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Search Results (4,354)

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Keywords = product’s life cycle

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13 pages, 2344 KiB  
Article
Study on the Risk of Reservoir Wellbore Collapse Throughout the Full Life Cycle of the Qianmiqiao Bridge Carbonate Rock Gas Storage Reservoir
by Yan Yu, Fuchun Tian, Feixiang Qin, Biao Zhang, Shuzhao Guo, Qingqin Cai, Zhao Chi and Chengyun Ma
Processes 2025, 13(8), 2480; https://doi.org/10.3390/pr13082480 - 6 Aug 2025
Abstract
Underground gas storage (UGS) in heterogeneous carbonate reservoirs is crucial for energy security but frequently faces wellbore instability challenges, which traditional static methods struggle to address due to dynamic full life cycle changes. This study systematically analyzes the dynamic evolution of wellbore stress [...] Read more.
Underground gas storage (UGS) in heterogeneous carbonate reservoirs is crucial for energy security but frequently faces wellbore instability challenges, which traditional static methods struggle to address due to dynamic full life cycle changes. This study systematically analyzes the dynamic evolution of wellbore stress in the Bs8 well (Qianmiqiao carbonate UGS) during drilling, acidizing, and injection-production operations, establishing a quantitative risk assessment model based on the Mohr–Coulomb criterion. Results indicate a significantly higher wellbore instability risk during drilling and initial gas injection stages, primarily manifested as shear failure, with greater severity observed in deeper well sections (e.g., 4277 m) due to higher in situ stresses. During acidizing, while the wellbore acid column pressure can reduce principal stress differences, the process also significantly weakens rock strength (e.g., by approximately 30%), inherently increasing the risk of wellbore instability, though the primary collapse mode remains shallow shear breakout. In the injection-production phase, increasing formation pressure is identified as the dominant factor, shifting the collapse mode from initial shallow shear failure to predominant wide shear collapse, notably at 90°/270° from the maximum horizontal stress direction, thereby significantly expanding the unstable zone. This dynamic assessment method provides crucial theoretical support for full life cycle integrity management and optimizing safe operation strategies for carbonate gas storage wells. Full article
(This article belongs to the Section Energy Systems)
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26 pages, 1407 KiB  
Review
ZnO Nanoparticles: Advancing Agricultural Sustainability
by Lekkala Venkata Ravishankar, Nidhi Puranik, VijayaDurga V. V. Lekkala, Dakshayani Lomada, Madhava C. Reddy and Amit Kumar Maurya
Plants 2025, 14(15), 2430; https://doi.org/10.3390/plants14152430 - 5 Aug 2025
Abstract
Micronutrients play a prominent role in plant growth and development, and their bioavailability is a growing global concern. Zinc is one of the most important micronutrients in the plant life cycle, acting as a metallic cofactor for numerous biochemical reactions within plant cells. [...] Read more.
Micronutrients play a prominent role in plant growth and development, and their bioavailability is a growing global concern. Zinc is one of the most important micronutrients in the plant life cycle, acting as a metallic cofactor for numerous biochemical reactions within plant cells. Zinc deficiency in plants leads to various physiological abnormalities, ultimately affecting nutritional quality and posing challenges to food security. Biofortification methods have been adopted by agronomists to increase Zn concentrations in crops through optimal foliar and soil applications. Changing climatic conditions and conventional agricultural practices alter edaphic factors, reducing zinc bioavailability in soils due to abrupt weather changes. Precision agriculture emphasizes need-based and site-specific technologies to address these nutritional deficiencies. Nanoscience, a multidimensional approach, reduces particle size to the nanometer (nm) scale to enhance their efficiency in precise amounts. Nanoscale forms of Zn+2 and their broad applications across crops are gaining attention in agriculture under varied application methods. This review focuses on the significance of Zn oxide (ZnO) nanoparticles (ZnONPs) and their extensive application in crop production. We also discuss optimum dosage levels, ZnONPs synthesis, application methods, toxicity, and promising future strategies in this field. Full article
(This article belongs to the Special Issue Nanotechnology in Crop Physiology and Sustainable Agriculture)
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32 pages, 1256 KiB  
Article
Bridging Interoperability Gaps Between LCA and BIM: Analysis of Limitations for the Integration of EPD Data in IFC
by Aitor Aragón, Paulius Spudys, Darius Pupeikis, Óscar Nieto and Marcos Garcia Alberti
Buildings 2025, 15(15), 2760; https://doi.org/10.3390/buildings15152760 - 5 Aug 2025
Abstract
The construction industry is a major consumer of raw materials and a significant contributor to environmental emissions. Life cycle assessment (LCA) using digital models is a valuable tool for conducting a science-based analysis to reduce these impacts. However, transferring data from environmental product [...] Read more.
