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Keywords = type II superconductors

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14 pages, 3426 KB  
Article
Limit to Self-Field Critical Current Density in Thin-Film, Type-II Superconductors
by Amit Goyal, Rohit Kumar, Armando Galluzzi and Massimiliano Polichetti
Materials 2026, 19(4), 745; https://doi.org/10.3390/ma19040745 - 14 Feb 2026
Viewed by 462
Abstract
In the last decade, the self-field critical current density Jc(s.f.) in Type-II superconductors has been considered fundamentally limited by a Silsbee-like criterion of Jc(s.f.) = Hc1/λ. We show that this universal limit to self-field critical current density [...] Read more.
In the last decade, the self-field critical current density Jc(s.f.) in Type-II superconductors has been considered fundamentally limited by a Silsbee-like criterion of Jc(s.f.) = Hc1/λ. We show that this universal limit to self-field critical current density Jc(s.f.) is not universally valid. We present several examples for this in YBa2Cu3O7−δ-type and REBa2Cu3O7−δ thin films and one for Nb thin films and show that calculated Jc(s.f.) using the Silsbee-like criterion using thermodynamic parameters has been substantially exceeded experimentally. We also show that Jc(s.f.) can be significantly improved by incorporation of artificial pinning centers (APCs), further implying that no such universal limit to Jc(s.f.) can exist because such an upper bound, Jc(s.f.) would have to be independent of APCs. These findings call for a revision of the accepted understanding of current-carrying limits in Type-II superconductors and reveal substantial potential for improving Jc in REBCO-based coated conductors through optimization of APCs for large-scale applications, including commercial nuclear fusion. Full article
(This article belongs to the Section Materials Physics)
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14 pages, 1476 KB  
Article
Magnetic Field-Driven Transport Properties of an Oxygen-Deficient Rectangular YBa2Cu3O7-δ Superconducting Structure
by Artūras Jukna
Materials 2025, 18(16), 3890; https://doi.org/10.3390/ma18163890 - 20 Aug 2025
Viewed by 1022
Abstract
The transport properties of biased type II superconductors are strongly influenced by external magnetic fields, which play a crucial role in optimizing the stability and performance of low-noise superconducting electronic devices. A major challenge is the stochastic behavior of Abrikosov vortices, which emerge [...] Read more.
The transport properties of biased type II superconductors are strongly influenced by external magnetic fields, which play a crucial role in optimizing the stability and performance of low-noise superconducting electronic devices. A major challenge is the stochastic behavior of Abrikosov vortices, which emerge in the mixed state and lead to energy dissipation through their nucleation, motion, and annihilation. Uncontrolled vortex dynamics can introduce electronic noise in low-power systems and trigger thermal breakdown in high-power applications. This study examines the effect of a perpendicular external magnetic field on vortex pinning in biased YBa2Cu3O7-δ devices containing laser-written, rectangular-shaped, partially deoxygenated regions (δ ≈ 0.2). The results show that increasing the magnetic field amplitude induces an asymmetry in the concentration of vortices and antivortices, shifting the annihilation line toward a region of lower flux density and altering the flux pinning characteristics. Oxygen-deficient segments aligned parallel to the current flow act as barriers to vortex motion, enhancing the net pinning force by preventing vortex–antivortex pairs from reaching their annihilation zone. The current–voltage characteristics reveal periodic voltage steps corresponding to the onset and suppression of thermally activated flux flow and flux creep. These features indicate magnetic field–tunable transport behavior within a narrow range of temperatures from 0.94·Tc to 0.98·Tc, where Tc is the critical temperature of the superconductor. These findings offer new insights into the design of vortex-motion-controlled superconducting electronics that utilize engineered pinning structures. Full article
(This article belongs to the Section Materials Physics)
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11 pages, 754 KB  
Article
Combustion Wave Properties of Normal Zone Propagation Induced by Micro-Sized Magnetic Cumulation in Thin YBaCuO Films
by Oleg Kiprijanovič and Linas Ardaravičius
Coatings 2025, 15(2), 134; https://doi.org/10.3390/coatings15020134 - 23 Jan 2025
Viewed by 992
Abstract
The process of normal (N) zone propagation in three superconducting YBaCuO thin films with different Pearl length values was theoretically studied. The point appearance of the N zone was found to result from powerful energy release caused by micro-sized magnetic cumulation. Solutions of [...] Read more.
