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Keywords = thermal balanced test

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29 pages, 3167 KiB  
Article
A Comparative Evaluation of Polymer-Modified Rapid-Set Calcium Sulfoaluminate Concrete: Bridging the Gap Between Laboratory Shrinkage and the Field Strain Performance
by Daniel D. Akerele and Federico Aguayo
Buildings 2025, 15(15), 2759; https://doi.org/10.3390/buildings15152759 - 5 Aug 2025
Abstract
Rapid pavement repair demands materials that combine accelerated strength gains, dimensional stability, long-term durability, and sustainability. However, finding materials or formulations that offer these balances remains a critical challenge. This study systematically evaluates two polymer-modified belitic calcium sulfoaluminate (CSA) concretes—CSAP (powdered polymer) and [...] Read more.
Rapid pavement repair demands materials that combine accelerated strength gains, dimensional stability, long-term durability, and sustainability. However, finding materials or formulations that offer these balances remains a critical challenge. This study systematically evaluates two polymer-modified belitic calcium sulfoaluminate (CSA) concretes—CSAP (powdered polymer) and CSA-LLP (liquid polymer admixture)—against a traditional Type III Portland cement (OPC) control under both laboratory and realistic outdoor conditions. Laboratory specimens were tested for fresh properties, early-age and later-age compressive, flexural, and splitting tensile strengths, as well as drying shrinkage according to ASTM standards. Outdoor 5 × 4 × 12-inch slabs mimicking typical jointed plain concrete panels (JPCPs), instrumented with vibrating wire strain gauges and thermocouples, recorded the strain and temperature at 5 min intervals over 16 weeks, with 24 h wet-burlap curing to replicate field practices. Laboratory findings show that CSA mixes exceeded 3200 psi of compressive strength at 4 h, but cold outdoor casting (~48 °F) delayed the early-age strength development. The CSA-LLP exhibited the lowest drying shrinkage (0.036% at 16 weeks), and outdoor CSA slabs captured the initial ettringite-driven expansion, resulting in a net expansion (+200 µε) rather than contraction. Approximately 80% of the total strain evolved within the first 48 h, driven by autogenous and plastic effects. CSA mixes generated lower peak internal temperatures and reduced thermal strain amplitudes compared to the OPC, improving dimensional stability and mitigating restraint-induced cracking. These results underscore the necessity of field validation for shrinkage compensation mechanisms and highlight the critical roles of the polymer type and curing protocol in optimizing CSA-based repairs for durable, low-carbon pavement rehabilitation. Full article
(This article belongs to the Special Issue Study on Concrete Structures—2nd Edition)
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20 pages, 7843 KiB  
Article
Effect of Ageing on a Novel Cobalt-Free Precipitation-Hardenable Martensitic Alloy Produced by SLM: Mechanical, Tribological and Corrosion Behaviour
by Inés Pérez-Gonzalo, Florentino Alvarez-Antolin, Alejandro González-Pociño and Luis Borja Peral-Martinez
J. Manuf. Mater. Process. 2025, 9(8), 261; https://doi.org/10.3390/jmmp9080261 - 4 Aug 2025
Abstract
This study investigates the mechanical, tribological, and electrochemical behaviour of a novel precipitation-hardenable martensitic alloy produced by selective laser melting (SLM). The alloy was specifically engineered with an optimised composition, free from cobalt and molybdenum, and featuring reduced nickel content (7 wt.%) and [...] Read more.
