Search Results (90)

Eutectic alloys stand out for their ability to combine high strength and good ductility; a behaviour rooted in their characteristic two-phase microstructure—lamellar or globular—formed at a constant solidification temperature that minimizes segregation and suppresses brittle phases. Their low interfacial energy limits microcrack propagation, while interfacial sliding and dislocation blocking at phase boundaries enhance both strength and toughness. In this work, we investigate how controlled microstructural modifications influence the behaviour of the eutectic high-entropy alloy AlCoCrFeNi2.1, composed of B2 (Ni–Al-rich) and L12 (Co–Fe–Ni-rich) phases. Because these phases exhibit distinct mechanical responses, microconstituent morphology becomes a design parameter. Powder metallurgy is the only processing route capable of providing the level of microstructural control required in this study. It preserves the rapidly solidified eutectic architecture of gas-atomised powders while allowing its intentional transformation during consolidation. Two strategies were implemented: (i) tuning the thermal–electrical input in Spark Plasma Sintering (SPS) and Electrical Resistance Sintering (ERS), and (ii) engineering the particle size distribution, including a bimodal design that enhances surface-energy-driven morphological transitions. SPS enables a gradual lamellar-to-globular evolution, whereas ERS induces ultrafast transformations governed by current intensity. The bimodal PSD significantly accelerates globularisation at lower energy input. EBSD-KAM (Electron Backscatter Diffraction—Kernel Average Misorientation) mapping identifies the lamellar B2 phase as metastable and highly strained, while globular B2 domains show reduced dislocation density. Nanoindentation confirms that intrinsic phase properties remain unchanged, whereas microhardness scales with morphology and lamellar spacing. These results demonstrate that the macroscopic mechanical response is governed by microstructure, establishing powder metallurgy as a uniquely powerful pathway for microstructure-driven design in eutectic HEAs. Full article

We present a rapid, energy-efficient, and ecofriendly route for the synthesis of alkaline earth titanate perovskites—CaTiO₃, SrTiO₃, and BaTiO₃—using an affordable, commercially available CO₂ laser engraver, commonly found in makerspaces and small-scale workshops. The method involves direct laser irradiation of compacted pellets composed of low-cost, abundant, and non-toxic precursors: TiO₂ and alkaline earth carbonates (CaCO₃, SrCO₃, BaCO₃). CaTiO₃ and BaTiO₃ were synthesized with phase purities exceeding 97%, eliminating the need for conventional high-temperature furnaces or prolonged thermal treatments. X-ray diffraction (XRD) coupled with Rietveld refinement confirmed the formation of orthorhombic CaTiO₃ (Pbnm), cubic SrTiO₃ (Pm3⁻m), and tetragonal BaTiO₃ (P4mm). Raman spectroscopy independently corroborated the perovskite structures, revealing vibrational fingerprints consistent with the expected crystal symmetries and Ti–O bonding environments. All samples contained only small amounts of unreacted anatase TiO₂, while BaTiO₃ exhibited a partially amorphous fraction, attributed to the sluggish crystallization kinetics of the Ba–Ti system and the rapid quenching inherent to laser processing. Transmission electron microscopy (TEM) revealed nanoparticles with average sizes of 50–150 nm, indicative of localized melting followed by ultrafast solidification. This solvent-free, low-energy, and highly accessible approach, enabled by widely available desktop laser systems, demonstrates exceptional simplicity, scalability, and sustainability. It offers a compelling alternative to conventional ceramic processing, with broad potential for the fabrication of functional oxides in applications ranging from electronics to photocatalysis. Full article

Diffractive optical elements (DOEs) are essential components in optical and photonic technologies, motivating the need for rapid mass production with high-precision fabrication methods. Photopolymers are particularly attractive for DOEs production because their optical phase can be modified via both surface and refractive index modulations. In this work, we report the fabrication of DOEs on PVA/AA photopolymers using ultrafast laser direct writing. By combining surface topography measurements with a phase depth model, we extract the surface and bulk phase depth contributions and demonstrate a transition from surface-dominated modulation at 1 kHz to bulk refractive index modification under cumulative conditions at 100 kHz. These outcomes highlight ultrafast laser direct writing as a powerful, rapid and controlled method for the high-quality and rapid fabrication of DOEs. Full article

