Search Results (505)

Successive ionic layer adsorption reaction (SILAR) was used to deposit Cu₂O nanosheets on anodized TiO₂ nanotubes at different deposition cycles (4, 8, 15, and 20). Compared to the bare TiO₂ nanotubes, these coatings were investigated for their tribological behavior (friction, wear and energy loss), scanning and transmission electron microscopy (SEM, TEM), X-ray Diffraction (XRD) was used to characterize Cu₂O/TiO₂ coatings to study the effect of number of cycles on the morphological and structural properties of the samples; these characteristics engage in determining the wear mechanisms. The assessment of the coating’s adhesion was determined by the obtained critical loads from the scratch test; the 15 cycles Cu₂O/TiO₂ exhibited higher critical loads, which corresponds to improved adhesion. This sample also showed a low wear volume of 7.5 × 10⁶ µm³ compared to other samples but higher energy loss due to the low shear strength of copper oxide. The friction coefficient, however, decreased from 0.7 for bare TiO₂ nanotubes to 0.48 for 20 cycles Cu₂O/TiO₂ coatings at higher loads, which proves the wear resistance enhancement. Since these coatings will be manufactured for orthopedic and dental implant applications, the corrosion resistance was tested, and the 15 cycles Cu₂O-NPs/TiO₂-NTs where these coatings exhibited the most favorable combination of a low corrosion current density (1.9 × 10⁻⁴ A/cm²) and a noble corrosion potential (−0.3 V/SCE); furthermore, there was a polarization resistance of 2.4 × 10⁴ Ω·cm² and a protection efficiency of 96.7%, indicating significantly enhanced corrosion resistance as opposed to the other samples. Full article

Thin wall composite fan blades in aircraft engines demand designs that ensure structural integrity under operational loads while resisting foreign object damage and bird strikes. This study presents a finite element investigation of thin wall composite blades with metal leading edge caps, modeled through parametric coupon analyses under static flexure loading using ANSYS APDL. Three metallic leading edge caps, Ti-6Al-4V, Inconel 718, and 15-5 PH stainless steel, were combined with IM7/8551-7 carbon fiber composites. Parametric variations included changes in metal cap material, geometric designs of the joint, and other things. Performance was evaluated in terms of failure stress, interlaminar shear strains, interface integrity, and failure margins. Results reveal that cap design and cap material critically govern structural response, with distinct interchanges between strength-to-weight efficiency, interface stresses, and interlaminar shear strain. Optimal designs reduced interlaminar shear strain levels in thin wall composite blades, while retaining adequate stiffness and strength. The results underscore the importance of interface design for effective load transfer and provide design guidelines for lightweight, damage-tolerant thin wall composite fan blade structures. Full article

This work focuses on obtaining a titanium nitride coating on the surfaces of titanium and its alloy powders using a novel method, self-shearing reactive milling, under a nitrogen pressure of 50 bar. The Ti, Ti6Al4V, and Ti-5553 spherical powders were milled for up to 10 h at ambient temperature without grinding balls. As a result of the experiments, a thin, brittle TiN coating formed on the powders’ surfaces. The cross-sections of the milled powders reveal that the TiN layer thickness is in the nanometer range (about 500 nm). By analyzing the sequence of X-ray diffraction patterns, it is evident that only for the Ti6Al4V powder milled for 10 h, two peaks are observed that can be attributed to a TiN phase. On the other hand, Raman spectroscopy revealed characteristic TiN spectra even for samples collected at the initial stage of self-shearing reactive milling. An important aspect of the experiment was the preservation of the spherical shape of the milled powders, which makes them a potential feedstock for additive manufacturing of functionally graded biomaterials. Full article

