Search Results (131)

The increasing adoption of exhaust gas cleaning systems (EGCSs) in the maritime industry has raised concerns regarding the management of sludge residues generated during wet scrubber operation. Conventional onboard sludge handling methods primarily rely on temporary storage and onshore disposal, resulting in increased storage requirements, disposal costs, and environmental burdens. Although vacuum drying has emerged as a promising approach for onboard sludge volume reduction, limited studies have addressed the integrated risk-informed design, reliability evaluation, and operational validation of onboard vacuum drying systems under marine operating conditions. This study proposes a risk-informed systems engineering framework for the design, reliability evaluation, and validation of an onboard vacuum drying system (VDS) for EGCS sludge treatment. The framework establishes a closed-loop process in which functional analysis and hazard identification inform quantitative reliability assessment and structural verification, which in turn drive design refinement and are subsequently confirmed through hardware-in-the-loop (HIL) validation and experimental testing. The results demonstrated stable vacuum operation at the designated pressure of 3 Torr for more than 30 min, with a minimum chamber pressure of 0.08 Torr. Structural assessment confirmed that the calculated stresses remained well below the allowable limits of ASME Section VIII Division 1, while modal analysis indicated acceptable dynamic stability. FMECA-based design refinement reduced the Risk Priority Number (RPN) values of major components by 50–67%, with an average reduction of 53.3%. HIL-based validation and experimental testing further verified the effectiveness of the control architecture and the operational feasibility of the system. The study demonstrates how a risk-informed systems engineering framework can systematically integrate structural verification, quantitative reliability improvement, and operational validation for onboard environmental treatment systems. The proposed framework provides a practical and transferable methodology for enhancing the safety, reliability, and operational feasibility of marine systems operating under complex onboard conditions. Full article

Spent water-based drilling fluids generated during the construction of technological wells impose substantial environmental, water-management, transportation, and energy burdens. Conventional practices, including storage in temporary pits, prolonged settling, and off-site disposal, do not enable process-water recovery and require repeated handling of suspensions with a high solids content. This study evaluates a pressure-driven cylindrical hydrodynamic disperser as the central component of a compact on-site treatment system. Unlike conventional mechanical mixers, the disperser contains no driven shaft within the active chamber. Particle–reagent contact is intensified through controlled jet shear, vortex-induced redistribution, and the motion of freely moving steel balls. Field-derived drilling fluids containing 30–40 wt.% solids, with densities of 1.12–1.17 g/cm³, pH values of 7.4–8.2, and median particle sizes of 15–50 μm, were treated at velocity gradients of 500–1500 s⁻¹ for 60–180 s using Superfloc N-300 dosages of 0–100 g/t. The optimal operating conditions were G = 1300 s⁻¹, τ = 150 s, and D = 50 g/t. Under these conditions, the separation efficiency reached 91–93%, the residual suspended-solids concentration decreased to 120–130 mg/L, process-water recovery reached 80%, sludge volume decreased by 40–60%, and specific energy consumption was approximately 0.30 kWh/m³. More intensive treatment increased the separation efficiency to 94–95% but resulted in a less favorable balance among energy consumption, reagent dosage, and resource recovery. Compared with mechanical mixing, the selected treatment system reduced flocculant consumption by 37.5%, treatment time by more than threefold, and specific energy consumption by 40%. These results support the use of modular on-site systems for process-water recirculation and reduced sludge-transport requirements at remote drilling sites. Full article

Wastewater treatment plants (WWTPs) can serve as hubs for converting waste into energy, thereby supporting a city’s energy needs. Thermal processes, especially gasification, enable the transformation of sewage sludge into valuable products by producing energy-rich syngas for electricity generation. However, conventional air-based gasification introduces nitrogen as a diluent, reducing the syngas energy density. Integrating electrolyzers for hydrogen production into WWTP operations offers a strategic advantage: the oxygen co-produced during water electrolysis can be utilized as a gasification agent, thereby minimizing nitrogen dilution and enhancing syngas quality. The present work assesses the simulation of a conventional WWTP integrated with gasification and electrolysis systems using Superpro Designer V13. The results demonstrate that using pure oxygen in the gasification unit reduces the process’s thermal energy requirements and increases the syngas energy content by 5.5% when operating in a CO₂ atmosphere at an equivalence ratio (ER) of 0.15. The integration of anaerobic digestion and sludge gasification improves the overall energy balance by increasing electrical output (67%) and enabling thermal energy recovery, allowing sludge drying without auxiliary fuel. Water electrolysis is integrated as an energy storage system, allowing flexible operation during periods of excess renewable electricity. However, a simplified balance of this strategy reveals negative economic results unless electricity prices are below 7.5 c€/kwh. This approach underscores the need for further research into the use of reclaimed water for hydrogen production, as well as improving process integration to reduce the energy and water footprints of technologies supporting the green transition. Full article