The process of normal (N) zone propagation in three superconducting YBaCuO thin films with different Pearl length values was theoretically studied. The point appearance of the N zone was found to result from powerful energy release caused by micro-sized magnetic cumulation. Solutions of the heat equation for hot electrons, diffusing to ~15 nm depth into the edge of the Pearl length, were obtained for the two length cases. The hot electron thermalization induced a transition to N state at the aforementioned depth due to fast exceeding of Tc, followed by flash high temperature growth. In the third case, we considered a process of crack branching when the superconducting current concentrated at the tips, followed by the transition to N state caused by exceeding jc. The superfast reaction of the superconductor allowed it to restore the energy loss at the Pearl length in all cases. This explains the step propagation process of the N zone with velocities up to 2.7 × 103 and 1.1 × 103 m/s in the first and second cases. In the third, the propagation can reach the detonation wave velocity of about 1 × 104 m/s. It is concluded that the process of the N zone propagation has the character of a combustion wave. Full article
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10 pages, 830 KB  
Article
Coexistence of Superconductivity and Magnetic Ordering in the In–Ag Alloy Under Nanoconfinement
by Marina V. Likholetova, Elena V. Charnaya, Evgenii V. Shevchenko, Yurii A. Kumzerov and Aleksandr V. Fokin
Nanomaterials 2024, 14(22), 1792; https://doi.org/10.3390/nano14221792 - 7 Nov 2024
Cited by 1 | Viewed by 1574
Abstract
The impact of the interface phenomena on the properties of nanostructured materials is the focus of modern physics. We studied the magnetic properties of the nanostructured In–Ag alloy confined within a porous glass. The alloy composition was close to the eutectic point in [...] Read more.
The impact of the interface phenomena on the properties of nanostructured materials is the focus of modern physics. We studied the magnetic properties of the nanostructured In–Ag alloy confined within a porous glass. The alloy composition was close to the eutectic point in the indium-rich range of the phase diagram. Temperature dependences of DC magnetization evidenced two superconducting transitions at 4.05 and 3.38 K. The magnetization isotherms demonstrated the superposition of two hysteresis loops with low and high critical fields below the second transition, a single hysteresis between the transitions and ferromagnetism with weak remanence in the normal state of the alloy. The shape of the loop seen below the second transition, which closes at a low magnetic field, corresponded to the intermediate state of the type-I superconductor. It was ascribed to strongly linked indium segregates. The loop observed below the first transition is referred to as type-II superconductivity. The secondary and tertiary magnetization branches measured at decreasing and increasing fields were shifted relative to each other, revealing the proximity of superconducting and ferromagnetic phases at the nanometer scale. This phenomenon was observed for the first time in the alloy, whose components were not magnetic in bulk. The sign of the shift shows the dominant role of the stray fields of ferromagnetic regions. Ferromagnetism was suggested to emerge at the interface between the In and AgIn2 segregates. Full article
(This article belongs to the Section Nanocomposite Materials)
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13 pages, 9089 KB  
Article
Casimir Forces with Periodic Structures: Abrikosov Flux Lattices
by Shunashi Guadalupe Castillo-López, Raúl Esquivel-Sirvent, Giuseppe Pirruccio and Carlos Villarreal
Physics 2024, 6(1), 394-406; https://doi.org/10.3390/physics6010026 - 12 Mar 2024
Cited by 4 | Viewed by 2443
Abstract
We investigate the influence of the Abrikosov vortex lattice on the Casimir force in a setup constituted by high-temperature superconductors subject to an external magnetic field. The Abrikosov lattice is a property of type II superconductors in which normal and superconducting carriers coexist [...] Read more.
