Search Results (196)

Records of recent past climate provide an essential window into understanding how changing climate influences environments and ecosystems such as lakes, which provide essential resources and services. Sediment carbon and nitrogen chemistry can offer insight into productivity and biochemistry, and anoxic sediments in particular can often preserve short-term changes in these signals. We used a decade-long compilation of sediment and environmental data from Middle Island Sinkhole, an anoxic sinkhole in Lake Huron, to investigate their interannual variability. We found that seasonal and annual changes in local ice season, chlorophyll, and precipitation influenced the amount and isotopic composition of carbon reaching and being recycled within the sediments. Carbon and nitrogen signals reflected the year or season of sample collection in sediments as deep as 12 cm, while the shallowest sediments were dominated by the influence of microbial mats. Our findings demonstrate that seasonal dynamics in surface water in this part of the Great Lakes are leading to increased export of organic carbon and nitrogen into sediments, but that in situ sediment processes may make teasing out short-term changes from sediment cores difficult even in an anoxic setting. These results emphasize the importance of winter conditions as a driver of short-term lacustrine carbon and nitrogen cycling in sediments and the water column. Full article

Polycyclic aromatic hydrocarbons (PAHs) represent a major class of ubiquitous environmental pollutants, posing significant risks to ecosystems and human health due to their persistence, toxicity, and potential for bioaccumulation. This review provides a comprehensive synthesis of current scientific knowledge on PAHs, integrating insights from chemical kinetics, environmental fate, and toxicological mechanisms. The fundamental structural chemistry of PAHs and its direct influence on their physicochemical properties and environmental properties are discussed. The major anthropogenic and natural sources of PAHs are detailed, alongside the chemical kinetics behind their formation during incomplete combustion and their transformation in environmental media. Unlike previous reviews that address PAH sources, remediation, or health effects as separate topics, this review uniquely traces the mechanistic continuum from molecular formation kinetics through physicochemical partitioning and environmental transport to toxicological endpoints, providing a causally linked framework for understanding how structural properties ultimately determine biological outcomes. A central focus is placed on the environmental fate and transport of PAHs across atmospheric, aquatic, and terrestrial compartments, highlighting processes such as gas–particle partitioning, sediment accumulation, and long-range transport. The review further elucidates the complex toxicological pathways of PAHs, including metabolic activation to reactive intermediates, DNA adduct formation, oxidative stress, and their roles in carcinogenesis and other systemic health effects. The analysis reveals strong scientific consensus on the carcinogenic mechanism of parent PAHs via CYP450-mediated metabolic activation to diol-epoxide intermediates while identifying critical areas of uncertainty: the current regulatory framework based on 16 priority PAHs underestimates total carcinogenic risk by a factor of 2–5, mixture toxicology remains poorly characterized, and dose–response relationships for non-cancer endpoints (cardiovascular, neurodevelopmental, immunotoxic) lack the quantitative data needed for robust risk assessment. Finally, human exposure pathways and health risk characterization approaches are discussed, highlighting the need for cumulative, mixture-based assessment frameworks. Full article

Arsenic represents a ubiquitous element in the environment, characterized by high mobility, complex chemical speciation and a strong sensitivity to redox conditions and biological activity, with microbial processes play a central role in its biogeochemical cycling. The present review provides a comprehensive and integrative synthesis of arsenic biogeochemical cycling across terrestrial, freshwater and marine environments, in which chemical speciation is explicitly treated as the central unifying concept controlling arsenic mobility, transformation and bioavailability, linking geological, chemical and biological processes across environmental compartments. Natural processes regulating arsenic distribution are examined from mineralogical sources and soil–water interactions to biologically mediated transformations in aquatic and marine biotic compartments, largely driven by microbial activity, highlighting the contrast between inorganic arsenic dominance in abiotic reservoirs and the prevalence of organoarsenicals in tissues of living organisms. The review further explores arsenic behaviour under natural environmental alterations and in extreme or unconventional ecosystems, where redox constraints, sulphide chemistry or intense fluid–sediment exchanges lead to deviations from the baseline speciation patterns. Against this framework, anthropogenic perturbations are discussed through several documented case studies, illustrating how industrial releases, the long-term effects of mining activities, agricultural practices and the use of synthetic arsenical compounds may change arsenic pathways primarily by altering geochemical and biological controls rather than through a generalized increase in total arsenic content. Overall, the topics covered provide an integrated framework for interpreting arsenic dynamics across environmental systems, emphasizing the complex biogeochemical processes governing arsenic cycling. Full article

