Search Results (182)

Located in the northeastern Tibetan Plateau, the Qaidam Basin hosts abundant strategic lithium (Li) and boron (B) salt lake resources crucial for national resource security. Existing studies focus on individual lakes, lacking systematic Li-B geochemical and source–transport–sink research across the geothermal–river–lake system. Based on 40 water samples from 16 lakes and multi-isotope and hydrochemical data, this study explores Li-B spatial distribution, isotopic evolution and enrichment rules. The results reveal prominent spatial heterogeneity of Li and B distributions. The contents of riverine Li and B are higher than the global average level, and terminal salt lakes show the highest enrichment degree. Specifically, southern lakes are Li-dominant, while northern lakes are B-dominant, with both reaching industrial exploitation grades. Significant Li and B isotopic fractionation occurs throughout the hydrological system, with geothermal fluids presenting depleted isotopic compositions and lake waters showing enriched features. H-O isotopic evidence and Gibbs diagram analysis indicate that surface waters in the basin are primarily recharged by atmospheric precipitation, and their hydrochemical compositions are jointly controlled by rock weathering and strong evaporative concentration, accompanied by distinct north–south hydrogeological zonation differences. Source analysis demonstrates that Li is mainly derived from high-temperature water–rock interactions of Li-rich volcanic and granitic rocks in the southern East Kunlun Mountains, whereas B originates from ultrahigh-pressure B-rich metamorphic rocks along the northern North Qaidam margin. The migration and accumulation sequence of Li and B follows the pathway: geothermal fluid emission → fluvial transportation → terminal lake enrichment. Evaporation and mineral precipitation are the dominant factors controlling elemental enrichment and isotopic fractionation. This basin-wide study supplements salt lake critical mineral metallogenic theories and guides efficient Li-B exploration and sustainable development. Full article

Quantifying the net hydrological impact of large dams amidst climatic and anthropogenic influences remains a major challenge. This study isolates the effect of Three Gorges Dam (TGD) regulation on discharge at Jiujiang Station in the middle Yangtze River (2009–2016) using a novel scenario-based framework. A Long Short-Term Memory (LSTM) network, optimized by the Sparrow Search Algorithm (SSA), simulated daily discharge with high accuracy (Nash–Sutcliffe Efficiency coefficient > 0.97). By comparing a “with-TGD” simulation against a “without-TGD” scenario—generated by replacing the dam’s regulated outflow with its reconstructed natural inflow—we quantified the net impact ($\Delta Q$). Results show that $\Delta Q$ is substantially modulated by river–lake interactions. For example, in December, the backwater effect from Poyang Lake amplified the direct flow reduction by an additional −82.5 m³/s. The “peak-shaving” effect was context dependent: TGD regulation increased high flows (>30,870 m³/s) by an average of +372 m³/s while slightly decreasing low flows (<12,711 m³/s) by −31 m³/s. The impact exhibits strong seasonality alongside considerable intra-seasonal variability, reflecting multi-objective operations (flood control, power generation, water supply). This framework provides a transferable approach for attributing hydrological change in large regulated rivers and supports integrated water resources management. Full article

The middle–lower Huaihe River Basin faces persistent flood and waterlogging threats, with river–lake interactions being a critical yet underexplored factor constraining flood discharge capacity. This study investigates the flood discharge capacity and erosion–deposition dynamics in the Bengbu–Hongze Lake reach and proposes sustainable management solutions. By analyzing long-term hydrological data (1954–2020) and cross-sectional measurements (1971–2025), we quantified changes in channel morphology and flood behavior. The results reveal that while upstream inflow has remained stable (annual runoff 20.5–33.3 billion m³), sediment concentration has continuously declined by approximately 80%—from 0.474 kg/m³ in the 1950s to 0.094 kg/m³ in the 2020s. The main channel exhibits persistent incision totaling 135.7 × 10⁶ m³, while floodplains have undergone progressive aggradation of 35.1 × 10⁶ m³, reflecting a sediment-starved river system in geomorphic disequilibrium. Critically, the riverbed leading to Hongze Lake exhibits an adverse slope, rising from –10 m at Fushan to over +9 m at Laozishan, while the lake’s sedimentation has reduced its storage capacity by 29% since the 1980s (from 31.27 × 10⁸ m³ to 22.15 × 10⁸ m³). Despite extensive engineering interventions, significant issues persist—including the backwater effect of Hongze Lake, prolonged high water levels during moderate floods (in 2020, water level at Fushan reached 18.34 m at only 61% of the design discharge), and exacerbated waterlogging in riparian lowlands. Therefore, we advocate for a paradigm shift towards a river–lake separation scheme, specifically, an inner-lake embankment approach. This nature-based solution aims to restore the river’s physical structure and harness its self-shaping morphological function for long-term flood management and ecological sustainability. Our findings provide a quantitative basis for re-evaluating the river–lake relationship and offer a strategic direction for sustainable flood management in highly altered alluvial river systems. Full article