We investigate the influence of the Abrikosov vortex lattice on the Casimir force in a setup constituted by high-temperature superconductors subject to an external magnetic field. The Abrikosov lattice is a property of type II superconductors in which normal and superconducting carriers coexist and the latter define a periodic pattern with square symmetry. We find that the optical properties determined by spatial redistribution of the superconducting order parameter induce Casimir forces with a periodic structure whose minimal strengths coincide with the vortex cores. Full article
(This article belongs to the Special Issue 75 Years of the Casimir Effect: Advances and Prospects)
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16 pages, 27450 KB  
Article
Enhanced Superconducting Critical Parameters in a New High-Entropy Alloy Nb0.34Ti0.33Zr0.14Ta0.11Hf0.08
by Rafał Idczak, Wojciech Nowak, Bartosz Rusin, Rafał Topolnicki, Tomasz Ossowski, Michał Babij and Adam Pikul
Materials 2023, 16(17), 5814; https://doi.org/10.3390/ma16175814 - 24 Aug 2023
Cited by 10 | Viewed by 2960
Abstract
The structural and physical properties of the new titanium- and niobium-rich type-A high-entropy alloy (HEA) superconductor Nb0.34Ti0.33Zr0.14Ta0.11Hf0.08 (in at.%) were studied by X-ray powder diffraction, energy dispersive X-ray spectroscopy, magnetization, electrical resistivity, and specific [...] Read more.
The structural and physical properties of the new titanium- and niobium-rich type-A high-entropy alloy (HEA) superconductor Nb0.34Ti0.33Zr0.14Ta0.11Hf0.08 (in at.%) were studied by X-ray powder diffraction, energy dispersive X-ray spectroscopy, magnetization, electrical resistivity, and specific heat measurements. In addition, electronic structure calculations were performed using two complementary methods: the Korringa–Kohn–Rostoker Coherent Potential Approximation (KKR-CPA) and the Projector Augmented Wave (PAW) within Density Functional Theory (DFT). The results obtained indicate that the alloy exhibits type II superconductivity with a critical temperature close to 7.5 K, an intermediate electron–phonon coupling, and an upper critical field of 12.2(1) T. This finding indicates that Nb0.34Ti0.33Zr0.14Ta0.11Hf0.08 has one of the highest upper critical fields among all known HEA superconductors. Full article
(This article belongs to the Special Issue Superconductors: Materials and Technology)
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12 pages, 319 KB  
Article
Continuous Gravitational Wave Emissions from Neutron Stars with Pinned Superfluids in the Core
by Brynmor Haskell, Marco Antonelli and Pierre Pizzochero
Universe 2022, 8(12), 619; https://doi.org/10.3390/universe8120619 - 24 Nov 2022
Cited by 10 | Viewed by 2197
Abstract
We investigate the effect of a pinned superfluid component on the gravitational wave emissions of a rotating neutron star. The pinning of superfluid vortices to the flux-tubes in the outer core (where the protons are likely to form a type-II superconductor) is a [...] Read more.
