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25 pages, 397 KB  
Review
Migration and Accumulation of Uranium-Associated Heavy Metals in Mining-Affected Ecosystems (Water, Soil, and Plants)
by Madina Kairullova, Meirat Bakhtin, Kuralay Ilbekova and Danara Ibrayeva
Biology 2026, 15(6), 502; https://doi.org/10.3390/biology15060502 (registering DOI) - 20 Mar 2026
Abstract
Uranium mining generates complex multi-element contamination that affects interconnected ecosystem components, posing long-term ecological and sanitary risks; this review places these impacts in a broad environmental context and aims to synthesize current knowledge on the distribution, migration, and accumulation of uranium and associated [...] Read more.
Uranium mining generates complex multi-element contamination that affects interconnected ecosystem components, posing long-term ecological and sanitary risks; this review places these impacts in a broad environmental context and aims to synthesize current knowledge on the distribution, migration, and accumulation of uranium and associated heavy metals in water, soil, and plants. A structured analysis of international peer-reviewed literature was conducted, focusing on documented pathways of metal release from tailings and waste dumps, geochemical controls on mobility, and biological uptake by vegetation. The reviewed studies consistently show that tailings and disturbed ore-bearing strata act as persistent sources of uranium and heavy metals (e.g., Cd, Pb, Cr, Ni, Zn, Mn, As), which migrate through infiltration, acid mine drainage, and atmospheric dispersion, leading to elevated concentrations in surface and groundwater and long-term accumulation in soils. Soils function as the principal sink controlling metal bioavailability, while vegetation reflects the bioavailable fraction and exhibits pronounced species-specific accumulation patterns. These processes establish an active “soil–water–plant” transfer chain that facilitates entry of contaminants into food webs. The synthesis indicates that combined uranium and heavy metal contamination represents a sustained ecological and public health concern in uranium-mining regions and underscores the need for integrated monitoring of soils, waters, and vegetation, along with quantitative risk assessment and scientifically grounded remediation strategies. Full article
(This article belongs to the Section Ecology)
16 pages, 5774 KB  
Article
The Influence of Co-Stacking Waste Rock and Tailings on the Saturation Line of Tailings Dams
by Taixu Sun, Bing Zhao, Rong Lan and Mingsheng Liu
Eng 2026, 7(1), 3; https://doi.org/10.3390/eng7010003 - 19 Dec 2025
Cited by 1 | Viewed by 283
Abstract
The large-scale development of mineral resources has led to a sharp increase in the amount of tailings and waste rock accumulated in tailings ponds and waste disposal sites, forming a large number of high-risk tailings dams and high-pile waste disposal sites. In recent [...] Read more.
The large-scale development of mineral resources has led to a sharp increase in the amount of tailings and waste rock accumulated in tailings ponds and waste disposal sites, forming a large number of high-risk tailings dams and high-pile waste disposal sites. In recent years, frequent incidents of tailings dam breaches and landslides in high-pile dumping sites have posed a serious threat to the lives and property of downstream residential areas. Therefore, studying the collaborative storage technology of waste rock and tailings is of great significance. By conducting physical model experiments on tailings dams of a similar scale and using the SEEP/W module in GeoStudio 2022.1 software for numerical simulation, the influence of the built-in waste-rock inclusions on the permeability characteristics of the dam body and the depth of the saturation line is analyzed. The results showed that the seepage flow increased with the decrease in fine particle content in the waste-rock inclusions, with the highest seepage flow in the C-grade waste-rock inclusions and the most significant decrease in the saturation line, and the seepage volume decreased with the increase in the spacing between waste-rock inclusions. The depth of the saturation line is negatively correlated with the distance between the centers of the waste-rock inclusions; that is, the smaller the distance (200 mm), the greater the depth of the saturation line. The research results can provide a reference for ensuring the safety and stability analysis of tailings dams. Full article
(This article belongs to the Section Chemical, Civil and Environmental Engineering)
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21 pages, 3832 KB  
Article
Restoration Potential of Vegetation: Soil Nutrient Responses and Heavy Metal Distribution in Coal Mine Tailings
by George Popescu, Cosmin Alin Popescu, Adina Horablaga, Florin Crista, Lucian Dragomir, Casiana Mihut, Adina Berbecea and Isidora Radulov
Land 2025, 14(11), 2274; https://doi.org/10.3390/land14112274 - 17 Nov 2025
Cited by 1 | Viewed by 734
Abstract
Coal mining leaves behind extensive tailing dumps that pose long-term ecological and soil degradation challenges. This study evaluates the restoration potential of vegetation on coal mine tailings in the Jiu Valley, Romania, focusing on soil nutrient dynamics and the heavy metal distribution. Field [...] Read more.
