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Keywords = tailpipe gas

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30 pages, 6709 KB  
Article
Human Toxicity Potential: A Lifecycle Evaluation in Current and Future Frameworks for Hydrogen-Based and Battery Electric Buses in the European Union
by Andrea Nicolò Damiani Ferretti, Pier Paolo Brancaleoni, Francesco Bellucci, Alessandro Brusa and Enrico Corti
Energies 2025, 18(18), 4932; https://doi.org/10.3390/en18184932 - 16 Sep 2025
Viewed by 379
Abstract
In recent years, governments have promoted the shift to low-emission transport systems, with electric and hydrogen vehicles emerging as key alternatives for greener urban mobility. Evaluating zero- or near-zero tailpipe solutions requires a Lifecycle Assessment (LCA) approach, accounting for emissions from energy production, [...] Read more.
In recent years, governments have promoted the shift to low-emission transport systems, with electric and hydrogen vehicles emerging as key alternatives for greener urban mobility. Evaluating zero- or near-zero tailpipe solutions requires a Lifecycle Assessment (LCA) approach, accounting for emissions from energy production, components and vehicle manufacturing. Such studies mainly address Greenhouse Gas (GHG) emissions, while other pollutants are often overlooked. This study compares the Human Toxicity Potential (HTP) of Battery Electric Vehicles (BEVs), Fuel Cell Vehicles (FCVs), Hydrogen Internal Combustion Engine Vehicles (H2ICEVs) and hybrid H2ICEVs for public transport in the European Union. Current and future scenarios (2024, 2030, 2050) are examined, considering evolving energy mixes and manufacturing impacts. Results underline that BEVs are characterized by the highest HTP in 2024, and that this trend is maintained even in future scenarios. As for hydrogen-based powertrains, they show lower HTPs, similar among them. This work underlines that current efforts must be intensified, especially for BEVs, to further limit harmful emissions from the mobility sector. Full article
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25 pages, 6370 KB  
Article
Emissions of Conventional and Electric Vehicles: A Comparative Sustainability Assessment
by Esra’a Alrashydah, Thaar Alqahtani and Abdulnaser Al-Sabaeei
Sustainability 2025, 17(15), 6839; https://doi.org/10.3390/su17156839 - 28 Jul 2025
Viewed by 1043
Abstract
Vehicle emissions, as a source of air pollution and greenhouse gases, have a significant impact on the environment and climate change. Battery electric vehicles (BEVs) have the potential to reduce air pollution and GHGs. However, BEVs often attract the criticism that their benefits [...] Read more.
Vehicle emissions, as a source of air pollution and greenhouse gases, have a significant impact on the environment and climate change. Battery electric vehicles (BEVs) have the potential to reduce air pollution and GHGs. However, BEVs often attract the criticism that their benefits are minimal as the power plant emissions compensate for emissions from the tailpipes of vehicles. This study compared two scenarios: scenario A considers all vehicles as internal combustion engine vehicles (ICEVs), and scenario B considers all vehicles as BEVs. The study used the City of San Antonio, Texas, as the study area. The study also focused on the seasonal and spatial variation in ICEV emissions. The results indicate that scenario A has a considerably higher volume of emissions than scenario B. For ICEVs, PM2.5 emissions were up to 50% higher in rural areas than urban areas, but 45% lower for unrestricted versus restricted conditions. CO2 emissions were highly affected by seasonal variations, with a 51% decrease from winter to summer. The full adoption of BEVs could reduce CO2 and N2O emissions by 99% and 58% per km, especially for natural gas power resources. Therefore, BEVs play a significant role in reducing emissions from the transportation sector. Full article
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24 pages, 4002 KB  
Article
CFD Simulation-Based Development of a Multi-Platform SCR Aftertreatment System for Heavy-Duty Compression Ignition Engines
by Łukasz Jan Kapusta, Bartosz Kaźmierski, Rohit Thokala, Łukasz Boruc, Jakub Bachanek, Rafał Rogóż, Łukasz Szabłowski, Krzysztof Badyda, Andrzej Teodorczyk and Sebastian Jarosiński
Energies 2025, 18(14), 3697; https://doi.org/10.3390/en18143697 - 13 Jul 2025
Viewed by 617
Abstract
Combustion processes in compression ignition engines lead to the inevitable generation of nitrogen oxides, which cannot be limited to the currently desired levels just by optimising the in-cylinder processes. Therefore, simulation-based engine development needs to include all engine-related aspects which contribute to tailpipe [...] Read more.