Marginal lacustrine systems are highly sensitive archives of hydrological fluctuations, climatic variability, and changes in sediment supply in continental basins. The Alagöz Formation (Late Miocene–Pliocene) exposed in the Haymana–Polatlı Basin, Central Anatolia, was investigated through integrated sedimentological, mineralogical, geochemical, and stable isotope analyses to constrain provenance, weathering history, and lacustrine hydrological variability. Facies analysis reveals a transition from alluvial–fluvial systems to a shallow marginal lacustrine environment subjected to short-term hydrological fluctuations. Mineralogical and geochemical data indicate that sedimentation occurred within a mixed carbonate–siliciclastic lacustrine system controlled by variable lake-water chemistry. Detrital mineral assemblages indicate contributions from metamorphic source rocks. Trace-element and REE signatures suggest derivation mainly from felsic-to-intermediate continental sources. Reworked carbonate fragments and fossil debris indicate recycling of older carbonate units. The occurrence of calcite, dolomite, and protodolomite reflects variable Mg/Ca ratios, whereas clay mineral assemblages record shifts between detrital input during relatively humid phases and chemically concentrated conditions. Palygorskite occurrence indicates localized and episodic alkaline conditions associated with short-lived evaporative concentration. Weathering indices (CIA, CIW, PIA, and ICV) suggest low-to-moderate chemical weathering and compositionally immature sediments, consistent with transitional humid to semi-arid climatic conditions. Trace-element systematics also indicate a minor mafic contribution to the detrital source. Stable isotope values (δ¹³C: −7.05‰ to +2.82‰; δ¹⁸O: −8.60‰ to −2.94‰ VPDB) and their weak correlation (r = 0.34) support a shallow, hydrologically dynamic lacustrine system dominated by freshwater input but episodically influenced by evaporative concentration. Taken together, the Alagöz Formation records a sensitive marginal lacustrine system shaped by short-term hydrological fluctuations. These findings provide a useful analog for understanding hydrologically sensitive marginal lacustrine systems developed in post-collisional continental basins under fluctuating semi-arid climatic conditions. Full article

Freshwater sediments play a central role in regulating methane (CH₄), carbon dioxide (CO₂) and nitrous oxide (N₂O) dynamics, yet the biogeochemical constraints shaping their short-term responses to redox change remain poorly resolved. Here, we used controlled aerobic and anaerobic slurry incubations of natural lake sediments to identify the environmental drivers governing early-stage greenhouse gas (GHG) dynamics. CH₄ exhibited minimal variation and no significant differences between live and sterilized treatments, indicating that methane turnover during the first hours of incubation is constrained primarily by rapid geochemical adjustments rather than by detectable microbial activity. In contrast, CO₂ and N₂O displayed clear biotic signals consistent with fast-responding respiratory and nitrogen-reducing processes. Across multivariate analyses and Random Forest models, redox-sensitive solutes (Fe³⁺, Fe²⁺, NO₃⁻, SO₄²⁻), together with dissolved organic carbon and NH₄⁺, emerged as key components of the biogeochemical framework structuring early GHG responses, highlighting coupled C–N–Fe controls on short-term gas dynamics. Microbial community analyses revealed the presence of methanogenic archaea (e.g., Methanomicrobiales, Methanofastidiosales), aerobic methanotrophs (Methylomonadaceae, Methylococcaceae) and nitrogen-transforming bacteria; however, their functional expression was limited during the short incubation period. Our results demonstrate that the earliest CH₄, CO₂ and N₂O responses in lake sediments are governed predominantly by rapid geochemical processes that regulate electron-acceptor availability and substrate chemistry, while microbial community composition plays a secondary role at short timescales. Full article