Coal mining leaves behind extensive tailing dumps that pose long-term ecological and soil degradation challenges. This study evaluates the restoration potential of vegetation on coal mine tailings in the Jiu Valley, Romania, focusing on soil nutrient dynamics and the heavy metal distribution. Field sampling was conducted across three vegetation types—unvegetated (UV), herbaceous (HV), and arboreal (AV, Robinia pseudoacacia)—at two intervals: three and six years post-plantation. Soil samples were analyzed for their pH, organic carbon, macronutrients, micronutrients, and heavy metals using standardized spectrometric and titrimetric methods. Between 2021 and 2024, AV plots showed a 9.5% increase in total nitrogen and a 5.2% rise in organic carbon, alongside a 6.9% reduction in soil pH. HV plots exhibited a 10.6% increase in magnesium availability and a 2.8% decrease in copper concentrations, indicating active nutrient cycling. In contrast, UV soils retained 68% higher total potassium and 24% more zinc than vegetated plots, likely due to limited biological uptake. Lead concentrations remained below the EU threshold of 60 mg kg−1, while nickel levels exceeded recommended limits across all variants, peaking at 76.08 mg kg−1. The vegetation type significantly influenced nutrient mobilization and metal stabilization, with arboreal cover demonstrating the most consistent ameliorative effects. These findings underscore the role of targeted revegetation—particularly with Robinia pseudoacacia—in improving soil quality and mitigating ecological risks in post-mining landscapes. Full article
(This article belongs to the Special Issue Land Use and Management for Waste Disposal and Wastewater Treatment)
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21 pages, 5917 KB  
Article
Cyanobacterial Assemblages Inhabiting the Apatity Thermal Power Plant Fly Ash Dumps in the Russian Arctic
by Denis Davydov and Anna Vilnet
Microorganisms 2025, 13(8), 1762; https://doi.org/10.3390/microorganisms13081762 - 28 Jul 2025
Cited by 1 | Viewed by 718
Abstract
In the process of the work of a coal power station is formed ash and slag, which, along with process water, are deposited in the dumps. Coal ash waste dumps significantly degrade the surrounding environment due to their unprotected surfaces, which are highly [...] Read more.
In the process of the work of a coal power station is formed ash and slag, which, along with process water, are deposited in the dumps. Coal ash waste dumps significantly degrade the surrounding environment due to their unprotected surfaces, which are highly susceptible to wind and water erosion. This results in the dispersion of contaminants into adjacent ecosystems. Pollutants migrate into terrestrial and aquatic systems, compromising soil quality and water resources, and posing documented risks to the environment and human health. Primary succession on the coal ash dumps of the Apatity thermal power plant (Murmansk Region, NW Russia) was initiated by cyanobacterial colonization. We studied cyanobacterial communities inhabiting three spoil sites that varied in time since decommissioning. These sites are characterized by exceptionally high concentrations of calcium and magnesium oxides—levels approximately double those found in the region’s natural soils. A total of 18 cyanobacterial taxa were identified in disposal sites. Morphological analysis of visible surface crusts revealed 16 distinct species. Furthermore, 24 cyanobacterial strains representing 11 species were successfully isolated into unialgal culture and tested with a molecular genetic approach to confirm their identification from 16S rRNA. Three species were determined with molecular evidence. Cyanobacterial colonization of coal fly ash disposal sites begins immediately after deposition. Primary communities initially exhibit low species diversity (four taxa) and do not form a continuous ground cover in the early years. However, as succession progresses—illustrated by observations from a 30-year-old deposit—spontaneous surface revegetation occurs, accompanied by a marked increase in cyanobacterial diversity, reaching 12 species. Full article
(This article belongs to the Special Issue Microbial Diversity Research in Different Environments)
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19 pages, 6727 KB  
Article
Soil Contamination and Related Ecological Risks: Complex Analysis of the Defor Petrila Tailings Dump, Romania
by Emilia-Cornelia Dunca, Mădălina-Flavia Ioniță and Sorin Mihai Radu
Land 2025, 14(7), 1492; https://doi.org/10.3390/land14071492 - 18 Jul 2025
Viewed by 784
Abstract
Assessing the risks associated with waste disposal is essential for environmental protection and sustainable development, especially given concerns about the impact of industrial activities on the environment. This study analyses soil contamination in the Defor Petrila tailings-dump area caused by the deposition of [...] Read more.