Black soil degradation poses critical threats to agricultural sustainability and global food security, yet systematic frameworks integrating ecological security assessment, driver identification, and forward-looking early warning remain underdeveloped for black soil watersheds. This study develops and implements a comprehensive assessment–interpretation–early warning framework for the Xingkai Lake Basin, a representative black soil region at the China–Russia border. We developed a multivariate ecological security index (MESI) to describe the spatiotemporal dynamics between 2000 and 2023. An XGBoost–SHAP framework was applied to quantify dominant drivers of ecological security spatial heterogeneity and examine synergistic effects among driving factors through geographical detector interaction analysis. A Bayesian network model was subsequently employed to simulate the probability of warning grade occurrence under multiple univariate and multivariate scenarios. Findings revealed the following: (1) Spatial analysis revealed persistent north–south differentiation, with high spatial association zones contracting from 25% to 21% despite strengthened global spatial auto correlation. (2) XGBoost–SHAP driver analysis quantified that land use intensity and landscape fragmentation collectively explained over 75% of spatial heterogeneity in MESI. (3) BN models demonstrated greater sensitivity in simulating no warning and severe warning levels. This study provides scientifically rigorous insights into the sustainable management of ecosystems in black soil river basins and offers a generalizable decision-support framework for conducting ecological safety early warning research in other regions facing similar agricultural pressures. Full article

River morphological changes significantly influence water purification functions; however, systematic research on the evolution of natural river morphology and its underlying mechanisms remains insufficient. This study investigates the Shiwuli River, a typical tributary of Chaohu Lake, by quantitatively analyzing its morphological evolution characteristics based on high-resolution satellite imagery from 2014 to 2024. Combined with field monitoring data from all four seasons of 2024, the study explores the influence mechanisms of river sinuosity, cascade flow, and wetlands on water purification. The results indicate significant morphological changes in the Shiwuli River: the total length decreased by 3.95 km, sinuosity decreased by 0.22, and the average width increased by 27.85 m. The comprehensive attenuation coefficient of pollutants in the monitored sections was consistently greater than zero, demonstrating the self-purification capacity of the natural meandering river, with the highest purification capacity observed in summer and the weakest in winter. Dissolved oxygen (DO) content was generally higher in concave banks than in convex banks, and the rate of increase in DO per unit length rose with increasing sinuosity. The cascade flow formed by rolling dams significantly enhanced DO concentration (by 19.23–26.25%), with average pollutant reduction rates ranging from 12.64% to 33.76%. The wetland sections exhibited average reduction rates of 79.07% for total phosphorus (TP), 39.33% for total nitrogen (TN), 47.43% for ammonia nitrogen (NH₃-N), and 45.67% for chemical oxygen demand (COD), demonstrating significantly better purification effects compared to the main river channel. This study reveals that the synergistic interaction among river sinuosity, cascade flow, and wetland systems enhances the water body’s self-purification capacity, providing a scientific basis for river ecological restoration and sustainable utilization of water resources. Full article

