strengthened etch-through 3D trench electrode detector is proposed to address the shortcomings of traditional 3D trench electrode silicon detectors; for example, the [...] Read more.
Three-dimensional trench electrode silicon detectors play an important role in particle physics research, nuclear radiation detection, and other fields. A novel polysilicon-fill-strengthened etch-through 3D trench electrode detector is proposed to address the shortcomings of traditional 3D trench electrode silicon detectors; for example, the distribution of non-uniform electric fields, asymmetric electric potential, and dead zone. The physical properties of the detector have been extensively and systematically studied. This study simulated the electric field, potential, electron concentration distribution, complete depletion voltage, leakage current, capacitance, transient current induced by incident particles, and weighting field distribution of the detector. It also systematically studied and analyzed the electrical characteristics of the detector. Compared to traditional 3D trench electrode silicon detectors, this new detector adopts a manufacturing process of double-side etching technology and double-side filling technology, which results in a more sensitive detector volume and higher electric field uniformity. In addition, the size of the detector unit is 120 µm × 120 µm × 340 µm; the structure has a small fully depleted voltage, reaching a fully depleted state at around 1.4 V, with a saturation leakage current of approximately 4.8×1010A, and a geometric capacitance of about 99 fF. Full article
(This article belongs to the Special Issue Photonic and Optoelectronic Devices and Systems, Third Edition)
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15 pages, 712 KB  
Article
Extracting Correlations in Arbitrary Diagonal Quantum States via Weak Couplings and Auxiliary Systems
by Hui Li, Chao Zheng, Yansong Li and Xian Lu
Symmetry 2025, 17(8), 1233; https://doi.org/10.3390/sym17081233 - 4 Aug 2025
Viewed by 271
Abstract
In this work, we introduce a novel method to extract correlations in diagonal quantum states in multi-particle quantum systems, addressing a significant limitation of traditional approaches that require prior knowledge of the density matrices of quantum states. Instead of relying on classical information [...] Read more.
In this work, we introduce a novel method to extract correlations in diagonal quantum states in multi-particle quantum systems, addressing a significant limitation of traditional approaches that require prior knowledge of the density matrices of quantum states. Instead of relying on classical information processing, our method is based on weak couplings and ancillary systems, eliminating the need for classical communication, optimization, and complex calculations. The concept of mutually unbiased bases is intrinsically linked to symmetry, as it entails the uniform distribution of quantum states across distinct bases. Within the framework of our theoretical model, mutually unbiased bases are employed to facilitate weak measurements and to function as the post-selected states. To quantify the correlations in the initial state, we employ the trace distance between the initial state and the product of its marginal states, and illustrate the feasibility and effectiveness of our approach. We generalize the approach to accommodate high-dimensional multi-particle systems for potential applications in quantum information processing and quantum networks. Full article
(This article belongs to the Topic Quantum Systems and Their Applications)
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11 pages, 3181 KB  
Article
Development of a Three-Dimensional Nanostructure SnO2-Based Gas Sensor for Room-Temperature Hydrogen Detection
by Zhilong Song, Yi Tian, Yue Kang and Jia Yan
Sensors 2025, 25(15), 4784; https://doi.org/10.3390/s25154784 - 3 Aug 2025
Viewed by 426
Abstract
The development of gas sensors with high sensitivity and low operating temperatures is essential for practical applications in environmental monitoring and industrial safety. SnO2-based gas sensors, despite their widespread use, often suffer from high working temperatures and limited sensitivity to H [...] Read more.
The development of gas sensors with high sensitivity and low operating temperatures is essential for practical applications in environmental monitoring and industrial safety. SnO2-based gas sensors, despite their widespread use, often suffer from high working temperatures and limited sensitivity to H2 gas, which presents significant challenges for their performance and application. This study addresses these issues by introducing a novel SnO2-based sensor featuring a three-dimensional (3D) nanostructure, designed to enhance sensitivity and allow for room-temperature operation. This work lies in the use of a 3D anodic aluminum oxide (AAO) template to deposit SnO2 nanoparticles through ultrasonic spray pyrolysis, followed by modification with platinum (Pt) nanoparticles to further enhance the sensor’s response. The as-prepared sensors were extensively characterized, and their H2 sensing performance was evaluated. The results show that the 3D nanostructure provides a uniform and dense distribution of SnO2 nanoparticles, which significantly improves the sensor’s sensitivity and repeatability, especially in H2 detection at room temperature. This work demonstrates the potential of utilizing 3D nanostructures to overcome the traditional limitations of SnO2-based sensors. Full article
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24 pages, 90648 KB  
Article
An Image Encryption Method Based on a Two-Dimensional Cross-Coupled Chaotic System
by Caiwen Chen, Tianxiu Lu and Boxu Yan
Symmetry 2025, 17(8), 1221; https://doi.org/10.3390/sym17081221 - 2 Aug 2025
Viewed by 443
Abstract
Chaotic systems have demonstrated significant potential in the field of image encryption due to their extreme sensitivity to initial conditions, inherent unpredictability, and pseudo-random behavior. However, existing chaos-based encryption schemes still face several limitations, including narrow chaotic regions, discontinuous chaotic ranges, uneven trajectory [...] Read more.