We investigate the effect of a pinned superfluid component on the gravitational wave emissions of a rotating neutron star. The pinning of superfluid vortices to the flux-tubes in the outer core (where the protons are likely to form a type-II superconductor) is a possible mechanism to sustain long-lived and non-axisymmetric neutron currents in the interior, which break the axial symmetry of the unperturbed hydrostatic configuration. We consider pinning-induced perturbations to a stationary corotating configuration and determine the upper limits on the strength of gravitational wave emissions due to the pinning of vortices with a strong toroidal magnetic field of the kind predicted by recent magneto-hydrodynamic simulations of neutron star interiors. We estimate the contributions to gravitational wave emissions from both the mass and current multipole generated by the pinned vorticity in the outer core and find that the mass quadrupole can be large enough for gravitational waves to provide the dominant spindown torque in millisecond pulsars. Full article
(This article belongs to the Special Issue Neutron Stars and Gravitational Wave Observations)
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10 pages, 1551 KB  
Article
Study of Energy Dissipation in the Mixed-State YBa2Cu3O7-δ Superconductor with Partially Deoxygenated Structures
by Artūras Jukna
Materials 2022, 15(12), 4260; https://doi.org/10.3390/ma15124260 - 16 Jun 2022
Cited by 3 | Viewed by 2009
Abstract
Energy dissipation from vortex motion, which appears as a resistivity of the mixed-state superconductor, limits the range of type II superconductors in low- and high-power electronics and optoelectronics. The level of dissipation increases with the development of the vortex motion phase from that [...] Read more.
Energy dissipation from vortex motion, which appears as a resistivity of the mixed-state superconductor, limits the range of type II superconductors in low- and high-power electronics and optoelectronics. The level of dissipation increases with the development of the vortex motion phase from that of the thermally activated flux flow to that of the flux creep and finally to that of the flux flow. The vortex motion regimes depend on the balance between bias current-self-produced Lorentz force, accelerating vortices, and the pinning force, which, together with a magnetic drag force from pinned vortices, tends to stop the vortex motion. The current paper reports on energy dissipation in YBa2Cu3O7-δ (YBCO) devices provided with partially deoxygenated structures mutually interacting by magnetic force with one another. The shape of the structure and the magnetic interaction between the trapped and moving vortices, as well as the magnetic interaction between neighboring structures, can cause the appearance of voltage steps in the device’s current–voltage characteristics observed in temperature range 0.94 ≥ T/Tc ≥ 0.98 (here, Tc = 91.4 K is the temperature of the superconducting transition in the YBCO material). Current findings demonstrate the potential of artificial structures to control vortex motion in a mixed-state YBCO superconductor by means of a temperature, bias current, and a specific configuration of the structure itself and a profile of the oxygen distribution in it. Full article
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15 pages, 3031 KB  
Article
On the Localization of Persistent Currents Due to Trapped Magnetic Flux at the Stacking Faults of Graphite at Room Temperature
by Regina Ariskina, Markus Stiller, Christian E. Precker, Winfried Böhlmann and Pablo D. Esquinazi
Materials 2022, 15(10), 3422; https://doi.org/10.3390/ma15103422 - 10 May 2022
Cited by 20 | Viewed by 2708
Abstract
Granular superconductivity at high temperatures in graphite can emerge at certain two-dimensional (2D) stacking faults (SFs) between regions with twisted (around the c-axis) or untwisted crystalline regions with Bernal (ABA…) and/or rhombohedral (ABCABCA…) stacking order. One way to observe experimentally such 2D superconductivity [...] Read more.
Granular superconductivity at high temperatures in graphite can emerge at certain two-dimensional (2D) stacking faults (SFs) between regions with twisted (around the c-axis) or untwisted crystalline regions with Bernal (ABA…) and/or rhombohedral (ABCABCA…) stacking order. One way to observe experimentally such 2D superconductivity is to measure the frozen magnetic flux produced by a permanent current loop that remains after removing an external magnetic field applied normal to the SFs. Magnetic force microscopy was used to localize and characterize such a permanent current path found in one natural graphite sample out of ∼50 measured graphite samples of different origins. The position of the current path drifts with time and roughly follows a logarithmic time dependence similar to the one for flux creep in type II superconductors. We demonstrate that a ≃10 nm deep scratch on the sample surface at the position of the current path causes a change in its location. A further scratch was enough to irreversibly destroy the remanent state of the sample at room temperature. Our studies clarify some of the reasons for the difficulties of finding a trapped flux in a remanent state at room temperature in graphite samples with SFs. Full article
(This article belongs to the Special Issue Advanced 2D Materials for New-Generation Electronic Devices)
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32 pages, 4087 KB  
Article
Superconducting Phases in Neutron Star Cores
by Toby S. Wood and Vanessa Graber
Universe 2022, 8(4), 228; https://doi.org/10.3390/universe8040228 - 8 Apr 2022
Cited by 25 | Viewed by 3746
Abstract
Using a phenomenological Ginzburg–Landau model that includes entrainment, we identify the possible ground states for the neutron and proton condensates in the core of a neutron star, as a function of magnetic field strength. Combining analytical and numerical techniques, we find that much [...] Read more.