The construction industry is a major consumer of raw materials and a significant contributor to environmental emissions. Life cycle assessment (LCA) using digital models is a valuable tool for conducting a science-based analysis to reduce these impacts. However, transferring data from environmental product declarations (EPDs) to BIM for the purpose of sustainability assessment requires significant resources for its interpretation and integration. This study is founded on a comprehensive review of the scientific literature and standards, an analysis of published digital EPDs, and a thorough evaluation of IFC (industry foundation classes), identifying twenty gaps for the automated incorporation of LCA data from construction products into BIM. The identified limitations were assessed using the digital model of a building pilot, applying simplifications to incorporate actual EPD data. This paper presents the identified barriers to the automated incorporation of digital EPDs into BIM, and proposes eleven concrete actions to improve IFC 4.3. While prior studies have analyzed the environmental data in IFC, this research is significant in two key areas. Firstly, it focuses on the direct machine interpretation of environmental information without human intervention. Secondly, it is intended to be directly applicable to a revision of the IFC standards. Full article
(This article belongs to the Special Issue Research on BIM—Integrated Construction Operation Simulation)
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32 pages, 1939 KiB  
Review
A Review on Anaerobic Digestate as a Biofertilizer: Characteristics, Production, and Environmental Impacts from a Life Cycle Assessment Perspective
by Carmen Martín-Sanz-Garrido, Marta Revuelta-Aramburu, Ana María Santos-Montes and Carlos Morales-Polo
Appl. Sci. 2025, 15(15), 8635; https://doi.org/10.3390/app15158635 (registering DOI) - 4 Aug 2025
Abstract
Digestate valorization is essential for sustainable waste management and circular economy strategies, yet large-scale adoption faces technical, economic, and environmental challenges. Beyond waste-to-energy conversion, digestate is a valuable soil amendment, enhancing soil structure and reducing reliance on synthetic fertilizers. However, its agronomic benefits [...] Read more.
Digestate valorization is essential for sustainable waste management and circular economy strategies, yet large-scale adoption faces technical, economic, and environmental challenges. Beyond waste-to-energy conversion, digestate is a valuable soil amendment, enhancing soil structure and reducing reliance on synthetic fertilizers. However, its agronomic benefits depend on feedstock characteristics, treatment processes, and application methods. This study reviews digestate composition, treatment technologies, regulatory frameworks, and environmental impact assessment through Life Cycle Assessment. It analyzes the influence of functional unit selection and system boundary definitions on Life Cycle Assessment outcomes and the effects of feedstock selection, pretreatment, and post-processing on its environmental footprint and fertilization efficiency. A review of 28 JCR-indexed articles (2018–present) analyzed LCA studies on digestate, focusing on methodologies, system boundaries, and impact categories. The findings indicate that Life Cycle Assessment methodologies vary widely, complicating direct comparisons. Transportation distances, nutrient stability, and post-processing strategies significantly impact greenhouse gas emissions and nutrient retention efficiency. Techniques like solid–liquid separation and composting enhance digestate stability and agronomic performance. Digestate remains a promising alternative to synthetic fertilizers despite market uncertainty and regulatory inconsistencies. Standardized Life Cycle Assessment methodologies and policy incentives are needed to promote its adoption as a sustainable soil amendment within circular economy frameworks. Full article
(This article belongs to the Special Issue Novel Research on By-Products and Treatment of Waste)
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29 pages, 1895 KiB  
Article
How Does Sharing Economy Advance Sustainable Production and Consumption? Evidence from the Policies and Business Practices of Dockless Bike Sharing
by Shouheng Sun, Yiran Wang, Dafei Yang and Qi Wu
Sustainability 2025, 17(15), 7053; https://doi.org/10.3390/su17157053 - 4 Aug 2025
Viewed by 64
Abstract
The sharing economy is considered to be a potentially efficacious approach for promoting sustainable production and consumption (SPC). This study utilizes dockless bike sharing (DBS) in Beijing as a case study to examine how sharing economy policies and business practices advance SPC. It [...] Read more.