Two-photon polymerization (2PP) is revolutionizing micro- and nanoscale manufacturing by enabling true 3D fabrication with feature sizes far below the diffraction limit—capabilities that traditional lithography cannot match. By using ultrafast femtosecond laser pulses and nonlinear absorption, 2PP initiates polymerization only at the laser’s focal point, offering unmatched spatial precision. This paper highlights key advancements driving the field forward: the development of new materials engineered for 2PP with improved sensitivity, mechanical strength, and the introduction of high-speed, parallelized fabrication strategies that significantly enhance throughput. These innovations are shifting 2PP from a prototyping tool to a viable method for scalable production. Applications now range from custom biomedical scaffolds to complex photonic and metamaterial structures, demonstrating their growing real-world impact. We also address persistent challenges—including slow writing speeds and limited material options—and explore future directions to overcome these barriers. With continued progress in materials and hardware, 2PP is well positioned to become a cornerstone of next-generation additive manufacturing. Full article

We report the synthesis, spectroscopic, structural, and ultrafast photophysical investigation of a series of homoleptic and heteroleptic Zn(II) complexes based on the donor-acceptor β-diketonate ligand 4,4,4-trifluoro-1-phenylbutane-1,3-dione. Mass spectrometry, infrared, and NMR analyses confirm complexation and indicate possible fragmentation pathways involving the sequential loss of β-diketonate ligands. Single-crystal X-ray diffraction revealed that all complexes adopt monomeric octahedral geometries, with the ancillary nitrogen-based ligands introducing variable distortions. Thermal analyses confirmed that the complexes are non-volatile and have an onset >250 °C, with thermal decomposition primarily to ZnO and ZnF₂. Complexes with aromatic Lewis base led to higher residue percentages, likely due to the final graphitic carbon content. UV-Vis absorption and femtosecond transient absorption spectroscopy demonstrate that the chelated β-diketonate ring serves as the main optically active chromophore, a property unaffected by the nitrogen ligands. The free ligand undergoes rapid internal conversion, whereas coordination to Zn stabilizes the triplet state via LMCT, producing long-lived and chemically reactive species relevant to dissociation processes. This study demonstrates how tailored ligand environments can be exploited to tune excited-state properties, offering a rational framework for the design of functional precursors suitable for nonlinear photolysis and advanced nanomaterial synthesis. Full article

Silicon carbide (SiC) is a promising semiconductor material for electronics and photonics. Ultrafast laser processing of SiC enables three-dimensional nanostructuring, enriching and expanding the functionalities of SiC devices. However, challenges arise in delivering uniform, high-aspect-ratio (length-to-width) nanostructures due to difficulties in confining light energy at the nanoscale while simultaneously regulating intense photo modifications. In this study, we report the controllable growth of long-distance, high-straightness, and high-parallelism multifilament structures in SiC using ultrafast laser processing. The mechanism is the formation of femtosecond multifilaments through the nonlinear effects of clamping equilibrium, which allow highly confined light to propagate without diffraction in parallel channels, further inducing high-aspect-ratio nanostripe-like photomodifications. By employing an elliptical Gaussian beam—rather than a circular one—and optimizing pulse durations to stabilize multifilaments with regular positional distributions, the induced multifilament structures can reach a length of approximately 90 μm with a minimum linewidth of only 28 nm, resulting in an aspect ratio of over 3200:1. Raman tests indicate that the photomodified regions consist of amorphous SiC, amorphous silicon, and amorphous carbon, and photoluminescence tests reveal that silicon vacancy color centers could be induced in areas with lower light power density. By leveraging femtosecond multifilaments for diffraction-less light confinement, this work proposes an effective method for manufacturing deep-subwavelength, high-aspect-ratio nanostructures in SiC. Full article

The Ti-6242 titanium alloy samples were forged at 1020 °C (slightly above the β-transus) and subjected to ultra-short isothermal holding (0–320 s) prior to quenching to investigate the rapid microstructural evolution in the parent β phase. Electron backscatter diffraction (EBSD) with parent β-phase reconstruction reveals that within only 1–3 s of holding, a pronounced <111> fiber texture develops along the forging axis, superseding the original <100> deformation fiber. This ultrafast texture change is attributed to metadynamic recrystallization (MDRX)—the post-deformation growth of nuclei formed during dynamic deformation. The newly formed <111>-oriented β grains still contain residual substructure, indicating incomplete strain release consistent with MDRX. Longer holds (tens of seconds) lead to more extensive static recrystallization and normal grain growth, which dilute the strong <111> fiber as grains of other orientations form and coarsen. These findings demonstrate that even a brief pause after forging can markedly alter the prior β texture via a MDRX mechanism. This insight highlights a novel approach to microtexture control in Ti-6242: by leveraging MDRX during short holds, one can potentially disrupt the formation of aligned α colony microtextured regions (MTRs, or “macrozones”) upon subsequent cooling, thereby mitigating dwell-fatigue susceptibility. The study revises the interpretation of the recrystallization mechanism in short-term holds and provides guidance for optimizing β-phase processing to improve fatigue performance. Full article

