Search Results (1,065)

This study examines the effect of temperature during pyrolysis on the capacity of cedar wood-derived biochar to be employed as a sustainable electrode material for supercapacitors. Cedar wood-derived biochars were produced at different temperatures of 800 °C, 900 °C, 1000 °C and 1100 °C and fully characterized in terms of their structural, physicochemical and electrochemical properties, including specific surface area, hydrophobicity, electrical conductivity, and surface functional groups. The results indicated that the cedar wood biochar obtained through pyrolysis at 900 °C (BC900) provided optimal electrical conductivity, hydrophobicity, and porosity characteristics relative to the other cedar wood biochars produced by pyrolysis at 800 °C to 1100 °C. Specifically, when compared to commercial activated carbon (AC), BC900 provided half the specific capacitance at a current density of 1 A g⁻¹ and indicated that there is more potential for improvement with further activation and doping. The influence of the binder (either polyvinylidene fluoride (PVDF) or chitosan) in combination with conductive carbon black (CB) was also examined. Electrodes fabricated with PVDF binder showed higher specific capacitance, while biochar electrodes made from CB and chitosan (BC900/CB/chitosan) showed better electrical conductivity, wettability, and good electrochemical stability with >95% capacity retention even after 10,000 cycles. Full article

In this study, we present a flexible piezoelectric nanogenerator based on a zinc oxide (ZnO)/polyvinylidene fluoride (PVDF) nanocomposite electrospun onto a hemisphere-patterned PDMS substrate. The nanogenerator was fabricated by replicating a silicon mold with inverted hemispheres into PDMS, followed by direct electrospinning of ZnO-dispersed PVDF nanofibers. Varying the ZnO concentration from 0.6 to 1.4 wt% allowed us to evaluate its effect on structural, dielectric, and piezoelectric properties. The nanogenerator containing 0.8 wt% ZnO exhibited the thinnest fibers (371 nm), the highest β-phase fraction (85.6%), and the highest dielectric constant (35.8). As a result, it achieved the maximum output voltage of 7.30 V, with excellent signal consistency under an applied pressure of 5 N. Comparisons with pristine PVDF- and ZnO/PVDF-only devices demonstrated the synergistic effect of ZnO loading and patterned PDMS on the enhancement of piezoelectric output. The hemisphere-patterned PDMS substrate improved the mechanical strain distribution, interfacial contact, and charge collection efficiency. These results highlight the potential of ZnO/PVDF/PDMS hybrid nanogenerators for use in wearable electronics and self-powered sensor systems. Full article

High safety gel polymer electrolyte (GPE) is used in lithium metal solid state batteries, which has the advantages of high energy density, wide temperature range, high safety, and is considered as a subversive new generation battery technology. However, solid-state lithium batteries with multiple layers and large capacity currently have poor cycle life and a large gap between the actual output cycle capacity retention rate and the theoretical level. In this paper, polyvinylidene fluoride-hexafluoropropylene (PVDF-HFP)/polyacrylonitrile (PAN)—lithium perchlorate (LiClO₄)—lithium lanthanum zirconium tantalate (LLZTO) gel polymer electrolytes was prepared by UV curing process using a UV curing machine at a speed of 0.01 m/min for 10 s, with the temperature controlled at 30 °C and wavelength 365 nm. In order to study the performance and failure mechanism of multilayer solid state batteries, single and three layers of solid state batteries with ceramic/polymer composite gel electrolyte were assembled. The results show that the rate and cycle performance of single-layer solid state battery with gel electrolyte are better than those of three-layer solid state battery. As the number of cycles increases, the interface impedance of both single-layer and three-layer electrolyte membrane solid-state batteries shows an increasing trend. Specifically, the three-layer battery impedance increased from 17 Ω to 42 Ω after 100 cycles, while the single-layer battery showed a smaller increase, from 2.2 Ω to 4.8 Ω, indicating better interfacial stability. After 100 cycles, the interface impedance of multi-layer solid-state batteries increases by 9.61 times that of single-layer batteries. After 100 cycles, the corresponding capacity retention rates were 48.9% and 15.6%, respectively. This work provides a new strategy for large capacity solid state batteries with gel electrolyte design. Full article