The sharing economy is considered to be a potentially efficacious approach for promoting sustainable production and consumption (SPC). This study utilizes dockless bike sharing (DBS) in Beijing as a case study to examine how sharing economy policies and business practices advance SPC. It also dynamically quantifies the environmental and economic performance of DBS practices from a life cycle perspective. The findings indicate that effective SPC practices can be achieved through the collaborative efforts of multiple stakeholders, including the government, operators, manufacturers, consumers, recycling agencies, and other business partners, supported by regulatory systems and advanced technologies. The SPC practices markedly improved the sustainability of DBS promotion in Beijing. This is evidenced by the increase in greenhouse gas (GHG) emission reduction benefits, which have risen from approximately 35.81 g CO2-eq to 124.40 g CO2-eq per kilometer of DBS travel. Considering changes in private bicycle ownership, this value could reach approximately 150.60 g CO2-eq. Although the economic performance of DBS operators has also improved, it remains challenging to achieve profitability, even when considering the economic value of the emission reduction benefits. In certain scenarios, DBS can maximize profits by optimizing fleet size and efficiency, without compromising the benefits of emission reductions. The framework of stakeholder interaction proposed in this study and the results of empirical analysis not only assist regulators, businesses, and the public in better understanding and promoting sustainable production and consumption practices in the sharing economy but also provide valuable insights for achieving a win-win situation of platform profitability and environmental benefits in the SPC practice process. Full article
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20 pages, 1639 KiB  
Case Report
The Power of Preventive Protection: Effects of Vaccination Strategies on Furunculosis Resistance in Large-Scale Aquaculture of Maraena Whitefish
by Kerstin Böttcher, Peter Luft, Uwe Schönfeld, Stephanie Speck, Tim Gottschalk and Alexander Rebl
Fishes 2025, 10(8), 374; https://doi.org/10.3390/fishes10080374 - 4 Aug 2025
Viewed by 148
Abstract
Furunculosis caused by Aeromonas salmonicida poses a significant challenge to the sustainable production of maraena whitefish (Coregonus maraena). This case report outlines a multi-year disease management strategy at a European whitefish facility with two production departments, each specialising in different life-cycle [...] Read more.
Furunculosis caused by Aeromonas salmonicida poses a significant challenge to the sustainable production of maraena whitefish (Coregonus maraena). This case report outlines a multi-year disease management strategy at a European whitefish facility with two production departments, each specialising in different life-cycle stages. Recurrent outbreaks of A. salmonicida necessitated the development of effective vaccination protocols. Herd-specific immersion vaccines failed to confer protection, while injectable formulations with plant-based adjuvants caused severe adverse reactions and mortality rates exceeding 30%. In contrast, the bivalent vaccine Alpha Ject 3000, containing inactivated A. salmonicida and Vibrio anguillarum with a mineral oil adjuvant, yielded high tolerability and durable protection in over one million whitefish. Post-vaccination mortality remained low (3.3%), aligning with industry benchmarks, and furunculosis-related losses were fully prevented in both departments. Transcriptomic profiling of immune-relevant tissues revealed distinct gene expression signatures depending on vaccine type and time post-vaccination. Both the herd-specific vaccine and Alpha Ject 3000 induced the expression of immunoglobulin and inflammatory markers in the spleen, contrasted by reduced immunoglobulin transcript levels in the gills and head kidney together with the downregulated expression of B-cell markers. These results demonstrate that an optimised injectable vaccination strategy can significantly improve health outcomes and disease resilience in maraena whitefish aquaculture. Full article
(This article belongs to the Special Issue Fish Pathogens and Vaccines in Aquaculture)
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27 pages, 3470 KiB  
Article
Spatiotemporal Evolution and Influencing Factors of Carbon Emission Efficiency of Apple Production in China from 2003 to 2022
by Dejun Tan, Juanjuan Cheng, Jin Yu, Qian Wang and Xiaonan Chen
Agriculture 2025, 15(15), 1680; https://doi.org/10.3390/agriculture15151680 - 2 Aug 2025
Viewed by 261
Abstract
Understanding the carbon emission efficiency of apple production (APCEE) is critical for promoting green and low-carbon agricultural development. However, the spatiotemporal dynamics and driving factors of APCEE in China remain inadequately explored. This study employs life cycle assessment, super-efficiency slacks-based measures, [...] Read more.