This study investigates the mechanical, tribological, and electrochemical behaviour of a novel precipitation-hardenable martensitic alloy produced by selective laser melting (SLM). The alloy was specifically engineered with an optimised composition, free from cobalt and molybdenum, and featuring reduced nickel content (7 wt.%) and 8 wt.% chromium. It has been developed as a cost-effective and sustainable alternative to conventional maraging steels, while maintaining high mechanical strength and a refined microstructure tailored to the steep thermal gradients inherent to the SLM process. Several ageing heat treatments were assessed to evaluate their influence on microstructure, hardness, tensile strength, retained austenite content, dislocation density, as well as wear behaviour (pin-on-disc test) and corrosion resistance (polarisation curves in 3.5%NaCl). The results indicate that ageing at 540 °C for 2 h offers an optimal combination of hardness (550–560 HV), tensile strength (~1700 MPa), microstructural stability, and wear resistance, with a 90% improvement compared to the as-built condition. In contrast, ageing at 600 °C for 1 h enhances ductility and corrosion resistance (Rp = 462.2 kΩ; Ecorr = –111.8 mV), at the expense of a higher fraction of reverted austenite (~34%) and reduced hardness (450 HV). This study demonstrates that the mechanical, surface, and electrochemical performance of this novel SLM-produced alloy can be effectively tailored through controlled thermal treatments, offering promising opportunities for demanding applications requiring a customised balance of strength, durability, and corrosion behaviour. Full article
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24 pages, 6999 KiB  
Article
Plasmid DNA Delivery to Cancer Cells with Poly(L-lysine)-Based Copolymers Bearing Thermally Sensitive Segments: Balancing Polyplex Tightness, Transfection Efficiency, and Biocompatibility
by Mustafa Kotmakci, Natalia Toncheva-Moncheva, Sahar Tarkavannezhad, Bilge Debelec Butuner, Ivaylo Dimitrov and Stanislav Rangelov
Pharmaceutics 2025, 17(8), 1012; https://doi.org/10.3390/pharmaceutics17081012 - 2 Aug 2025
Viewed by 229
Abstract
Background/Objectives. Efficient nucleic acid delivery into target cells remains a critical challenge in gene therapy. Due to its advantages in biocompatibility and safety, recent research has increasingly focused on non-viral gene delivery. Methods. A series of copolymers—synthesized by integrating thermally sensitive poly(N-isopropylacrylamide) [...] Read more.
Background/Objectives. Efficient nucleic acid delivery into target cells remains a critical challenge in gene therapy. Due to its advantages in biocompatibility and safety, recent research has increasingly focused on non-viral gene delivery. Methods. A series of copolymers—synthesized by integrating thermally sensitive poly(N-isopropylacrylamide) (PNIPAm), hydrophilic poly(ethylene glycol) (PEG) grafts, and a polycationic poly(L-lysine) (PLL) block of varying lengths ((PNIPAm)77-graft-(PEG)9-block-(PLL)z, z = 10–65)—were investigated. Plasmid DNA complexation with the copolymers was achieved through temperature-modulated methods. The resulting polyplexes were characterized by evaluating complex strength, particle size, zeta potential, plasmid DNA loading capacity, resistance to anionic stress, stability in serum, and lysosomal membrane destabilization assay. The copolymers’ potential for plasmid DNA delivery was assessed through cytotoxicity and transfection studies in cancer cell lines. Results. Across all complexation methods, the copolymers effectively condensed plasmid DNA into stable polyplexes. Particle sizes (60–90 nm) ranged with no apparent correlation to copolymer type, complexation method, or N/P ratio, whereas zeta potentials (+10–+20 mV) and resistance to polyanionic stress were dependent on the PLL length and N/P ratio. Cytotoxicity analysis revealed a direct correlation between PLL chain length and cell viability, with all copolymers demonstrating minimal cytotoxicity at concentrations required for efficient transfection. PNL-20 ((PNIPAm)77-graft-(PEG)9-block-(PLL)20) exhibited the highest transfection efficiency among the tested formulations while maintaining low cytotoxicity. Conclusions. The study highlights the promising potential of (PNIPAm)77-graft-(PEG)9-block-(PLL)z copolymers for effective plasmid DNA delivery to cancer cells. It reveals the importance of attaining the right balance between polyplex tightness and plasmid release to achieve improved biocompatibility and transfection efficiency. Full article
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19 pages, 439 KiB  
Article
Multi-Objective Optimization for Economic and Environmental Dispatch in DC Networks: A Convex Reformulation via a Conic Approximation
by Nestor Julian Bernal-Carvajal, Carlos Arturo Mora-Peña and Oscar Danilo Montoya
Electricity 2025, 6(3), 43; https://doi.org/10.3390/electricity6030043 - 1 Aug 2025
Viewed by 197
Abstract
This paper addresses the economic–environmental dispatch (EED) problem in DC power grids integrating thermoelectric and photovoltaic generation. A multi-objective optimization model is developed to minimize both fuel costs and CO2 emissions while considering power balance, voltage constraints, generation limits, and thermal line [...] Read more.