Al/TiB₂ aluminum alloy laminates were fabricated using a combination of accumulative roll bonding (ARB) and cold rolling processes. The Al/TiB₂ interface and microstructure were meticulously characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The mechanical properties of the laminates were assessed through tensile testing. The experimental results demonstrate that with an increasing cold rolling reduction, a laminated composite sheet with a nanocrystalline structure was successfully produced. The critical strain for the onset of plastic instability was also investigated. The findings indicate that as the cold rolling reduction increases, severe necking occurs in the Al12Zn2.2Mg1.7Cu3TiB₂ layer. At a reduction of 80%, the necking region approaches fracture. Tensile results reveal that this pronounced necking has a detrimental effect on the strength of the laminate. It is proposed that the plastic instability originates from shear bands, and the mechanical property mismatch between the constituent layers is identified as the primary reason for the localized preferential deformation. Full article

Adiabatic shear banding (ASB) is a critical failure mechanism in titanium alloys subjected to high-strain-rate deformation, and its initiation is strongly influenced by the initial crystallographic texture. The dynamic response and ASB sensitivity of extruded and annealed Ti-6Al-4V (TC4) alloy rods were investigated under dynamic compression of cubic specimens along the extrusion direction (ED) and the transverse direction (TD) at a strain rate of 2500 s⁻¹. Split Hopkinson pressure bar (SHPB) tests combined with digital image correlation (DIC) were employed to obtain the stress–strain response and the evolution of strain localization. A dislocation density-based crystal plasticity finite element model (CPFEM), incorporating the measured texture, was established to elucidate the correlation between texture and ASB behavior. The experimental results show that TD specimens exhibit a yield strength approximately 100 MPa higher than that of ED specimens, while both orientations display comparable post-yield hardening behavior. ASB initiation occurs earlier in TD (compressive strain ~0.13) than in ED (~0.23), indicating greater ASB sensitivity in the TD orientation. The CPFEM successfully reproduces the directional stress–strain responses and the observed localization morphology, enabling mechanistic interpretation in terms of slip activity and thermomechanical coupling. The simulations indicate that ED loading is dominated by prismatic ⟨a⟩ slip, resulting in lower flow stress and more dispersed strain localization. In contrast, TD loading is governed primarily by pyramidal ⟨c + a⟩ slip, leading to elevated flow stress and intensified localization. The higher ASB sensitivity in the TD orientation is therefore attributed to texture-controlled slip-mode partitioning, enhanced thermomechanical coupling, and a more concentrated crystallographic orientation distribution that facilitates intergranular slip transfer. These findings provide guidance for tailoring microtexture to mitigate dynamic failure in titanium alloys subjected to high-strain-rate loading. Full article

Nickel-titanium (NiTi) alloys are attractive for functional and biomedical applications due to their shape memory effect, superelasticity, and favorable corrosion resistance and biocompatibility. In this work, the influence of strut size on the compressive response of laser-based powder bed fusion (PBF-LB/M) fabricated NiTi ortho-octahedral porous scaffolds was systematically investigated using combined experiments and finite element simulations. Four scaffold designs with identical unit-cell size (2 mm) but different strut sizes (280, 320, 360, and 400 μm) were fabricated, and their forming quality and deformation behaviors were examined. The as-built scaffolds exhibited high geometric fidelity to the CAD models and stable manufacturability across the investigated parameter range. Quasi-static compression tests revealed a typical three-stage response (linear-elastic regime, plateau/collapse regime, and densification), with both elastic modulus and compressive strength increasing markedly with strut size. Specifically, the modulus increased from 1.17 to 4.28 GPa and the compressive strength increased from 155 to 564 MPa as the strut size increased from 280 to 400 μm. A pronounced oscillatory plateau was observed for the 280 μm scaffolds, indicating progressive layer-by-layer collapse, whereas larger struts promoted a shear-band-dominated failure mode characterized by an approximately 45° fracture zone. Explicit quasi-static simulations reproduced the experimentally observed collapse sequence and demonstrated that stress preferentially concentrates at nodal junctions, with load transfer dominated by struts aligned with the loading direction. The agreement between experiments and simulations confirms the predictive capability of the proposed modeling framework and provides mechanistic insights into geometry-controlled failure. These findings establish a structure-property-failure relationship for PBF-LB/M-fabricated NiTi octahedral scaffolds and offer practical guidance for tailoring stiffness, strength, and collapse mode through strut-size design. Full article