Chaotic systems have demonstrated significant potential in the field of image encryption due to their extreme sensitivity to initial conditions, inherent unpredictability, and pseudo-random behavior. However, existing chaos-based encryption schemes still face several limitations, including narrow chaotic regions, discontinuous chaotic ranges, uneven trajectory distributions, and fixed pixel processing sequences. These issues substantially hinder the security and efficiency of such algorithms. To address these challenges, this paper proposes a novel hyperchaotic map, termed the two-dimensional cross-coupled chaotic map (2D-CFCM), derived from a newly designed 2D cross-coupled chaotic system. The proposed 2D-CFCM exhibits enhanced randomness, greater sensitivity to initial values, a broader chaotic region, and a more uniform trajectory distribution, thereby offering stronger security guarantees for image encryption applications. Based on the 2D-CFCM, an innovative image encryption method was further developed, incorporating efficient scrambling and forward and reverse random multidirectional diffusion operations with symmetrical properties. Through simulation tests on images of varying sizes and resolutions, including color images, the results demonstrate the strong security performance of the proposed method. This method has several remarkable features, including an extremely large key space (greater than 2912), extremely high key sensitivity, nearly ideal entropy value (greater than 7.997), extremely low pixel correlation (less than 0.04), and excellent resistance to differential attacks (with the average values of NPCR and UACI being 99.6050% and 33.4643%, respectively). Compared to existing encryption algorithms, the proposed method provides significantly enhanced security. Full article
(This article belongs to the Special Issue Symmetry in Chaos Theory and Applications)
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15 pages, 2172 KB  
Article
Quantifying Macropore Variability in Terraced Paddy Fields Using X-Ray Computed Tomography
by Rong Ma, Linlin Chu, Lidong Bi, Dan Chen and Zhaohui Luo
Agronomy 2025, 15(8), 1873; https://doi.org/10.3390/agronomy15081873 - 1 Aug 2025
Viewed by 343
Abstract
Large soil pores critically influence water and solute transport in soils. The presence of preferential flow paths created by soil macropores can profoundly impact water quality, underscoring the necessity of accurately assessing the characteristics of these macropores. However, it remains unclear whether variations [...] Read more.
Large soil pores critically influence water and solute transport in soils. The presence of preferential flow paths created by soil macropores can profoundly impact water quality, underscoring the necessity of accurately assessing the characteristics of these macropores. However, it remains unclear whether variations in macropore structure exist between different altitudes and positions of terraced paddy fields. The primary objective of this research was to utilize X-ray computed tomography (CT) and image analysis techniques to characterize the soil pore structure at both the inner field and ridge positions across different altitude levels (high, medium, and low altitude) within terraced paddy fields. The results indicate that there are significant differences in the distribution of large soil pores at different altitudes, with large pores concentrated in the surface layer (0–10 cm) in low-altitude areas, while in high-altitude areas, the distribution of large pores is more uniform. Additionally, as altitude increases, the porosity of large pores shows an increasing trend. The three-dimensional equivalent diameter and large pore volume are primarily characterized by large pores ranging from 1 to 2 mm and 0 to 5 mm3, respectively, with their morphology predominantly appearing spherical or ellipsoidal. The connectivity of large pores in the surface layer of paddy soil is stronger than that in the bunds. However, this connectivity gradually weakens with increasing soil depth. The findings from this study provide valuable quantitative insights into the unique characteristics of soil macropores that vary according to the altitude and position in terraced paddy fields. Moreover, this study emphasizes the necessity for future research that encompasses a broader range of soil types, altitudes, and terraced paddy locations to validate and further explore the identified relationships between altitude and macropore characteristics. Full article
(This article belongs to the Section Precision and Digital Agriculture)
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21 pages, 5468 KB  
Article
Simulation Study of Cylinder-to-Cylinder Variation Phenomena and Key Influencing Factors in a Six-Cylinder Natural Gas Engine
by Demin Jia, Qi Cao, Xiaoying Xu, Zhenlin Wang, Dan Wang and Hongqing Wang
Energies 2025, 18(15), 4078; https://doi.org/10.3390/en18154078 - 1 Aug 2025
Viewed by 265
Abstract
Cylinder-to-cylinder variation (CTCV) is a prevalent issue for natural gas (NG) premixed engines with port fuel injection (PFI), which significantly impacts the engine’s power performance, fuel economy, and reliability. Focusing on this issue, this study established a three-dimensional simulation platform based on a [...] Read more.