Understanding the carbon emission efficiency of apple production (APCEE) is critical for promoting green and low-carbon agricultural development. However, the spatiotemporal dynamics and driving factors of APCEE in China remain inadequately explored. This study employs life cycle assessment, super-efficiency slacks-based measures, and a panel Tobit model to evaluate the carbon footprint, APCEE, and its determinants in China’s two major production regions from 2003 to 2022. The results reveal that: (1) Producing one ton of apples in China results in 0.842 t CO2e emissions. Land carbon intensity and total carbon emissions peaked in 2010 (28.69 t CO2e/ha) and 2014 (6.52 × 107 t CO2e), respectively, exhibiting inverted U-shaped trends. Carbon emissions from various production areas show significant differences, with higher pressure on carbon emission reduction in the Loess Plateau region, especially in Gansu Province. (2) The APCEE in China exhibits a W-shaped trend (mean: 0.645), with overall low efficiency loss. The Bohai Bay region outperforms the Loess Plateau and national averages. (3) The structure of the apple industry, degree of agricultural mechanization, and green innovation positively influence APCEE, while the structure of apple cultivation, education level, and agricultural subsidies negatively impact it. Notably, green innovation and agricultural subsidies display lagged effects. Moreover, the drivers of APCEE differ significantly between the two major production regions. These findings provide actionable pathways for the green and low-carbon transformation of China’s apple industry, emphasizing the importance of spatially tailored green policies and technology-driven decarbonization strategies. Full article
(This article belongs to the Section Agricultural Economics, Policies and Rural Management)
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15 pages, 5152 KiB  
Article
Assessment of Emergy, Environmental and Economic Sustainability of the Mango Orchard Production System in Hainan, China
by Yali Lei, Xiaohui Zhou and Hanting Cheng
Sustainability 2025, 17(15), 7030; https://doi.org/10.3390/su17157030 - 2 Aug 2025
Viewed by 229
Abstract
Mangoes are an important part of Hainan’s tropical characteristic agriculture. In response to the requirements of building an ecological civilization pilot demonstration zone in Hainan, China, green and sustainable development will be the future development trend of the mango planting system. However, the [...] Read more.
Mangoes are an important part of Hainan’s tropical characteristic agriculture. In response to the requirements of building an ecological civilization pilot demonstration zone in Hainan, China, green and sustainable development will be the future development trend of the mango planting system. However, the economic benefits and environmental impact during its planting and management process remain unclear. This paper combines emergy, life cycle assessment (LCA), and economic analysis to compare the system sustainability, environmental impact, and economic benefits of the traditional mango cultivation system (TM) in Dongfang City, Hainan Province, and the early-maturing mango cultivation system (EM) in Sanya City. The emergy evaluation results show that the total emergy input of EM (1.37 × 1016 sej ha−1) was higher than that of TM (1.32 × 1016 sej ha−1). From the perspective of the emergy index, compared with TM, EM exerted less pressure on the local environment and has better stability and sustainability. This was due to the higher input of renewable resources in EM. The LCA results showed that based on mass as the functional unit, the potential environmental impact of the EM is relatively high, and its total environmental impact index was 18.67–33.19% higher than that of the TM. Fertilizer input and On-Farm emissions were the main factors causing environmental consequences. Choosing alternative fertilizers that have a smaller impact on the environment may effectively reduce the environmental impact of the system. The economic analysis results showed that due to the higher selling price of early-maturing mango, the total profit and cost–benefit ratio of the EM have increased by 55.84% and 36.87%, respectively, compared with the TM. These results indicated that EM in Sanya City can enhance environmental sustainability and boost producers’ annual income, but attention should be paid to the negative environmental impact of excessive fertilizer input. These findings offer insights into optimizing agricultural inputs for Hainan mango production to mitigate multiple environmental impacts while enhancing economic benefits, aiming to provide theoretical support for promoting the sustainable development of the Hainan mango industry. Full article
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17 pages, 2459 KiB  
Article
Comparative Life Cycle Assessment of Rubberized Warm-Mix Asphalt Pavements: A Cradle-to-Gate Plus Maintenance Approach
by Ana María Rodríguez-Alloza and Daniel Garraín
Coatings 2025, 15(8), 899; https://doi.org/10.3390/coatings15080899 (registering DOI) - 1 Aug 2025
Viewed by 190
Abstract
In response to the escalating climate crisis, reducing greenhouse gas emissions (GHG) has become a top priority for both the public and private sectors. The pavement industry plays a key role in this transition, offering innovative technologies that minimize environmental impacts without compromising [...] Read more.