Polluted mangroves are ecologically sensitive habitats that provide ecosystem services. In a selected polluted forest of Simaisma, viable aerobic, halophilic, and heterotrophic hydrocarbon-degrading bacterial strains were isolated from both rhizosphere and non-rhizosphere regions. The chemical composition of sediment showed a clear distinction between the rhizosphere and non-rhizosphere sites, as well as coastal and non-coastal sediments, as per Principal Component Analysis (PCA) clustering. Anthracene, an indicator of oil pollution, was present along with vanadium, another marker of oil pollution. Through selective enrichment cultures, a total of 25 hydrocarbon-degrading bacterial strains were isolated, including Lysinibacillus xylanilyticus, Bacillus cereus, Lysinibacillus sphaericus, Pseudomonas stutzeri, Acinetobacter calcoaceticus, and Staphylococcus warneri. To link the adaptation of bacteria to sediment chemistry, nine B. cereus strains were investigated using their MALDI-TOF MS protein profiles combined with their dendrogram. The relationship between protein profiles of B. cereus strains with their biosurfactant production capabilities was explained by a tanglogram. The tanglegram suggests that biosurfactant production is an important functional trait in B. cereus, but it is not consistently reflected in the overall protein profile. This suggests that bacterial adaptation in the polluted mangrove sediments may involve changes at multiple cellular levels, including metabolic activity and variation in protein expression profiles. These findings confirm the involvement of mangrove-associated bacteria in the sustainability of mangrove forests by promoting bioremediation of oil pollution, thereby protecting coastal ecosystems and their environmental and socio-economic aspects. Full article

Neoproterozoic iron formations (NIFs), deposited during Cryogenian glaciation events, are critical for understanding early Earth oxidation events and the evolution of glacial–interglacial environments. Apatite, a common accessory mineral in iron formations, holds significant implications for sedimentary environments and diagenetic processes, but these aspects remain underexplored. This study focuses on the Hengyang NIF in the Nanhua Basin, South China. Using whole-rock geochemistry and major and trace element analysis of apatite, we investigate the environmental significance of apatite and associated diagenetic processes. Our results show that the Hengyang NIF are formed through the mixing of low-temperature hydrothermal fluids, seawater, and terrigenous detrital materials, with hydrothermal contributions increasing progressively from the bottom to the top of the iron formation layers. Whole-rock geochemical proxies indicate that the depositional water column evolved from relatively oxidizing to weakly oxidizing conditions. The study further demonstrates that the rare earth element patterns in apatite, characterized by middle rare earth element enrichment, are primarily controlled by porewater chemistry during diagenesis. In contrast, Ce anomalies and the V/Cr and V/(V + Ni) ratios in apatite, which are strongly influenced by fluid–rock interactions and magnetite recrystallization, no longer reliably reflect the primary depositional environment. The Th/U ratio in apatite, due to its geochemical stability, aligns with whole-rock trends and serves as a more reliable redox proxy. Based on these findings, we propose a three-stage depositional-diagenetic model: the early and late stages are characterized by high-energy, rapid sedimentation with minimal diagenetic modification, while the middle stage is dominated by low-energy, stagnant conditions with slow sedimentation rates, leading to prolonged diagenesis and significant decoupling of mineral geochemical signatures. This study emphasizes the need to distinguish between sedimentary and diagenetic signals when using mineral geochemical proxies to reconstruct paleoenvironments and provides new insights into the genesis of Neoproterozoic iron formations. Full article

