Search Results (998)

This article presents a diagnostic study on the characterization of community and walkable rooftops in Barcelona’s historic district. The study aims to evaluate the potential for efficient improvement solutions that align with contemporary regulations for safety, accessibility, and energy efficiency. It is part of the REVTER project, which seeks to recover flat roofs as non-public collective areas in densely populated environments. The research emphasizes the importance of understanding the technical aspects of these rooftops before interventions, focusing on construction and performance to establish guidelines for future improvements. The methodology includes cartographies, on-site inspections, and performance evaluations, aiming to create a district-level overview, characterize roofing solutions chronologically, assess current technical performance, and identify deficiencies to develop intervention guidelines. Key findings highlight the evolution of construction practices across three distinct periods, revealing significant shifts in materials and techniques. The research underscores the necessity of data-driven technical characterization and proposes a systematic approach for evaluating historic architectural spaces. By selecting a broad study sample and using a GIS approach, the study sets a precedent for understanding and improving the technical characteristics of urban rooftops, contributing significantly to sustainable urban development and heritage conservation within Ciutat Vella. Full article

Procyanidins, a class of substances widely distributed in nature, have attracted the attention of the scientific community due to their bioactive properties, especially with regard to human health. This review is based on an extensive examination of peer-reviewed literature, patents, and clinical trial reports published between 2005 and 2025. From an initial pool of more than 300 documents, 283 studies were selected according to criteria of scientific rigor, methodological clarity, and relevance to the research objectives. A literature search was performed using PubMed, PubChem, Google Scholar, Scopus and ResearchGate employing keywords such as Procyanidins, chemical structure, extraction, and health effects. This article provides a comprehensive overview of current methods for obtaining these compounds, which include both natural sources and synthetic approaches. It provides a concise summary of the molecular structure of procyanidins and emphasizes the importance of understanding their conformational features for predicting biological activity. The challenges of establishing correlations between the structural features of procyanidins and their properties are described. In addition, this article explores the many potential applications of these compounds, spanning both biochemistry and the field of design and synthesis of novel materials. This review provides a comprehensive evaluation of Procyanidins, focusing on their geometrical conformation analysis through advanced NMR spectroscopy techniques including homonuclear correlation (COSY, TOCSY), heteronuclear one-bond (HSQC, HMQC), multiple-bond (HMBC) experiments, and through-space correlation (NOESY) in conjunction with various extraction methodologies. Full article

Objectives: This study evaluated the effect of three root canal filling material (RCFM) removal techniques—mechanical, thermo-mechanical, and chemico-mechanical—on the micro push-out bond strength of fiber posts to root dentin in endodontically treated teeth. Materials and Methods: Forty-five single-rooted human premolars were endodontically treated and randomly allocated into three groups (n = 15) according to the RCFM removal technique used during post-space preparation: mechanical, thermo-mechanical, or chemico-mechanical. Fiber posts were luted using a dual-cure resin cement. Roots were embedded in resin and sectioned into coronal, middle, and apical thirds. Micro push-out bond strength was measured using a universal testing machine. Failure modes were examined under a stereomicroscope and validated using scanning electron microscopy. Statistical analysis used two-way ANOVA and Chi-square tests (α = 0.05). Results: Both the thermo-mechanical and mechanical groups showed significantly higher bond strength values than the chemico-mechanical group (p < 0.001). Across all groups, the coronal third recorded the highest bond strength, while the apical third presented the lowest values (p < 0.001). Adhesive failure at the dentin–cement interface was the most frequent failure mode. Conclusions: The gutta-percha removal technique and the root canal region significantly influence fiber-post bond strength. Solvent-based chemico-mechanical methods may adversely affect adhesion quality. Clinical Relevance: Thermo-mechanical and mechanical removal techniques may provide more reliable post retention during retreatment procedures, improving adhesion and reducing the risk of post debonding in daily practice. Full article