In response to the escalating climate crisis, reducing greenhouse gas emissions (GHG) has become a top priority for both the public and private sectors. The pavement industry plays a key role in this transition, offering innovative technologies that minimize environmental impacts without compromising performance. Among these, the incorporation of recycled tire rubber and warm-mix asphalt (WMA) additives represents a promising strategy to reduce energy consumption and resource depletion in road construction. This study conducts a comparative life cycle assessment (LCA) to evaluate the environmental performance of an asphalt pavement incorporating recycled rubber and a WMA additive—referred to as R-W asphalt—against a conventional hot-mix asphalt (HMA) pavement. The analysis follows the ISO 14040/44 standards, covering material production, transport, construction, and maintenance. Two service-life scenarios are considered: one assuming equivalent durability and another with a five-year extension for the R-W pavement. The results demonstrate environmental impact reductions of up to 57%, with average savings ranging from 32% to 52% across key impact categories such as climate change, land use, and resource use. These benefits are primarily attributed to lower production temperatures and extended maintenance intervals. The findings underscore the potential of R-W asphalt as a cleaner engineering solution aligned with circular economy principles and climate mitigation goals. Full article
(This article belongs to the Special Issue Surface Protection of Pavements: New Perspectives and Applications)
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29 pages, 1079 KiB  
Article
Electricity-Related Emissions Factors in Carbon Footprinting—The Case of Poland
by Anna Lewandowska, Katarzyna Joachimiak-Lechman, Jolanta Baran and Joanna Kulczycka
Energies 2025, 18(15), 4092; https://doi.org/10.3390/en18154092 - 1 Aug 2025
Viewed by 158
Abstract
Electricity is a significant factor in the life cycle of many products, so the reliability of greenhouse gas (GHG) emissions data is crucial. The article presents publicly available sources of emission factors representative of Poland. The aim of the study is to assess [...] Read more.
Electricity is a significant factor in the life cycle of many products, so the reliability of greenhouse gas (GHG) emissions data is crucial. The article presents publicly available sources of emission factors representative of Poland. The aim of the study is to assess their strengths and weaknesses in the context of the calculation requirements of carbon footprint analysis in accordance with the GHG Protocol. The article presents the results of carbon footprint calculations for different ranges of emissions in the life cycle of 1 kWh of electricity delivered to a hypothetical organization. Next, a discussion on the quality of the emissions factors has been provided, taking account of data quality indicators. It was concluded that two of the emissions factors that are compared—those based on the national consumption mix and the residual mix for Poland—have been recognized as suitable for use in carbon footprint calculations. Beyond the calculation results, the research highlights the significance of the impact of the selection of emissions factors on the reliability of environmental analysis. The article identifies methodological challenges, including the risk of double counting, limited transparency, methodological inconsistency, and low correlation of data with specific locations and technologies. The insights presented contribute to improving the robustness of carbon footprint calculations. Full article
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33 pages, 1166 KiB  
Article
Evaluating Freshwater, Desalinated Water, and Treated Brine as Water Feed for Hydrogen Production in Arid Regions
by Hamad Ahmed Al-Ali and Koji Tokimatsu
Energies 2025, 18(15), 4085; https://doi.org/10.3390/en18154085 - 1 Aug 2025
Viewed by 113
Abstract
Hydrogen production is increasingly vital for global decarbonization but remains a water- and energy-intensive process, especially in arid regions. Despite growing attention to its climate benefits, limited research has addressed the environmental impacts of water sourcing. This study employs a life cycle assessment [...] Read more.