Climate change and rapid urbanization increasingly threaten water security in large river basins, yet existing assessments often fail to capture the multi-scale interactions between hydroclimatic extremes and human activities. To address this gap, we developed an integrated framework combining risk assessment, multi-method driver diagnosis (Geodetector, Multi-Scale Geographically Weighted Regression (MGWR), and Structural Equation Modeling (SEM)), and Zoned Management. Using a landscape-derived Ecological Risk Index (ERI) as a proxy indicator of runoff and non-point source potential, based on established empirical linkages between landscape metrics and hydrological processes, we applied the framework to three major urban agglomerations in the Yangtze River Basin from 2000 to 2020. Our results reveal three distinct risk mechanisms: in the Chengdu–Chongqing area (CYUA), a 165.8% increase in impervious surfaces drives altered runoff; in the Middle Reaches (MRC), the q-value of the Standardized Precipitation Index (SPI) rose from 0.017 in 2000 to 0.146 in 2020, corresponding to a 759% relative increase. Although the absolute q-value of SPI remains moderate at around 0.15, its rapid rise suggests increasing hydrological sensitivity of the MRC’s river–lake system to precipitation extremes; in the Yangtze River Delta (YRD), socioeconomic activities exert overriding pressure. Based on these diagnostics, we propose tailored strategies for water environment management, adaptive planning, and disaster mitigation. This framework offers a scientific basis for differentiated water governance in large river basins facing coupled anthropogenic and hydroclimatic pressures. Full article

Rapid urbanization, climate change, and uneven regional development have increasingly intensified spatial heterogeneity in food security. As one of China’s major commercial grain-producing areas, the Main Grain-Producing Region in the Middle Reaches of the Yangtze River (MGPR-MRYR) plays a critical role in ensuring national food security. However, existing studies have paid limited attention to spatial heterogeneity and driving mechanisms at the urban agglomeration scale. Taking the Wuhan (WUA), Changsha–Zhuzhou–Xiangtan (CZXUA), and Poyang Lake (PYLUA) urban agglomerations as analytical units, this study constructs a multidimensional food security evaluation framework covering supply security, production resource security, and circulation–consumption security. Based on panel data from 2013 to 2023, the entropy weight method, kernel density estimation (KDE), Theil index decomposition, spatial autocorrelation analysis, and the optimal-parameter geographical detector (OPGD) model were employed. Food security levels in the MGPR-MRYR exhibited an overall upward trend, particularly after 2020, although significant spatial heterogeneity persisted among urban agglomerations. A spatial pattern of “higher in the west than east, and inland over lakeside” emerged, with significant positive clustering gradually expanding westward. Intra-agglomeration disparities—especially within the WUA—contributed more to regional inequality than inter-agglomeration differences. Agricultural machinery power and rural population remained the dominant driving factors, while the influence of urbanization and annual precipitation increased over time. All factor interactions showed enhancement effects, indicating that food security is shaped by the synergistic interplay of natural, socioeconomic, and agricultural production factors. This study reveals the transition of driving mechanisms from traditional factor dependence to multi-factor system synergy. These findings suggest that food security governance in rapidly urbanizing grain-producing regions should shift from uniform policies to differentiated, synergy-oriented strategies tailored to each urban agglomeration’s development stage and resource constraints. Full article