Mechanical and thermoelectric performance of a SiGe thermoelectric module were investigated through finite element analysis. N-type and P-type SiGe thermoelectric materials were synthesized, and their mechanical and thermoelectric properties were experimentally measured. Thermal stress distributions within the SiGe module and the integrated “heat collector–module–heat sink” assembly are simulated, and the results were compared with the measured mechanical strength of the SiGe materials. The simulations show that among the three electrode structures evaluated—C/W/C sandwich, 0.5 mm W/C, and 0.1 mm W/C—the C/W/C sandwich configuration yields the lowest thermal stress. An inter-leg spacing of 0.5 mm also leads to reduced stress compared to a 0.1 mm gap. However, fully constraining the cold end or directly integrating the module with heat collection and dissipation components significantly increases thermal stress. The use of copper cooling plates induces higher stress than C-C plates, exceeding the tolerable strength of the materials. Simulation of a module with 28 SiGe legs (each 10 mm × 10 mm × 1.5 mm) predicts an output power of 7.42 W and a conversion efficiency of 7.11% at a hot-side temperature of 967 °C and a cold-side temperature of 412 °C. Full article

CubeSats are a fundamental tool of space exploration, allowing for the testing of novel ideas that can be upscaled to more efficient satellite systems. This work presents the development and characterisation of an additively manufactured aluminium mechanism designed to enable the self-functionalisation of CubeSat structures through material extrusion metal additive manufacturing, as a foundation for sensor integration. A space-grade AlSi7Mg alloy was selected and prepared as a filament to print a fully functional hinge geometry, aiming to evaluate the feasibility of producing movable metallic components using a low-cost and sustainable extrusion-based process. Produced parts were subjected to debinding and vacuum sintering, achieving a densification above 85% and an average hardness of 52.2 HV. Further characterisation, including micro-computed tomography, X-ray diffraction and dynamic mechanical analysis, was used to assess the microstructural integrity, present phase, and mechanical behaviour of the sintered components. The designed shrinkage-compensated hinge mechanism preserved its rotational mobility after sintering, validating the mechanical inter-locking strategy and the design for additive manufacturing methodology used. The results demonstrate that material extrusion enables the fabrication of lightweight, functional, and integrated aluminium mechanisms suitable for sensor incorporation and actuation in small satellite systems. This proof-of-concept highlights material extrusion as a sustainable and economically viable route for developing intelligent aero-space structures, paving the way for future adaptive and sensor-integrated CubeSat subsystems. Full article

The successful deployment of 3D printing in outdoor applications is contingent upon the selection of materials capable of withstanding the degrading effects of weather. This study evaluates the colorimetric performance of various 3D-printed polymers exposed to natural weathering conditions in Brasov, Romania, from November 2024 to March 2025. Color changes were monitored through spectrophotometry using a PCE-XXM 20 color meter, and data were recorded in the LAB color space. The results indicate substantial differences in color stability among the tested materials, with some exhibiting unacceptable levels of fading and discoloration. These findings have significant implications for the design and implementation of outdoor 3D-printed products in climates analogous to that of Brasov, underscoring the importance of selecting materials with demonstrated resistance to weathering and color change. Full article

Background/Objectives: This study aimed to perform a comparative analysis of the original Viagra^® product and sildenafil-containing tablets obtained from illegal sources (the darknet). Specifically, the analyzed material consisted of samples seized by Polish law enforcement authorities from unverified vendors operating within the Central European darknet market. The study utilized thermal methods, specifically Thermogravimetry (TG), Derivative Thermogravimetry (DTG), and calculated Differential Thermal Analysis (c-DTA), as well as colorimetric analysis based on the International Commission on Illumination (CIE) L*a*b* system. Methods: Thermal analyses enabled the assessment of the thermal stability of the tested samples, identification of characteristic stages of thermal decomposition, and determination of differences in thermal behavior between the pure substance, the original preparation, and darknet samples. In turn, color measurements in the CIE L*a*b* space allowed for an objective comparison of tablet appearance and determination of the degree of color similarity to the original product. Results: The obtained results showed that only a few samples (V1, V3, V4, V6, V8) exhibited features similar to the original Viagra^®, both in terms of thermal profile and color. Most of the tested tablets were characterized by significant variability in physicochemical properties, indicating a lack of quality control and inconsistency in formulation. Samples V2 and V7 deviated particularly strongly—both thermally and visually—suggesting that they might not contain the original active substance or contained it in a different chemical form. Conclusions: The use of combined thermal and colorimetric methods proved to be an effective tool in the identification of counterfeit pharmaceutical products, enabling simultaneous evaluation of their composition and authenticity. The results confirm the validity of employing integrated physicochemical analyses for the detection of falsified medicines present on the illegal market. Full article