The reconstruction of detrital flux, paleoclimate, paleosalinity, paleo-primary productivity, paleohydrodynamic conditions, and paleo-water depth enhances understanding of sedimentary processes and their drivers during deep-time greenhouse-icehouse transitions, such as the Eocene–Oligocene transition. This study uses detailed geochemical analyses of major oxides and trace elements in sediment samples collected from the Beni Suef Formation (Bartonian–Priabonian) and the Maadi Formation (Priabonian) in the southern Tethys shelf (Egypt, northeastern Desert). Detrital proxies, including Si/Al, Ti/Al, and Zr/Al, indicate an enhanced influx of terrigenous sediments in the middle portion of the Qurn Member of the Beni Suef Formation, as further supported by noticeable facies variations, particularly the transition from shale to coarser silt- and sand-sized fractions. Paleoclimate indicators (Sr/Ba, Rb/Sr, K₂O/Al₂O₃, and Sr/Cu) point to a climatic shift from humid to arid conditions, consistent with the regional Late Eocene aridification across the Tethyan realm. Paleosalinity proxies (Sr/Ba, Ca/Al, and Mg/Al×100) suggest episodic intensification of open-marine influence and a reduction in freshwater input, with an upsection increase in Sr/Ba ratios, reflecting phases of enhanced marine water settings or decreased terrestrial runoff. Primary productivity was evaluated using multiple geochemical proxies, including P, Ni/Al, Cu/Al, P/Al, P/Ti, and Babio ratios. These collectively indicate generally low primary productivity interrupted by intervals of enhanced paleoproductivity or increased organic matter export to the sediments. This interpretation is further supported by the low total organic carbon (TOC) values. These results highlight the sensitivity of the southern Tethys shelf to Middle–Late Eocene climatic variability and the key role of prevailing paleoenvironmental conditions in controlling sediment supply, water chemistry, and biological productivity. Full article

The growing demand for environmentally responsible lubricants motivates the use of bio-based base stocks and benign solid additives. This study assesses the tribological performance of two Amazonian vegetable oils, Carapa guianensis (andiroba) and Copaifera spp. (copaiba resin) and a paraffinic mineral oil (PNL30) formulated with different zinc oxide (ZnO) particles, namely nanocrystals and microcrystals, at 0.01, 0.05, and 0.10 wt.%. Reciprocating sliding tests, coupled with 3D profilometry, viscosity, and sedimentation analyses, were used to link dispersion stability with friction and wear responses. A preliminary stability screening constrained the practical loading window to ≤0.10 wt.% for reproducible suspensions. Performance depended on the interplay between particle type and base-oil chemistry. Andiroba exhibited the most pronounced gains, with ZnO microcrystals near 0.05 wt.% delivering the best friction outcomes and the largest wear reductions (up to ~35%). In copaiba resin oil, nanocrystals produced small, sometimes non-significant improvements, whereas microcrystals tended to worsen wear consistent with abrasive third-body effects in a less polar matrix. In PNL30, the overall benefits were modest: nanocrystal additions generally increased wear, whereas microcrystals particularly at the highest loading 0.10 wt.% achieved a 36.4% reduction in SWR, representing a measurable and statistically significant improvement in wear resistance. These results highlight that eco-efficient lubricant design should co-optimize particle characteristics and dosage with base-oil polarity and film-forming tendencies, prioritizing dispersion stability alongside tribological targets. Full article

Stream sediments can provide extensive information about rocks from their catchments. Heavy mineral concentrates from stream sediments could be used during regional targeting when exploring for a range of different deposit types. Here, we present an example of using mineral chemistry coupled with U/Pb geochronology for zircons, titanites, and rutiles from a regional stream sediment study in Yukon with implications for porphyry Cu and orogenic Au deposit exploration in the region and globally. In this region, the location of the porphyry Cu deposit was determined based on rutile compositions, while an orogenic Au signature was identified primarily in titanite and rutile chemistry. The locations identified based on stream sediment mineral chemistry corresponded to the approximate locations of the Casino porphyry Cu and Coffee orogenic Au deposits. Other potential targets for follow-up exploration are also highlighted. This study accentuates that the addition of trace element mineral chemistry and U/Pb geochronology analyses to an exploration program provides substantial benefits in terms of constraining the ages of basement and host rocks and prioritising targets. The application of heavy mineral chemistry from stream sediments used for regional-scale targeting, followed by rock chip sampling and analysis at the camp scale, can provide significant exploration results, as demonstrated in this study. Full article