Combustion processes in compression ignition engines lead to the inevitable generation of nitrogen oxides, which cannot be limited to the currently desired levels just by optimising the in-cylinder processes. Therefore, simulation-based engine development needs to include all engine-related aspects which contribute to tailpipe emissions. Among them, the SCR (selective catalytic reduction) aftertreatment-related processes, such as urea–water solution injection, urea decomposition, mixing, NOx catalytic reduction, and deposits’ formation, are the most challenging, and require as much attention as the processes taking place inside the cylinder. Over the last decade, the urea-SCR aftertreatment systems have evolved from underfloor designs to close-coupled (to the engine) architecture, characterised by the short mixing length. Therefore, they need to be tailor-made for each application. This study presents the CFD-based development of a multi-platform SCR system with a short mixing length for mobile non-road applications, compliant with Stage V NRE-v/c-5 emission standard. It combines multiphase dispersed flow, including wall wetting and urea decomposition kinetic reaction modelling to account for the critical aspects of the SCR system operation. The baseline system’s design was characterised by the severe deposit formation near the mixer’s outlet, which was attributed to the intensive cooling in the mounting area. Moreover, as the simulations suggested, the spray was not appropriately mixed with the surrounding gas in its primary zone. The proposed measures to reduce the wall film formation needed to account for the multi-platform application (ranging from 56 to 130 kW) and large-scale production capability. The performed simulations led to the system design, providing excellent UWS–exhaust gas mixing without a solid deposit formation. The developed system was designed to be manufactured and implemented in large-scale series production. Full article
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23 pages, 1942 KB  
Article
Hybrid Electric Vehicles as a Strategy for Reducing Fuel Consumption and Emissions in Latin America
by Juan C. Castillo, Andrés F. Uribe, Juan E. Tibaquirá, Michael Giraldo and Manuela Idárraga
World Electr. Veh. J. 2025, 16(2), 101; https://doi.org/10.3390/wevj16020101 - 13 Feb 2025
Viewed by 2764
Abstract
The vehicle fleets in Latin America are increasingly incorporating hybrid electric vehicles due to the economic and non-economic incentives provided by governments aiming to reduce energy consumption and emissions in the transportation sector. However, the impacts of implementing hybrid vehicles remain uncertain, especially [...] Read more.
The vehicle fleets in Latin America are increasingly incorporating hybrid electric vehicles due to the economic and non-economic incentives provided by governments aiming to reduce energy consumption and emissions in the transportation sector. However, the impacts of implementing hybrid vehicles remain uncertain, especially in Latin American, which poses a risk to the achievement of environmental objectives in developing countries. The aim of this study is to evaluate the benefits of incorporating hybrid vehicles to replace internal combustion vehicles, considering the improvement in the level of emission standards. This study uses data reported by Colombian vehicle importers during the homologation process in Colombia and the number of vehicles registered in the country between 2010 and 2022. The Gompertz model and logistic growth curves are used to project the total number of vehicles, taking into account the level of hybridization and including conventional natural gas and electric vehicles. In this way, tailpipe emissions and energy efficiency up to 2040 are also projected for different hybrid vehicle penetration scenarios. Results show that the scenario in which the share of hybrid vehicles remains stable (Scenario 1) shows a slight increase in energy consumption compared to the baseline scenario, about 1.72% in 2035 and 2.87% in 2040. The scenario where the share of MHEVs, HEVs, and PHEVs reaches approximately 50% of the vehicle fleet in 2040 (Scenario 2) shows a reduction in energy consumption of 24.64% in 2035 and 33.81% in 2040. Finally, the scenario that accelerates the growth of HEVs and PHEVs while keeping MHEVs at the same level of participation from 2025 (Scenario 3) does not differ from Scenario 2. Results show that the introduction of full hybrids and plug-in hybrid vehicles improve fleet fuel consumption and emissions. Additionally, when the adoption rates of these technologies are relatively low, the benefits may be questionable, but when the market share of hybrid vehicles is high, energy consumption and emissions are significantly reduced. Nevertheless, this study also shows that Mild Hybrid Electric Vehicles (MHEVs) do not provide a significant improvement in terms of fuel consumption and emissions. Full article
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20 pages, 7115 KB  
Article
Effect of Selective Non-Catalytic Reduction Reaction on the Combustion and Emission Performance of In-Cylinder Direct Injection Diesel/Ammonia Dual Fuel Engines
by Zhongcheng Wang, Ruhong Li, Jie Zhu and Zhenqiang Fu
Energies 2025, 18(3), 565; https://doi.org/10.3390/en18030565 - 25 Jan 2025
Cited by 1 | Viewed by 795
Abstract
Ammonia, as a hydrogen carrier and an ideal zero-carbon fuel, can be liquefied and stored under ambient temperature and pressure. Its application in internal combustion engines holds significant potential for promoting low-carbon emissions. However, due to its unique physicochemical properties, ammonia faces challenges [...] Read more.