Using a phenomenological Ginzburg–Landau model that includes entrainment, we identify the possible ground states for the neutron and proton condensates in the core of a neutron star, as a function of magnetic field strength. Combining analytical and numerical techniques, we find that much of the outer core is likely to be a “type-1.5” superconductor (instead of a type-II superconductor as often assumed), in which magnetic flux is distributed inhomogeneously, with bundles of magnetic fluxtubes separated by flux-free Meissner regions. We provide an approximate criterion to determine the transition between this type-1.5 phase and the type-I region in the inner core. We also show that bundles of fluxtubes can coexist with non-superconducting regions, but only in a small part of the parameter space. Full article
(This article belongs to the Special Issue Superfluidity and Superconductivity in Neutron Stars)
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20 pages, 7636 KB  
Article
Multi-Steps Magnetic Flux Entrance/Exit at Thermomagnetic Avalanches in the Plates of Hard Superconductors
by Viktor Chabanenko, Adam Nabiałek and Roman Puźniak
Materials 2022, 15(6), 2037; https://doi.org/10.3390/ma15062037 - 10 Mar 2022
Cited by 5 | Viewed by 2478
Abstract
Avalanche cascades of magnetic flux have been detected at thermomagnetic instability of the critical state in the plates of Nb-Ti alloy. It was found that, the magnetic flux Φ enters conventional superconductor in screening regime and leaves in trapping regime in the form [...] Read more.
Avalanche cascades of magnetic flux have been detected at thermomagnetic instability of the critical state in the plates of Nb-Ti alloy. It was found that, the magnetic flux Φ enters conventional superconductor in screening regime and leaves in trapping regime in the form of a multistage “stairways”, with the structure dependent on the magnetic field strength and magnetic history, with approximately equal successive portions ΔΦ in temporal Φ(t) dependence, and with the width depending almost linearly on the plate thickness. The steady generation of cascades was observed for the full remagnetization cycle in the field of 2–4 T. The structure of inductive signal becomes complex already in the field of 0–2 T and it was shown, on the base of Fourier analysis, that, the avalanche flux dynamic produces, in this field range, multiple harmonics of the electric field. The physical reason of complex spectrum of the low-field avalanche dynamics can be associated with rough structure of moving flux front and with inhomogeneous relief of induction. It was established that the initiation of cascades occurs mainly in the central part of the lateral surface. The mechanism of cascades generation seems to be connected to the “resonator’s properties” of the plates. Full article
(This article belongs to the Topic Electromaterials for Environment & Energy)
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21 pages, 3383 KB  
Article
Critical State Theory for the Magnetic Coupling between Soft Ferromagnetic Materials and Type-II Superconductors
by Muhammad U. Fareed and Harold S. Ruiz
Materials 2021, 14(20), 6204; https://doi.org/10.3390/ma14206204 - 19 Oct 2021
Cited by 3 | Viewed by 4066
Abstract
Improving our understanding of the physical coupling between type-II superconductors (SC) and soft ferromagnetic materials (SFM) is the root for progressing to the application of SC-SFM metastructures in scenarios such as magnetic cloaking, magnetic shielding, and power transmission systems. However, in the latter, [...] Read more.