This paper addresses the economic–environmental dispatch (EED) problem in DC power grids integrating thermoelectric and photovoltaic generation. A multi-objective optimization model is developed to minimize both fuel costs and CO2 emissions while considering power balance, voltage constraints, generation limits, and thermal line capacities. To overcome the non-convexity introduced by quadratic voltage products in the power flow equations, a convex reformulation is proposed using second-order cone programming (SOCP) with auxiliary variables. This reformulation ensures global optimality and enhances computational efficiency. Two test systems are used for validation: a 6-node DC grid and an 11-node grid incorporating hourly photovoltaic generation. Comparative analyses show that the convex model achieves objective values with errors below 0.01% compared to the original non-convex formulation. For the 11-node system, the integration of photovoltaic generation led to a 24.34% reduction in operating costs (from USD 10.45 million to USD 7.91 million) and a 27.27% decrease in CO2 emissions (from 9.14 million kg to 6.64 million kg) over a 24 h period. These results confirm the effectiveness of the proposed SOCP-based methodology and demonstrate the environmental and economic benefits of renewable integration in DC networks. Full article
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13 pages, 3081 KiB  
Review
Surface Air-Cooled Oil Coolers (SACOCs) in Turbofan Engines: A Comprehensive Review of Design, Performance, and Optimization
by Wiktor Hoffmann and Magda Joachimiak
Energies 2025, 18(15), 4052; https://doi.org/10.3390/en18154052 - 30 Jul 2025
Viewed by 242
Abstract
Surface Air-Cooled Oil Coolers (SACOCs) can become a critical component in managing the increasing thermal loads of modern turbofan engines. Installed within the bypass duct, SACOCs utilize high-mass flow bypass air for convective heat rejection, reducing reliance on traditional Fuel-Oil Heat Exchangers. This [...] Read more.
Surface Air-Cooled Oil Coolers (SACOCs) can become a critical component in managing the increasing thermal loads of modern turbofan engines. Installed within the bypass duct, SACOCs utilize high-mass flow bypass air for convective heat rejection, reducing reliance on traditional Fuel-Oil Heat Exchangers. This review explores SACOC design principles, integration challenges, aerodynamic impacts, and performance trade-offs. Emphasis is placed on the balance between thermal efficiency and aerodynamic penalties such as pressure drop and flow distortion. Experimental techniques, including wind tunnel testing, are discussed alongside numerical methods, and Conjugate Heat Transfer modeling. Presented studies mostly demonstrate the impact of fin geometry and placement on both heat transfer and drag. Optimization strategies and Additive Manufacturing techniques are also covered. SACOCs are positioned to play a central role in future propulsion systems, especially in ultra-high bypass ratio and hybrid-electric architectures, where traditional cooling strategies are insufficient. This review highlights current advancements, identifies limitations, and outlines research directions to enhance SACOC efficiency in aerospace applications. Full article
(This article belongs to the Special Issue Heat Transfer Analysis: Recent Challenges and Applications)
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22 pages, 6208 KiB  
Article
Corrosion Behavior of Annealed 20MnCr5 Steel
by Dario Kvrgić, Lovro Liverić, Paweł Nuckowski and Sunčana Smokvina Hanza
Materials 2025, 18(15), 3566; https://doi.org/10.3390/ma18153566 - 30 Jul 2025
Viewed by 189
Abstract
This study investigated the influence of various annealing treatments on the microstructure and corrosion behavior of 20MnCr5 steel in a 3.5% NaCl solution. A combination of microstructural analysis, hardness testing, and electrochemical techniques was used to comprehensively characterize each condition. To enhance data [...] Read more.