Ammonia, as a hydrogen carrier and an ideal zero-carbon fuel, can be liquefied and stored under ambient temperature and pressure. Its application in internal combustion engines holds significant potential for promoting low-carbon emissions. However, due to its unique physicochemical properties, ammonia faces challenges in achieving ignition and combustion when used as a single fuel. Additionally, the presence of nitrogen atoms in ammonia results in increased NOx emissions in the exhaust. High-temperature selective non-catalytic reduction (SNCR) is an effective method for controlling flue gas emissions in engineering applications. By injecting ammonia as a NOx-reducing agent into exhaust gases at specific temperatures, NOx can be reduced to N2, thereby directly lowering NOx concentrations within the cylinder. Based on this principle, a numerical simulation study was conducted to investigate two high-pressure injection strategies for sequential diesel/ammonia dual-fuel injection. By varying fuel spray orientations and injection durations, and adjusting the energy ratio between diesel and ammonia under different operating conditions, the combustion and emission characteristics of the engine were numerically analyzed. The results indicate that using in-cylinder high-pressure direct injection can maintain a constant total energy output while significantly reducing NOx emissions under high ammonia substitution ratios. This reduction is primarily attributed to the role of ammonia in forming NH2, NH, and N radicals, which effectively reduce the dominant NO species in NOx. As the ammonia substitution ratio increases, CO2 emissions are further reduced due to the absence of carbon atoms in ammonia. By adjusting the timing and duration of diesel and ammonia injection, tailpipe emissions can be effectively controlled, providing valuable insights into the development of diesel substitution fuels and exhaust emission control strategies. Full article
(This article belongs to the Section B: Energy and Environment)
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19 pages, 1345 KB  
Article
Evaluating the Impacts of Autonomous Electric Vehicles Adoption on Vehicle Miles Traveled and CO2 Emissions
by Jingyi Xiao, Konstadinos G. Goulias, Srinath Ravulaparthy, Shivam Sharda, Ling Jin and C. Anna Spurlock
Energies 2024, 17(23), 6127; https://doi.org/10.3390/en17236127 - 5 Dec 2024
Viewed by 1801
Abstract
Autonomous electric vehicles (AEVs) can potentially revolutionize the transportation landscape, offering a safer, contact-free, easily accessible, and more eco-friendly mode of travel. Prior to the market uptake of AEVs, it is critical to understand the consumer segments that are most likely to adopt [...] Read more.