Cerium (Ce³⁺)-doped gadolinium orthoborate (GdBO₃) phosphor powders were synthesized via an aqueous sol–gel route, with systematic variation in solution pH (2, 5, and 8) and annealing temperature (600–1200 °C, in 100 °C increments) to investigate their influence on structural, optical, and scintillation properties. The materials were comprehensively characterized using thermogravimetric and differential thermal analysis (TG–DTA) to assess thermal behavior, X-ray diffraction (XRD) for crystal structure determination, Fourier-transform infrared spectroscopy (FTIR) for vibrational analysis, and both photoluminescence (PL) and radioluminescence (RL) spectroscopies to evaluate optical and scintillation performance. All samples crystallized in the hexagonal GdBO₃ vaterite phase (space group P6₃/mcm). The PL and RL emission spectra were consistent with the Ce³⁺ 5d–4f transitions, and scintillation yields under X-ray excitation were quantified relative to a standard Gadox phosphor. A decrease in photoluminescence quantum yield (PLQY) was observed at annealing temperatures above 800 °C, which is attributed to the incorporation of Ce³⁺ into the host lattice. Scintillation decay profiles were recorded, enabling extraction of timing kinetics parameters. Overall, the results reveal clear correlations between synthesis conditions, structural evolution, and luminescence behavior, providing a rational basis for the optimization of Ce³⁺-doped GdBO₃ phosphors for scintillation applications. Full article

Research on barn technology, technical equipment, and related cattle welfare indicates a growing emphasis on assessing sources of animal comfort as the subject of scientific research. In practice, dairy cattle housing conditions are also assessed directly by farmers responsible for the animals’ living conditions in barns; therefore, it is worthwhile to ask farmers about their approaches to improving the housing and comfort of dairy cattle in barns. The aim of this study was to evaluate non-standard technical solutions implemented by farmers in tie-stall and loose-housing barns; the research study design included visits to and observations at 40 dairy farms, selected purposively based on prior knowledge or expectations regarding equipping barns with non-standard technical solutions. An index of non-standard solutions in livestock buildings (S_ns) was proposed based on the ratio of the number of non-standard solutions in a barn to usable floor space in the barn. The S_ns index was higher in tie-stall barns (0.0012–0.0192) than in loose-housing barns (0.00–0.0023). Non-standard technical solutions implemented by farmers were most common in barns with tie-stall housing systems, especially in feeding areas. Knowledge about non-standard technical solutions in barns can be used in practice by various stakeholders as inspiration for barn retrofits, training materials for advisors, or a starting point for targeted welfare research. Full article