Assessing the risks associated with waste disposal is essential for environmental protection and sustainable development, especially given concerns about the impact of industrial activities on the environment. This study analyses soil contamination in the Defor Petrila tailings-dump area caused by the deposition of waste material resulting from coal exploitation. To characterise the heavy-metal contamination in detail, we applied a comprehensive methodology that includes the calculation of the geo-accumulation index (Igeo), contamination factor (Cf), and potential ecological risk index (PERI), along with an analysis of the heavy-metal concentration isolines and a statistical analysis using the Pearson correlation coefficient. The results reveal varying levels of heavy-metal concentrations, as indicated by the calculated indices. The findings underscore the need for remediation and ongoing monitoring to mitigate the environmental impacts. This study provides a scientific basis for decision making in environmental management and highlights the importance of assessing mining-waste disposal near human settlements using various contamination-assessment methods. Full article
(This article belongs to the Section Land Use, Impact Assessment and Sustainability)
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29 pages, 28225 KB  
Review
Toxic Legacy—Environmental Impacts of Historic Metal Mining and Metallurgy in the Harz Region (Germany) at Local, Regional and Supra-Regional Levels
by Louisa Friederike Steingräber, Friedhart Knolle, Horst Kierdorf, Catharina Ludolphy and Uwe Kierdorf
Environments 2025, 12(7), 215; https://doi.org/10.3390/environments12070215 - 26 Jun 2025
Cited by 2 | Viewed by 5544
Abstract
As a legacy of historical metal mining and the processing and smelting of metalliferous ores, metal pollution is a serious environmental problem in many areas around the globe. This review summarizes the history, technical development and environmental hazards of historic metal mining and [...] Read more.
As a legacy of historical metal mining and the processing and smelting of metalliferous ores, metal pollution is a serious environmental problem in many areas around the globe. This review summarizes the history, technical development and environmental hazards of historic metal mining and metallurgical activities in the Harz Region (Germany), one of the oldest and most productive mining landscapes in Central Europe. The release of large amounts of metal-containing waste into rivers during historic ore processing and the ongoing leaching of metals from slag heaps, tailings dumps and contaminated soils and sediments are the main sources of metal pollution in the Harz Mountains and its foreland. This pollution extends along river systems with tributaries from the Harz Mountains and can even be detected in mudflats of the North Sea. In addition to fluvial discharges, atmospheric pollution by smelter smoke has led to long-term damage to soils and vegetation in the Harz Region. Currently, the ecological hazards caused by the legacy pollution from historical metal mining and metallurgy in the Harz Region are only partially known, particularly regarding the effects of changes in river ecosystems as a consequence of climate change. This review discusses the complexity and dynamics of human–environment interactions in the Harz Mountains and its surroundings, with a focus on lead (Pb) pollution. The paper also identifies future research directions with respect to metal contamination. Full article
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20 pages, 3109 KB  
Article
A New Conservative Approach for Statistical Data Analysis in Surveying for Trace Elements in Solid Waste Ponds
by Andrei-Lucian Timiş, Ion Pencea, Adrian Priceputu, Constantin Ungureanu, Zbynek Karas, Florentina Niculescu, Ramona-Nicoleta Turcu, Gheorghe Iacob, Dragoș Florin Marcu and Alexandru Constantin Macovei
Appl. Sci. 2025, 15(8), 4246; https://doi.org/10.3390/app15084246 - 11 Apr 2025
Cited by 1 | Viewed by 696
Abstract
Solid waste treatment and resourceization critically depend on waste characterization. Heavy metals and critical raw materials are found as trace elements in solid waste dumps, and their reliable quantification plays a critical role for decision risk regarding effective waste management. The reliable quantification [...] Read more.