Autonomous electric vehicles (AEVs) can potentially revolutionize the transportation landscape, offering a safer, contact-free, easily accessible, and more eco-friendly mode of travel. Prior to the market uptake of AEVs, it is critical to understand the consumer segments that are most likely to adopt these vehicles. Beyond market adoption, it is also important to quantify the impact of AEVs on broader transportation systems and the environment, such as impacts on the annual vehicle miles traveled (VMT) and greenhouse gas (GHG) emissions. In this pilot study, using survey data, a statistical model correlating AEV adoption intention and socioeconomic and built environment attributes was estimated, and a sensitivity analysis was conducted to understand the importance of factors impacting AEV adoption. We found that the market segments range from early adopters who are wealthy, technologically savvy, and relatively young to non-adopters who are more cautious to new technologies. This is followed by a synthetic population microsimulation of market penetration for the San Francisco Bay Area. With five household vehicle replacement scenarios, we assessed the annual VMT and tailpipe carbon dioxide (CO2) emissions change associated with vehicle replacement. It is found that adopting AEVs can potentially reduce more than 5 megatons of CO2 yearly, which is approximately 30% of the total CO2 emitted by internal combustion engine (ICE) cars in the region. Full article
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18 pages, 3359 KB  
Article
Alternative Analyzers for the Measurement of Gaseous Compounds During Type-Approval of Heavy-Duty Vehicles
by Ricardo Suarez-Bertoa, Roberto Gioria, Christian Ferrarese, Lorenzo Finocchiaro and Barouch Giechaskiel
Energies 2024, 17(22), 5676; https://doi.org/10.3390/en17225676 - 13 Nov 2024
Viewed by 1419
Abstract
Emissions standards describe the fuels, the procedures, and, among others, the analyzers to be used for the measurement of the different compounds during the type-approval of heavy-duty engines and vehicles. Traditionally, NOx, CO, hydrocarbons, and CO2 were the gaseous compounds measured within [...] Read more.
Emissions standards describe the fuels, the procedures, and, among others, the analyzers to be used for the measurement of the different compounds during the type-approval of heavy-duty engines and vehicles. Traditionally, NOx, CO, hydrocarbons, and CO2 were the gaseous compounds measured within the Euro standard, with the later addition of CH4 and NH3. Euro 7, introduced in early 2024, expanded those compounds, requiring the measurement of N2O and HCHO. With an increasing number of molecules that need to be measured and introducing carbonless fuels, such as hydrogen, that present different requirements compared to carbon-based fuels, the test procedure needs to be updated. The performances of three laboratory-grade instruments and three portable emissions measurement systems based on Fourier-transformed infrared (FTIR) or quantum cascade laser infrared (QCL-IR) technologies were investigated while measuring from the tailpipe of a Diesel engine and a compressed natural gas (CNG) vehicle. All instruments presented good agreement when emissions of NOx, CO, CH4, NH3, N2O, HCHO, and CO2 were compared using: Z-score, F-test and two tail t-test of student. Water concentration measured by the four FTIRs was also in good agreement. Moreover, the dry emissions of CO2 and CO measured by the laboratory non-dispersive infrared (NDIR) and corrected using water were a few percentages different from those obtained using the regulated carbon-based approach. The results indicate that all the investigated systems are suitable for the measurement of the investigated gaseous compounds, including CO2 and H2O. Full article
(This article belongs to the Section B: Energy and Environment)
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13 pages, 3167 KB  
Article
The Effects of Varying Altitudes on the Rates of Emissions from Diesel and Gasoline Vehicles Using a Portable Emission Measurement System
by Zhaoyu Qi, Ming Gu, Jianguo Cao, Zhiwei Zhang, Chuanzhou You, Yue Zhan, Zhongwu Ma and Wei Huang
Atmosphere 2023, 14(12), 1739; https://doi.org/10.3390/atmos14121739 - 26 Nov 2023
Cited by 11 | Viewed by 3996
Abstract
The high altitude in mountainous regions results in lower atmospheric pressure, oxygen concentration and temperature, leading to lower combustion efficiency in motor vehicles. Therefore, there may be differences in carbon dioxide (CO2), carbon monoxide (CO), and nitrogen oxides (NOx) [...] Read more.