This study aims to establish a method-integrative framework for emotion-oriented architectural image generation. The framework combines Stable Diffusion with targeted LoRA (Low-Rank Adaptation), a lightweight and parameter-efficient fine-tuning approach, together with ControlNet-based structural constraints, to examine how controllable design-element manipulations influence emotional responses. The methodology follows a closed-loop “generation–evaluation” workflow, with each LoRA module independently targeting a single design element. Guided by the relaxation–arousal emotional dimension, the framework is evaluated using subjective ratings and electroencephalogram (EEG) measures. Twenty-seven participants viewed six architectural space categories, each comprising four conditions (baseline, color, material, and form modification). EEG α/β power ratio (RAB) served as the primary neurophysiological marker of arousal. Statistical analysis indicated that LoRA-based modifications of design elements produced distinct emotional responses: color and material changes induced lower arousal, whereas changes in form elicited a bidirectional pattern involving relaxation and arousal. The right parietal P4 electrode site showed the most sensitive emotional response to design element changes, with consistent statistical significance. P4 is a human scalp EEG location associated with cortical activity related to visuospatial processing. Descriptive results suggested opposite directional effects with similar intensity trends; however, linear mixed-effects model (LMM) inference did not support significant group-level linear coupling, indicating individual variation. This study demonstrates the feasibility of emotion-guided architectural image generation, showing that controlled manipulation of color, material, and form can elicit measurable emotional responses in human brain activity. The findings provide a methodological basis for future multimodal, adaptive generative systems and offer a quantitative pathway for investigating the relationship between emotional states and architectural design elements. Full article

Data encryption is a core mechanism in modern security services for protecting confidential data at rest and in transit. This work introduces the Super Encryption Standard (SES), a symmetric block cipher that follows the overall workflow of the Advanced Encryption Standard (AES) but adopts a key-dependent design to enlarge the effective key space and improve execution efficiency. The SES accepts a user-supplied key file and a selectable block dimension, from which it derives per-block round material and a dynamic substitution box generated using SHA-512. Each round relies only on XOR and a conditional half-byte swap driven by key-derived row and column vectors, enabling lightweight diffusion and confusion with low implementation cost. Experimental evaluation using multiple color images of different sizes shows that the proposed SES algorithm achieves faster encryption than the AES baseline and produces a ciphertext that behaves statistically like random noise. The encrypted images exhibit very low correlation between adjacent pixels, strong sensitivity to even minor changes in the plaintext and in the key, and resistance to standard statistical and differential attacks. Analysis of the SES substitution box also indicates favorable differential and linear properties that are comparable to those of the AES. The SES further supports a very wide key range, scaling well beyond typical fixed-length keys, which substantially increases brute-force difficulty. Therefore, the SES is a promising cipher for image encryption and related data-protection applications. Full article

Textile-reinforced concrete (TRC) is an alternative class of mechanical reinforcement for cement composites. The biaxial braided reinforcement structure in composite materials with diverse cross-sectional shapes offers high adaptability, torsional stability, and resistance to damage. In general, 3D textile reinforcements improve the mechanical properties of composites compared to 2D reinforcements. This study aimed to verify reinforcement behavior by comparing multidimensional braided textiles, 2D (one- and two-layer) reinforcements, and 3D reinforcement in composite cementitious boards. Experimental tests were performed to evaluate the effect of textile structures on cementitious composites using four-point bending tests, porosity measurements, and crack patterns. All textiles showed sufficient space between yarns, allowing the matrix (a commercial formulation) to infiltrate and influence the composite mechanical properties. All composites presented ductility behavior. The two layers of 2D textile composites displayed thicker cracks, influenced by shear forces. Three-dimensional textiles exhibited superior values in four-point bending tests for modulus of rupture (7.4 ± 0.5 MPa) and specific energy (5.7 ± 0.3 kJ/m²). No delamination or debonding failure was observed in the boards after the bending tests. The 3D textile structure offers a larger contact area with the cementitious matrix and creates a continuous network, enabling more uniform force distribution in all directions. Full article