The management of livestock manure is associated with substantial ammonia (NH₃) emissions and the accumulation of emerging contaminants, including antibiotics, antibiotic resistance genes (ARGs), and microplastics, posing risks to environmental quality and public health. Biochar has emerged as a promising strategy for mitigating gaseous emissions and reducing contaminant mobility during manure storage and composting processes. This review synthesizes recent research on the application of biochar in livestock manure management systems, focusing on NH₃ emissions, antibiotic degradation, ARG reduction, and microplastic removal. Particular attention is given to the effectiveness of biochar in mitigating pollutants during manure storage, housing operations, and composting processes. Across the literature, reported NH₃ mitigation efficiencies vary widely, from negligible effects to reductions exceeding 90–97%, depending on feedstock type, pyrolysis conditions, particle size, and application strategy. Biochar also promotes antibiotic degradation and ARG mitigation, with reductions of up to 98% reported in composting systems. Emerging evidence further suggests that biochar can reduce microplastics by approximately 15–64% in sludge composting. Plant-derived and chemically modified biochars generally outperform manure-derived biochars due to higher surface area, cation exchange capacity, and greater abundance of functional groups. The review highlights that activation treatments, co-composting strategies, and microbial interactions are key factors controlling pollutant mitigation efficiency. Despite promising outcomes, large-scale application remains limited by economic constraints, variability in biochar properties, and the lack of long-term field-scale validation. Future research should prioritize standardized production protocols, field implementation studies, and integrated environmental and economic assessments to support the practical adoption of biochar in sustainable livestock waste management systems. Full article

The high-rate biological contactor (HRBC) is an enhanced-primary, biosorption-based, carbon-diversion wastewater treatment process with short hydraulic retention time (HRT), short solids retention time (SRT), low dissolved oxygen (DO), and high food-to-microorganism ratio (F/M). This paper presents modifications to a commercial full-plant wastewater biodegradation model using extracellular polymeric substances (EPS) in waste activated sludge (WAS) to simulate pilot test biosorption data. Bench-scale HRBC tests found that each mg of EPS as COD (COD_EPS) biosorbed 1.02 mg sCOD contained in raw wastewater. The fraction of AS organics identified as EPS in terms of COD was 37% in a conventional AS (CAS), 33% in a trickling filter-solids contact (TF/SC), and 18% in a membrane bioreactor (MBR). The modeling process used stoichiometry equations to convert EPS from its constituent concentrations (carbohydrates, proteins, humic acids, uronic acids) into COD. The conversion did not alter the finding that the normalized total EPS showed a positive relationship with soluble chemical oxygen demand sCOD biosorption with a 0.91 coefficient of determination. The modified commercial biodegradation model gave a maximum error of −12.6% when simulating pilot-scale results, and 80% of all data points were less than ±10% error. The modified model predicted 16% sCOD biosorption by EPS using the design data for a full-scale HRBC facility currently under construction. Full article