Solid waste treatment and resourceization critically depend on waste characterization. Heavy metals and critical raw materials are found as trace elements in solid waste dumps, and their reliable quantification plays a critical role for decision risk regarding effective waste management. The reliable quantification of trace elements is a very challenging issue. Hence, in this study, a new conservative approach for data analysis in screening for trace elements in waste dumps is presented. We propose a theoretical model for statistical data interpretation to overcome the drawbacks of conventional approaches based on unproven hypotheses, such as binomial, Poisson, or Gaussian distributions of the particles carrying the analyte. Our model addresses concentration values close to the limit of quantification (LOQ) of an analytical method. This model fills the gap of data analysis when a set of analytical results are uniformly distributed. Our approach deals with results reported as being lower than the LOQ. The model was applied on XRFS results from studies carried out on tailings to emphasize the differences among classic, robust, and conservative data analyses. Classical analyses overestimate the concentration values and underestimate the associated uncertainties increasing the decision risk. This study demonstrates that a conservative approach is mandatory when screening for trace elements if the concentration values are uniformly distributed. The proposed model can be applied to any solid waste dump, regardless of the analytical method used for trace element screening. Full article
(This article belongs to the Special Issue Advances in Solid Waste Treatment and Recycling)
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23 pages, 10335 KB  
Article
Multitemporal Spatial Analysis for Monitoring and Classification of Coal Mining and Reclamation Using Satellite Imagery
by Koni D. Prasetya and Fuan Tsai
Remote Sens. 2025, 17(6), 1090; https://doi.org/10.3390/rs17061090 - 20 Mar 2025
Cited by 3 | Viewed by 3307
Abstract
Observing coal mining and reclamation activities using remote sensing avoids the need for physical site visits, which is important for environmental and land management. This study utilizes deep learning techniques with a U-Net and ResNet architecture to analyze Sentinel imagery in order to [...] Read more.
Observing coal mining and reclamation activities using remote sensing avoids the need for physical site visits, which is important for environmental and land management. This study utilizes deep learning techniques with a U-Net and ResNet architecture to analyze Sentinel imagery in order to track changes in coal mining and reclamation over time in Tapin Regency, Kalimantan, Indonesia. After gathering Sentinel 1 and 2 satellite imagery of Kalimantan Island, manually label coal mining areas are used to train a deep learning model. These labelled areas included open cuts, tailings dams, waste rock dumps, and water ponds associated with coal mining. Applying the deep learning model to multitemporal Sentinel 1 and 2 imagery allowed us to track the annual changes in coal mining areas from 2016 to 2021, while identifying reclamation sites where former coal mines had been restored to non-coal-mining use. An accuracy assessment resulted in an overall accuracy of 97.4%, with a Kappa value of 0.91, through a confusion matrix analysis. The results indicate that the reclamation effort increased more than twice in 2020 compared with previous years’ reclamation. This phenomenon was mainly affected by the massive increase in coal mining areas by over 40% in 2019. The proposed method provides a practical solution for detecting and monitoring open-pit coal mines while leveraging freely available data for consistent long-term observation. The primary limitation of this approach lies in the use of medium-resolution satellite imagery, which may result in lower precision compared to direct field measurements; however, the ability to integrate historical data with consistent temporal coverage makes it a viable alternative for large-scale and long-term monitoring. Full article
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21 pages, 13959 KB  
Article
Utilisation of Zinc Processing Tailings (ZPTs) in Fired Clay Bricks Manufacturing: Case Study
by Ali Messai, Juan M. Menéndez-Aguado, Linda Berrekbia, Ikram Meramria, Begoña Fernández Pérez, Vladimir Nikolić, Milan Trumić and Amir Boustila
Minerals 2025, 15(3), 325; https://doi.org/10.3390/min15030325 - 20 Mar 2025
Cited by 1 | Viewed by 1341
Abstract
Zinc processing tailings (ZPTs) of the Kharzet Youcef processing complex, Setif, Algeria, are mainly stockpiled in tailing dumps without use, occupying significant surfaces and negatively influencing the human environment and health. Incorporating ZPTs into building materials manufacturing is an effective solution to meet [...] Read more.
