Search Results (22)

Under the influence of the sedimentation process, the phenomenon of intraformational non-homogeneity is widely observed in low-permeability reservoirs. In the development process of water and gas replacement (WAG), the transport law of water and gas and the distribution of residual oil are seriously affected by the non-homogeneity of reservoir properties. In this paper, a study on two types of reservoirs with certain lengths and thicknesses is carried out, and a reasonable development method is proposed according to the characteristics of each reservoir. Firstly, through indoor physical simulation experiments combined with low-field nuclear magnetic resonance scanning (NMR), this study investigates the influence of injection rate and core length on the double-layer low-permeability inhomogeneous core replacement and pore throat mobilization characteristics. Then, a two-layer inhomogeneous low-permeability microscopic model is designed to investigate the model’s replacement and pore throat mobilization characteristics under the combined influence of rhythmites, gravity, the injection rate, etc. Finally, based on the results of the core replacement and numerical simulation, a more reasonable development method is proposed for each type of reservoir. The results show that for inhomogeneous cores of a certain length, the WAG process can significantly increase the injection pressure and effectively seal the high-permeability layer through the Jamin effect to improve the degree of recovery. Moreover, for positive and reverse rhythm reservoirs of a certain thickness, the injection rate can be reduced according to the physical properties of the reservoir, and the gravity overburden phenomenon of the gas is used to achieve the effective development of the upper layers. The effect of the development of a positive rhythm reservoir therefore improved significantly. These findings provide data support for improving the development effectiveness of CO₂ in low-permeability inhomogeneous reservoirs and emphasize the importance of the influence of multiple factors, such as injection flow rate, gravity, and rhythm, in CO₂ replacement. Full article

Capturing and storing CO₂ (CCS) was once regarded as a significant, urgent, and necessary option for reducing the emissions of CO₂ from coal and oil and gas industries and mitigating the serious impacts of CO₂ on the atmosphere and the environment. This recognition came about as a result of extensive research conducted in the past. The CCS cycle comes to a close with the last phase of CO₂ storage, which is accomplished primarily by the adsorption of CO₂ in the ocean and injection of CO₂ subsurface reservoir formation, in addition to the formation of limestone via the process of CO₂ reactivity with reservoir formation minerals through injectivities. CCS is the last stage in the carbon capture and storage (CCS) cycle and is accomplished chiefly via oceanic and subterranean geological sequestration, as well as mineral carbonation. The injection of supercritical CO₂ into geological formations disrupts the sub-surface’s existing physical and chemical conditions; changes can occur in the pore fluid pressure, temperature state, chemical reactivity, and stress distribution of the reservoir rock. This paper aims at advancing our current knowledge in CO₂ injection and storage systems, particularly CO₂ storage methods and the challenges encountered during the implementation of each method and analyses on how key uncertainties in CCS can be reduced. CCS sites are essentially unified systems; yet, given the scientific context, these storage systems are typically split during scientific investigations based on the physics and spatial scales involved. Separating the physics by using the chosen system as a boundary condition is a strategy that works effectively for a wide variety of physical applications. Unfortunately, the separation technique does not accurately capture the behaviour of the larger important system in the case of water and gas flow in porous media. This is due to the complexity of geological subsurface systems, which prevents the approach from being able to effectively capture the behaviour of the larger relevant system. This consequently gives rise to different CCS technology with different applications, costs and social and environmental impacts. The findings of this study can help improve the ability to select a suitable CCS application method and can further improve the efficiency of greenhouse gas emissions and their environmental impact, promoting the process sustainability and helping to tackle some of the most important issues that human being is currently accounting global climate change. Though this technology has already had large-scale development for the last decade, some issues and uncertainties are identified. Special attention was focused on the basic findings achieved in CO₂ storage operational projects to date. The study has demonstrated that though a number of CCS technologies have been researched and implemented to date, choosing a suitable and acceptable CCS technology is still daunting in terms of its technological application, cost effectiveness and socio-environmental acceptance. Full article

The Brayton cycle system, as a closed cycle working under high-temperature, high-pressure and high-speed conditions, presents significant prospects in many fields. However, the flow behavior and energy efficiency of supercritical CO₂ is severely influenced by the structures of face seals and the sealing temperature, especially when the sealing gas experiment is the supercritical transformation process. Therefore, a numerical model was established to investigate the high-temperature flow behavior and energy consumption of face seals with different surface grooves. The effects of the operation parameters and groove structure on the temperature distribution and sealing performance are further studied. The obtained results show that the supercritical effect of the gas film has a more obvious influence on the flow velocity u_θ than u_r. Moreover, it can be found that the temperature distribution, heat dissipation and leakage rate of the gas face seals present a dramatic change when the working condition exceeds the supercritical point. For the spiral groove, the change rate of heat dissipation becomes larger, from 3.6% to 8.1%, with the increase in sealing pressure from 15 to 50 MPa, when the temperature grows from 300 to 320 K. Meanwhile, the open force maintains a stable state with the increasing temperature and pressure even at the supercritical point. The proposed model could provide a theoretical basis for seal design with different grooves on the supercritical change range in the future. Full article