The high altitude in mountainous regions results in lower atmospheric pressure, oxygen concentration and temperature, leading to lower combustion efficiency in motor vehicles. Therefore, there may be differences in carbon dioxide (CO2), carbon monoxide (CO), and nitrogen oxides (NOx) emissions characteristics at different altitudes. In this study, a portable emission measurement system was used to investigate the effects of varying elevations on the emission factors of CO2, CO, and NOx on diesel and gasoline-powered vehicles at altitudes ranging from 2270 to 4540 m in the Qinghai–Tibet Plateau of China. Additionally, the influencing factors of CO2, CO, and NOx emissions were studied. Results showed that the CO2, CO, and NOx emission factors for diesel vehicles varied in the range of 161.83–195.54, 0.59–0.77, and 4.61–6.58 g/km; the population means with 90% confidence intervals were 178.54, 0.68, and 5.60 g/km, respectively. For gasoline vehicles, the CO2, CO, and NOx emission factors varied in the range of 161.66–181.98, 0.95–1.06, and 0.12–0.25 g/km; the population means with 90% confidence intervals were 171.82, 1.01, and 0.19 g/km, respectively. Overall, the emission factors of diesel vehicles were higher than those of gasoline vehicles, and the emissions increased with increasing altitude. Atmospheric pressure was identified as the primary environmental factor affecting CO2, CO, and NOx emissions. As the speed of motor vehicles increased, the emission of CO2 also increased, while there was a quadratic relationship with acceleration. This study provides a reference and guidance for vehicle pollution control in high-altitude regions. Full article
(This article belongs to the Special Issue Novel Techniques for Measuring Greenhouse Gases (2nd Edition))
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14 pages, 1725 KB  
Article
Cradle-to-Grave Lifecycle Analysis of Greenhouse Gas Emissions of Light-Duty Passenger Vehicles in China: Towards a Carbon-Neutral Future
by Yu Gan, Zifeng Lu, Xin He, Michael Wang and Amer Ahmad Amer
Sustainability 2023, 15(3), 2627; https://doi.org/10.3390/su15032627 - 1 Feb 2023
Cited by 12 | Viewed by 5187
Abstract
Vehicle electrification is considered a pathway for on-road transportation decarbonization in China. Different from the conventional gasoline vehicles whose emissions are mainly released from vehicle tailpipes, emissions of battery electric vehicles (BEVs) are from the upstream processes of electricity generation and vehicle manufacturing, [...] Read more.
Vehicle electrification is considered a pathway for on-road transportation decarbonization in China. Different from the conventional gasoline vehicles whose emissions are mainly released from vehicle tailpipes, emissions of battery electric vehicles (BEVs) are from the upstream processes of electricity generation and vehicle manufacturing, thus a comprehensive lifecycle analysis and comparison of BEVs with gasoline vehicles is required to quantify the emission mitigation benefit of vehicle electrification and determine the path to a carbon-neutral future. In the study, we compare the cradle-to-grave (C2G) lifecycle greenhouse gas emissions of gasoline and electric vehicles in China and analyze the greenhouse gas emission reduction of vehicle electrification in different provinces. Results show that under the current technologies, the national average C2G GHG emissions for battery electric vehicles (BEVs) of 100 miles (i.e., 160 km) and 300 miles (i.e., 480 km) all-electric range (AER) are 231 and 279 g CO2eq/km, respectively, 22% and 5% lower than those for gasoline internal combustion engine vehicles (ICEVs). Improving vehicle fuel efficiency by hybridizing gasoline ICEVs can effectively reduce C2G emissions to 212 g CO2eq/km. At the provincial level, C2G GHG emissions of BEVs vary according to the provincial electricity mix. In eight provinces, C2G GHG emissions of BEVs with 300 miles AER (BEV300s) are higher than those of gasoline ICEVs due to the GHG-intensive coal-based electricity mix. In the future scenario, with low carbon fuels (such as high-level bioethanol blending gasoline) and electricity decarbonization, the national average C2G emissions of hybrid electric vehicles (HEVs) and BEV300s can be reduced to 55 and 73 g CO2eq/km, respectively. Further decrease of C2G GHG emissions relies on reducing vehicle-cycle emissions from material processing and vehicle component manufacturing. Full article
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33 pages, 2516 KB  
Article
Assessing and Managing the Direct and Indirect Emissions from Electric and Fossil-Powered Vehicles
by Adekunle Mofolasayo
Sustainability 2023, 15(2), 1138; https://doi.org/10.3390/su15021138 - 7 Jan 2023
Cited by 21 | Viewed by 6223
Abstract
Efforts to improve air quality and concerns about global warming make transportation mediums that do not produce emissions more attractive to end users. Meanwhile, some of these transportation mediums are powered by an electricity grid that generates a great deal of emissions. This [...] Read more.