Cylinder-to-cylinder variation (CTCV) is a prevalent issue for natural gas (NG) premixed engines with port fuel injection (PFI), which significantly impacts the engine’s power performance, fuel economy, and reliability. Focusing on this issue, this study established a three-dimensional simulation platform based on a six-cylinder natural gas premixed engine. Quantitative analysis was conducted to discuss the differences in the main boundaries, combustion process, and engine power between cylinders. Additionally, influencing factors of CTCV were explored in terms of mixture uniformity and distribution uniformity. The results indicate that, for the NG premixed engine, many parameters vary significantly between cylinders even under the economical operating condition of 1200 rpm. For example, the difference rate in the peak cylinder pressure and peak phase between cylinder 3 and cylinder 2 can reach 23.5% and 24.3%, respectively. Through the design of simulation cases, it was found that improving the mixture uniformity had a more significant impact on CTCV than improving the distribution uniformity. For example, the relative standard deviation (RSD) of peak pressure decreased by 2.15% through mixture uniformity improvement, while it only decreased by 0.39% through distribution uniformity improvement. At a high speed of 1800 rpm, the influence of distribution uniformity on CTCV increased notably, but the influence of mixture uniformity still remained greater than that of distribution uniformity. Full article
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17 pages, 6842 KB  
Article
Inside the Framework: Structural Exploration of Mesoporous Silicas MCM-41, SBA-15, and SBA-16
by Agnieszka Karczmarska, Wiktoria Laskowska, Danuta Stróż and Katarzyna Pawlik
Materials 2025, 18(15), 3597; https://doi.org/10.3390/ma18153597 - 31 Jul 2025
Viewed by 457
Abstract
In the rapidly evolving fields of materials science, catalysis, electronics, drug delivery, and environmental remediation, the development of effective substrates for molecular deposition has become increasingly crucial. Ordered mesoporous silica materials have garnered significant attention due to their unique structural properties and exceptional [...] Read more.
In the rapidly evolving fields of materials science, catalysis, electronics, drug delivery, and environmental remediation, the development of effective substrates for molecular deposition has become increasingly crucial. Ordered mesoporous silica materials have garnered significant attention due to their unique structural properties and exceptional potential as substrates for molecular immobilization across these diverse applications. This study compares three mesoporous silica powders: MCM-41, SBA-15, and SBA-16. A multi-technique characterization approach was employed, utilizing low- and wide-angle X-ray diffraction (XRD), nitrogen physisorption, and transmission electron microscopy (TEM) to elucidate the structure–property relationships of these materials. XRD analysis confirmed the amorphous nature of silica frameworks and revealed distinct pore symmetries: a two-dimensional hexagonal (P6mm) structure for MCM-41 and SBA-15, and three-dimensional cubic (Im3¯m) structure for SBA-16. Nitrogen sorption measurements demonstrated significant variations in textural properties, with MCM-41 exhibiting uniform cylindrical mesopores and the highest surface area, SBA-15 displaying hierarchical meso- and microporosity confirmed by NLDFT analysis, and SBA-16 showing a complex 3D interconnected cage-like structure with broad pore size distribution. TEM imaging provided direct visualization of particle morphology and internal pore architecture, enabling estimation of lattice parameters and identification of structural gradients within individual particles. The integration of these complementary techniques proved essential for comprehensive material characterization, particularly for MCM-41, where its small particle size (45–75 nm) contributed to apparent structural inconsistencies between XRD and sorption data. This integrated analytical approach provides valuable insights into the fundamental structure–property relationships governing ordered mesoporous silica materials and demonstrates the necessity of combined characterization strategies for accurate structural determination. Full article
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20 pages, 8499 KB  
Article
Characterization of Low-Temperature Waste-Wood-Derived Biochar upon Chemical Activation
by Bilge Yilmaz, Vasiliki Kamperidou, Serhatcan Berk Akcay, Turgay Kar, Hilal Fazli and Temel Varol
Forests 2025, 16(8), 1237; https://doi.org/10.3390/f16081237 - 27 Jul 2025
Viewed by 359
Abstract
Depending on the feedstock type and the pyrolysis conditions, biochars exhibit different physical, chemical, and structural properties, which highly influence their performance in various applications. This study presents a comprehensive characterization of biochar materials derived from the waste wood of pine (Pinus [...] Read more.
Depending on the feedstock type and the pyrolysis conditions, biochars exhibit different physical, chemical, and structural properties, which highly influence their performance in various applications. This study presents a comprehensive characterization of biochar materials derived from the waste wood of pine (Pinus sylvestris L.) and beech (Fagus sylvatica) after low-temperature pyrolysis at 270 °C, followed by chemical activation using zinc chloride. The resulting materials were thoroughly analyzed in terms of their chemical composition (FTIR), thermal behavior (TGA/DTG), structural morphology (SEM and XRD), elemental analysis, and particle size distribution. The successful modification of raw biomass into carbon-rich structures of increased aromaticity and thermal stability was confirmed. Particle size analysis revealed that the activated carbon of Fagus sylvatica (FSAC) exhibited a monomodal distribution, indicating high homogeneity, whereas Pinus sylvestris-activated carbon showed a distinct bimodal distribution. This heterogeneity was supported by elemental analysis, revealing a higher inorganic content in pine-activated carbon, likely contributing to its dimensional instability during activation. These findings suggest that the uniform morphology of beech-activated carbon may be advantageous in filtration and adsorption applications, while pine-activated carbon’s heterogeneous structure could be beneficial for multifunctional systems requiring variable pore architectures. Overall, this study underscored the potential of chemically activated biochar from lignocellulosic residues for customized applications in environmental and material science domains. Full article
(This article belongs to the Section Wood Science and Forest Products)
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