This study systematically investigates the influence of annealing time on the microstructure and mechanical properties of a (CoCrNi)_93.5Al₃Ti₃C_0.5 medium-entropy alloy. Following hot-rolling, the alloy was subjected to annealing treatments at 900 °C for 10 min (HA900-10) and 60 min (HA900-60). Microstructural characterization revealed that both alloys contained three types of precipitates: intergranular M₂₃C₆ and MC-type carbides, as well as γ′ phase. The HA900-10 specimen exhibited a low degree of recrystallization, whereas prolonged annealing promoted partial recrystallization, leading to the formation of a slightly heterogeneous structure (HA900-60). Additionally, the extended annealing facilitated the intragranular precipitation of nanoscale γ′ phase. Room-temperature tensile tests demonstrated that the HA900-10 and HA900-60 specimens achieved yield strengths of 1276 MPa and 1202 MPa, with total elongations reaching 26% and 28%, respectively. Quantitative strengthening analysis indicated that the strength of HA900-10 primarily originated from dislocation and grain boundary strengthening. For HA900-60, an additional significant contribution arose from the dislocation shearing mechanism induced by the intragranular γ′ precipitates. Analysis of the deformation mechanisms revealed that planar slip, assisted by the formation of stacking faults, dominated the room-temperature deformation, thereby ensuring sustained work-hardening capacity. This research provides a theoretical foundation for tailoring the microstructure and properties of multi-phase medium-entropy alloys through annealing process control. Full article

Background/Objectives: This study aimed to compare the cleaning efficacy, biomechanical stress distribution under simulated occlusal loading after instrumentation, and irrigant dynamics of three NiTi rotary systems, namely ProTaper Gold, TruNatomy, and SlimShaper, using a combined experimental, finite element analysis (FEA), and computational fluid dynamics (CFD) approach. Methods: Transparent 3D replicas of mandibular mesial roots filled with a gel-like pulp tissue were instrumented with the three systems (n = 13 per group). Standardized irrigation was performed with 4% NaOCl delivered through IrriFlex^® needles positioned 2 mm from the working length. Cleaning effectiveness was assessed through digital image analysis, FEA simulation of occlusal loading, and CFD evaluation of irrigation flow, wall shear stress, and dynamic pressure. Results: All systems left residual tissue, with no statistically significant differences in cleaning efficacy among them (p > 0.05). Descriptively, ProTaper Gold showed the lowest mean residual tissue (0.15 ± 0.25%), followed by SlimShaper (2.50 ± 3.81%) and TruNatomy (4.20 ± 5.12%). CFD revealed that ProTaper Gold generated the highest irrigant velocities and wall shear stresses, while SlimShaper showed the highest dynamic pressure. FEA indicated that ProTaper Gold produced the highest stress concentrations, especially in the pericervical dentin, whereas TruNatomy and SlimShaper preserved more dentin. Conclusions: Cleaning efficacy was comparable across systems. CFD/FEA from representative models illustrated patterns of irrigant dynamics and dentin preservation without supporting system superiority. Full article

This study tests TiO₂ and SiO₂ nanolubricants in PAG oil using a Mini Traction Machine and an Ultra Shear Viscometer. The loads were 20 N and 40 N. The entrainment speeds ranged from 2.5 to 500 mm/s. The slide-to-roll ratio (SRR) ranged from 25 to 150%. The nanoparticle concentrations were 0.01, 0.03, and 0.05%. The ball size was 19.05 mm, and the disc was 46 mm. All tests were run at 40 °C. Only the 0.05% concentration lowered traction compared with PAG at a fixed SRR. TiO₂ at 0.05% showed the largest drop, up to 4.89% at 20 N and 2.99% at 40 N. However, lower concentrations increased traction. All the nanolubricants reduced wear. TiO₂ at 0.03% gave the lowest wear, with a reduction of about 35 µm at 40 N. Nanolubricant samples stayed between 40.2 and 40.5 °C, while PAG reached about 41.0 °C. TiO₂ produced slightly lower temperatures than SiO₂. Ultra-shear tests from 40 to 100 °C showed shear thinning. In most conditions, TiO₂ at 0.05% kept the highest viscosity at 40 and 60 °C, up to 12% above PAG. SiO₂ showed smaller changes. TiO₂ delivered better friction, wear, temperature, and viscosity performance. Overall, both nanolubricants at 0.03% are suitable when wear reduction and thermal stability are prioritised over traction reduction, such as in refrigeration applications, while the 0.05% suits high-load or high-shear use. Full article