Understanding the environmental pathways and surface modification of beach sand grains is essential for reconstructing coastal dynamics and assessing the suitability of natural sands for engineering applications. This study applies a multiproxy approach—integrating grain roundness classification, SEM microtextural analysis, and XPS surface chemistry—to beach sediments from four coastal sectors of Latvia: Liepaja, Ventspils, Riga, and Salacgrīva. The results reveal clear spatial differences in grain maturity, abrasion signatures, biological imprinting, and nanoscale surface composition. Liepaja is characterised by sub-rounded to rounded grains with abundant percussion pits and abrasion surfaces, indicating prolonged high-energy wave reworking. Ventspils retains angular grains with fresh conchoidal fractures, reflecting rapid sediment renewal from glacial and coastal sources. Riga exhibits weak abrasion and hydrated particulate coatings typical of low-energy brackish environments. Salacgrīva displays strong fluvial influence, including persistent diatom and algal microtextural features and elevated oxygenated carbon and metal-associated XPS signals. These findings demonstrate strong coupling between grain-surface microtextures and surface chemistry and reveal distinct sedimentary fingerprints linked to environmental setting. The multiproxy framework presented here improves understanding of Baltic coastal sediment pathways and provides a preliminary basis for future evaluation of natural sands in filtration and other environmental engineering applications. Full article

Diatoms are key primary producers and sensitive indicators in polar freshwater ecosystems, responding to environmental change. This study investigates diatom species richness and the influence of environmental variables in fourteen coastal lakes on King George and Horseshoe Islands in the Maritime Antarctic. Water and surface sediment samples collected in 2017, 2019, and 2020 were analyzed using light and scanning electron microscopy, revealing 83 taxa (species and genera combined) across all lakes except one. King George Island exhibited higher species richness, with frequent occurrences of Planothidium lanceolatum, Fragilaria cf. capucina and Nitzschia cf. homburgiensis. On Horseshoe Island, common taxa included Achnanthes, Achnanthidium, Fragilaria, Nitzschia, Navicula, and Gomphonema. Among the previously measured water chemistry variables, HCO₃⁻ (ρ = 0.78, p = 0.005) and K+ (ρ = 0.69, p = 0.019) showed the strongest positive correlations with diatom species richness. Major ions and nutrients, as well as dissolved oxygen, salinity, and pH, exhibited moderate relationships. In contrast, temperature and trace metals displayed weak or negligible correlations, suggesting indirect influences on diatom diversity. These findings demonstrate that diatom communities in the Maritime Antarctic lakes are diverse and are shaped by variations in water chemistry, underscoring the ecological sensitivity of these freshwater ecosystems. Full article

Tropical cyclones can rapidly alter watershed chemistry by shifting hydrologic pathways and mobilizing stored nutrients, yet these disturbances often remain undetected when storms cause little visible flooding or geomorphic damage. During Hurricane Helene 2024, intense rainfall across the Oconee River watershed in Georgia generated sharp increases in discharge that triggered substantial nutrient export despite minimal physical alteration to the landscape. High-frequency measurements of nitrate, phosphate, and sulfate in urban, forested, and recreational settings revealed pronounced and synchronous post-storm increases in all three solutes. Nitrate showed the strongest and most persistent response, with mean concentrations increasing from approximately 1–3 mg/L during pre-storm conditions to 6–14 mg/L post-storm across sites, and remaining elevated for several months after hydrologic conditions returned to baseline. Phosphate concentrations increased sharply during the post-storm period, rising from pre-storm means of ≤0.3 mg/L to a post-storm average of 1.5 mg/L, but declined more rapidly during recovery, consistent with sediment-associated mobilization and subsequent attenuation. Sulfate concentrations also increased substantially across the watershed, with post-storm mean values commonly exceeding 20 mg/L and maximum concentrations reaching 41 mg/L, indicating sustained dissolved-phase release and enhanced temporal variability. Recovery trajectories differed by solute: phosphate returned to baseline within weeks, nitrate declined gradually, and sulfate remained elevated throughout the winter. These findings demonstrate that substantial chemical perturbations can occur even in the absence of visible storm impacts, underscoring the importance of event-based, high-resolution monitoring to detect transient but consequential shifts in watershed biogeochemistry. They also highlight the need to better resolve solute-specific pathways that govern nutrient mobilization during extreme rainfall in mixed-use watersheds with legacy nutrient stores and engineered drainage networks. Full article