Hydrogen production is increasingly vital for global decarbonization but remains a water- and energy-intensive process, especially in arid regions. Despite growing attention to its climate benefits, limited research has addressed the environmental impacts of water sourcing. This study employs a life cycle assessment (LCA) approach to evaluate three water supply strategies for hydrogen production: (1) seawater desalination without brine treatment (BT), (2) desalination with partial BT, and (3) freshwater purification. Scenarios are modeled for the United Arab Emirates (UAE), Australia, and Spain, representing diverse electricity mixes and water stress conditions. Both electrolysis and steam methane reforming (SMR) are evaluated as hydrogen production methods. Results show that desalination scenarios contribute substantially to human health and ecosystem impacts due to high energy use and brine discharge. Although partial BT aims to reduce direct marine discharge impacts, its substantial energy demand can offset these benefits by increasing other environmental burdens, such as marine eutrophication, especially in regions reliant on carbon-intensive electricity grids. Freshwater scenarios offer lower environmental impact overall but raise water availability concerns. Across all regions, feedwater for SMR shows nearly 50% lower impacts than for electrolysis. This study focuses solely on the environmental impacts associated with water sourcing and treatment for hydrogen production, excluding the downstream impacts of the hydrogen generation process itself. This study highlights the trade-offs between water sourcing, brine treatment, and freshwater purification for hydrogen production, offering insights for optimizing sustainable hydrogen systems in water-stressed regions. Full article
(This article belongs to the Special Issue Advances in Hydrogen Production in Renewable Energy Systems)
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23 pages, 2888 KiB  
Review
Machine Learning in Flocculant Research and Application: Toward Smart and Sustainable Water Treatment
by Caichang Ding, Ling Shen, Qiyang Liang and Lixin Li
Separations 2025, 12(8), 203; https://doi.org/10.3390/separations12080203 - 1 Aug 2025
Viewed by 197
Abstract
Flocculants are indispensable in water and wastewater treatment, enabling the aggregation and removal of suspended particles, colloids, and emulsions. However, the conventional development and application of flocculants rely heavily on empirical methods, which are time-consuming, resource-intensive, and environmentally problematic due to issues such [...] Read more.
Flocculants are indispensable in water and wastewater treatment, enabling the aggregation and removal of suspended particles, colloids, and emulsions. However, the conventional development and application of flocculants rely heavily on empirical methods, which are time-consuming, resource-intensive, and environmentally problematic due to issues such as sludge production and chemical residues. Recent advances in machine learning (ML) have opened transformative avenues for the design, optimization, and intelligent application of flocculants. This review systematically examines the integration of ML into flocculant research, covering algorithmic approaches, data-driven structure–property modeling, high-throughput formulation screening, and smart process control. ML models—including random forests, neural networks, and Gaussian processes—have successfully predicted flocculation performance, guided synthesis optimization, and enabled real-time dosing control. Applications extend to both synthetic and bioflocculants, with ML facilitating strain engineering, fermentation yield prediction, and polymer degradability assessments. Furthermore, the convergence of ML with IoT, digital twins, and life cycle assessment tools has accelerated the transition toward sustainable, adaptive, and low-impact treatment technologies. Despite its potential, challenges remain in data standardization, model interpretability, and real-world implementation. This review concludes by outlining strategic pathways for future research, including the development of open datasets, hybrid physics–ML frameworks, and interdisciplinary collaborations. By leveraging ML, the next generation of flocculant systems can be more effective, environmentally benign, and intelligently controlled, contributing to global water sustainability goals. Full article
(This article belongs to the Section Environmental Separations)
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20 pages, 1701 KiB  
Article
Life Cycle Assessment of Biomass Waste and Coal Co-Firing: Advancing Circular Economy in Energy Production
by Stiven J. Sofán-Germán, Miguel E. Doria-Oviedo, Jesus D. Rhenals-Julio and Jorge M. Mendoza-Fandiño
Recycling 2025, 10(4), 151; https://doi.org/10.3390/recycling10040151 - 1 Aug 2025
Viewed by 196
Abstract
This study uses life cycle analysis (LCA) to evaluate the environmental impacts of co-firing bituminous coal with agricultural biomass waste, such as coconut and rice husks, emphasising circular economy principles. Seven experimental scenarios with different coal-to-biomass ratios were designed, ranging from pure coal [...] Read more.
