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Keywords = pre-treated crumb rubber

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43 pages, 4655 KB  
Review
Advancements in Characterization and Potential Structural Seismic Performance of Alkali-Activated Concrete Incorporating Crumb Rubber: A State-of-the-Art Review
by Yousef Elbaz, Aman Mwafy, Hilal El-Hassan and Tamer El-Maaddawy
Sustainability 2025, 17(13), 6043; https://doi.org/10.3390/su17136043 - 1 Jul 2025
Cited by 1 | Viewed by 1733
Abstract
The production of ordinary Portland cement has had a significant environmental impact, leading to increased interest in sustainable alternatives. This comprehensive review thus explores the performance and applications of rubberized alkali-activated concrete (RuAAC), an innovative material combining alkali-activated concrete with crumb rubber (CR) [...] Read more.
The production of ordinary Portland cement has had a significant environmental impact, leading to increased interest in sustainable alternatives. This comprehensive review thus explores the performance and applications of rubberized alkali-activated concrete (RuAAC), an innovative material combining alkali-activated concrete with crumb rubber (CR) from waste tires as a coarse/fine aggregate replacement. The study examined current research on the components, physical and mechanical properties, and seismic performance of RuAAC structures. Key findings revealed that CR addition enhances dynamic characteristics while reducing compressive strength by up to 63% at 50% CR replacement, though ductility improvements partially offset this reduction. Novel CR pretreatment methods, such as eggshell catalyzation, can enhance seismic resilience potential. While studies on the structural seismic performance of RuAAC are limited, relevant research on rubberized conventional concrete indicated several potential benefits, highlighting a critical gap in the current body of knowledge. Research on the behavior of RuAAC in full-scale structural elements and under seismic loading conditions remains notably lacking. By examining existing research and identifying crucial research gaps, this review provides a foundation for future investigations into the structural behavior and seismic response of RuAAC, potentially paving the way for its practical implementation in earthquake-resistant and sustainable construction. Full article
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21 pages, 3696 KB  
Article
Research on the Durability of Modified Crumb Rubber Asphalt Mixtures in High-Altitude and Seasonally Frozen Regions
by Song Liu, Peng Lu, Xuecong Sun, Hongchang Wang and Zhuang Fei
Coatings 2025, 15(1), 102; https://doi.org/10.3390/coatings15010102 - 17 Jan 2025
Cited by 8 | Viewed by 3421
Abstract
Asphalt pavements in high-altitude and seasonally frozen regions of China encounter significant challenges that impact their stability and durability. This study aims to evaluate the performance of modified crumb rubber (MCR) asphalt mixtures under typical conditions of high-altitude seasonal frozen regions, specifically focusing [...] Read more.
Asphalt pavements in high-altitude and seasonally frozen regions of China encounter significant challenges that impact their stability and durability. This study aims to evaluate the performance of modified crumb rubber (MCR) asphalt mixtures under typical conditions of high-altitude seasonal frozen regions, specifically focusing on the effects of ultraviolet (UV) exposure and freeze–thaw cycling. Laboratory tests were designed to simulate UV irradiation and freeze–thaw cycling on asphalt mixtures, and then a series of tests were conducted on the pre-treated asphalt mixture specimens to investigate the effects on the performance including cohesion, high-temperature stability, low-temperature cracking resistance, water stability, and fatigue resistance. The MCR asphalt mixtures were tested in comparison to the Styrene–Butadiene–Styrene (SBS) modified asphalt and conventional crumb rubber modified asphalt mixtures. The test results indicated that MCR-modified asphalt mixture exhibited better cohesion and water stability than other tested mixtures. Under UV aging conditions, it showed a relatively slow performance degradation rate due to its unique composition that mitigates stress sensitivity. Also, when subjected to freeze–thaw cycling, the incorporation of MCR particles in the asphalt mixture resulted in delayed micro-crack propagation and a self-healing effect, thus mitigating its performance degradation rate compared to the other mixtures. The findings suggest that MCR MCR-modified asphalt mixture is a promising alternative for improving the durability of pavement in high-altitude and seasonally frozen regions. Full article
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23 pages, 5999 KB  
Article
Enhancing the Strength and the Environmental Performance of Concrete with Pre-Treated Crumb Rubber and Micro-Silica
by M. R. Rajagopal, Jyothikumari Ganta and Yashwanth Pamu
Recycling 2024, 9(3), 32; https://doi.org/10.3390/recycling9030032 - 24 Apr 2024
Cited by 10 | Viewed by 4840
Abstract
Dumped non-biodegradable tires present a significant environmental threat, with overflowing landfills and associated health risks highlighting the urgency of tire waste disposal. Current disposal methods, such as stacking tires in open spaces, exacerbate the problem. The large-scale recycling of tire rubber waste offers [...] Read more.