Improving our understanding of the physical coupling between type-II superconductors (SC) and soft ferromagnetic materials (SFM) is the root for progressing to the application of SC-SFM metastructures in scenarios such as magnetic cloaking, magnetic shielding, and power transmission systems. However, in the latter, some intriguing and yet unexplained phenomena occurred, such as a noticeable rise in the SC energy losses, and a local but not isotropic deformation of its magnetic flux density. These phenomena, which are in apparent contradiction with the most fundamental theory of electromagnetism for superconductivity, that is, the critical state theory (CST), have remained unexplained for about 20 years, given the acceptance of the controversial and yet paradigmatic existence of the so-called overcritical current densities. Therefore, aiming to resolve these long-standing problems, we extended the CST by incorporating a semi-analytical model for cylindrical monocore SC-SFM heterostructures, setting the standards for its validation with a variational approach of multipole functionals for the magnetic coupling between Sc and SFM materials. It is accompanied by a comprehensive numerical study for SFM sheaths of arbitrary dimensions and magnetic relative permeabilities μr, ranging from μr=5 (NiZn ferrites) to μr = 350,000 (pure Iron), showing how the AC-losses of the SC-SFM metastructure radically changes as a function of the SC and the SFM radius for μr100. Our numerical technique and simulations also revealed a good qualitative agreement with the magneto optical imaging observations that were questioning the CST validness, proving therefore that the reported phenomena for self-field SC-SFM heterostructures can be understood without including the ansatz of overcritical currents. Full article
(This article belongs to the Special Issue Engineering Properties of Superconducting Materials (Second Volume))
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26 pages, 7017 KB  
Article
Structure and Superconductivity of Tin-Containing HfTiZrSnM (M = Cu, Fe, Nb, Ni) Medium-Entropy and High-Entropy Alloys
by Darja Gačnik, Andreja Jelen, Mitja Krnel, Stanislav Vrtnik, Jože Luzar, Primož Koželj, Marion van Midden, Erik Zupanič, Magdalena Wencka, Anton Meden, Qiang Hu, Sheng Guo and Janez Dolinšek
Materials 2021, 14(14), 3953; https://doi.org/10.3390/ma14143953 - 15 Jul 2021
Cited by 6 | Viewed by 3272
Abstract
In an attempt to incorporate tin (Sn) into high-entropy alloys composed of refractory metals Hf, Nb, Ti and Zr with the addition of 3d transition metals Cu, Fe, and Ni, we synthesized a series of alloys in the system HfTiZrSnM ( [...] Read more.
In an attempt to incorporate tin (Sn) into high-entropy alloys composed of refractory metals Hf, Nb, Ti and Zr with the addition of 3d transition metals Cu, Fe, and Ni, we synthesized a series of alloys in the system HfTiZrSnM (M = Cu, Fe, Nb, Ni). The alloys were characterized crystallographically, microstructurally, and compositionally, and their physical properties were determined, with the emphasis on superconductivity. All Sn-containing alloys are multi-phase mixtures of intermetallic compounds (in most cases four). A common feature of the alloys is a microstructure of large crystalline grains of a hexagonal (Hf, Ti, Zr)5Sn3 partially ordered phase embedded in a matrix that also contains many small inclusions. In the HfTiZrSnCu alloy, some Cu is also incorporated into the grains. Based on the electrical resistivity, specific heat, and magnetization measurements, a superconducting (SC) state was observed in the HfTiZr, HfTiZrSn, HfTiZrSnNi, and HfTiZrSnNb alloys. The HfTiZrSnFe alloy shows a partial SC transition, whereas the HfTiZrSnCu alloy is non-superconducting. All SC alloys are type II superconductors and belong to the Anderson class of “dirty” superconductors. Full article
(This article belongs to the Section Metals and Alloys)
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18 pages, 756 KB  
Review
Superinsulators: An Emergent Realisation of Confinement
by Maria Cristina Diamantini and Carlo A. Trugenberger
Universe 2021, 7(6), 201; https://doi.org/10.3390/universe7060201 - 17 Jun 2021
Cited by 1 | Viewed by 3010
Abstract
Superinsulators (SI) are a new topological state of matter, predicted by our collaboration and experimentally observed in the critical vicinity of the superconductor-insulator transition (SIT). SI are dual to superconductors and realise electric-magnetic (S)-duality. The effective field theory that describes this topological phase [...] Read more.