This study systematically investigates the microstructure evolution, mechanical properties, and residual stress distribution in diffusion-bonded joints between Al₂O₃ ceramic and TC4 alloy. Motivated by the need for reliable high-temperature joints in advanced applications, this work addresses the challenges posed by the materials’ physicochemical differences. Joints were fabricated at temperatures ranging from 800 °C to 950 °C under a pressure of 3 MPa for 2 h. Microstructural characterization revealed the formation of a multi-layered interfacial structure, dominated by a Ti₃Al reaction layer, whose thickness increased with bonding temperature. The highest shear strength of 54 MPa was achieved at 850 °C, representing a key quantitative outcome of this parameter optimization. Beyond this temperature, excessive growth of the brittle Ti₃Al layer and associated residual stresses led to strength degradation and interfacial cracking. A three-dimensional finite element model was developed to simulate residual stress distributions, highlighting significant tensile stresses within the Ti₃Al layer and compressive stresses in the Al₂O₃ near the interface. The model further identified critical tensile stress concentrations along the vertical edges of the ceramic, which contribute to failure during shear testing. Full article

A comprehensive analysis of the notch toughness of Electron Beam Powder Bed Fused (EB-PBF) Ti-6Al-4V was conducted, which focused on the influence of build orientation and correlations with key mechanical properties. Horizontal and vertical specimens were fabricated with optimized process parameters and reused powder. The microhardness and microstructure of the metal were examined and both profilometry and scanning electron microscopy were used in evaluating the fracture surfaces. Results showed that the metal with vertical build orientation absorbed ~46% higher impact energy than the horizontal orientation due to crack propagation perpendicular to the prior-β grains, lower microhardness, and greater ductility. The importance of ductility to the vertical specimens was evidenced by greater shear lip width (~51%) and height (~35%), greater shear lip length (~18%), and higher roughness of the fracture surface (~15%). Shear width measurements showed the highest correlation with absorbed impact energy. Overall, results show that the notch toughness of EB-PBF Ti-6Al-4V is dependent on the build orientation due to differences in microstructure and the bulk mechanical properties. The notch toughness is well correlated with tensile properties as well. Lastly, a framework for relating the notch toughness in dynamic loading and quasi-static fracture toughness for EB-PBF Ti-6Al-4V is proposed. Full article

The rising global demand for prosthetic limbs, driven by approximately 185,000 amputations annually in the United States, underscores the need for innovative and cost-efficient solutions. This study explores the integration of hybrid materials, advanced 3D printing techniques, and smart sensing technologies to enhance prosthetic finger production. A Taguchi-based design of experiments (DoE) approach using an L09 orthogonal array was employed to systematically evaluate the effects of infill density, infill pattern, and print speed on the tensile behavior of FDM-printed PLA components. Findings reveal that higher infill densities (90%) and hexagonal patterns significantly enhance yield strength, ultimate tensile strength, and stiffness. Additionally, the rheological properties of polydimethylsiloxane (PDMS) were optimized at various temperatures (30–70 °C), characterizing its viscosity, shear-thinning factors, and stress behaviors for 3D bioprinting of flexible sensors. Barium titanate (BaTiO₃) was incorporated into PDMS to fabricate a flexible tactile sensor, achieving reliable open-circuit voltage readings under applied forces. Structural and functional components of the finger prosthesis were fabricated using FDM, stereolithography (SLA), and extrusion-based bioprinting (EBP) and assembled into a functional prototype. This research demonstrates the feasibility of integrating hybrid materials and advanced printing methodologies to create cost-effective, high-performance prosthetic components with enhanced mechanical properties and embedded sensing capabilities. Full article