The accelerating generation of waste streams is observed globally. Spanning lignocellulosic biomass, plastic waste, sewage sludge, and industrial residues, this review presents both an urgent management challenge and a compelling materials opportunity. Carbon materials derived from these waste streams offer a sustainable route to functional carbons applicable in electrochemical energy storage, adsorption, heterogeneous catalysis, and high-temperature applications. Yet their rational design remains constrained by incomplete understanding of the relationships between feedstock composition, processing pathway, structural characteristics, and functional performance. This review provides an integrated analysis of waste-derived carbon materials from processing pathways to structure–property–function relationships. The principal feedstock categories are examined for their compositional characteristics and implications for carbon yield and structure. Five primary processing routes are assessed. The five routes examined are pyrolysis, hydrothermal carbonisation, physical and chemical activation, and microwave-assisted processing. They are assessed comparatively with emphasis on structural outcomes and governing parameters. The resulting structural characteristics are discussed. These are morphology, hierarchical pore architecture, surface chemistry, heteroatom doping, and crystallinity. They are discussed alongside their characterisation methods and known limitations as performance predictors. Structure–property relationships are examined quantitatively. Heteroatom-doped hierarchical porous carbons achieve 612 F/g specific capacitance. Turbostratic hard carbons deliver 450 mAh/g sodium storage with over 90% retention. Hierarchical porous carbons demonstrate CO₂ uptake of 5.0 mmol/g and dye adsorption exceeding 9000 mg/g under optimised laboratory conditions; these values reflect individual studies and are not directly comparable across systems. Biomass-derived sulfonated carbon catalysts sustain biodiesel yields above 90% over multiple cycles. Challenges of feedstock variability, process scalability, environmental compliance, and economic feasibility are addressed, and machine learning-guided design, standardised characterisation methodology, and circular economy policy frameworks are identified as key enablers for translating laboratory performance into industrial reality. Full article

While there is some agreement on estimating construction cost contingency for “known unknowns,” there is little consensus on estimating management reserves for “unknown unknowns.” Definitions of risk and uncertainty also differ between the economics and finance literature and the cost engineering literature. This paper examines how cost engineering guidance on estimating management reserves is applied in government-sponsored project cost estimates. This lack of consensus is evident in a specific program: the management, treatment, and disposal of 212,000 cubic meters of mixed radioactive and hazardous chemical waste generated by plutonium production at the Hanford Nuclear Site. Over $30 billion has been invested in treatment facilities, vitrification plants, and laboratories analyzing gases, liquids, sludges, and salt cake from 177 aging storage tanks. The remaining construction and operating costs are highly uncertain, with estimates ranging from $300 billion to $640 billion. Analyses of alternatives for constructing Hanford waste treatment facilities assume 15% contingencies and 40% management reserves. A method is presented to compute the implicit moments of Extreme Value distributions of cost estimates for different options, helping determine whether one alternative’s cost estimate stochastically dominates others. Adopting industry definitions of contingency and management reserves by federal government agencies could improve construction cost estimation in government-financed programs. Full article

Conventional aerobic composting is limited by incomplete organic matter degradation, long composting times, and low product quality. Hyperthermophiles have been applied in composting, but systematic studies on their storage conditions and inoculation strategies are lacking. In this study, the hyperthermophilic microbial consortium, designated as NJ, maintained higher post-storage regrowth capacity after 6-month storage at 25 °C and 4 °C than at −80 °C. Furthermore, inoculated at the medium-temperature stage, NJ enhanced organic matter decomposition and shortened the composting time by 50% compared with high-temperature stage inoculation (>55 °C). Compared with a commercial inoculant, NJ shortened composting time by 67%, increased the germination index from 70% to 85%,raised DTN by 40%, and led to humic substance accumulation by the end of composting, indicating improved product quality. Consequently, medium-temperature stage inoculation of NJ enhances composting efficiency and product quality by enabling earlier functional expression and effective ecological niche occupation. Full article

The treatment of oily wastewater represents a significant environmental challenge, requiring efficient separation technologies and waste valorization. This study evaluated different types of coagulants (ferric chloride 38% m/m, aluminum polychloride 18% m/m, aluminum sulfate 8% m/m, and ferrous sulfate 6% m/m) and anionic polymers (from six suppliers) for treating poultry slaughterhouse effluent, aiming to optimize both clarification and oil recovery from the floated sludge. Bench-scale jar tests (G = 300 s⁻¹ and 30 s⁻¹) were followed by full-scale validation in a dissolved air flotation unit (100 m³ h⁻¹) at a poultry processing WWTP. Recovered oil was extracted by hot cooking (95 °C) and tridecanter centrifugation, and its quality (moisture, acidity, saponification index) was assessed. A techno-economic analysis, including simple/discounted payback, NPV, IRR, Monte Carlo simulation (10,000 iterations, Python), and deterministic sensitivity analysis, was performed. Ferric chloride (38% m/m) produced the best technical results: treated effluent turbidity < 30 NTU, oil yield of 360 L day⁻¹ with moisture < 2% at the tridecanter outlet, and consistent sludge dewaterability (moisture 55–65%). Oil moisture increased dramatically (to >30%) after storage due to condensate contamination from an inefficient exhaust system, a critical operational flaw that must be corrected. No statistically significant effect of polymer type on oil recovery was observed, although high variability (CV > 50%) was noted during PAC tests. The simple payback period for ferric chloride was 60.7 months (discounted: 64.1 months), with a positive median NPV (USD 7925) under a 12% p.a. discount rate. Sensitivity analysis showed that the investment is most sensitive to oil price: a 20% drop in oil price leads to a negative NPV (−USD 21,727). Despite this risk, the project provides environmental compliance and waste-to-value benefits. The study demonstrates that ferric chloride enables effective oil extraction from poultry wastewater, but proper exhaust design is essential to maintain oil quality. Future work should focus on standardized test durations (≥72 h) and automated monitoring to reduce variability. Full article