Dumped non-biodegradable tires present a significant environmental threat, with overflowing landfills and associated health risks highlighting the urgency of tire waste disposal. Current disposal methods, such as stacking tires in open spaces, exacerbate the problem. The large-scale recycling of tire rubber waste offers environmental benefits. This study examines the effects of pre-treatment using NaOH and micro-silica as a mineral admixture on the mechanical strength of crumb rubber concrete (CRC) with partial replacement of natural sand. Samples of M20 and M30 grade were prepared with varying levels of crumb rubber (CR) replacement and evaluated at 28 days. CRC prepared with pre-treated NaOH solution and micro-silica showed improved workability and strength compared to conventional concrete and untreated CRC, with the highest strength observed for 5% CR replacement using micro-silica. Predictive models and micro-structural analysis validated these findings. Life Cycle Assessment (LCA) using OpenLCA v2.10 software and the ecoinvent database revealed that incorporating micro-silica into CRC did not significantly increase environmental impacts, compared to conventional concrete across different mixes. Full article
(This article belongs to the Special Issue Recycling of Rubber Waste, 2nd Edition)
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25 pages, 10905 KB  
Article
Mechanical Properties of Rubberised Geopolymer Concrete
by Md Kamrul Hassan, Mohammed Irfan Ibrahim, Sukanta Kumer Shill and Safat Al-Deen
Materials 2024, 17(5), 1031; https://doi.org/10.3390/ma17051031 - 23 Feb 2024
Cited by 12 | Viewed by 3356
Abstract
The environmental impact of non-biodegradable rubber waste can be severe if they are buried in moist landfill soils or remain unused forever. This study deals with a sustainable approach for reusing discarded tires in construction materials. Replacing ordinary Portland cement (OPC) with an [...] Read more.
The environmental impact of non-biodegradable rubber waste can be severe if they are buried in moist landfill soils or remain unused forever. This study deals with a sustainable approach for reusing discarded tires in construction materials. Replacing ordinary Portland cement (OPC) with an environmentally friendly geopolymer binder and integrating crumb rubber into pre-treated or non-treated geopolymer concrete as a partial replacement of natural aggregate is a great alternative to utilise tire waste and reduce CO2 emissions. Considering this, two sets of geopolymer concrete (GPC) mixes were manufactured, referred to as core mixes. Fine aggregates of the core geopolymer mixes were partially replaced with pre-treated and non-treated rubber crumbs to produce crumb rubber geopolymer concrete (CRGPC). The mechanical properties, such as compressive strength, stress–strain relationship, and elastic modulus of a rubberised geopolymer concrete of the reference GPC mix and the CRGPC were examined thoroughly to determine the performance of the products. Also, the mechanical properties of the CRGPC were compared with the existing material models. The result shows that the compressive strength and modulus of elasticity of CRGPC decrease with the increase of rubber content; for instance, a 33% reduction of the compressive strength is observed when 25% natural fine aggregate is replaced with crumb rubber. However, the strength and elasticity reduction can be minimised using pre-treated rubber particles. Based on the experimental results, stress–strain models for GPC and CRGPC are developed and proposed. The proposed models can accurately predict the properties of GPC and CRGPC. Full article
(This article belongs to the Special Issue Durability and Time-Dependent Properties of Sustainable Concrete)
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15 pages, 8436 KB  
Article
Study on the Physical and Rheological Characterisation of Low-Density Polyethylene (LDPE)/Recycled Crumb Rubber (RCR) on Asphalt Binders
by Shibo Zhang, Yong Yan, Yang Yang and Rongxin Guo
Molecules 2024, 29(3), 716; https://doi.org/10.3390/molecules29030716 - 4 Feb 2024
Cited by 8 | Viewed by 2730
Abstract
Recycled crumb rubber (RCR) is considered a reliable asphalt modifier and a solution to the problem of scrap tyre recycling. RCR-modified asphalt (RCRMA) typically has good low-temperature performance and storage stability. However, the pre-treatment of crumb rubber (CR) impairs its physical properties, resulting [...] Read more.