This study explores using polyvinylidene fluoride (PVDF) membranes modified with multi-walled carbon nanotubes (MWCNTs) to treat simulated and industrial brine from coal power stations. The MWCNTs were acid-treated and characterized using Fourier Transform Infrared Spectroscopy (FTIR), Raman, and nitrogen sorption at 77 K, Thermogravimetric analysis (TGA), and Transmission electron microscopy (TEM). The desired membranes were obtained by casting from a solution of N-Methyl-2-pyrrolidone, PVDF, various weight percentages of MWCNTs, and a small amount of polyvinylpyrrolidone. The acid treatment of the MWCNTs introduced oxygen moieties on the surface, and increased pore volume and surface area while maintaining crystallinity and structural integrity remain preserved. The maximum rejection rate achieved was 41.82% with 1 wt.% of acid-treated MWCNTs in the PVDF membrane. Acid-treated MWCNTs loaded membranes had an improved rejection rate, which was 5× higher than membranes without MWCNTs. Full article

This paper proposes an Adam-optimized Deep Belief Networks (Adam-DBNs) denoising method for throat-attached piezoelectric signals. The method aims to process mechanical vibration signals captured through polyvinylidene fluoride (PVDF) sensors attached to the throat region, which are typically contaminated by environmental noise and physiological noise. First, the short-time Fourier transform (STFT) is utilized to convert the original signals into the time–frequency domain. Subsequently, the masked time–frequency representation is reconstructed into the time domain through a diagonal average-based inverse STFT. To address complex nonlinear noise structures, a Deep Belief Network is further adopted to extract features and reconstruct clean signals, where the Adam optimization algorithm ensures the efficient convergence and stability of the training process. Compared with traditional Convolutional Neural Networks (CNNs), Adam-DBNs significantly improve waveform similarity by 6.77% and reduce the local noise energy residue by 0.099696. These results demonstrate that the Adam-DBNs method exhibits substantial advantages in signal reconstruction fidelity and residual noise suppression, providing an efficient and robust solution for throat-attached piezoelectric sensor signal enhancement tasks. Full article

The inherent hydrophobic nature of PVDF material renders it challenging to establish a stable aqueous hydration layer, thereby limiting its suitability as a substrate for the preparation of nanofiltration (NF) membranes. In this study, we developed a novel modification approach that effectively enhances the hydrophilicity of PVDF substrates through the incorporation of sulfonic acid-doped polyaniline (SPANI) and hyperbranched polyester (HPE) into the PVDF casting solution, followed by cross-linking with trimesoyl chloride (TMC). The introduction of SPANI and HPE, which contain reactive polar amino and hydroxyl groups, improved the hydrophilicity of the substrate, while the subsequent cross-linking with TMC effectively anchored these components within the substrate through the covalent linking between TMC and the reactive sites. Additionally, the hydrolysis of TMC yielded non-reactive carboxyl groups, which further enhanced the hydrophilicity of the substrate. As a result, the modified PVDF substrate exhibited improved hydrophilicity, facilitating the construction of an intact polyamide layer. In addition, the fabricated TFC NF membrane demonstrated excellent performance in the advanced treatment of tap water, achieving a total dissolved solid removal rate of 57.9% and a total organic carbon removal rate of 85.3%. This work provides a facile and effective route to modify PVDF substrates for NF membrane fabrication. Full article

Planar heaters are designed to deliver uniform heat across broad surfaces and serve as critical components in applications requiring energy efficiency, safety, and mechanical flexibility, such as wearable electronics and smart textiles. However, conventional metal-based heaters are limited by poor adaptability to curved or complex surfaces, low mechanical compliance, and susceptibility to oxidation-induced degradation. To overcome these challenges, we applied a protein-assisted electroless copper (Cu) plating strategy to electrospun poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) nanofiber substrates to fabricate flexible, conductive planar heating membranes. For interfacial functionalization, a protein-based engineering approach using bovine serum albumin (BSA) was employed to facilitate palladium ion coordination and seed formation. The resulting membrane exhibited a dense, continuous Cu coating, low sheet resistance, excellent durability under mechanical deformation, and stable heating performance at low voltages. These results demonstrate that the BSA-assisted strategy can be effectively extended to complex three-dimensional fibrous membranes, supporting its scalability and practical potential for next-generation conformal and wearable planar heaters. Full article