At an extremely high Mach number, the regenerative cooling of traditional kerosene cannot meet the requirement of the heat sink caused by aerodynamic heating and internal combustion in a scramjet propulsion system. As a supplement of traditional regenerative cooling, supercritical CO₂ is regarded as an effective coolant in severe heating environments due to its excellent properties of heat and mass transportation. In this paper, the heat transfer and flow structure characteristics of regenerative cooling in a rectangular channel using supercritical CO₂ are analyzed numerically using a validated model. The effect of heat flux magnitude, nonuniform heat flux, acceleration and buoyancy and flow pattern are considered to reveal the regenerative cooling mechanism of supercritical CO₂ in the engine condition of a scramjet. The results indicate that the heat transfer deterioration phenomenon becomes obvious in the cooling channel loaded with relatively high heat flux. Compared with the cooling channels loaded with increased heat flux distribution, the maximum temperature increased for the channel loaded with decreased heat flux distributions. When larger acceleration is applied, a relatively lower wall temperature distribution and higher heat transfer coefficients are obtained. The wall temperature distribution becomes more uniform and the high-temperature region is weakened when the coolants in adjacent channels are arranged as a reversed flow pattern. Overall, the paper provides some references for the utilization of supercritical CO₂ in regenerative cooling at an extremely high Mach number in a scramjet. Full article

Experimental studies have confirmed the permeability reduction of coal samples upon the adsorption of CO₂. However, these studies were carried out under limited experimental conditions. In this study, CO₂ flow behaviors in a macro-scale coal sample were numerically simulated using a coupled gas flow, mechanical deformation, and sorption-induced deformation finite element model. The simulation results show that the effect of the reduction of effective stress on the enhancement of permeability is greater than the negative effect of permeability reduction due to CO₂ adsorption for low injection pressures. CO₂ pressure development in the sample increases with increasing injection pressure due to the enhanced advection flux for sub-critical CO₂ injections, while for super-critical CO₂ injections, CO₂ pressure development, as well as concentrations in the sample, decreases compared to sub-critical CO₂ injections because of greater density and viscosity of super-critical CO₂ as well as coal matrix swelling induced by the adsorption of super-critical CO₂. Increasing axial stress (buried depth) obstructs CO₂ migration in the sample due to the increased effective stress, and this effect is more influential for low injection pressures, which indicates that high CO₂ injection pressures are preferred for CO₂ sequestration in deep coal seams. Full article

This paper describes the findings of detailed simulations performed to investigate the impact of seal teeth cavity leakage flow on the aerodynamic and thermal performance of a three-stage supercritical CO${}_2$ axial compressor. The study compares a shrouded stator configuration (with cavities) to a cantilevered stator configuration (without cavities) to highlight their differences. High-fidelity computational fluid dynamics simulations were performed using non-linear harmonic (NLH) and mixing plane assumptions, considering various possible rotor/stator interface configurations for mixing plane calculations. The key performance parameters for each case were compared, and the best-performing configuration selected for further analysis. The individual stage performance parameters are also examined and compared between the cantilevered and shrouded configurations. It was observed that in the shrouded case, the leakage flow enters the cavity downstream of the stator trailing edge and gets entrained into the primary flow upstream of the stator, leading to boundary layer changes at the hub and degradation of stator and downstream rotor performance. Vortical flow structures were also observed in the stator wells, which tended to change the flow angles around the region, thereby affecting mixing and velocity distribution, resulting in a slight deterioration of compressor performance. Additionally, the study examines windage heating due to shear work from rotating walls, including the seal teeth surface. The amount of shear work done on the leakage flow and the corresponding rise in fluid temperature were quantified, tabulated, and further compared with a simple analytical model, showing good agreement between them and, hence, validating the numerical approach used. Full article