Recycled crumb rubber (RCR) is considered a reliable asphalt modifier and a solution to the problem of scrap tyre recycling. RCR-modified asphalt (RCRMA) typically has good low-temperature performance and storage stability. However, the pre-treatment of crumb rubber (CR) impairs its physical properties, resulting in poor high-temperature performance, which limits the industrial application of RCRMA. In this study, low-density polyethylene (LDPE) composite RCR was used to modify asphalt, and LDPE/RCR-composite-modified asphalt (L-RCRMA) was produced to compensate for the deficiencies in the high-temperature performance of RCRMA. The comprehensive physical properties of L-RCRMA were elucidated using tests such as the conventional properties, rotational viscosity, and rheological tests. The results showed that the incorporation of LDPE improved the high-temperature stability and rutting resistance of the asphalt, but an excessive amount of LDPE impaired the low-temperature performance and storage stability of L-RCRMA. Therefore, it is necessary to control the amount of LDPE to balance the performance of the asphalt. On this basis, we recommend a dosage of 20% for RCR and 1.5% for LDPE. Full article
(This article belongs to the Section Materials Chemistry)
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17 pages, 3946 KB  
Article
Effect of Fractionation Process and Addition of Composite Crumb Rubber-Modified Asphalt on Road Performance Variability of Recycled Asphalt Mixtures with High Reclaimed Asphalt Pavement (RAP) Content
by Wenwu Wei, Chao Ji, Honggang Song, Zhigang Li, Zhen Liu, Lijun Sun and Zhou Zhou
Buildings 2023, 13(11), 2729; https://doi.org/10.3390/buildings13112729 - 29 Oct 2023
Cited by 19 | Viewed by 2399
Abstract
The application of reclaimed asphalt pavement (RAP) can help reduce resource waste and environmental pollution in road construction. However, so far, only a small percentage of RAP materials can be used in road construction. The key obstacles to the application of a recycled [...] Read more.
The application of reclaimed asphalt pavement (RAP) can help reduce resource waste and environmental pollution in road construction. However, so far, only a small percentage of RAP materials can be used in road construction. The key obstacles to the application of a recycled asphalt mixture (RAM) with high RAP content are the variability of RAP materials and the difficulty of fully rejuvenating aged asphalt. However, there is still a lack of research on the effect of the variability of RAP materials and recycled asphalt on the quality control of a RAM. Therefore, this study investigates the effects of sieve pretreatment of RAP material using 4.75 mm sieve mesh and the use of composite crumb rubber-modified asphalt (CCRMA) to reclaim aged asphalt on the road performance and frame variability of reclaimed asphalt mixtures. Therefore, this study investigates the effects of the fractionation process of RAP material using 4.75 mm sieve mesh and the use of CCRMA to reclaim aged asphalt on the road performance of a RAM. The results show that the fractionation process can effectively reduce the mitigation of RAP agglomeration and reduce the variability of gradation, which in turn reduces the variability of road performance. The incorporation of CCRMA can effectively improve the high-temperature stability performance and low-temperature cracking resistance. The dynamic stability and the fracture energy of the CRAM (RAM prepared using CCRMA) were four and one and a half times as large as that of the NAM (RAM prepared using base asphalt), respectively. The fractionation process of RAP material and the utilization of CCRMA could help reduce the variability of the RAM while improving the road performance of the RAM. Full article
(This article belongs to the Special Issue Mechanical Properties of Asphalt and Asphalt Mixtures)
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5 pages, 888 KB  
Proceeding Paper
The Behavior of Pre-Treated Crumb Rubber and Polypropylene-Fiber-Incorporated Mortar Subjected to Elevated Temperatures
by Manail Shafqat, Muhammad Basit Khan and Hamad Hassan Awan
Eng. Proc. 2023, 44(1), 12; https://doi.org/10.3390/engproc2023044012 - 25 Aug 2023
Cited by 1 | Viewed by 1581
Abstract
Rubber is a waste product produced by the industrial sector in large quantities. Due to its non-degradable nature, it has been a serious threat to the environment. Thus, it is recommended to develop concrete or mortar containing rubber, so that it can save [...] Read more.
