Hydrochemical Tracing for Solute Sources and Enrichment Mechanisms in Inland Lake Waters of the Qiangtang Plateau, Northern Tibet, China

To elucidate the solute sources, migration and enrichment mechanisms of water bodies in the endorheic lake region of the Qiangtang Plateau on the Tibetan Plateau and clarify the hydrogeochemical cycling patterns in alpine arid environments, this study focuses on two core scientific objectives: quantitative identification of the multi-source contributions of aquatic solutes, and revelation of the key processes governing the enrichment of strategic elements including lithium (Li) and boron (B). To achieve these goals, we conducted systematic hydrogeological field investigations and collected 28 multi-type water samples, covering springs, rivers, thermal springs, freshwater lakes, salt lake brines, atmospheric precipitation, and glacial meltwater. The physicochemical properties, major ions, and trace elements of all samples were comprehensively analyzed. On this basis, the hydrogeochemical characteristics, evolutionary processes, and solute origins of regional waters were systematically explored. Combined with PHREEQC numerical simulation, principal component analysis (PCA), and Pearson correlation analysis, the dominant controlling factors of water geochemistry were quantified, and a conceptual hydrogeochemical evolution model was established. The results reveal a clear hydrogeochemical evolutionary gradient across the study area: water bodies evolve from low-salinity HCO₃-Ca recharge end-members and transitional HCO₃·SO₄-Ca(Mg) type water to highly mineralized Cl-Na (SO₄·Cl-Na) salt lake brines, accompanied by synchronous enrichment of Li, B, arsenic (As), and other characteristic elements. Solute accumulation in regional waters is governed by the ternary coupling effects of evaporative concentration, rock weathering and leaching, and deep geothermal fluid input, while cation exchange and mineral dissolution–precipitation reactions further modulate ionic composition and ratios. Elements including As, Li, B, and chloride (Cl⁻) exhibit conservative migration behaviors in non-hydrothermal waters, whereas thermal springs possess unique geochemical signatures driven by deep fluid recharge. PCA results indicate that evaporative concentration serves as the primary controlling factor with a contribution rate of 55.39%; rock weathering provides the basic solute load (17.09%); and the coupled processes of deep fluid mixing and carbonate precipitation regulate elemental fractionation (14.21%). These findings systematically clarify the hydrogeochemical evolution laws and multi-source coupling mechanisms of inland lake waters in the Qiangtang Plateau. Furthermore, this study establishes a conceptual framework of “multi-source recharge–water–rock interaction–evaporative concentration”, advances the understanding of alpine hydrological cycling under climate change, and provides a solid scientific foundation for hydrological cycle research and green exploration of strategic mineral resources in endorheic salt lake regions.