Ultrafast laser processing can produce micro/nanostructures, which is of great interest in advanced manufacturing. Ultrafast laser-induced events include non-equilibrium dynamic phenomena, occurring on the femtosecond to picosecond time scale and nanometer to micron space scale. Single-shot ultrafast imaging can provide multiple time-correlated evolution frames in one non-repeatable event with a temporal resolution of sub-picoseconds. However, previous approaches suffer from degraded spatial resolution, which is a bottleneck in microscopic imaging. For the spatial-frequency multiplexing methods based on structured illumination, a reconstruction strategy was proposed utilizing the frames’ conjugate symmetry in the Fourier domain. The spatial resolution is double that of the traditional algorithm by evaluating with synthetic data, revealing that the reconstruction resolution can reach the diffraction limitation. A two-frame microscopic system was constructed with a frame interval of 300 fs and a maximum spatial resolution of 1.4 μm. The interaction between a femtosecond laser and a fused silica glass plate was captured in a single shot and the dynamic evolution of the induced plasma was observed, verifying the application feasibility in ultrafast laser processing, providing experimental observations for interaction mechanism research and theoretical model optimization. Full article

A spectral filter utilizing dispersive prisms and an optical fiber collimator is presented as an attractive alternative to diffraction grating-based spectral filters. A simplified analytical expression for this prism-based spectral filter is derived. A spectral filter constructed using SF11 flint glass prisms demonstrates Gaussian spectral filter profiles with bandwidths of 8 nm and 4 nm, closely matching with theoretical predictions. Using these filters, we demonstrate two types of mode-locking regimes: a dissipative soliton (DS) pulse and a self-similar (SS) pulse. The dissipative soliton pulses deliver 3.3 nJ with dechirped pulse durations of 206 fs, while the self-similar pulses deliver 2.1 nJ with durations of 120 fs. The results demonstrate that the prism-based filters are well-suited for ultrafast mode-locked fiber lasers. Full article

Recent achievements in ultrafast spin physics have enabled the use of heterostructures composed of ferromagnetic (FM)/non-magnetic (NM) thin layers for terahertz (THz) generation. The mechanism of THz emission from FM/NM multilayers has been typically ascribed to the inverse spin Hall effect (ISHE). In this work, we probe the mechanism of the ISHE by inserting a second ferromagnetic layer in the form of an alloy between the FM/NM system. In particular, by utilizing the co-sputtering technique, we fabricate Fe/L1₀-FePt/Pt ultra-thin heterostructures. We successfully grow the tetragonal phase of FePt (L1₀-phase) as revealed by X-ray diffraction and reflection techniques. We show the strong magnetic coupling between Fe and L1₀-FePt using magneto-optical and Superconducting Quantum Interference Device (SQUID) magnetometry. Subsequently, by utilizing THz time domain spectroscopy technique, we record the THz emission and thus we the reveal the efficiency of spin-to-charge conversion in Fe/L1₀-FePt/Pt. We establish that Fe/L1₀-FePt/Pt configuration is significantly superior to the Fe/Pt bilayer structure, regarding THz emission amplitude. The unique trilayer structure opens new perspectives in terms of material choices for the future spintronic THz sources. Full article

In this paper, we report on the growth and characterization of high doping concentration (2.1 at%) ytterbium (Yb) doped lithium niobate (Yb:LiNbO₃) crystal. By using a slightly modified Czochralski method, we have successfully grown a usable size (2 mm × 2 mm × 30 mm) Yb:LiNbO₃ single crystal. We also conducted the energy-dispersive X-ray spectroscopy (EDS) and the X-ray diffraction (XRD) analyses, which experimentally confirm that the grown crystal is a Yb:LiNbO₃ single crystal. We also measured the absorption and emission spectra of the grown crystal. It was found out that there is a near-flat broad emission within a spectral range of 1004–1030 nm when excited at 980 nm for this high doping concentration Yb:LiNbO₃ crystal. Such a near-flat broad emission can be very useful for realizing high slope efficiency ultrafast (femtosecond) lasing in the Yb:LiNbO₃ crystal due to the low quantum defect of the Yb:LiNbO₃ crystal. We also investigated the electro-optic effect of the Yb:LiNbO₃. The experimental result confirms that the electro-optic (EO) effect of a highly doped (2.1 at%) lithium niobate crystal is close to the EO value of the pure lithium niobate. Thus, the highly doped Yb:LiNbO₃ crystal can still be an effective electrically tunable lasing medium. It can enable electrically tunable, high slope efficiency femtosecond lasing due to the combined features, including (1) a near flat broad emission spectrum at the spectral range of 1004–1030 nm, (2) a non-compromised electro-optic effect at high doping concentration Yb:LiNbO₃ crystal, and (3) a low quantum defect. Full article