To elucidate the solute sources, migration and enrichment mechanisms of water bodies in the endorheic lake region of the Qiangtang Plateau on the Tibetan Plateau and clarify the hydrogeochemical cycling patterns in alpine arid environments, this study focuses on two core scientific objectives: quantitative identification of the multi-source contributions of aquatic solutes, and revelation of the key processes governing the enrichment of strategic elements including lithium (Li) and boron (B). To achieve these goals, we conducted systematic hydrogeological field investigations and collected 28 multi-type water samples, covering springs, rivers, thermal springs, freshwater lakes, salt lake brines, atmospheric precipitation, and glacial meltwater. The physicochemical properties, major ions, and trace elements of all samples were comprehensively analyzed. On this basis, the hydrogeochemical characteristics, evolutionary processes, and solute origins of regional waters were systematically explored. Combined with PHREEQC numerical simulation, principal component analysis (PCA), and Pearson correlation analysis, the dominant controlling factors of water geochemistry were quantified, and a conceptual hydrogeochemical evolution model was established. The results reveal a clear hydrogeochemical evolutionary gradient across the study area: water bodies evolve from low-salinity HCO₃-Ca recharge end-members and transitional HCO₃·SO₄-Ca(Mg) type water to highly mineralized Cl-Na (SO₄·Cl-Na) salt lake brines, accompanied by synchronous enrichment of Li, B, arsenic (As), and other characteristic elements. Solute accumulation in regional waters is governed by the ternary coupling effects of evaporative concentration, rock weathering and leaching, and deep geothermal fluid input, while cation exchange and mineral dissolution–precipitation reactions further modulate ionic composition and ratios. Elements including As, Li, B, and chloride (Cl⁻) exhibit conservative migration behaviors in non-hydrothermal waters, whereas thermal springs possess unique geochemical signatures driven by deep fluid recharge. PCA results indicate that evaporative concentration serves as the primary controlling factor with a contribution rate of 55.39%; rock weathering provides the basic solute load (17.09%); and the coupled processes of deep fluid mixing and carbonate precipitation regulate elemental fractionation (14.21%). These findings systematically clarify the hydrogeochemical evolution laws and multi-source coupling mechanisms of inland lake waters in the Qiangtang Plateau. Furthermore, this study establishes a conceptual framework of “multi-source recharge–water–rock interaction–evaporative concentration”, advances the understanding of alpine hydrological cycling under climate change, and provides a solid scientific foundation for hydrological cycle research and green exploration of strategic mineral resources in endorheic salt lake regions. Full article

Intensive human activities are reshaping inland tail-end deltas. Based on hydrological and sediment data from 1950 to 2023 and physical model experiments, this study examines the Ganjiang tail-end delta to analyze channel evolution, driving mechanisms, and management pathways. Results indicate that the Wan’an Reservoir and large-scale sand mining are the dominant drivers of flow-sediment regime shifts and channel reshaping. Sand mining has caused severe riverbed incision, with a local maximum depth of 16.5 m. During the dry season, the flow diversion ratio of the West Branch exceeds 90%, fundamentally altering the flow distribution pattern. Although riverbed incision has enhanced local flood conveyance, the overall flood discharge capacity of the tail-end delta remains limited due to backwater from Poyang Lake, introducing new flood risks. Reduced sediment supply and hydrological changes have exacerbated wetland shrinkage and eutrophication. Physical model experiments show that the comprehensive regulation project can raise dry-season water levels by approximately 5 m through sluice operation, optimize flow diversion, and increase wetland surface water area by 56%. This project integrates flood control, ecological protection, and water resource utilization, representing a proactive exploration of adaptive management for deltas and providing scientific references for understanding evolution and guiding management in similar inland tail-end deltas. Full article

Numerical simulations quantify the transient impacts of implementing green infrastructure (GI) grass swales on unconfined aquifer storage and groundwater-surface water interactions around the Red Butte Creek (RBC) of Utah, USA. The Red Butte Creek Watershed (RBCW) transitions from undeveloped mountainous National Forest land to downstream urbanized areas within Salt Lake Valley (SLV). This reconnaissance-level study demonstrates that increasing stormwater infiltration in urbanized areas during the rainy months (April-June) can, until at least the subsequent March, (a) enhance aquifer recharge and support sustainable groundwater yields; and (b) improve surface water availability. Simulations predict hydrologic impacts of aquifer recharge resulting from hypothetical grass-swale implementation within a 704-acre area located around RBC. The employed model, HyperRBC, is an adaptation of a United States Geological Survey (USGS) transient numerical flow, MODFLOW, model implementation for SLV. Adaptations involved (a) uniformly refined horizontal discretization of seven aquifer layers within a sub-area encompassing parts of RBCW and an adjacent watershed; (b) updated input data; and (c) MODFLOW’s Streamflow-Routing (SFR) package to simulate RBC flow and aquifer-stream seepage. Model predictions indicated that by the end of next March: (a) about 3% of the GI-induced recharge would remain within the unconfined aquifer in the HyperRBC area; (b) 66.6% of the recharge would flow northward into the downgradient continuation of the unconfined aquifer; and (c) 30.3% would discharge to nearby stream and river. In summary, predicted hydrologic changes due to the short-term GI-induced recharge highlight increased groundwater availability within and outside the study area for at least the subsequent 12 months, including high-water-demand summer. These findings show the importance of GI in interim environmental management and in enhancing the effective use of water resources. Full article