Efforts to improve air quality and concerns about global warming make transportation mediums that do not produce emissions more attractive to end users. Meanwhile, some of these transportation mediums are powered by an electricity grid that generates a great deal of emissions. This study compared the greenhouse gas GHG emissions for both electric and fossil-powered vehicles using estimates of tailpipe emissions of fossil-powered vehicles and the indirect emissions from the electricity grid. Furthermore, a system dynamic model was developed for a more holistic review of the GHG emissions for both electric and fossil-powered vehicles. The result indicated that in terms of associated emissions from the grid, electric-powered vehicles are not always better than fossil-powered vehicles when the electricity is not from a renewable source. The GHG emissions for electric-powered vehicles are dependent on both the electricity usage rate of the vehicle and the GHG emissions that are associated with the production of that amount of electricity. Further opportunities exist in renewable and clean energy technologies for various operations. Based on reports from previous works, this report also presented potential strategies to achieve a significant reduction in GHG emissions for both the electricity grid and fossil fuel refining processes. Full article
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14 pages, 4493 KB  
Article
Euro VI-d Compliant Diesel Engine’s Sub-23 nm Particle Emission
by Norbert Biró and Péter Kiss
Sensors 2023, 23(2), 590; https://doi.org/10.3390/s23020590 - 4 Jan 2023
Cited by 8 | Viewed by 3455
Abstract
Passenger and commercial transportation significantly contribute to hazardous air pollution. Exhaust gas after-treatment technology advances closely to the emission regulations throughout the world. The upcoming legislation will be EURO VII in European Union, which requirements are not set yet, but the Solid Particle [...] Read more.
Passenger and commercial transportation significantly contribute to hazardous air pollution. Exhaust gas after-treatment technology advances closely to the emission regulations throughout the world. The upcoming legislation will be EURO VII in European Union, which requirements are not set yet, but the Solid Particle Number (SPN) diameter range is expected to be more severe compared to EURO VI. This paper will revisit the measurement principle differences between over 10 nm and over 23 nm diameter particles in theory and practical engine bench measurement. Two different types of particle counters have performed the soot particle counting measurement; therefore, the applied sensors are different in terms of applied counting principles. The measurement principles of both devices will be introduced, and the experiment’s result will reflect on the sensor differences. From this, a conclusion can be derived in order to determine the severity of the upcoming EURO VII legislation in terms of SPN, and the experiment will also reflect on the measurement sensor differences. The overall results suggested that extending the lower range of the measurement increases the tailpipe particle emission by 20%, although the DPF filtration efficiency is still over 99%. Full article
(This article belongs to the Section Vehicular Sensing)
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17 pages, 1903 KB  
Article
Comparing e-Fuels and Electrification for Decarbonization of Heavy-Duty Transports
by Matteo Prussi, Lorenzo Laveneziana, Lorenzo Testa and David Chiaramonti
Energies 2022, 15(21), 8075; https://doi.org/10.3390/en15218075 - 31 Oct 2022
Cited by 26 | Viewed by 4885
Abstract
The freight sector is expected to keep, or even increase, its fundamental role for the major modern economies, and therefore actions to limit the growing pressure on the environment are urgent. The use of electricity is a major option for the decarbonization of [...] Read more.
The freight sector is expected to keep, or even increase, its fundamental role for the major modern economies, and therefore actions to limit the growing pressure on the environment are urgent. The use of electricity is a major option for the decarbonization of transports; in the heavy-duty segment, it can be implemented in different ways: besides full electric-battery powertrains, electricity can be used to supply catenary roads, or can be chemically stored in liquid or gaseous fuels (e-fuels). While the current EU legislation adopts a tailpipe Tank-To-Wheels approach, which results in zero emissions for all direct uses of electricity, a Well-To-Wheels (WTW) method would allow accounting for the potential benefits of using sustainable fuels such as e-fuels. In this article, we have performed a WTW-based comparison and modelling of the options for using electricity to supply heavy-duty vehicles: e-fuels, eLNG, eDiesel, and liquid Hydrogen. Results showed that the direct use of electricity can provide high Greenhouse Gas (GHG) savings, and also in the case of the e-fuels when low-carbon-intensity electricity is used for their production. While most studies exclusively focus on absolute GHG savings potential, considerations of the need for new infrastructures, and the technological maturity of some options, are fundamental to compare the different technologies. In this paper, an assessment of such technological and non-technological barriers has been conducted, in order to compare alternative pathways for the heavy-duty sector. Among the available options, the flexibility of using drop-in, energy-dense liquid fuels represents a clear and substantial immediate advantage for decarbonization. Additionally, the novel approach adopted in this paper allows us to quantify the potential benefits of using e-fuels as chemical storage able to accumulate electricity from the production peaks of variable renewable energies, which would otherwise be wasted due to grid limitations. Full article
(This article belongs to the Special Issue Advances in Fuels and Energy Conversion)
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16 pages, 3316 KB  
Article
Determination of Carbonyls Compound, Ketones and Aldehydes Emissions from CI Diesel Engines Fueled with Pure Diesel/Diesel Methanol Blends
by Hani Al-Rawashdeh, Ahmad O. Hasan, Mohamed R. Gomaa, Ahmad Abu-jrai and Mohammad Shalby
Energies 2022, 15(21), 7933; https://doi.org/10.3390/en15217933 - 26 Oct 2022
Cited by 8 | Viewed by 2387
Abstract
Quantitative and qualitative analyses of chemical species out of CI engine tailpipe emissions fueled with pure diesel and diesel methanol blends, trapped in dinitro phenylhydrazine (DNPH) solutions, were performed. The formed hydrazine was studied using high-performance liquid chromatography (HPLC) accompanied by a detector [...] Read more.