This study investigated the influence of various annealing treatments on the microstructure and corrosion behavior of 20MnCr5 steel in a 3.5% NaCl solution. A combination of microstructural analysis, hardness testing, and electrochemical techniques was used to comprehensively characterize each condition. To enhance data interpretability, a correlation analysis was performed and visualized through a correlation diagram, enabling statistical assessment of the relationships between grain features, phase distribution, mechanical properties, and corrosion indicators. The results demonstrated that corrosion resistance in 20MnCr5 steel is not governed by a single parameter but by the interplay between grain size, morphology, and phase balance. Excessive pearlite content or coarse, irregular grains were consistently associated with higher corrosion rates and lower electrochemical stability. In contrast, a moderate phase ratio and equiaxed grain structure, achieved through normalization, resulted in better corrosion resistance, confirmed by the highest polarization resistance and lowest corrosion current density values among all samples. Although increased grain refinement improved the hardness, it did not always correlate with a better corrosion performance, especially when morphological uniformity was lacking. This highlights the importance of balancing mechanical and corrosion properties through carefully controlled thermal processing. Full article
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13 pages, 2134 KiB  
Article
Optimising Tubular Solar Still Performance with Gamma Aluminium Nanocoatings: Experimental Insights on Yield, Efficiency, and Economic Viability
by Ajay Kumar Kaviti, Niharika Mudavath and Vineet Singh Sikarwar
Processes 2025, 13(8), 2413; https://doi.org/10.3390/pr13082413 - 29 Jul 2025
Viewed by 292
Abstract
This study evaluates the performance of tubular solar stills coated with gamma aluminium nanocoatings at concentrations of 5%, 10%, and 15%, compared to a conventional tubular solar still. This is the first experimental study to apply gamma aluminium nanocoatings on tubular solar stills [...] Read more.
This study evaluates the performance of tubular solar stills coated with gamma aluminium nanocoatings at concentrations of 5%, 10%, and 15%, compared to a conventional tubular solar still. This is the first experimental study to apply gamma aluminium nanocoatings on tubular solar stills (TSS). The stills were tested for three days, from 9:00 a.m. to 5:00 p.m., under consistent conditions with varying water depths of 1 cm, 2 cm, and 3 cm. The results indicated that the 5% nanocoating achieved the highest water yield, producing 2.571 L/m2 with a 1 cm water depth. The 10% coating produced 2.514 L/m2, while the conventional solar still generated 2.286 L/m2. Thermal efficiency was highest on Day 1 for the 5% concentration, reaching 60.9%, followed by 10% concentration at 59.1%, while the 15% concentration showed the lowest efficiency at 33.8%. In terms of cost-effectiveness, the 5% concentration was the most economical, with the lowest cost per litre (CPL) of USD 0.10 and a payback period of 3.03 months. The 10% concentration had a CPL of USD 0.11 and a payback period of 3.33 months, while the 15% concentration had the highest CPL at USD 0.19 and the longest payback period of 5.63 months. Overall, the 5% concentration offered the best balance of water yield, efficiency, and cost-effectiveness. This research highlights γ-Al2O3 as an innovative, cost-effective material for solar distillation, paving the way for sustainable freshwater production. Full article
(This article belongs to the Section Chemical Processes and Systems)
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21 pages, 2828 KiB  
Article
A Novel Loss-Balancing Modulation Strategy for ANPC Three-Level Inverter for Variable-Speed Pump Storage Applications
by Yali Wang, Liyang Liu, Tao Liu, Yikai Li, Kai Guo and Yiming Ma
Electronics 2025, 14(15), 2944; https://doi.org/10.3390/electronics14152944 - 23 Jul 2025
Viewed by 175
Abstract
The non-uniform thermal distribution in the active neutral-point clamped (ANPC) topology causes significant thermal gradients during high-power operation, restricting its use in large-capacity power conversion systems like variable-speed pumped storage. This study introduces a novel hybrid fundamental frequency modulation strategy. Through a dynamic [...] Read more.