The Xianglaqu River Basin, a major recharge area of the Xiagacuo endorheic lake basin on the Tibetan Plateau, provides an ideal setting for investigating hydrochemical evolution in alpine arid closed basins. In this study, 27 groundwater, spring-water, and surface-water samples collected from June to August 2023 were analyzed using correlation analysis, Piper diagrams, Gibbs diagrams, and ion-ratio methods. The results show that groundwater, spring water, and most surface water are predominantly of the HCO₃⁻–Ca·Mg type, indicating overall hydrochemical consistency across the basin. However, marked spatial differentiation occurs along the flow system: upstream waters are relatively simple and stable, whereas downstream and terminal surface waters show pronounced increases in Na⁺, Cl⁻, SO₄²⁻, and TDS, and some samples exhibit a tendency toward HCO₃⁻–Na facies. These patterns reflect progressive solute accumulation and terminal enrichment in the closed basin. Hydrochemical evolution is controlled mainly by water–rock interaction, with carbonate weathering as the dominant source of major ions, while silicate weathering, minor local saline-mineral dissolution, cation exchange, and evaporation concentration further influence water chemistry. Overall, the basin is characterized by local weathering release, along-path solute accumulation, and terminal evaporative enrichment. Full article

Shallow lakes in the Yangtze River Delta are characterized by fragile ecosystems, strong sediment–water interactions, and poor resistance to pollution shocks; they are prone to shift from macrophyte-dominated clear-water states to phytoplankton-dominated turbid states under intensive human disturbance. To improve the efficacy of aquatic ecological restoration, this study takes a typical shallow urban lake—Kuilei Lake in Kunshan—as the research object, and establishes a two-dimensional hydrodynamic and water quality model to simulate the temporal and spatial variations in flow fields, flow circulations, and water quality indicators (TP, NH₃-N, COD_Mn) throughout the year. The results are as follows: (1) The hydrodynamic regime of Kuilei Lake is dominated by wind-driven currents, with seasonal flow circulations regulating pollutant migration and the suitability for submerged macrophyte growth; (2) Intense circulations in summer (July–September) enhance sediment resuspension and endogenous nutrient release, which are unfavorable for submerged plant colonization; (3) April–June is the optimal window for ecological restoration, with a mean flow velocity of 2.0–2.5 cm/s, TP ≤ 0.06 mg/L, NH₃-N ≤ 0.20 mg/L, COD_Mn ≤ 3.0 mg/L, and water temperature of 15–25 °C, providing favorable thresholds for submerged macrophyte recovery. This study reveals the coupled hydrodynamic–water environmental thresholds for shallow lake restoration, and offers a scientific basis for flow field regulation and ecological reconstruction of shallow lakes in the Yangtze River Delta. Full article

Dissolved organic matter (DOM) plays a central role in estuarine carbon cycling and exhibits dynamically coupled interactions with chlorophyll-a (Chl-a). Under increasing nutrient loads, elevated Chl-a concentrations and shifts in DOM composition serve as key indicators of eutrophication in estuarine aquatic ecosystems. Previous studies have mainly focused on the composition and fluorescence properties of DOM in rivers and lakes. Here, 84 water samples were collected from the Ganjiang River Estuary of Lake Poyang during wet, normal, and dry seasons across the mainstream, middle, and south branches. The average Chl-a concentration showed wet season (6.61 μg·L⁻¹) > normal season (4.54 μg·L⁻¹) > dry season (2.01 μg·L⁻¹). By employing EEM-PARAFAC, five fluorescent components were identified, including C1, C2, C3, C4, and C5. Notably, microbial humic-like substances remained consistently high during the wet season. Two-dimensional correlation spectroscopy was further employed to evaluate sequential changes in DOM components, while a moving window was used to identify temporal variation characteristics. Based on Noda’s rules, the DOM response sequence was identified as C3→C2→C1→C4→C5. Kernel PCA showed that the variable cluster represented by PC1, which consisted of organic pollutants and nutrients, co-varied negatively with Chl-a, whereas the PC2 cluster, representing biogenic organic matter, co-varied positively with Chl-a. Moreover, partial least squares path modeling showed that humic-like and tryptophan-like substances were positively correlated with Chl-a, with the path coefficients of 0.47 and 0.19, respectively. These findings revealed the interaction patterns between DOM components and Chl-a at the river-lake confluence zone, thereby enhancing our understanding of the factors influencing the spatio-temporal variations in Chl-a concentration, and further providing a guide for the control of algal blooms. Full article