Bismuth telluride (Bi₂Te₃) has attracted significant attention due to its broadband ultrafast optical response and strong nonlinearity at high laser fluence in the field of optoelectronic materials. The objective of this work is to study the effect of Al doping on the structure, linear optical properties, and nonlinear optical absorption behavior of Bi₂Te₃ thin films. The amorphous Al-doped Bi₂Te₃ thin films with varying Al doping concentrations were prepared using magnetron co-sputtering. The structure and linear optical properties were characterized using X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, spectroscopic ellipsometry, and UV/Vis/NIR spectrophotometry. The third-order nonlinear optical absorption properties of Al: Bi₂Te₃ thin films were investigated using the open-aperture Z-scan system with a 100 fs laser pulse width at a wavelength of 800 nm and a repetition rate of 1 kHz. The results indicate that Al dopant reduces both the refractive index and extinction coefficient and induces a redshift in the optical bandgap. The optical properties of the films can be effectively modulated by varying the Al doping concentration. Compared with undoped Bi₂Te₃ thin films, Al-doped Bi₂Te₃ thin films exhibit larger nonlinear optical absorption coefficients and higher damage thresholds and maintaining high transmittance. These findings provide experimental evidence and a reliable approach for the further optimization and design of ultrafast nonlinear optical devices. Full article

Drawing on formal parallels between scalar diffraction theory and quantum mechanics, it is demonstrated that quantum wavefunction propagation requires a holographic model of time. Measurable time manifests between interactions as a duration which is encoded in the frequency domain. It is thus a unified entity, and attempts to subdivide these intervals introduce oscillatory artifacts or spectral broadening, altering the system’s physical characteristics. Analogous to spatial holograms, where information is distributed across interference patterns, temporal intervals encode information as a discrete whole. This framework challenges the concept of continuous time evolution, suggesting instead that discrete trajectories define a frequency spectrum which holographically constructs the associated time interval, giving rise to the experimentally observed energy spread of particles in applications such as time-bin entanglement, ultra-fast light pulses, and the temporal double slit. A generalized model of quantum wavefunction propagation based on recursive Fourier transforms is discussed, and novel applications are proposed, including starlight analysis and quantum cryptography. Full article

Rapid thermal annealing (RTA) has been widely used in semiconductor device processing. However, the rise time of RTA, limited to the millisecond (ms) range, is unsuitable for advanced nanometer-scale electronic devices. Using sub-energy bandgap (E_G) 532 nm ultra-fast 15 nanosecond (ns) pulsed laser annealing, a record-high dielectric constant (high-κ) of 67.8 and a capacitance density of 75 fF/μm² at −0.2 V were achieved in Ni/ZrO₂/TiN capacitors. According to heat source and diffusion equations, the surface temperature of TiN can reach as high as 870 °C at a laser energy density of 16.2 J/cm², effectively annealing the ZrO₂ material. These record-breaking results are enabled by a novel annealing method—the surface plasma effect generated on the TiN metal. This is because the 2.3 eV (532 nm) pulsed laser energy is significantly lower than the 5.0–5.8 eV energy bandgap (E_G) of ZrO₂, making it unabsorbable by the ZrO₂ dielectric. X-ray diffraction analysis reveals that the large κ value and capacitance density are attributed to the enhanced crystallinity of the cubic-phase ZrO₂, which is improved through laser annealing. This advancement is critical for monolithic three-dimensional device integration in the backend of advanced integrated circuits. Full article

The discovery of two-dimensional (2D) van der Waals ferromagnetic materials opens up new avenues for making devices with high information storage density, ultra-fast response, high integration, and low power consumption. Fe₅GeTe₂ has attracted much attention because of its ferromagnetic transition temperature near room temperature. However, the investigation of its phase transition is rare until now. Here, we have successfully synthesized a single crystal of the layered ferromagnet Fe₅GeTe₂ by chemical vapor phase transport, soon after characterized by X-ray diffraction (XRD), DC magnetization M(T), and isotherm magnetization M(H) measurements. A paramagnetic to ferromagnetic transition is observed at ≈302 K (T_C) in the temperature dependence of the DC magnetic susceptibility of Fe₅GeTe₂. We found an unconventional potential spin glass state in the low-temperature regime that differs from the conventional spin glass states and Griffiths phase (GP) in the high-temperature regime. The physical mechanisms behind the potential spin glass state of Fe₅GeTe₂ at low temperatures and the Griffith phase at high temperatures need to be further investigated. Full article