With engineering plastics increasingly replacing traditional materials in various drive and control gear systems across numerous industrial sectors, material selection for any gearwheel critically impacts its mechanical and thermal properties. This paper investigates the engagement of steel and Polyvinylidene Fluoride (PVDF) gear pairs tested under several load conditions to determine polymer gears’ characteristic service life and failure modes. Furthermore, recognizing that the application of polymer gears is limited by insufficient data on their temperature-dependent mechanical properties, this study establishes a correlation between the tribological contact, meshing temperatures, and wear coefficients of PVDF gears. The results demonstrate that the flank surface wear of the PVDF gears is directly proportional to the temperature and load level of the tested gears. Several distinct load-induced failure modes have been detected and categorized into three groups: abrasive wear resulting from the hardness disparity between the engaging surfaces, thermal failure caused by heat accumulation at higher load levels, and tooth fracture occurring due to stiffness changes induced by the compromised tooth cross-section after numerous operating cycles at a specific wear rate. Full article

Background/Objectives: Airborne viral diseases pose a health risk, due to which there is a growing interest in developing filter materials capable of capturing fine particles containing virions from the air and that also have a virucidal effect. Nanofiber membranes made of poly(vinylidene fluoride) dissolved in N,N-dimethylacetamide and functionalized with copper, silver, and zinc nanoclusters were fabricated via electrospinning. This study aims to evaluate and compare the virucidal effects of nanofibers functionalized with metal nanoclusters against the human influenza A virus A/WSN/1933 (H1N1) and SARS-CoV-2. Methods: A comprehensive characterization of materials, including X-ray diffraction, scanning electron microscopy, microwave plasma atomic emission spectroscopy, thermogravimetric analysis, contact angle measurements, nitrogen sorption analysis, mercury intrusion porosimetry, filtration efficiency, and virucidal tests, was used to understand the interdependence of the materials’ physical characteristics and biological effects, as well as to determine their suitability for application as antiviral materials in air filtration systems. Results: All the filter materials tested demonstrated very high particle filtration efficiency (≥98.0%). The material embedded with copper nanoclusters showed strong virucidal efficacy against the SARS-CoV-2 alpha variant, achieving an approximately 1000-fold reduction in infectious virions within 12 h. The fibrous nanowire polymer functionalized with zinc nanoclusters was the most effective material against the human influenza A virus strain A/WSN/1933 (H1N1). Conclusions: The materials with Cu nanoclusters can be used with high efficiency to passivate and kill the SARS-CoV-2 alpha variant virions, and Zn nanoclusters modified activated porous membranes for killing human influenza A virus A7WSN/1933 (H1N1) virions. Full article

Active packaging films have been an essential component in food material research to ensure the safe and efficient preservation of food, fruit, and vegetables. The shelf life of fruits and vegetables may likely be extended by covering them with high-performance nanofiber (NF) films. The selection of materials for active packaging film has been a critical factor in preventing food materials from environmental contaminants (microbes) and extending the shelf life. This study aims to develop NF-based materials for cherry tomatoes to prevent fungal and bacterial damage. Bioactive NFs were produced through an electrospinning process using tannic acid (TA) within a polyvinylidene fluoride (PVDF) template. These NFs offer a sustainable alternative to synthetic packaging for food preservation. TA was incorporated into the PVDF matrix at varying concentrations (0.4 to 1.2%). Key parameters, including moisture content, thickness, opacity, water-contact angle, and thermal shrinkage, were assessed. The physicochemical results indicate that the TA NFs are suitable for further shelf-life performance evaluations. The antifungal and antibiofilm activity of the NFs was tested, showing that the TA_1.2 in the PVDF matrix was more effective than other concentrations. Shelf-life tests demonstrated that cherry tomatoes covered with TA_1.2 NFs showed no surface changes for up to 4 days. Importantly, the NFs were confirmed to be non-toxic to normal cells, as evidenced by tests on mouse 3T3-L1 fibroblast cells. In summary, we have developed bioactive NFs composed of TA in a PVDF matrix that enhance the shelf life of cherry tomatoes by preventing bacterial and fungal attacks on the fruit surfaces. Full article

Polymer composites with high dielectric permittivity (>10) and low dielectric loss are critical for energy storage and microelectronic applications. This study reports on a semi-transparent composite of a PVDF copolymer filled with Cu₇S₄ nanoparticles synthesized via a wet chemical route. Only a small content (6%) of copper sulfide increases the dielectric permittivity of the material from 10.4 to 15.9 (1 kHz), maintaining a low dielectric loss coefficient (less than 0.1). The incorporated nanoparticles affect the morphology of the composite film surface and crystalline phases in the whole volume, which was studied with FTIR spectroscopy, differential scanning calorimetry and scanning probe microscopy. Full article