Rubber is a waste product produced by the industrial sector in large quantities. Due to its non-degradable nature, it has been a serious threat to the environment. Thus, it is recommended to develop concrete or mortar containing rubber, so that it can save our environment, and it is economical too. Crumb rubber, when incorporated in mortar, reduces its strength, so it can be used along with some fibers to enhance its strength. This study examined the effect of elevated temperatures, i.e., 150, 300, 450, 600, and 750 °C, on mortar samples containing 5% crumb rubber replacement of fine aggregate by volume, and with the incorporation of 1% PPF. The findings indicated a rise in compressive strength up to 300 °C, followed by a subsequent decline. It was also observed that the weight loss of the samples increased with an increase in temperature. Full article
(This article belongs to the Proceedings of The 5th Conference on Sustainability in Civil Engineering)
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5 pages, 549 KB  
Proceeding Paper
Linear and Non-Linear Regression Analysis on the Prediction of Compressive Strength of Sodium Hydroxide Pre-Treated Crumb Rubber Concrete
by Hamza Aamir, Kinza Aamir and Muhammad Faisal Javed
Eng. Proc. 2023, 44(1), 5; https://doi.org/10.3390/engproc2023044005 - 23 Aug 2023
Cited by 3 | Viewed by 2417
Abstract
This research focuses on dataset development using NaOH treatment period (NaTP), NaOH concentration (NaCon), coarse aggregates (gravel), fine aggregates (sand), water, water–cement ratio (w/c), crumb rubber percentage (CR%), and equations to predict the CS of concrete. The criteria for the model accuracy included [...] Read more.
This research focuses on dataset development using NaOH treatment period (NaTP), NaOH concentration (NaCon), coarse aggregates (gravel), fine aggregates (sand), water, water–cement ratio (w/c), crumb rubber percentage (CR%), and equations to predict the CS of concrete. The criteria for the model accuracy included the coefficient of regression (R2), mean absolute error (MAE), and root mean square deviation (RMSE). In this study, Multiple Non-Linear Regression (MNLR) performed better compared to Multiple Linear Regression (MLR). The MNLR values obtained for R2, MAE, and RMSE were 0.88, 4.64, and 6.15; and the MLR values were 0.82, 5.86, and 7.43 for R2, MAE, and RMSE, respectively. Full article
(This article belongs to the Proceedings of The 5th Conference on Sustainability in Civil Engineering)
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16 pages, 8590 KB  
Article
Study on the Low-Temperature Pre-Desulfurization of Crumb Rubber-Modified Asphalt
by Shibo Zhang, Yang Yang, Rongxin Guo, Yong Yan, Haiyang Huan and Bangwei Wan
Polymers 2023, 15(10), 2273; https://doi.org/10.3390/polym15102273 - 11 May 2023
Cited by 16 | Viewed by 3006
Abstract
Waste tires can be ground as crumb rubber (CR) and incorporated into asphalt pavement for efficient resource utilization. However, due to its thermodynamic incompatibility with asphalt, CR cannot be uniformly dispersed in the asphalt mix. In order to address this issue, pretreating the [...] Read more.
Waste tires can be ground as crumb rubber (CR) and incorporated into asphalt pavement for efficient resource utilization. However, due to its thermodynamic incompatibility with asphalt, CR cannot be uniformly dispersed in the asphalt mix. In order to address this issue, pretreating the CR with desulfurization is a common way to restore some of the properties of natural rubber. The main technique of desulfurization and degradation is dynamic desulfurization, requiring a high temperature that may lead to asphalt fires, aging, and the volatilization of light substances, generating toxic gases and resulting in environmental pollution. Therefore, a green and low-temperature controlled desulfurization technology is proposed in this study to exploit the maximum potential of CR desulfurization and obtain high-solubility “liquid waste rubber” (LWR) close to the ultimate regeneration level. In this work, LWR-modified asphalt (LRMA) with superior low-temperature performance and processability, stable storage, and less susceptibility to segregation was developed. Nevertheless, its rutting and deformation resistance deteriorated at high temperatures. The results showed that the proposed CR-desulfurization technology could produce LWR with 76.9% solubility at a low temperature of 160 °C, which is close to or even better than the finished products produced at the preparation temperature of TB technology, i.e., 220–280 °C. Full article
(This article belongs to the Section Polymer Applications)
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18 pages, 4929 KB  
Article
Evaluating the High-Temperature Properties and Reaction Mechanism of Terminal Blend Rubber/Nano Silica Composite Modified Asphalt Using Activated Rubber
by Nonde Lushinga, Zejiao Dong and Liping Cao
Nanomaterials 2022, 12(24), 4388; https://doi.org/10.3390/nano12244388 - 9 Dec 2022
Cited by 14 | Viewed by 2777
Abstract
Terminal blend (TB) rubberized asphalt is a popular technology in the production of rubberized asphalt. However, it always presents challenges regarding the inadequate high-temperature rutting performance of the binders. Additionally, crumb rubber (CR), a modifier of asphalt is a cross-linked material which presents [...] Read more.