Tailings are unconventional geomaterials that require dynamic characterisation due to seismic hazards at several storage facilities. Due to the anthropic origin of these materials, their dynamic properties differ from those reported for natural soils. In particular, the damping ratio is a relevant parameter that controls the dynamic response of tailings storage facilities. It can be estimated using different experimental methods. The objective of this research is to disclose the results obtained through laboratory tests in which the damping ratio was evaluated independently by Half-Power Bandwidth or the free-vibration decay methods. A comprehensive testing plan comprising resonant column tests and free-vibration decay tests was carried out on three types of tailings from the Riotinto mines (Huelva, Spain): Cerro Salomón Sand (CSS), High-Density Sludge (HDS), and Copper Lamas (CL). These tests were carried out under different effective consolidation pressures and torsional excitations. The results allowed the establishment of a series of relationships between the testing conditions and the identification of differences between the methods for tailings. Full article

The escalating production of sewage sludge presents a significant environmental challenge, while the construction industry simultaneously seeks sustainable raw materials to improve its circularity. This review analyses the technical and regulatory landscape for valorizing SS within the Latvian construction sector, set against the divergent strategies of its Baltic neighbours. While global research confirms the technical viability of using SS in fired-clay bricks and as a supplementary cementitious material (SCM), national management approaches differ starkly. Lithuania has adopted widespread incineration, and Estonia has focused on advanced composting. In contrast, Latvia’s national strategy is failing, with 51% of its 2024 sludge production diverted to “temporary storage”. This review identifies this crisis as a unique opportunity, arguing that incorporating dewatered digestate into fired-clay bricks is the most logical and economically viable pathway for Latvia, as it leverages existing industrial infrastructure. The primary obstacle to this circular solution is not technical but legal, specifically the lack of a national “End-of-Waste” (EoW) criterion for sludge-derived construction materials. Therefore, this article proposes a strategic roadmap for Latvia, centred on developing this essential legal framework, creating a national sludge characterization map, and initiating a pilot project to bridge the research-to-industry gap. Although Latvia is the primary focus of this review, the regulatory, infrastructural and material constraints analysed here are common in many small and mid-sized countries, making the insights applicable beyond the Latvian context. Full article

This study aimed to evaluate the process of formation, storage and reactivation of aerobic granular sludge (AGS) in real dyeing wastewater. An SBR was employed for the AGS operation, and the results showed that AGS could form in the SBR within 30 days and was reactivated in 20 days after 300 days of storage. The nutrient removal efficiency remained stable after formation and reactivation. Metal ions (Fe and Ca) and inorganic matter from raw wastewater not only improved AGS formation efficiency but also ensured its structural stability during long-term storage. The initially formed AGS was enriched with Fe and Ca. However, during storage, Fe deposited on the AGS surface was lost due to iron-reducing bacteria (Shewanella). In the reactivated AGS, Ca deposited in the core became dominant. This work fully describes the formation, storage, and reactivation of AGS in real dyeing wastewater and reveals the stabilization mechanism of Ca- and Fe-rich AGS during long-term storage. Full article