The non-uniform thermal distribution in the active neutral-point clamped (ANPC) topology causes significant thermal gradients during high-power operation, restricting its use in large-capacity power conversion systems like variable-speed pumped storage. This study introduces a novel hybrid fundamental frequency modulation strategy. Through a dynamic allocation mechanism based on a reference signal, this strategy alternates inner and outer power switches at the fundamental frequency, ensuring balanced switching frequency across devices. Consequently, it effectively mitigates the inherent loss imbalance in conventional ANPC topologies. Quantitative analysis using a power device loss model shows that, compared to conventional carrier phase-shift modulation, the proposed method reduces total system losses by 39.98% and improves the loss-balancing index by 18.27% over inner-switch fundamental frequency modulation. A multidimensional validation framework, including an MW-level hardware platform, numerical simulations, and test data, was established. The results confirm the proposed strategy’s effectiveness in improving power device thermal balance. Full article
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26 pages, 2162 KiB  
Article
Developing Performance Measurement Framework for Sustainable Facility Management (SFM) in Office Buildings Using Bayesian Best Worst Method
by Ayşe Pınar Özyılmaz, Fehmi Samet Demirci, Ozan Okudan and Zeynep Işık
Sustainability 2025, 17(14), 6639; https://doi.org/10.3390/su17146639 - 21 Jul 2025
Viewed by 497
Abstract
The confluence of financial constraints, climate change mitigation efforts, and evolving user expectations has significantly transformed the concept of facility management (FM). Traditional FM has now evolved to enhance sustainability in the built environment. Sustainable facility management (SFM) can add value to companies, [...] Read more.
The confluence of financial constraints, climate change mitigation efforts, and evolving user expectations has significantly transformed the concept of facility management (FM). Traditional FM has now evolved to enhance sustainability in the built environment. Sustainable facility management (SFM) can add value to companies, organizations, and governments by balancing the financial, environmental, and social outcomes of the FM processes. The systematic literature review revealed a limited number of studies developing a performance measurement framework for SFM in office buildings and/or other building types in the literature. Given that the lack of this theoretical basis inhibits the effective deployment of SFM practices, this study aims to fill this gap by developing a performance measurement framework for SFM in office buildings. Accordingly, an in-depth literature review was initially conducted to synthesize sustainable performance measurement factors. Next, a series of focus group discussion (FGD) sessions were organized to refine and verify the factors and develop a novel performance measurement framework for SFM. Lastly, consistency analysis, the Bayesian best worst method (BBWM), and sensitivity analysis were implemented to determine the priorities of the factors. What the proposed framework introduces is the combined use of two performance measurement mechanisms, such as continuous performance measurement and comprehensive performance measurement. The continuous performance measurement is conducted using high-priority factors. On the other hand, the comprehensive performance measurement is conducted with all the factors proposed in this study. Also, the BBWM results showed that “Energy-efficient material usage”, “Percentage of energy generated from renewable energy resources to total energy consumption”, and “Promoting hybrid or remote work conditions” are the top three factors, with scores of 0.0741, 0.0598, and 0.0555, respectively. Moreover, experts should also pay the utmost attention to factors related to waste management, indoor air quality, thermal comfort, and H&S measures. In addition to its theoretical contributions, the paper makes practical contributions by enabling decision makers to measure the SFM performance of office buildings and test the outcomes of their managerial processes in terms of performance. Full article
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30 pages, 3950 KiB  
Article
Estimation of Peak Junction Hotspot Temperature in Three-Level TNPC-IGBT Modules for Traction Inverters Through Chip-Level Modeling and Experimental Validation
by Ahmed H. Okilly, Peter Nkwocha Harmony, Cheolgyu Kim, Do-Wan Kim and Jeihoon Baek
Energies 2025, 18(14), 3829; https://doi.org/10.3390/en18143829 - 18 Jul 2025
Viewed by 323
Abstract
Monitoring the peak junction hotspot temperature in IGBT modules is critical for ensuring the reliability of high-power industrial multilevel inverters, particularly when operating under extreme thermal conditions, such as in traction applications. This study presents a comprehensive chip-level analytical loss and thermal model [...] Read more.