Terminal blend (TB) rubberized asphalt is a popular technology in the production of rubberized asphalt. However, it always presents challenges regarding the inadequate high-temperature rutting performance of the binders. Additionally, crumb rubber (CR), a modifier of asphalt is a cross-linked material which presents poor compatibility between CR particles and bitumen. Incorporating nanomaterials and pretreating CR particles are two possible solutions to address this drawback. But the performance improvement and modification mechanism of the composite TB binders is not clearly understood. Therefore, the purpose of this research was to evaluate the high-temperature properties and reaction mechanism of the TB rubber/nano silica composite modified asphalt using microwave activated rubber. To achieve the research purpose, bitumen penetration grade 80–100 was first modified with 8% CR particles at elevated temperature to produce TB rubberized asphalt followed by the addition of 0.5, 1.5 and 3.0% weight percentage of nano silica to produce TB rubber/nano silica composite modified asphalt. Short and long-term aging tests were performed on samples by thin film oven test (TFOT) and pressure aging vessel (PAV) prior to chemical and rheological tests. The results of the study shows that nano silica has a great influence on the high temperature rutting resistance, storage stability and anti-aging properties of TB rubberized asphalt. Nano silica promoted good interaction and compatibility between CR particles and bitumen and improved the overall rheological properties of the binders. XRD test results revealed that the TB rubberized/nano silica composite modified asphalt samples were amorphous materials and did not have a crystalline structure. The reaction mechanism between rubber and asphalt was found to be physical, whereas nano silica interacted chemically with TB rubberized asphalt. In light of these findings, this research concluded that nano silica evidently improves the high-temperature rutting properties of TB rubberized asphalt, which deserves further exploration and application. Full article
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13 pages, 4116 KB  
Article
Effect of Rubber Heat Treatment on Rubberized-Concrete Mechanical Performance
by Abdelrahman Swilam, Ahmed M. Tahwia and Osama Youssf
J. Compos. Sci. 2022, 6(10), 290; https://doi.org/10.3390/jcs6100290 - 2 Oct 2022
Cited by 26 | Viewed by 5620
Abstract
To eliminate the unfavorable effect of the accumulation of end-of-life car tires on the environment, many studies have been conducted to recycle those tires in concrete as a partial or full replacement of its natural aggregates. However, the produced rubberized concrete suffers from [...] Read more.