Zinc processing tailings (ZPTs) of the Kharzet Youcef processing complex, Setif, Algeria, are mainly stockpiled in tailing dumps without use, occupying significant surfaces and negatively influencing the human environment and health. Incorporating ZPTs into building materials manufacturing is an effective solution to meet the dual objectives of environmental protection and economic development. This study investigates the influence of firing temperature and integrating ZPTs as a partial replacement for clay on the physic-mechanical properties of fired clay bricks (FCBs). Microstructural, chemical, and mineralogical analyses of ZPTs and clay were carried out by SEM-EDS, XRF, and XRD, respectively. Seven mixtures were produced with various percentages of ZPTs added to clay (0%, 5%, 10%, 15%, 20%, 25%, and 30%) and were fired at two different temperatures (900 and 1000 °C) at a ramp rate of 5 °C. Physic-mechanical tests were carried out on different brick specimens, and the results obtained showed that the FCBs incorporated with 10% of ZPTs produced the highest flexural strength of 6.24 MPa, compressive resistance of 29.78 MPa, bulk density of 1.37 g/cm3, and water absorption of 15.1% at 900 °C. Therefore, the recycling of ZPTs for FCBs manufacturing is feasible and an effective alternative waste disposal solution for sustainable development while reducing negative environmental impacts. Full article
(This article belongs to the Special Issue Mineral Processing and Recycling Technologies for Sustainable Future)
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29 pages, 13791 KB  
Article
Autogenously Calcined Clays from Coal Tailings Dumps as Supplementary Cementitious Material: From Exploratory Investigations to an Industrial Trial
by Steffen Overmann and Anya Vollpracht
Materials 2025, 18(5), 993; https://doi.org/10.3390/ma18050993 - 24 Feb 2025
Cited by 2 | Viewed by 985
Abstract
Autogenously calcined clays from tailings dumps, which are formed by the ignition of the contained residual coal, represent a huge resource of potentially pozzolanic material worldwide. This work presents preliminary studies of samples from the Western coal regions in Germany and investigations on [...] Read more.