Monitoring the peak junction hotspot temperature in IGBT modules is critical for ensuring the reliability of high-power industrial multilevel inverters, particularly when operating under extreme thermal conditions, such as in traction applications. This study presents a comprehensive chip-level analytical loss and thermal model for estimation of the peak junction hotspot temperature in a three-level T-type neutral-point-clamped (TNPC) IGBT module. The developed model includes a detailed analytical assessment of conduction and switching losses, along with transient thermal network modeling, based on the actual electrical and thermal characteristics of the IGBT module. Additionally, a hybrid thermal–electrical stress experimental setup, designed to replicate real operating conditions, was implemented for a balanced three-phase inverter circuit utilizing a Semikron three-level IGBT module, with testing currents reaching 100 A and a critical case temperature of 125 °C. The analytically estimated module losses and peak junction hotspot temperatures were validated through direct experimental measurements. Furthermore, thermal simulations were conducted with Semikron’s SemiSel benchmark tool to cross-validate the accuracy of the thermo-electrical model. The outcomes show a relative estimation error of less than 1% when compared to experimental data and approximately 1.15% for the analytical model. These findings confirm the model’s accuracy and enhance the reliability evaluation of TNPC-IGBT modules in extreme thermal environments. Full article
(This article belongs to the Special Issue Power Electronics Technology and Application)
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27 pages, 4651 KiB  
Article
Thermal Infrared UAV Applications for Spatially Explicit Wildlife Occupancy Modeling
by Eve Bohnett, Babu Ram Lamichanne, Surendra Chaudhary, Kapil Pokhrel, Giavanna Dorman, Axel Flores, Rebecca Lewison, Fang Qiu, Doug Stow and Li An
Land 2025, 14(7), 1461; https://doi.org/10.3390/land14071461 - 14 Jul 2025
Viewed by 457
Abstract
Assessing the impact of community-based conservation programs on wildlife biodiversity remains a significant challenge. This pilot study was designed to develop and demonstrate a scalable, spatially explicit workflow using thermal infrared (TIR) imagery and unmanned aerial vehicles (UAVs) for non-invasive biodiversity monitoring. Conducted [...] Read more.
Assessing the impact of community-based conservation programs on wildlife biodiversity remains a significant challenge. This pilot study was designed to develop and demonstrate a scalable, spatially explicit workflow using thermal infrared (TIR) imagery and unmanned aerial vehicles (UAVs) for non-invasive biodiversity monitoring. Conducted in a 2-hectare grassland area in Chitwan, Nepal, the study applied TIR-based grid sampling and multi-species occupancy models with thin-plate splines to evaluate how species detection and richness might vary between (1) morning and evening UAV flights, and (2) the Chitwan National Park and Kumroj Community Forest. While the small sample area inherently limits ecological inference, the aim was to test and demonstrate data collection and modeling protocols that could be scaled to larger landscapes with sufficient replication, and not to produce generalizable ecological findings from a small dataset. The pilot study results revealed higher species detection during morning flights, which allowed us to refine our data collection. Additionally, models accounting for spatial autocorrelation using thin plate splines suggested that community-based conservation programs effectively balanced ecosystem service extraction with biodiversity conservation, maintaining richness levels comparable to the national park. Models without splines indicated significantly higher species richness within the national park. This study demonstrates the potential for spatially explicit methods for monitoring grassland mammals using TIR UAV as indicators of anthropogenic impacts and conservation effectiveness. Further data collection over larger spatial and temporal scales is essential to capture the occupancy more generally for species with larger home ranges, as well as any effects of rainfall, flooding, and seasonal variability on biodiversity in alluvial grasslands. Full article
(This article belongs to the Section Land, Biodiversity, and Human Wellbeing)
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15 pages, 2537 KiB  
Article
A Comparative Experimental Analysis of a Cold Latent Thermal Storage System Coupled with a Heat Pump/Air Conditioning Unit
by Claudio Zilio, Giulia Righetti, Dario Guarda, Francesca Martelletto and Simone Mancin
Energies 2025, 18(13), 3485; https://doi.org/10.3390/en18133485 - 2 Jul 2025
Viewed by 328
Abstract
The decarbonization of residential cooling systems requires innovative solutions to overcome the mismatch between the renewable energy availability and demand. Integrating latent thermal energy storage (LTES) with heat pump/air conditioning (HP/AC) units can help balance energy use and enhance efficiency. However, the dynamic [...] Read more.