To eliminate the unfavorable effect of the accumulation of end-of-life car tires on the environment, many studies have been conducted to recycle those tires in concrete as a partial or full replacement of its natural aggregates. However, the produced rubberized concrete suffers from low compressive strength due to low adhesion at the rubber/cement interface. Pre-treating of rubber surfaces before use in concrete is the most effective way to overcome this adverse effect on the concrete strength. Several studies introduced different methods to enhance rubberized-concrete strength through pre-treating rubber particles, especially when using a high content of rubber in concrete. This study presents the results of experimental work on the effect of heat treatment on crumb-rubber–concrete mechanical performance. Rubber contents of 40%, 60% and 80% of sand volume were the variables in this study. Workability, density, compressive strength, and impact resistance were the measurements in this experimental work. The results showed that using saturated-surface dry (SSD) rubber can eliminate the adverse effect on concrete slump when using a high rubber volume or the heat-treated rubber. Using heat-treated rubber at 200 °C for 2 h as 40%, 60%, and 80% displayed compressive strength recoveries of 14.9%, 10.4% and 9.7%, respectively. Heat treatment of 40%, 60%, and 80% rubber contents increased the impact resistance for ultimate failure by 57%, 28%, and 7%, respectively, compared with those of the control mix. The thermal treatment enhanced the impact resistance at ultimate failure by 37%, 28%, and 15%, respectively, for mixes containing 40%, 60%, and 80% rubber contents compared with those of as-received rubber. Full article
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23 pages, 4434 KB  
Article
Experimental and Statistical Investigation to Evaluate Impact Strength Variability and Reliability of Preplaced Aggregate Concrete Containing Crumped Rubber and Fibres
by Packirisamy Swaminathan, Kothandapani Karthikeyan, Siva Ramakrishnan Subbaram, Jayaraman Sethuraman Sudharsan, Sallal R. Abid, Gunasekaran Murali and Nikolai Ivanovich Vatin
Materials 2022, 15(15), 5156; https://doi.org/10.3390/ma15155156 - 25 Jul 2022
Cited by 25 | Viewed by 2691
Abstract
The proper disposal of used rubber tires has emerged as a primary concern for the environment all over the globe. Millions of tires are thrown away, buried and discarded every year, posing a major environmental concern owing to their slow decomposition. As a [...] Read more.
The proper disposal of used rubber tires has emerged as a primary concern for the environment all over the globe. Millions of tires are thrown away, buried and discarded every year, posing a major environmental concern owing to their slow decomposition. As a result, it is advantageous to use recycled waste rubber aggregates as an additional building resource. Recycling crushed rubber would lead to a long-term solution to the problem of decreasing natural aggregate resources while conserving the environment. This study examines the impact strength variability and reliability of preplaced aggregate concrete containing crumped rubber and fibres. Ten different mixtures were prepared by replacing natural aggregate with crumped rubber (5, 10, 15 and 20%). The crumped rubber was pretreated by the water with sodium hydroxide dilution for 30 min before usage. Hooked-end steel fibres were used at a dosage of 1.5%. The compressive strength, impact strength, impact ductility index and failure pattern were examined and discussed. In addition, a statistical method called Weibull distribution is used to analyze the scattered experimental results. The results showed that when the crumb rubber content was raised, the retained first cracking and failure impact numbers increased. As a result of substituting crumb rubber for 20% of the coarse aggregate in plain and fibrous mixes, the percentage development in first crack and failure was between 33% and 76% and 75% to 129%, respectively. Full article
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20 pages, 11271 KB  
Article
Mechanical, Microstructural and Drying Shrinkage Properties of NaOH-Pretreated Crumb Rubber Concrete: RSM-Based Modeling and Optimization
by Pretta Malaysia Appana, Bashar S. Mohammed, Isyaka Abdulkadir, M. O. A. Ali and M. S. Liew
Materials 2022, 15(7), 2588; https://doi.org/10.3390/ma15072588 - 1 Apr 2022
Cited by 25 | Viewed by 2951
Abstract
One of the primary causes of the low mechanical properties of rubberized concrete is the weak bond between crumb rubber (CR) and hardened cement paste. Many CR pretreatment techniques have been researched in an attempt to mitigate this problem. The NaOH pretreatment method [...] Read more.