The ultrasonic guided wave method is successfully used for structural health monitoring (SHM) of aircraft structures utilizing PZT (Pb-Zr-Ti based piezoceramic material) sensors for guided wave generation and detection. To increase the mechanical durability of the sensors in operational conditions, this paper demonstrates the feasibility of the integration of PZTs into the Glass fiber/Polymethyl methacrylate (G/PMMA) composite plate and evaluates the possibility of impact damage detection using generated guided waves. Two types of PZT sensors were embedded into different layers during the manufacturing process. Generally, radial mode disc sensors are used for Lamb wave generation, and thickness-shear square-shaped sensors are used for both Lamb and shear wave generation. First, the wave propagation was analyzed considering the sensor type and sensor placement within the layup. The main objective was to propose the optimal sensor network with embedded sensors for successful impact damage detection. Lamb wave frequency tuning of disk sensors and unique vibrational characteristics of integrated shear sensors were exploited to selectively actuate only one guided wave mode. Finally, the Reconstruction Algorithm for the Probabilistic Inspection of Damage (RAPID) was utilized for damage localization and visualization. Full article

This study investigated the use of oscillating laser welding with Cu, Mo, and Nb interlayers to mitigate the issue of brittle intermetallic compound (IMC) formation in titanium-steel dissimilar welding for TC4/304SS lap joints. This study systematically examined the influence of interlayer type on joining mechanisms, microstructure, and mechanical properties. Results indicated that direct welding produced Ti-Fe IMCs (TiFe phase) through fusion, resulting in a thick brittle layer. The Cu interlayer facilitated fusion welding while promoting the formation of TiFe₂ and TiCu₄ phases. Mo and Nb interlayers, through fusion-brazing and brazing mechanisms, respectively, inhibited Ti-Fe IMCs by generating Fe-Mo/Nb IMCs and (Ti, Mo/Nb) solid solutions. Mechanical testing indicated that Mo-interlayer joints exhibited the highest shear strength at 1129.53 N, representing a 31% increase relative to direct joining. This was followed by Nb at 1004.4 N, Cu at 871.6 N, and direct welding at 859.13 N. Fracture transitioned from brittle IMC layers in Cu and direct welding to interfaces between interlayers and TC4 in Mo and Nb systems. This study presents Mo/Nb interlayers as the most effective choice for high-strength Ti-steel joints, providing insights for the selection of interlayers in engineering applications. Full article

The exploration of chalcogenides is on the rise owing to their desirable optical, electronic, thermoelectric, and thermal properties. Chalcogenide materials have been investigated for possible applications in areas such as non-linear optics and solar cells. Among these materials are BaTiS₃ and BaTiSe₃. BaTiS₃ has shown promise in the above-mentioned applications due to its low thermal conductivity. However, neither the thermal properties of BaTiSe₃ nor the mechanical properties of both BaTiS₃ and BaTiSe₃ have been reported. In this work, we performed a computational study of the mechanical and thermal properties of both materials within the density functional theory using Quantum Espresso and BoltzTrap2 codes, employing generalized gradient approximation. The results showed that the computed thermal conductivity of BaTiS₃ at 0.43 W/m/K is comparable to the literature values. The computed elastic constants of BaTiS₃ (bulk modulus of 44.7 GPa, shear modulus of 11.2 GPa, Young’s modulus of 29.6 GPa, and Vickers hardness of 1.053 GPa) were higher than those of BaTiSe₃. The calculated properties obtained in this work add to the literature on the properties of BaTiS₃ and BaTiSe₃. However, since the work was computational, the results can be verified by an experimental investigation. Full article