The decarbonization of residential cooling systems requires innovative solutions to overcome the mismatch between the renewable energy availability and demand. Integrating latent thermal energy storage (LTES) with heat pump/air conditioning (HP/AC) units can help balance energy use and enhance efficiency. However, the dynamic behavior of such integrated systems, particularly under low-load conditions, remains underexplored. This study investigates a 5 kW HP/AC unit coupled with an 18 kWh LTES system using a bio-based Phase Change Material (PCM) with a melting temperature of 9 °C. Two configurations were tested: charging the LTES using either a thermostatic bath or the HP/AC unit. Key parameters such as the stored energy, temperature distribution, and cooling capacity were analyzed. The results show that, under identical conditions (2 °C inlet temperature, 16 L/min flow rate), the energy stored using the HP/AC unit was only 6.3% lower than with the thermostatic bath. Nevertheless, significant cooling capacity fluctuations occurred with the HP/AC unit due to compressor modulation and anti-frost cycles. The compressor frequency varied from 75 Hz to 25 Hz, and inefficient on-off cycling appeared in the final phase, when the power demand dropped below 1 kW. These findings highlight the importance of integrated system design and control strategies. A co-optimized HP/AC–LTES setup is essential to avoid performance degradation and to fully exploit the benefits of thermal storage in residential cooling. Full article
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28 pages, 5469 KiB  
Article
Mechanical Properties and Performance of CNT–Reinforced Mortars (CEM II/B–L and CEM I) for Crack Bridging and Protective Coating Applications
by Nikolaos Chousidis
Buildings 2025, 15(13), 2296; https://doi.org/10.3390/buildings15132296 - 30 Jun 2025
Viewed by 350
Abstract
Cement–based mortars are essential in both modern construction and heritage conservation, where balancing mechanical strength with material compatibility is crucial. Mortars containing ––binders with low hydraulic activity, such as CEM II/B–L, often exhibit increased porosity and diminished strength, limiting their suitability for structurally [...] Read more.
Cement–based mortars are essential in both modern construction and heritage conservation, where balancing mechanical strength with material compatibility is crucial. Mortars containing ––binders with low hydraulic activity, such as CEM II/B–L, often exhibit increased porosity and diminished strength, limiting their suitability for structurally demanding applications. This study investigates the potential of multiwalled carbon nanotubes (MWCNTs) to enhance the mechanical and microstructural properties of mortars formulated with both CEM II/B–L and CEM I binders. The influence of CNT incorporation was systematically assessed through compressive and flexural strength tests, vacuum saturation tests, mercury intrusion porosimetry (MIP), scanning electron microscopy (SEM), and differential thermal analysis (DTA). The results demonstrate significant mechanical improvements attributable to nanoscale mechanisms including crack bridging, pore–filling, and stress redistribution. Microstructural characterization revealed a refined pore network, increased densification of the matrix, and morphological modifications of hydration products. These findings underscore the effectiveness of CNT reinforcement in cementitious matrices and highlight the critical role of binder composition in influencing these effects. This work advances the development of high–performance mortar systems, optimized for enhanced structural integrity and long–term durability. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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17 pages, 3640 KiB  
Article
Sustainable Development of PLA-Based Biocomposites Reinforced with Pineapple Core Powder: Extrusion and 3D Printing for Thermal and Mechanical Performance
by Kawita Chattrakul, Anothai Pholsuwan, Athapon Simpraditpan, Ekkachai Martwong and Wichain Chailad
Polymers 2025, 17(13), 1792; https://doi.org/10.3390/polym17131792 - 27 Jun 2025
Viewed by 439
Abstract
This study developed sustainable biocomposites composed of polylactic acid (PLA) and surface-treated pineapple core powder (PACP), fabricated via extrusion and fused deposition modelling (FDM). PACP loadings of 1–3 vol% were combined after chemical modification with NaOH and silane to improve interfacial bonding. Particle [...] Read more.