The United Kingdom’s (UK) retrofit revolution is at a crossroads and the efficacy of retrofit interventions is not solely a function of insulation thickness. To truly slash emissions and lift households out of fuel poverty, we must solve the persistent problem of thermal bridging (TB), i.e., the hidden flaws that cause heat to escape, dampness to form, and well-intentioned retrofits to fail. This review moves beyond basic principles to spotlight the emerging tools and transformative strategies to make a difference. We explore the role of advanced modelling techniques, including finite element analysis (FEA), in pinpointing thermal and moisture-related risks, and how emerging materials like vacuum-insulated panels (VIPs) offer high-performance solutions in tight spaces. Crucially, we demonstrate how an integrated fabric-first approach, guided by standards like PAS 2035, is essential to manage moisture, ensure durability, and deliver the comfortable, low-energy homes the UK desperately needs. Therefore, achieving net-zero targets is critically dependent on the systematic upgrade of the building envelope, with the mitigation of TB representing a fundamental prerequisite. The EnerPHit approach applies a rigorous fabric-first methodology to eliminate TB and significantly reduce the building’s overall heat demand. This reduction enables the use of a compact heating system that can be efficiently powered by renewable energy sources, such as solar photovoltaic (PV). Moreover, this review employs a systematic literature synthesis to critically evaluate the integration of TB mitigation within the PAS 2035 framework, identifying key technical interdependencies and research gaps in whole-house retrofit methodology. This article provides a comprehensive review of established FEA modelling methodologies, rather than presenting results from original simulations. Full article

This study presents the results of laser beam welding of dissimilar high-alloy super stainless steels. Differences in their thermal and mechanical properties pose significant challenges in manufacturing processes. The present work demonstrates the potential advantages of using 309L filler material in laser welding of high-alloy materials with different properties. The research focuses on a comparative evaluation of the effects of 309L filler metal on the TP904L—TP347 joint in terms of joint strength and microstructure. The analysis of the joints provides insight into the role of the filler metal in improving joint properties. The obtained results show that both welds exhibit a similar microstructure composed of pillar, cellular, and equiaxed dendrites; however, they differ in dendrite growth orientation, calculated ferrite number (FN), the G/R ratio, and dendrite arm spacing, indicating a lower thermal gradient in the joint welded with filler metal. The results also reveal the presence of precipitates in the welds near the TP904L steel fusion line, most likely Cr₂₃C₆ type. Mechanical properties evaluation, based on standard and miniaturized tensile tests as well as hardness measurement, shows that the use of 309L filler metal improves both the joint strength and ductility, although it does not significantly affect the material hardness. Full article

Introduction: The contribution of SARS-CoV-2 infection to the severity of placental alterations in preeclampsia remains unclear. This study aimed to evaluate the morphological changes in placentas of women who experienced COVID-19 during pregnancy, with a focus on the presence or absence of preeclampsia. Materials and Methods: The study included placentas from: (1) patients with both COVID-19 during pregnancy and preeclampsia (n = 20, 2022); (2) patients with COVID-19 during pregnancy without preeclampsia (n = 20, 2022); (3) patients with preeclampsia but without COVID-19 (n = 5, 2019); (4) patients with physiological pregnancies without COVID-19 or gestational complications (n = 5, 2019). Histological and immunohistochemical examinations of the placentas were performed using antibodies against the SARS-CoV-2 spike protein, DPP4 (CD26), and VEGF. Results: Placentas from patients with both COVID-19 and preeclampsia demonstrated the most pronounced stromal and vascular alterations, including pseudo-infarctions and villous fibrosis. Chorangiosis, excessive fibrinoid deposition in the intervillous space, and accelerated villous maturation with an increased number of syncytial knots were more common in the preeclampsia groups, regardless of prior COVID-19 infection. Symptomatic forms of coronavirus infection were associated with more severe manifestations of malperfusion. Expression of the SARS-CoV-2 spike protein was detected in 78% of syncytiotrophoblast cells and 37% of decidual cells in 28 of 40 placentas from women with previous COVID-19, while its presence in the vascular endothelium, macrophages, and villous fibroblasts was focal, as was CD26 expression. VEGF expression did not differ significantly between patients with and without COVID-19. Conclusions: COVID-19 is associated with more pronounced stromal–vascular alterations in the placenta; however, not all of these changes are directly caused by the virus itself but rather reflect the severe course of preeclampsia. Inflammatory alterations are nonspecific for COVID-19, even though CD26 and the SARS-CoV-2 spike protein are detectable in nearly all placental structures, whereas VEGF levels remain comparable to those observed in placentas prior to the coronavirus pandemic. Full article