Triboelectric nanogenerators (TENGs), as an emerging energy harvesting device, can efficiently convert the weak mechanical energy in the environment into electrical energy, demonstrating significant potential in self-powered systems. In this study, polyvinylidene fluoride (PVDF) nanofiber films mixed with a small amount of n-propyl gallate (PG) were prepared by using the electrospinning technique, and TENGs were fabricated based on these films. Unexpectedly, experimental results showed that PG (with 0.5–2.5 wt%) did not affect the β phase of the PVDF. However, the TENG based on PVDF/PG composite nanofiber film with 1 wt% PG (PG1-TENG) exhibited large output values of 334 V, 4.36 μA, and 78.4 nC for output voltage, current, and transferred charge, respectively, with a power density of 5.27 W/m², which highlights ~60% improvement in output voltage over pristine PVDF-TENG. This observation was attributed to the unique charge regulation ability of PG, without altering PVDF’s β phase. Furthermore, application potential of PG1-TENG was demonstrated by powering up an LCD calculator and 480 LEDs. Full article

The application of an ultrafiltration (UF) process with periodic membrane cleaning with the use of alkaline detergent solutions was proposed for the recovery of wash water from car wash effluent. In order to test the resistance of the membranes to the degradation caused by the cleaning solutions, a pilot plant study was carried out for almost two years. The installation included an industrial module with FP100 tubular membranes made of polyvinylidene fluoride (PVDF). The module was fed with synthetic effluent obtained by mixing foaming agents and hydrowax. To limit the fouling phenomenon, the membranes were cleaned cyclically with P3 Ultrasil 11 solution (pH = 11.7) or Insect solution (pH = 11.5). During plant shutdowns, the membrane module was maintained with a sodium metabisulphite solution. Changes in the permeate flux, turbidity, COD, and surfactant rejection were analysed during the study. Scanning electron microscopy (SEM), atomic force microscopy (AFM), differential scanning calorimetry (DSC), and Fourier-transform infrared spectroscopy (FTIR) analysis were used to determine the changes in the membrane structure. As a result of the repeated chemical cleaning, the pore size increased, resulting in a more than 50% increase in permeate flux. However, the quality of the recovered wash water did not deteriorate, as an additional separation layer was formed on the membrane surface due to the fouling phenomenon. Full article

To improve solid-state lithium batteries, solution casting has been employed to create lithium ion-conducting copolymer electrolytes involving poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP)/polyvinylpyrrolidone (PVP) blend polymers with various compositions. Following X-ray diffraction and Fourier transformation (FTIR), the structural characterisation and identification of molecular bonding in polymer electrolytes were confirmed. Through AC impedance analysis, the electrical characteristics of the solid-state polymer films were investigated. The dielectric conductivity of the sample was found to obey the modified Arrhenius relationship, while in the case of a sample with higher conductivity, it followed Arrhenius behaviour. The relaxation parameters and dielectric behaviour of the samples are demonstrated and discussed. Full article

This study examines how the frequency of an innovative energy harvester is tuned and how it behaves. This harvester transforms thermal energy into mechanical oscillations of two polyvinylidene fluoride (PVDF) piezoelectric beams, which produce electrical energy via a shape memory alloy (SMA) thread. The oscillation frequency is modified by two magnetic weights that are positioned symmetrically on the SMA thread and interact with stationary NdFeB permanent magnets. The SMA thread shifts laterally due to longitudinal thermal contraction and expansion induced by a constant-temperature heater. Temperature gradients above the heater trigger cyclical variations in the length of the SMA thread, leading to autonomous vibrations of the masses in both the vertical and horizontal planes. An experimental apparatus was constructed to analyze the harvester by tracking the motions of the masses and the voltages produced by the piezoelectric beams. Information was gathered regarding the correlation between output voltage and power with the consumer’s load resistance. These outcomes were confirmed using a multiphysics dynamic simulation that incorporated the interconnections among mechanical, thermal, magnetic, and electrical systems. The findings indicate that the use of permanent magnets increases the bending vibration frequency from 8.3 Hz to 9.2 Hz. For a heater maintained at 70 °C, this boosts the output power from 1.9 µW to 8.18 µW. A notable property of the considered energy harvester configuration is its ability to operate at cryogenic temperatures. Full article