Autogenously calcined clays from tailings dumps, which are formed by the ignition of the contained residual coal, represent a huge resource of potentially pozzolanic material worldwide. This work presents preliminary studies of samples from the Western coal regions in Germany and investigations on the first industrially produced cement with autogenously calcined tailings concerning its suitability as supplementary cementitious material (SCM). Samples of the tailings materials and blended cements were thoroughly characterized physically, chemically and mineralogically. The reactivity was studied using the R3 test and mortar compressive strength testing. The influence on cement hydration was studied using X-ray diffractometry (XRD) and isothermal calorimetry. The preliminary investigations showed that the material is basically suitable as SCM, as it consists mainly of SiO2 and Al2O3, which partially occurs in X-ray amorphous form and has a low content of impurities, which can impair cement properties such as carbon or sulfur. The R3 reactivity and the relative compressive strength differed significantly depending on the sample. For the industrial cement production trial, low-processed material was used which still contained inert fractions. The average sample showed a relatively low R3 reactivity but still significantly higher than mostly inert materials such as limestone or quartz powder. Calorimetry and XRD investigations on cement pastes showed that the clinker reactions remain basically unaffected by the tailings. Mortar tests showed that the material contributes to strength development at a late age. It can be concluded that the tailings are basically suitable as SCM and, in appropriate blends, the clinker factor and, thus, the CO2 footprint of cement can be reduced. Full article
(This article belongs to the Section Construction and Building Materials)
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20 pages, 4697 KB  
Article
Utilization of Copper Flotation Tailings in Geopolymer Materials Based on Zeolite and Fly Ash
by Marija Štulović, Dragana Radovanović, Jelena Dikić, Nataša Gajić, Jovana Djokić, Željko Kamberović and Sanja Jevtić
Materials 2024, 17(24), 6115; https://doi.org/10.3390/ma17246115 - 14 Dec 2024
Cited by 7 | Viewed by 2047
Abstract
Copper flotation tailings (FTs), resulting from the separation and beneficiation processes of ores, are a significant source of environmental pollution (acid mine drainage, toxic elements leaching, and dust generation). The most common disposal method for this industrial waste is dumping. However, due to [...] Read more.
Copper flotation tailings (FTs), resulting from the separation and beneficiation processes of ores, are a significant source of environmental pollution (acid mine drainage, toxic elements leaching, and dust generation). The most common disposal method for this industrial waste is dumping. However, due to their favorable physical and chemical properties—the high content of aluminosilicate minerals (60–90%)—flotation tailings can be effectively treated and reused through geopolymerization technology, thereby adding value to this waste. The objective of this study was to evaluate the potential of utilizing the geopolymerization of FTs to produce sustainable materials. Geopolymers based on natural zeolite (NZ), sodium-modified natural zeolite (NaZ), and fly ash (FA) were prepared using 20%, 35%, and 50% of FTs, activated with a 10 M NaOH solution. The study investigated the influence of Ca/Si, Si/Al, and Na/Al molar ratios on the structural, thermal, and mechanical properties (XRD, TG/DTG and unconfined compressive strength, UCS), and contaminant immobilization (TCLP method) of geopolymers. Geochemical modeling via the PHREEQC program was employed to interpret the results. The findings indicated that the UCS value decreased in zeolite-based geopolymers as the content of FT increased due to the inertness of the tailings and the low calcium content in the system (Ca/Si ≤ 0.3), in contrast to the FA-based geopolymer. The highest UCS of 44.3 MPa was recorded in an FA-based geopolymer containing 50% flotation tailings, with optimal molar ratios of 0.4 for Ca/Si, 3.0 for Si/Al, and 1.1 for Na/Al. In conclusion, the geopolymerization process has been determined to be a suitable technological approach for the sustainable treatment and reuse of FTs. Full article
(This article belongs to the Section Polymeric Materials)
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9 pages, 1802 KB  
Communication
The Past Is Never Dead: Soil Pollution from Mining in the Copiapó River Basin (Northern Chile)
by Luna Araceli Pérez, Tatiana Izquierdo, Manuel Abad, Manuel Caraballo, Sebastián Ureta and Francisco Ruiz
Soil Syst. 2024, 8(4), 106; https://doi.org/10.3390/soilsystems8040106 - 11 Oct 2024
Cited by 1 | Viewed by 2579
Abstract
This short paper analyses the concentrations of two major components (Fe, S) and eight trace elements (As, Au, Co, Cu, Hg, Ni, Mn, Zn) in soils and tailings from Tierra Amarilla (northern Chile) using ICP-Ms analysis. The levels of As, Au, Cu, Fe [...] Read more.