Mixing under high pressure conditions plays a central role in several engineering applications, such as direct-injection engines and liquid rocket engines. Numerical flow simulations have become a complementary tool to study the mixing process under these conditions but require complex thermodynamic modeling as well as validation with accurate experimental data. For this reason, we use experiments of supercritical single-phase jet mixing from the literature, where the mixing is quantified by the mixture speed of sound, as a reference for our work. We here focus on the thermodynamic modeling of multi-component flows under high pressure conditions and the analytical calculation of the mixture speed of sound. Our thermodynamic model is based on cubic equations of state extended for multi-components. Using an extension of OpenFOAM, we perform large-eddy simulations of hexane and pentane injections and compare our results with the experimentally measured mixture speed of sound at specific positions. The simulation results show the same characteristic trends, indicating that the mixing effects are well reproduced in the simulations. Additionally, the effect of the sub-grid scale modeling is assessed by comparing results using different models (Smagorinsky, Vreman, and Wall-Adapting Local Eddy-viscosity). The comprehensive simulation data presented here, in combination with the experimental data, provide a benchmark for numerical simulations of jet mixing in high pressure conditions. Full article

Saudi Arabia is one of the major producers of date (Phoenix dactylifera) fruit. Date fruit flesh is considered a healthy food due to the presence of natural antioxidants. Green and innovative supercritical fluid (SFE, 52.5 °C temperature, 27.50 MPa pressure, 5 mL CO₂/min flow rate) and subcritical (SubCO₂, 250 extraction cycles, 29 °C temperature, 6.8 MPa, 12 h, ethanol solvent) extraction techniques were used to produce flesh extracts from four Saudi date fruits (Sukari (SKFE), Ambara (AMFE), Majdool (MJFE) and Sagai (SGFE)), and extracts prepared using 6 h Soxhlet extraction at 70 °C for 16 h using n-hexane as solvent, were taken as control. SFE produced the highest (p < 0.05) extract yields, whereas the SubCO₂ method recovered significantly higher (p < 0.05) amounts of phytochemicals. Total phenolics (186.37–447.31 mg GAE/100 g), total flavonoids (82.12–215.28 mg QE/100 g), total anthocyanins (0.41–1.34 mg/100 g), and total carotenoid (1.24–2.85 mg BCE/100 g) were quantified in all the flesh extracts. The biological properties evaluation showed that flesh extracts had high antioxidant (17.79–45.08 µg AAE/mL), antiradical (191.36–34.66 µg/mL DPPH IC₅₀), ferric-reducing (2.18–5.01 mmol TE/100 g) and ABTS-scavenging (444.75–883.96 µmol TE/100 g) activities. SubCO₂ was the best technique and Majdool the best date variety, in terms of both phytochemicals and biological properties. Full article

The flow distribution in a printed circuit heat exchanger (PCHE) is of great theoretical and practical significance in the Brayton cycle power generation system. For the straight barrel inlet header PCHE, when S-CO₂ flows in the PCHE, the structural types and working parameters of the inlet header and diversion zone may lead to differences in the flow distribution in each channel of the PCHE. This flow distribution difference affects the thermal hydraulic characteristics of the PCHE. A numerical simulation method was applied to explore the flow uniformity of the PCHE and the overall performance and analyze the influence of the type of straight barrel inlet header PCHE. Within each layer, the flow showed an uneven flow distribution, and the optimized inlet header was the tapered type. The results showed that when the taper angle varies from 6° to 9°, the flow distribution in each layer is relatively uniform. The comprehensive heat transfer performance of the straight-channel PCHE can be improved by 17.3–19.7%. Finally, the response surface and a genetic algorithm were combined to optimize the inlet header. The heat transfer performance of the optimized PCHE was improved by 19.7%. Full article

This paper analyses the stability of thin power-law fluid flowing down a moving plane in a vertical direction by using the long-wave perturbation method. Linear and nonlinear stability are discussed. The linear stable region increases as the downward speed increases and the power-law index increases. More accurate results are obtained on the coefficients of the nonlinear generalized kinematic equation in the power-law part. The regions of sub-critical instability and absolute stability are expanded when the downward movement of plane increases, or the power-law index increases, and meanwhile the parts of supercritical stability and explosive supercritical instability are compressed. By substituting the power-law index and moving speed into the generalized nonlinear kinematic equation of the power-law film on the free surface, the results can be applied to estimate the stability of the thin film flow in the field of engineering. Full article

A transient model to simulate the temperature and pressure in CO₂ injection wells is proposed and solved using the finite difference method. The model couples the variability of CO₂ properties and conservation laws. The maximum error between the simulated and measured results is 5.04%. The case study shows that the phase state is primarily controlled by the wellbore temperature. Increasing the injection temperature or decreasing the injection rate contributes to obtaining the supercritical state. The variability of density can be ignored when the injection rate is low, but for a high injection rate, ignoring this may cause considerable errors in pressure profiles. Full article