Yangtze finless porpoise (Neophocaena asiaeorientalis) is the only extant cetacean species in the Yangtze River, a national first-class protected wild animal in China, and a key indicator reflecting the health status of the Yangtze River ecosystem. Environmental changes can induce adaptive trophic responses in animal communities; thus, clarifying the dynamic interactions between fish assemblages and dietary shifts in the Yangtze finless porpoise after the fishing moratorium is critically important. In this study, fishery resources in Poyang Lake were surveyed using triple-layer composite gill nets and cage traps, with samples collected and analyzed accordingly. A total of 81 fish species belonging to 8 orders and 16 families were recorded. Following the fishing ban, the abundance of small-bodied fish species (e.g., Hemiculter bleekeri, Carassius auratus) decreased, while the proportion of piscivorous species among the top ten dominant fish increased from 40% to 60%. DNA barcoding was used to analyze gastric contents of 10 dead porpoises found post-moratorium, and the results were compared with pre-ban data. Gastric content analysis identified 11 prey taxa, and comparative analysis demonstrated that prey selectivity was closely correlated with local prey availability. Concomitant with the structural reorganization of the fish community in Poyang Lake during the early stage of the fishing ban, the Yangtze finless porpoise exhibited adaptive dietary shifts toward benthic and small-bodied fish species, suggesting a potential linkage between these ecological responses. These findings provide direct implications for formulating targeted conservation strategies for this endangered cetacean and highlight the necessity of protecting small and benthic fish populations to ensure their long-term survival. Full article

Per- and polyfluoroalkyl substances (PFASs) have raised considerable concern due to their ubiquity, persistence, bioaccumulation, and toxicity. However, cost-effective, high-performance adsorbents for PFAS removal from aquatic environments remain limited. Here, we synthesized a porous graphitic biochar adsorbent (Zn-BBC) from banana peel waste via zinc chloride (ZnCl₂) activation and applied it to removing ten legacy and alternative PFASs from water. Zn-BBC achieved removal efficiencies > 95% for all target PFASs. The adsorption of PFASs onto Zn-BBC followed pseudo-second-order (PSO) kinetics, suggesting chemisorption. Additionally, the adsorption isotherms were well described by the Sips model, indicating surface heterogeneity. Zn-BBC exhibited robust performance over a broad pH range (3–9). Coexisting ions (CO₃²⁻, SO₄²⁻, Zn²⁺, Ca²⁺, and Mg²⁺), tested individually at 10 mM each, had negligible effects on the adsorption of the PFASs examined, except for perfluorobutanoic acid (PFBA). In contrast, humic acid (10 mM) significantly reduced the removal rates of PFBA, perfluorohexanoic acid (PFHxA), and hexafluoropropylene oxide dimer acid (GenX). Nevertheless, in river and lake waters, Zn-BBC achieved >85.0% removal of all PFASs except PFBA. In regeneration experiments, Zn-BBC exhibited excellent reusability. Experimental characterization and density functional theory (DFT) calculations jointly revealed that PFAS adsorption involves electrostatic interactions, hydrophobic interactions, π-CF interactions, surface complexation, and hydrogen bonding. These results suggest that Zn-BBC is a promising sorbent for PFAS removal in water. Full article