This study developed sustainable biocomposites composed of polylactic acid (PLA) and surface-treated pineapple core powder (PACP), fabricated via extrusion and fused deposition modelling (FDM). PACP loadings of 1–3 vol% were combined after chemical modification with NaOH and silane to improve interfacial bonding. Particle morphology showed increased porosity and surface roughness following treatment. The melt flow index (MFI) increased from 31.56 to 35.59 g/10 min at 2 vol% PACP, showing improved flowability. Differential scanning calorimetry (DSC) showed the emergence of cold crystallization (Tcc ~121 °C) and an increase in crystallinity from 35.7% (neat PLA) to 47.3% (2 vol% PACP). Thermogravimetric analysis showed only slight decreases in T5 and Tmax, showing the thermal stability. The mechanical testing of extruded filaments showed increased modulus (1463 to 1518 MPa) but a decrease in tensile strength and elongation. For the 3D-printed samples, elongation at break increased slightly at 1–2 vol% PACP, likely because of the improvement in interlayer fusion. Though, at 3 vol% PACP, the mechanical properties declined, consistent with filler agglomeration observed in SEM. Overall, 2 vol% PACP offered the optimal balance between printability, crystallinity, and mechanical performance. These results reveal the possibility of PACP as a value-added biowaste filler for eco-friendly PLA composites suitable for extrusion and 3D printing applications. Full article
(This article belongs to the Special Issue Sustainable Biopolymers and Bioproducts from Bioresources)
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22 pages, 6793 KiB  
Article
Effect of Nano-Modified Recycled Wood Fibers on the Micro/Macro Properties of Rapid-Hardening Sulfoaluminate Cement-Based Composites
by Chunyu Ma, Liang Wang, Yujiao Li, Qiuyi Li, Gongbing Yue, Yuanxin Guo, Meinan Wang and Xiaolong Zhou
Nanomaterials 2025, 15(13), 993; https://doi.org/10.3390/nano15130993 - 26 Jun 2025
Viewed by 317
Abstract
Recycled wood fiber (RWF) obtained through the multi-stage processing of waste wood serves as an eco-friendly green construction material, exhibiting lightweight, porous, and high toughness characteristics that demonstrate significant potential as a cementitious reinforcement, offering strategic advantages for environmental protection and resource recycling. [...] Read more.
Recycled wood fiber (RWF) obtained through the multi-stage processing of waste wood serves as an eco-friendly green construction material, exhibiting lightweight, porous, and high toughness characteristics that demonstrate significant potential as a cementitious reinforcement, offering strategic advantages for environmental protection and resource recycling. In this study, high-performance sulfoaluminate cement (SAC)-RWF composites prepared by modifying RWFs with nano-silica (NS) and a silane coupling agent (KH560) were developed and their effects on mechanical properties, shrinkage behavior, hydration characteristics, and microstructure of SAC-RWF composites were systematically investigated. Optimal performance was achieved at water–cement ratio of 0.5 with 20% RWF content, where the KH560-modified samples showed superior improvement, with 8.5% and 14.3% increases in 28 d flexural and compressive strength, respectively, compared to the control groups, outperforming the NS-modified samples (3.6% and 8.6% enhancements). Both modifiers improved durability, reducing water absorption by 6.72% (NS) and 7.1% (KH560) while decreasing drying shrinkage by 4.3% and 27.2%, respectively. The modified SAC composites maintained favorable thermal properties, with NS reducing thermal conductivity by 6.8% through density optimization, whereas the KH560-treated specimens retained low conductivity despite slight density increases. Micro-structural tests revealed accelerated hydration without new hydration product formation, with both modifiers enhancing cementitious matrix hydration product generation by distinct mechanisms—with NS acting through physical pore-filling, while KH560 established Si-O-C chemical bonds at paste interfaces. Although both modifications improved mechanical properties and durability, the KH560-modified SAC composite group demonstrated superior overall performance than the NS-modified group, providing a technical pathway for developing sustainable, high-performance recycled wood fiber cement-based materials with balanced functional properties for low-carbon construction applications. Full article
(This article belongs to the Special Issue Nanocomposite Modified Cement and Concrete)
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