This short paper analyses the concentrations of two major components (Fe, S) and eight trace elements (As, Au, Co, Cu, Hg, Ni, Mn, Zn) in soils and tailings from Tierra Amarilla (northern Chile) using ICP-Ms analysis. The levels of As, Au, Cu, Fe and S are very high and come from polymetallic sulphides from nearby mines, together with minor contributions of Co, Ni and Mn. Hg has its origin in the extreme seasonal flows of the Copiapó River, which erodes the dumps of old precious metal mines. These high concentrations require further analysis of possible metal immobilisation techniques, bioavailability or analysis in cultivated plants. Full article
(This article belongs to the Special Issue Research on Heavy Metals in Soils and Sediments)
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17 pages, 2611 KB  
Article
Mineralogical Insights into PGM Recovery from Middle Group (1–4) Chromite Tailings
by Nomsa Precilla Baloyi, Willie Nheta, Vusumuzi Sibanda and Mehdi Safari
Minerals 2024, 14(9), 924; https://doi.org/10.3390/min14090924 - 10 Sep 2024
Cited by 4 | Viewed by 3716
Abstract
Variations in the recovery of platinum group metals (PGMs) are often attributed to mineralogical and other natural ore-type variations. To increase the recovery of PGMs by the flotation process, a comprehensive understanding of gangue and valuable minerals is essential for optimising the extraction [...] Read more.
Variations in the recovery of platinum group metals (PGMs) are often attributed to mineralogical and other natural ore-type variations. To increase the recovery of PGMs by the flotation process, a comprehensive understanding of gangue and valuable minerals is essential for optimising the extraction and processing of metals. Recoveries may be improved if the questions of how, where, and why losses occur can be answered with a certain degree of confidence. A requirement is the availability of statistically reliable mineralogical data. The PGMs of MG-1–4 chromite tailings dumps of the western limb of the Bushveld complex (BC) were studied in detail to unravel the PGMs and the nature of the platinum group minerals in the sample. Characterisation of the chromite tailings via deportment analysis revealed that the sample contained a significant amount of 3E PGM + Au (Pt, Pd, Ru, and Au) and was concentrated in the -25 µm fraction. The results of automated mineralogical analysis showed that the sample was composed of the PGE-sulphides group, comprising 63.6 vol%, PGE-sulfarsenides 10.4 vol%, PGE-arsenides 1.3 vol%, PGE-bismuth tellurides 3.3 vol%, PGMs-alloy 4.1 vol%, and Laurite comprising 17.3 vol% of the total PGE population. The sample was composed of 66.5 vol% of liberated PGMs, 0.2 vol% attached to liberated BMS, 27.3 vol% of PGMs attached to or locked within silicate or oxide gangue composite particles, 0.2 vol% of PGMs associated with BMS attached to silicate or oxide gangue particles, and a low proportion (5.8 vol%) of PGMs reported being locked within gangue or oxide particles. The majority of PGM grains observed were reported in the fast-floating category (64.4 vol%), 27.6 vol% in the slow-floating 1 category, 2.2 vol% in the slow-floating 2 category, and 5.8 vol% to the non-floating category. The results of the study revealed that the PGMs of MG 1–4 chromite tailings were liberated; however, the low liberation index (<0.2) suggested that a significant portion of PGMs remained trapped within gangue, hindering their recovery. This highlights the need for effective comminution (crushing and grinding) to achieve better liberation. The sample contained fine particles that were more prone to being lost in the tailings and to lowering recovery due to the slimes coating valuable minerals. The recovery of the PGMs from this complex’s polymetallic bodies of low-grade and complex mineralogy will be insufficient with traditional methods and thus innovation is needed. Innovation like advanced comminution, novel flotation equipment or reagents, selective leaching and bioprocessing can overcome these challenges. Full article
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24 pages, 4316 KB  
Article
Profile of Bacterial Communities in Copper Mine Tailings Revealed through High-Throughput Sequencing
by Joseline Jiménez-Venegas, Leonardo Zamora-Leiva, Luciano Univaso, Jorge Soto, Yasna Tapia and Manuel Paneque
Microorganisms 2024, 12(9), 1820; https://doi.org/10.3390/microorganisms12091820 - 3 Sep 2024
Cited by 2 | Viewed by 4014
Abstract
Mine-tailing dumps are one of the leading sources of environmental degradation, often with public health and ecological consequences. Due to the complex ecosystems generated, they are ideal sites for exploring the bacterial diversity of specially adapted microorganisms. We investigated the concentrations of trace [...] Read more.