The South Sakhalin mud volcano (Sakhalin Island, Russia) emits HCO₃-Cl/Na-Mg water, emanates CO₂ prevailing over CH₄ in the gas phase, and extrudes mud bearing five carbonate mineral species. The study focuses on the distribution, diversity, and origin of the carbonate minerals from the mud volcano (MV) ejecta, in terms of carbon cycle processes. The data presented include a synthesis of field observations, compositions of MV gases and waters, chemistry of carbonate minerals, as well as stable isotope geochemistry of MV waters (δ¹³C, δD, and δ¹⁸O) and carbonates (δ¹³C and δ¹⁸O). The sampled MV waters are isotopically heavy, with δ¹⁸O = +5.7‰ to +7.5‰ VSMOW, δD = −18.0‰ to −11.0‰ VSMOW, and ¹³C (δ¹³C_DIC = +6.9‰ to +8.1‰ VPDB). This composition may be due to the dilution of basinal water with dehydration water released during the diagenetic illitization of smectite. Carbonates in the sampled mud masses belong to three genetically different groups. Mg-rich siderite, (Fe_0.54–0.81Mg_0.04–0.30Ca_0.05–0.23Mn_0.00–0.08)CO₃, disseminated in abundance throughout the mud masses, coexists with common calcite and sporadic ankerite. The trace-element chemistry of Mg-siderite, as well as the oxygen (δ¹⁸O = +34.4‰ to +36.8‰ VSMOW) and carbon (δ¹³C = −1.3‰ to +0.6‰ VPDB) isotopic signatures, confirms its authigenic origin. Siderite formed during early diagenesis of the Upper Cretaceous sandy and clayey marine sediments mobilized by mud volcanism in the area. Another assemblage, composed of dawsonite, siderite, and vein calcite (±kaolinite), represents altered arkose sandstones found as few fragments in the mud. This assemblage may be a marker of later CO₂ flooding into the sandstone aquifer in the geological past. The trace-element chemistry, particular morphology, and heavy C (δ¹³C = +5.5‰ to +7.0‰ VPDB) and O (δ¹⁸O = +39.1‰ to +39.5‰ VSMOW) isotope compositions indicate that aragonite is the only carbonate species that is related to the current MV activity. It crystallized in a shallow reservoir and was maintained by CO₂ released from rapidly ascending liquefied mud and HCO₃-Cl/Na-Mg-type of MV waters. Full article

The valorization of dredged sediments represents a major environmental and logistical challenge, particularly in the context of forthcoming regulations restricting their marine disposal. This study investigates the potential of untreated dredged sediments as sustainable raw materials for geopolymer binder development, with the dual objective of sustainable sediment management and reduction in cement-related environmental impact. Dredged sediments from the Grand Port Maritime de Bordeaux (GPMB) were activated with sodium hydroxide (NaOH) and sodium silicate (Na₂SiO₃), both alone and in combination, with supplementary aluminosilicate and calcium-rich co-products, to assess their reactivity and effect on binder performance. A multi-scale experimental approach combining mechanical testing, calorimetry, porosity analysis, Scanning Electron Microscopy and Energy-Dispersive Spectroscopy (SEM–EDS), X-ray diffraction (XRD), Thermogravimetric Analysis (TGA), and solid-state Nuclear Magnetic Resonance (NMR) was employed to challenge the commonly assumed inert behavior of sediments within geopolymer matrices, to elucidate gel formation mechanisms, and to optimize binder formulation. The results show that untreated sediments actively participate in alkali activation, reaching compressive strengths of up to 5.16 MPa at 90 days without thermal pre-treatment. Calcium-poor systems exhibited progressive long-term strength development associated with the formation of homogeneous aluminosilicate gels and refined microporosity, whereas calcium-rich systems showed higher early age strength but more limited long-term performance, linked to heterogeneous gel coexistence and increased total porosity. These findings provide direct evidence of the intrinsic reactivity of untreated dredged sediments and highlight the critical role of gel chemistry and calcium content in controlling long-term performance. The proposed approach offers a viable pathway for low-impact, on-site sediment valorization in civil engineering applications. Full article