The water–energy–carbon (WEC) nexus provides a systems framework for minimizing trade-offs among water security, energy reliability, and carbon mitigation. Within this framework, waste-derived biochar catalysts offer a circular pathway that simultaneously valorizes residues, reduces process energy demand, and supports carbon management through stable carbon storage and catalytic co-benefits. This review consolidates recent advances in biochar-based catalysts engineered from agricultural, industrial, municipal, and sludge-derived wastes, highlighting how feedstock selection and thermochemical processing, namely pyrolysis, hydrothermal carbonization (HTC), and torrefaction, as well as activation and post-modification (heteroatom doping and metal/metal-oxide incorporation) govern structure–property–performance relationships. The synthesized catalysts have been widely applied in water and wastewater treatment, including adsorption–advanced oxidation process (AOP) hybrids, Fenton-like systems, peroxydisulfate/persulfate (PS) and peroxymonosulfate (PMS) activation, photocatalysis, and the removal of emerging contaminants. They have also demonstrated strong potential in energy conversion processes such as the hydrogen evolution reaction (HER), oxygen reduction and evolution reactions (ORR/OER), biomass reforming, and carbon dioxide (CO₂) conversion. In addition, these materials contribute to carbon management through sequestration pathways, avoided emissions, and life cycle assessment (LCA)-based sustainability evaluations. Finally, we propose a WEC-aligned design roadmap integrating techno-economic analysis (TEA), LCA, and scale-up considerations to guide next-generation biochar catalysts toward robust performance in real matrices and deployment-ready systems. Full article

Biochar application has been proposed as a promising strategy to improve soil functioning, defined as the integrated regulation of water storage, nutrient availability, and biological activity influencing crop productivity and crop performance in water-limited environments. However, its effectiveness depends on soil properties, climatic variability, and dominant processes. This study evaluated the effects of sewage sludge biochar on soil quality, water dynamics, nutrient availability, and bean productivity in sandy soil under rainfed semiarid conditions across two contrasting cropping cycles. A soil quality index (SQI) based on a minimum data set (MDS) derived from principal component analysis (PCA) was used to identify the dominant processes controlling soil functioning under different hydrological regimes. The two cropping cycles corresponded to wetter (Cycle I) and drier (Cycle II) hydrological conditions within the same agricultural year. Biochar application increased soil organic carbon and nitrogen stocks, enhanced phosphorus availability, and improved soil water storage. Despite similar evapotranspiration among treatments, water productivity increased, indicating more efficient conversion of stored soil water into yield. Biological indicators were more responsive during the wetter cycle, whereas physicochemical indicators dominated under drier conditions, revealing a shift in the processes regulating soil functioning. The minimum data set varied between cycles, demonstrating the environmental dependency of the SQI components. Overall, biochar improved soil resilience by enhancing nutrient retention and buffering crop response to water limitation, and the integrative SQI approach effectively captured these functional changes. Full article

Background: Microplastics (MPs) and nanoplastics (NPs) are now common in land and water ecosystems. Their spread is an increasing issue from a One Health perspective. These particles end up in soils, water, air, and farm inputs. This poses direct risks to animal health and indirect risks to people who eat animal-derived food. There are also risks from plastic additives and pesticides migrating with these particles in animal-based food. Scope and Approach: This review summarizes how MPs and NPs move in agroecosystems and livestock production. It covers their main sources, such as agricultural plastics, sludge-amended soils, plastic-lined storage, and environmental fallout. It explains how farm animals are exposed, including through feed, water, soil contact, and inhalation. Evidence is condensed for occurrence in manure, tissues, and animal products. The review also highlights key analysis challenges, especially those limiting the assessment of nanoplastic exposure. Key Findings: Field surveys show very different contamination levels in the environment. Agricultural soils range from 0.36 to 42,960 particles/kg. Livestock indicators, like contaminated feed and manure, range from 10² to 10⁵ particles/kg. In free-roaming systems, chicken feces have very high loads, showing trophic transfer in land food chains. A pilot study found plastic particles in pig and cow blood, suggesting some particles cross the gut into the blood. Experimental models link MPs/NPs to oxidative stress, inflammation, mitochondrial dysfunction, metabolic disturbance, and potential reproductive toxicity in livestock and poultry. Conclusions and outlook: Animal-based foods provide a major source of human exposure. MPs and NPs have been observed in milk and poultry products, such as packaged meat and eggs (mean 11.67 ± 3.98 particles/egg). There is still a research gap on raw milk taken directly from the teat and on raw eggs that have not been handled or packaged. This gap makes it hard to identify real contamination sources and control strategies. The review stresses the need for harmonized detection methods (especially for NPs), monitoring from farm to fork, and practical ways to reduce plastic use on farms and minimize contamination during processing, feed handling, and packaging. Full article