Superinsulators (SI) are a new topological state of matter, predicted by our collaboration and experimentally observed in the critical vicinity of the superconductor-insulator transition (SIT). SI are dual to superconductors and realise electric-magnetic (S)-duality. The effective field theory that describes this topological phase of matter is governed by a compact Chern-Simons in (2+1) dimensions and a compact BF term in (3+1) dimensions. While in a superconductor the condensate of Cooper pairs generates the Meissner effect, which constricts the magnetic field lines penetrating a type II superconductor into Abrikosov vortices, in superinsulators Cooper pairs are linearly bound by electric fields squeezed into strings (dual Meissner effect) by a monopole condensate. Magnetic monopoles, while elusive as elementary particles, exist in certain materials in the form of emergent quasiparticle excitations. We demonstrate that at low temperatures magnetic monopoles can form a quantum Bose condensate (plasma in (2+1) dimensions) dual to the charge condensate in superconductors. The monopole Bose condensate manifests as a superinsulating state with infinite resistance, dual to superconductivity. The monopole supercurrents result in the electric analogue of the Meissner effect and lead to linear confinement of the Cooper pairs by Polyakov electric strings in analogy to quarks in hadrons. Superinsulators realise thus one of the mechanism proposed to explain confinement in QCD. Moreover, the string mechanism of confinement implies asymptotic freedom at the IR fixed point. We predict thus for superinsulators a metallic-like low temperature behaviour when samples are smaller than the string scale. This has been experimentally confirmed. We predict that an oblique version of SI is realised as the pseudogap state of high-TC superconductors. Full article
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11 pages, 2252 KB  
Article
Overview of Spark Plasma Texturing of Functional Ceramics
by Jacques G. NOUDEM and Yiteng XING
Ceramics 2021, 4(1), 97-107; https://doi.org/10.3390/ceramics4010009 - 15 Mar 2021
Cited by 8 | Viewed by 4186
Abstract
This work reports the progress in the preparation of superconducting and thermoelectric lamellar compounds processed by the unconventional Spark Plasma Sintering (SPS). The SPS equipment was modified with the aim of obtaining the textured and dense superconductor Bi2Sr2Ca2 [...] Read more.
This work reports the progress in the preparation of superconducting and thermoelectric lamellar compounds processed by the unconventional Spark Plasma Sintering (SPS). The SPS equipment was modified with the aim of obtaining the textured and dense superconductor Bi2Sr2Ca2Cu3O10,p-type oxide thermoelectric bulk as Ca3Co4O9 and Ca3-xAgxCo4O9/Ag composites respectively. The new process is referred to as Spark Plasma Texturing (SPT). During SPT, the bulk material can freely deform. As a result, inter-grain preferential crystallographic orientation is created. The series of sintered and textured samples using the same Ag content were processed respectively. From the results, we can evidence: (i) the magnetic and/or structural transition around 350 °C, for both series of samples. (ii) The electrical resistivity (ρ) decreases with increasing Ag-substituted or Ag-added. (iii) The Seebeck coefficient (S) of the textured series is higher than that of the sintered series. In the case of the Ag-substituted, S, decreases with Ag content. The optimized composite is found to be Ca2.6Ag0.4Co4O9/8wt% Ag. We can note the remarkable reduction of ρ, and the improvement of power factor values up to 360 μW.m−1.K−2.The superconducting properties of single phased Bi2Sr2Ca2Cu3O10 (Bi2223) consolidated using SPS and SPT will also be discussed. Full article
(This article belongs to the Special Issue Spark Plasma Sintering Technology)
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