Quantitative and qualitative analyses of chemical species out of CI engine tailpipe emissions fueled with pure diesel and diesel methanol blends, trapped in dinitro phenylhydrazine (DNPH) solutions, were performed. The formed hydrazine was studied using high-performance liquid chromatography (HPLC) accompanied by a detector for ultraviolet (UV). A set of carbonyl-DNPH derivative standards was developed and compared with engine tailpipe gases produced by both fuel modes. An understanding of carbonyl chemical compounds such as formaldehyde, acetaldehyde, and acrolein (HCHO, CH3CHO, and H2 = CHCHO, respectively) is essential for researchers to know how these chemicals affect human health and the environment. In both fuel modes, acetaldehyde was the main combustible product 25 ppm followed by formaldehyde 17 ppm, croton aldehydes 16 ppm, acrolein 12 ppm, and iso-valerdyhyde 10 ppm. In addition to these species, only a few other chemical species were detected in the exhaust gas. According to this study, carbonyl compounds from blended fuel contribute 15–22% of pure diesel fuel emissions. As shown by the results, engine operating conditions and fuel mode have a strong impact on the total amount of carbonyls released by the engine. Engine performance was highly influenced by different fuel modes and engine speeds. Using pure diesel, the regulated emissions, HC, CO, and NOx, registered high concentrations at a lower speed (1500 rpm) and NOx presented with the highest concentration of 4 g/kWh followed by CO with 1 g/kWh and HC with 0.5 g/kWh. Full article
(This article belongs to the Special Issue Advanced Engine Technologies and Fuels)
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22 pages, 7283 KB  
Article
A Multiphysics Co-Simulation Framework of a Gas Engine and Three-Way Catalyst toward a Complete Vehicle Design Model
by Dario Di Maio, Elena Stramaccioni, Daniela Anna Misul, Pierpaolo Napolitano and Carlo Beatrice
Machines 2022, 10(10), 852; https://doi.org/10.3390/machines10100852 - 24 Sep 2022
Cited by 3 | Viewed by 3903
Abstract
In view of the increasingly stringent emission regulations, the automotive sector needs considerable support from the development of robust and reliable engine and aftertreatment models. Accurate reproduction of engine-out and tailpipe pollutants plays a crucial role in complying with these legislations. Given the [...] Read more.