One of the primary causes of the low mechanical properties of rubberized concrete is the weak bond between crumb rubber (CR) and hardened cement paste. Many CR pretreatment techniques have been researched in an attempt to mitigate this problem. The NaOH pretreatment method is one of the most widely used, although the reported results are inconsistent due to the absence of standardized NaOH pretreatment concentrations and CR replacement levels. This study aims to develop models for predicting the mechanical and shrinkage properties of NaOH-pretreated CR concrete (NaOH-CRC) and conduct multi-objective optimization using response surface methodology (RSM). The RSM generated experimental runs using three levels (0, 5, and 10%) of both NaOH pretreatment concentration and the CR replacement level of fine aggregate by volume as the input factors. At 28 days, the concrete’s compressive, flexural, and tensile strengths (CS, FS, and TS), as well as its drying shrinkage (S), were evaluated as the responses. The results revealed that higher CR replacements led to lower mechanical strengths and higher shrinkage. However, the strength loss and the shrinkage significantly reduced by 22%, 44%, 43%, and 60% for CS, FS, TS, and S, respectively, after the pretreatment. Using field-emission scanning electron microscopy (FESEM), the microstructural investigation indicated a significantly reduced interfacial transition zone (ITZ) with increasing NaOH pretreatment. The developed RSM models were evaluated using ANOVA and found to have high R2 values ranging from 78.7% to 98%. The optimization produced NaOH and CR levels of 10% and 2%, respectively, with high desirability of 71.4%. Full article
(This article belongs to the Section Construction and Building Materials)
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16 pages, 5724 KB  
Article
Preparation and Properties Study of Cementitious Grouts Containing Crumb Rubber
by Wei Yuan, Renfeng Yang, Jianyou Yu, Shixin Zhou, Shaoqian Cui, Jian Kang and Zechen Yao
Buildings 2021, 11(11), 555; https://doi.org/10.3390/buildings11110555 - 18 Nov 2021
Cited by 6 | Viewed by 3060
Abstract
This article aims to improve the toughness of pre-packaged grouts (PPG) by incorporating crumb rubber. The mechanism for toughness of PPG with crumb rubber was analyzed based on the uniaxial compression model. Crumb rubber with surfaces treated by different methods (NaOH solutions or [...] Read more.
This article aims to improve the toughness of pre-packaged grouts (PPG) by incorporating crumb rubber. The mechanism for toughness of PPG with crumb rubber was analyzed based on the uniaxial compression model. Crumb rubber with surfaces treated by different methods (NaOH solutions or microwave treatment) was observed by scanning electron microscopy (SEM). The effects of mesh sizes, amounts, surface-treated methods of crumb rubber, and mixing procedures on the PPG’s mechanical strength and rheological properties were investigated. The results showed that, firstly, the addition of crumb rubber improves the PPG’s toughness, while its mechanical strength is reduced. Adding NaOH solutions or microwave-treated crumb rubber into PPG can weaken the negative effects of crumb rubber on the PPG’s mechanical strength; however, this function is limited. Secondly, the crumb rubber grouts’ rheological properties can be fully exploited by increasing the stirring rate and time so that the fluidity of crumb rubber grouts is improved, which fulfils the characteristics of no bleeding and micro-expansion. Finally, the optimal formula and mixing technique of crumb rubber grouts were proposed in this paper.The results of this paper can provide a significant reference for the application of scrap tires. Full article
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16 pages, 6017 KB  
Article
On Developing a Hydrophobic Rubberized Cement Paste
by Chi-Yao Chen, Zih-Yao Shen and Maw-Tien Lee
Materials 2021, 14(13), 3687; https://doi.org/10.3390/ma14133687 - 1 Jul 2021
Cited by 8 | Viewed by 3256
Abstract
It is well known that most cement matrix materials are hydrophilic. For structural materials, hydrophilicity is harmful because the absorption of water will induce serious damage to these materials. In this study, crumb rubber was pretreated by partial oxidation and used as an [...] Read more.
It is well known that most cement matrix materials are hydrophilic. For structural materials, hydrophilicity is harmful because the absorption of water will induce serious damage to these materials. In this study, crumb rubber was pretreated by partial oxidation and used as an additive to develop a hydrophobic rubberized cement paste. The pretreated crumb rubber was investigated using Fourier-transform infrared spectrometry (FT-IR) to understand the function groups on its surface. The pyrolysis oil adsorbed on the surface of the crumb rubber was observed by FT-IR and nuclear magnetic resonance (NMR) spectroscopy. A colloid probe with calcium silicate hydrate (C–S–H) at the apex was prepared to measure the intermolecular interaction forces between the crumb rubber and the C-S-H using an atomic force microscope (AFM). Pure cement paste, cement paste with the as-received crumb rubber, and cement paste with pretreated crumb rubber were prepared for comparison. FT-IR, X-ray diffraction (XRD), and scanning electron microscopy (SEM) were used to understand the microstructure of the pastes. The static contact angle was used as the index of the hydrophobicity of the pastes. Experimental results showed that the hardened cement paste containing partially oxidized crumb rubber had excellent hydrophobic properties with an insignificant reduction in the compressive strength. Full article
(This article belongs to the Special Issue Development and Research of Cementitious Materials)
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