Mine-tailing dumps are one of the leading sources of environmental degradation, often with public health and ecological consequences. Due to the complex ecosystems generated, they are ideal sites for exploring the bacterial diversity of specially adapted microorganisms. We investigated the concentrations of trace metals in solid copper (Cu) mine tailings from the Ovejería Tailings Dam of the National Copper Corporation of Chile and used high-throughput sequencing techniques to determine the microbial community diversity of the tailings using 16S rRNA gene-based amplicon sequence analysis. The concentrations of the detected metals were highest in the following order: iron (Fe) > Cu > manganese (Mn) > molybdenum (Mo) > lead (Pb) > chromium (Cr) > cadmium (Cd). Furthermore, 16S rRNA gene-based sequence analysis identified 12 phyla, 18 classes, 43 orders, 82 families, and 154 genera at the three sampling points. The phylum Proteobacteria was the most dominant, followed by Chlamydiota, Bacteroidetes, Actinobacteria, and Firmicutes. Genera, such as Bradyrhizobium, Aquabacterium, Paracoccus, Caulobacter, Azospira, and Neochlamydia, showed high relative abundance. These genera are known to possess adaptation mechanisms in high concentrations of metals, such as Cd, Cu, and Pb, along with nitrogen-fixation capacity. In addition to their tolerance to various metals, some of these genera may represent pathogens of amoeba or humans, which contributes to the complexity and resilience of bacterial communities in the studied Cu mining tailings. This study highlights the unique microbial diversity in the Ovejería Tailings Dam, including the discovery of the genus Neochlamydia, reported for the first time for heavy metal resistance. This underscores the importance of characterizing mining sites, particularly in Chile, to uncover novel bacterial mechanisms for potential biotechnological applications. Full article
(This article belongs to the Special Issue Advances in Soil Microbial Ecology)
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21 pages, 9141 KB  
Article
Heavy Metal Groundwater Transport Mitigation from an Ore Enrichment Plant Tailing at Kazakhstan’s Balkhash Lake
by Dauren Muratkhanov, Vladimir Mirlas, Yaakov Anker, Oxana Miroshnichenko, Vladimir Smolyar, Timur Rakhimov, Yevgeniy Sotnikov and Valentina Rakhimova
Sustainability 2024, 16(16), 6816; https://doi.org/10.3390/su16166816 - 8 Aug 2024
Cited by 5 | Viewed by 3867
Abstract
Sustainable potable groundwater supply is crucial for human development and the preservation of natural habitats. The largest endorheic inland lake in Kazakhstan, Balkhash Lake, is the main water resource for the arid southeastern part of the country. Several ore enrichment plants that are [...] Read more.
Sustainable potable groundwater supply is crucial for human development and the preservation of natural habitats. The largest endorheic inland lake in Kazakhstan, Balkhash Lake, is the main water resource for the arid southeastern part of the country. Several ore enrichment plants that are located along its shore have heavy metal pollution potential. The study area is located around a plant that has an evident anthropogenic impact on the Balkhash Lake aquatic ecological system, with ten known heavy metal toxic hotspots endangering fragile habitats, including some indigenous human communities. This study assessed the risk of heavy metal contamination from tailing dump operations, storage ponds, and related facilities and suggested management practices for preventing this risk. The coastal zone risk assessment analysis used an innovative integrated groundwater numerical flow and transport model that predicted the spread of groundwater contamination from tailing dump operations under several mitigation strategies. Heavy metal pollution prevention models included a no-action scenario, a filtration barrier construction scenario, and two scenarios involving the drilling of drainage wells between the pollution sources and the lake. The scenario assessment indicates that drilling ten drainage wells down to the bedrock between the existing drainage channel and the lake is the optimal engineering solution for confining pollution. Under these conditions, pollution from tailings will not reach Lake Balkhash during the forecast period. The methods and tools used in this study to enable mining activity without environmental implications for the region can be applied to sites with similar anthropogenic influences worldwide. Full article
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