This study uses life cycle analysis (LCA) to evaluate the environmental impacts of co-firing bituminous coal with agricultural biomass waste, such as coconut and rice husks, emphasising circular economy principles. Seven experimental scenarios with different coal-to-biomass ratios were designed, ranging from pure coal to pure biomass. The results show that Scenario B (100% rice husk) achieved the best overall environmental performance, with the lowest global warming potential (300 kg CO2 equivalent), eutrophication potential (4.742 kg PO4 equivalent), and smog formation potential (0.012 kg C2H4 equivalent). Additionally, Scenario F (15% biomass mix) recorded the lowest acidification potential (57.39 kg SO2 eq), indicating that even partial substitution can yield significant environmental benefits. In contrast, Scenario C (100% coal) exhibited the highest acidification (164.08 kg SO2 eq) and eutrophication (8.82 kg PO4 eq) potential. Overall, the results demonstrate that co-firing biomass waste significantly reduces pollutant emissions compared to burning coal alone. This study highlights the effectiveness of biomass waste co-firing in mitigating environmental impacts, promoting resource recovery, and supporting a sustainable energy transition within a circular economy framework. Full article
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14 pages, 4979 KiB  
Article
Oxygen Vacancy-Engineered Ni:Co3O4/Attapulgite Photothermal Catalyst from Recycled Spent Lithium-Ion Batteries for Efficient CO2 Reduction
by Jian Shi, Yao Xiao, Menghan Yu and Xiazhang Li
Catalysts 2025, 15(8), 732; https://doi.org/10.3390/catal15080732 - 1 Aug 2025
Viewed by 245
Abstract
Accelerated industrialization and surging energy demands have led to continuously rising atmospheric CO2 concentrations. Developing sustainable methods to reduce atmospheric CO2 levels is crucial for achieving carbon neutrality. Concurrently, the rapid development of new energy vehicles has driven a significant increase [...] Read more.
Accelerated industrialization and surging energy demands have led to continuously rising atmospheric CO2 concentrations. Developing sustainable methods to reduce atmospheric CO2 levels is crucial for achieving carbon neutrality. Concurrently, the rapid development of new energy vehicles has driven a significant increase in demand for lithium-ion batteries (LIBs), which are now approaching an end-of-life peak. Efficient recycling of valuable metals from spent LIBs represents a critical challenge. This study employs conventional hydrometallurgical processing to recover valuable metals from spent LIBs. Subsequently, Ni-doped Co3O4 (Ni:Co3O4) supported on the natural mineral attapulgite (ATP) was synthesized via a sol–gel method. The incorporation of a small amount of Ni into the Co3O4 lattice generates oxygen vacancies, inducing a localized surface plasmon resonance (LSPR) effect, which significantly enhances charge carrier transport and separation efficiency. During the photocatalytic reduction of CO2, the primary product CO generated by the Ni:Co3O4/ATP composite achieved a high production rate of 30.1 μmol·g−1·h−1. Furthermore, the composite maintains robust catalytic activity even after five consecutive reaction cycles. Full article
(This article belongs to the Special Issue Heterogeneous Catalysis in Air Pollution Control)
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42 pages, 3564 KiB  
Review
A Review on Sustainable Upcycling of Plastic Waste Through Depolymerization into High-Value Monomer
by Ramkumar Vanaraj, Subburayan Manickavasagam Suresh Kumar, Seong Cheol Kim and Madhappan Santhamoorthy
Processes 2025, 13(8), 2431; https://doi.org/10.3390/pr13082431 - 31 Jul 2025
Viewed by 603
Abstract
Plastic waste accumulation is one of the most pressing environmental challenges of the 21st century, owing to the widespread use of synthetic polymers and the limitations of conventional recycling methods. Among available strategies, chemical upcycling via depolymerization has emerged as a promising circular [...] Read more.
Plastic waste accumulation is one of the most pressing environmental challenges of the 21st century, owing to the widespread use of synthetic polymers and the limitations of conventional recycling methods. Among available strategies, chemical upcycling via depolymerization has emerged as a promising circular approach that converts plastic waste back into valuable monomers and chemical feedstocks. This article provides an in-depth narrative review of recent progress in the upcycling of major plastic types such as PET, PU, PS, and engineering plastics through thermal, chemical, catalytic, biological, and mechanochemical depolymerization methods. Each method is critically assessed in terms of efficiency, scalability, energy input, and environmental impact. Special attention is given to innovative catalyst systems, such as microsized MgO/SiO2 and Co/CaO composites, and emerging enzymatic systems like engineered PETases and whole-cell biocatalysts that enable low-temperature, selective depolymerization. Furthermore, the conversion pathways of depolymerized products into high-purity monomers such as BHET, TPA, vanillin, and bisphenols are discussed with supporting case studies. The review also examines life cycle assessment (LCA) data, techno-economic analyses, and policy frameworks supporting the adoption of depolymerization-based recycling systems. Collectively, this work outlines the technical viability and sustainability benefits of depolymerization as a core pillar of plastic circularity and monomer recovery, offering a path forward for high-value material recirculation and waste minimization. Full article
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