In view of the increasingly stringent emission regulations, the automotive sector needs considerable support from the development of robust and reliable engine and aftertreatment models. Accurate reproduction of engine-out and tailpipe pollutants plays a crucial role in complying with these legislations. Given the difficulty in characterizing some critical phenomena, frequently caused by strong dynamics and related to experimental uncertainties, communication between several calibrated and reliable models is mandatory. This is certainly valid for powertrains that will be powered with alternative gas fuels such as natural gas, bio-methane and hydrogen in the future. This paper describes a methodology to co-simulate a 1D CNG HD 6-cyl engine model and a 1D quasi-steady Three-Way Catalyst model in a global framework for high-fidelity virtual prototyping of the vehicle system. Through the implementation of a dedicated control logic in MATLAB/Simulink, the modeling architecture allows for the reproduction of the engine performance parameters together with the evaluation of the TWC pollutants’ conversion efficiency. An extensive database of experimental tests was used to assess the model response. The latter was validated in multiple steady-state operating conditions of the engine workplan. Using a semi-predictive combustion model, the validation was carried out over a wide range of different air-to-fuel ratios and during fast rich/lean transitions to evaluate the formation and conversion phenomena of the main chemical species, both engine-out and tailpipe. Subsequently, the complete model was validated in dynamic conditions throughout a WHTC, accurately reproducing the cut-off phases and their sudden accelerations. The numerical–experimental agreement on pollutant reproduction is generally good and globally below 3%. Larger deviations occur in extremely rich conditions and in CH4 emission evaluation due to the lack of information related to the combustion process and chemical mechanisms involving the Pd surface. Full article
(This article belongs to the Section Vehicle Engineering)
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29 pages, 8170 KB  
Article
Development of Two-Step Exhaust Rebreathing for a Low-NOx Light-Duty Gasoline Compression Ignition Engine
by Praveen Kumar, Mark Sellnau, Ashish Shah, Christopher Whitney and Rafael Sari
Energies 2022, 15(18), 6565; https://doi.org/10.3390/en15186565 - 8 Sep 2022
Cited by 10 | Viewed by 2737
Abstract
The global automotive industry is undergoing a significant transition as battery electric vehicles enter the market and diesel sales decline. It is widely recognized that internal combustion engines (ICE) will be needed for transport for years to come; however, demands on ICE fuel [...] Read more.
The global automotive industry is undergoing a significant transition as battery electric vehicles enter the market and diesel sales decline. It is widely recognized that internal combustion engines (ICE) will be needed for transport for years to come; however, demands on ICE fuel efficiency, emissions, cost, and performance are extremely challenging. Gasoline compression ignition (GCI) is one approach for achieving the demanding efficiency and emissions targets. A key technology enabler for GCI is partially-premixed, compression ignition (PPCI) combustion, which involves two high-pressure, late fuel injections during the compression stroke. Both NOx and smoke emissions are greatly reduced relative to diesel, and this reduces the aftertreatment (AT) requirements significantly. For robust low-load and cold operation, a two-step valvetrain system is used for exhaust rebreathing (RB). Exhaust rebreathing involves the reinduction of hot exhaust gases into the cylinder during a second exhaust lift event during the intake stroke to help promote autoignition. The amount of exhaust rebreathing is controlled by exhaust backpressure, created by the vanes on the variable nozzle turbine (VNT) turbocharger. Because of the higher cycle temperatures during rebreathing, exhaust HC and CO may be significantly reduced, while combustion robustness and stability also improve. Importantly, exhaust rebreathing significantly increases exhaust temperatures in order to maintain active catalysis in the AT system for ultra-low tailpipe emissions. To achieve these benefits, it is important to optimize the rebreathe valve lift profile and develop an RB ON→OFF (mode switch) strategy that is easy to implement and control, without engine torque fluctuation. In this study, an engine model was developed using GT-Suite to conduct steady-state and transient engine simulations of the rebreathing process, followed by engine tests. The investigation was conducted in four parts. In part 1, various rebreathe lift profiles were simulated. The system performance was evaluated based on in-cylinder temperature, exhaust temperature, and pumping work. The results were compared with alternative variable valve actuation (VVA) strategies such as early exhaust valve closing (EEVC), negative valve overlap (NVO), positive valve overlap (PVO). In part 2, steady-state simulations were conducted to determine an appropriate engine load range for mode switching (exhaust rebreathing ON/OFF and vice-versa). The limits for both in-cylinder temperature and exhaust gas temperature, as well as the external exhaust gas recirculation (EGR) delivery potential were set as the criteria for load selection. In part 3, transient simulations were conducted to evaluate various mode switch strategies. For RB OFF, the cooled external EGR was utilized with the goal to maintain exhaust gas dilution during mode switches for low NOx emissions. The most promising mode-switch strategies produced negligible torque fluctuation during the mode switch. Finally, in part 4, engine tests were conducted, using the developed RB valve lift profile, at various low-load operating conditions. The mode switch experiments correlated well with the simulation results. The tests demonstrated the simplicity and robustness of the exhaust rebreathing approach. A robust engine response, low CNL, high exhaust gas temperature, and low engine out emissions were achieved in the low load region. Full article
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