The flow topology of the wake behind a circular cylinder at the super-critical Reynolds number of $Re=7.2\times {10}^5$ is investigated by means of large eddy simulations. In spite of the many research works on circular cylinders, there are no studies concerning the main characteristics and topology of the near wake in the super-critical regime. Thus, the present work attempts to fill the gap in the literature and contribute to the analysis of both the unsteady wake and the turbulent statistics of the flow. It is found that although the wake is symmetric and preserves similar traits to those observed in the sub-critical regime, such as the typical two-lobed configuration in the vortex formation zone, important differences are also observed. Owing to the delayed separation of the flow and the transition to turbulence in the attached boundary layer, Reynolds stresses peak in the detached shear layers close to the separation point. The unsteady mean flow is also investigated, and topological critical points are identified in the vortex formation zone and the near wake. Finally, time-frequency analysis is performed by means of wavelets. The study shows that in addition to the vortex shedding frequency, the inception of instabilities that trigger transition to turbulence occurs intermittently in the attached boundary layer and is registered as a phenomenon of variable intensity in time. Full article

Bubble growth in the polymer extrusion foaming process occurs under a dynamic melt flow. For non-Newtonian fluids, this work successfully coupled the dynamic melt flow simulation with the bubble growth model to realize bubble growth predictions in an extrusion flow. The initial thermophysical properties and dynamic rheological property distribution at the cross section of the die exit were calculated based on the finite element method. It was found that dynamic rheological properties provided a necessary solution for predicting bubble growth during the supercritical CO₂ polyethylene terephthalate (PET) extrusion foaming process. The introduction of initial melt stress could effectively inhibit the rapid growth of bubbles and reduce the stable size of bubbles. However, the initial melt stress was ignored in previous work involving bubble growth predictions because it was not available. The simulation results based on the above theoretical model were consistent with the evolution trends of cell morphology and agreed well with the actual experimental results. Full article

Shear deformation of a solid-fluid, two-phase material induces a fluid segregation process that produces fluid-enriched bands and fluid-depleted regions, and a crystallographic preferred orientation (CPO) characterized by girdles of [100] and [001] axes sub-parallel to the shear plane and a cluster of [010] axes sub-normal to the shear plane, namely the AG-type fabric. Based on experiments of two-phase aggregates of olivine + basalt, a two-phase flow theory and a CPO formation model were established to explain these microstructures. Here, we investigate the microstructure in a two-phase aggregate with supercritical CO₂ as the fluid phase and examine the theory and model, to evaluate differences in rheological properties due to the presence of CO₂ or basaltic melt. We conducted high-temperature and high-pressure shear deformed experiments at 1 GPa and 1100 °C in a Griggs-type apparatus on samples made of olivine + dolomite, which decomposed into carbonate melt and CO₂ at experimental conditions. After deformation, CO₂ segregation and an AG-type fabric were observed in these CO₂-bearing samples, similar to basaltic melt-bearing samples. An SPO-induce CPO model was used to explain to the formation of the fabric. Our results suggest that the influences of CO₂ as a fluid phase on the microstructure of a two-phase olivine aggregate is similar to that of basaltic melt and can be explained by the CPO formation model for the solid-fluid system. Full article

The effects of gravity on the heat transfer performance of supercritical CO₂ flowing within a vertical tube with a diameter of 4.75 mm are numerically studied in this paper. The main objectives are to comprehensively investigate the action of gravity and buoyancy on the supercritical heat transfer. An effective numerical method, which employs a modified Shear Stress Transfer k-ω model (SST k-ω), is applied at various gravity conditions. It is found that, for both upward and downward flows, the heat transfer of supercritical CO₂ is improved with increased gravity magnitude. The effect of gravity on heat transfer are more pronounced under a low mass flux condition than that under a high mass flux condition and it is closely related to the variations of thermal properties. For the upward flow, the increased gravity magnitude accelerates the near wall fluid and creates a classic “M-shaped” radial velocity distribution. For the downward flow, the increased gravity magnitude decelerates the near wall fluid and creates a parabola-like radial velocity distribution. On one hand, the turbulent kinetic energies of both the upward and downward flows are enhanced as the gravity magnitude increases, which benefits heat transfer dominated by turbulent eddy diffusion. On the other hand, high-density fluid with high thermal conductivity occupies the near wall region as the gravity magnitude increases, which benefits heat transfer dominated by molecular diffusion. The results might provide some instructive advice to improve the design and operation safety of heat exchanger at various gravity conditions. Full article