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Keywords = polarization holographic gratings

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32 pages, 19989 KB  
Article
Design and Fabrication of Volume Phase Holographic Gratings for CO2 Detection: A Multi-Objective Optimization Approach
by Lei Dai, Chao Lin, Zhenhua Ji, Yang Fu, Shuo Wang and Yuquan Zheng
Photonics 2026, 13(5), 501; https://doi.org/10.3390/photonics13050501 - 18 May 2026
Viewed by 767
Abstract
Volume phase holographic gratings (VPHGs) are high-performance dispersive elements characterized by high diffraction efficiency and low noise. When used as dispersive components in imaging spectrometers for CO2 detection, they can significantly enhance instrument performance, detection capability, and measurement accuracy. However, for short-wave [...] Read more.
Volume phase holographic gratings (VPHGs) are high-performance dispersive elements characterized by high diffraction efficiency and low noise. When used as dispersive components in imaging spectrometers for CO2 detection, they can significantly enhance instrument performance, detection capability, and measurement accuracy. However, for short-wave infrared (SWIR) applications requiring high dispersion and operational efficiency, traditional design approaches struggle to effectively balance the trade-offs among multidimensional diffraction performance metrics, resulting in low optimization efficiency. Furthermore, as spectrometers require dispersive elements, established fabrication methods lack robust methodologies for producing large-area VPHGs. To address these gaps, we developed both a design approach and a fabrication process for VPH gratings tailored to CO2 detection. On the design front, we propose a novel method that integrates a multi-objective simulated annealing optimization algorithm with Kogelnik’s coupled-wave theory. The optimized gratings achieve diffraction efficiencies of 95.35% (TE polarization) and 82.21% (TM polarization) across the target spectral range, with polarization sensitivity maintained below 6.57%. For fabrication, we developed holographic plate fabrication via a blade-coating technique coupled with an optimized aging protocol. A medium-to-large aperture holographic recording and exposure system with a wavefront error better than λ/25 RMS was developed. Post-processing conditions were systematically optimized based on experimental diffraction efficiency measurements, enabling the successful fabrication of VPHGs. It is explicitly noted that the experimental validation of the fabricated VPHGs is limited to the 1.620–1.630 μm wavelength range, while the full target design range of 1.620–1.650 μm has not been experimentally verified in this work. This work provides a valuable reference for the selection of dispersive elements for next-generation CO2 detection satellites. The designed gratings fully meet application requirements, while the established fabrication process lays a solid foundation for the production of high-performance VPHGs. Full article
(This article belongs to the Section Lasers, Light Sources and Sensors)
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14 pages, 2693 KB  
Article
Multilayered DNA Complex/Azo-Carbazole Films for Enhanced Holographic Recording
by Abishaka Arul Dhas, Diaa Hamed Abdelshafy Abdelsalam, Kenji Kinashi, Wataru Sakai, Naoto Tsutsumi and Jackin Boaz Jessie
Photonics 2026, 13(1), 1; https://doi.org/10.3390/photonics13010001 - 19 Dec 2025
Viewed by 1308
Abstract
Azobenzene-based hologram recording materials are well known for their rewritable and polarization-selective properties that enable polarization-multiplexed recording and high-density optical storage. High diffraction efficiency, longer retention time, and shorter response time are desirable for rewritable recording materials, but they always require a trade-off [...] Read more.
Azobenzene-based hologram recording materials are well known for their rewritable and polarization-selective properties that enable polarization-multiplexed recording and high-density optical storage. High diffraction efficiency, longer retention time, and shorter response time are desirable for rewritable recording materials, but they always require a trade-off relationship. In this study, we show that by simply coating the Azobenzene-based film with multiple layers of a suitable material, these parameters can be improved simultaneously without compromise. Bilayer films and triple layer films were prepared by depositing a DNA–surfactant complex-based layer above and below the azobenzene-based poly(CACzE-MMA) copolymer layer. The hologram recording performance was evaluated in terms of the diffraction efficiency, photoresponse time, and retention behavior of the recorded gratings. Compared with monolayer copolymer films, the multilayer DNA–surfactant complex-based copolymer films exhibited enhanced diffraction efficiency and faster photoresponse. In particular, the bilayer and trilayer structures showed a marked improvement in retention time, indicating suppressed relaxation of refractive index modulation. This enhancement is attributed to molecular confinement at the DNA–surfactant complex and copolymer interfaces generated by the layered architecture. These results demonstrate that a DNA–surfactant complex-based layering approach is an effective strategy for improving hologram stability and highlight the potential of DNA–surfactant complex-derived matrices as effective alternatives to poly(methyl methacrylate) (PMMA) in holographic applications. Full article
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38 pages, 6873 KB  
Review
Next-Generation Visual Experience: Polarization Volume Gratings in Holographic Waveguides for AR/VR
by Ali Zia, Mohamed Hassan Eisa, Sadaf Saeed and Kinza Arshad
Spectrosc. J. 2025, 3(4), 25; https://doi.org/10.3390/spectroscj3040025 - 21 Oct 2025
Cited by 1 | Viewed by 6721
Abstract
Polarization volume gratings (PVGs) have been recognized as a groundbreaking technology with the potential to revolutionize holographic waveguides and facilitate immersive experiences in augmented and virtual reality (AR/VR) applications. This study investigated the design, fabrication, and utilization of PVGs within the framework of [...] Read more.
Polarization volume gratings (PVGs) have been recognized as a groundbreaking technology with the potential to revolutionize holographic waveguides and facilitate immersive experiences in augmented and virtual reality (AR/VR) applications. This study investigated the design, fabrication, and utilization of PVGs within the framework of holographic waveguides for immersive encounters. The essay begins by presenting a comprehensive overview of waveguide technologies. The display devices and optical combiners combine the actual and virtual worlds that the naked eye can see. This review categorizes current visual solutions for micro-optical combiners in augmented reality head-mounted displays (AR-HMDs). Subsequently, an investigation was carried out into the manufacturing process, physical principles, optical structures, performance characteristics, and other aspects. Furthermore, a review and assessment of their merits and drawbacks were conducted. Full article
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19 pages, 17495 KB  
Article
Study on the Design Method of High-Resolution Volume-Phase Holographic Gratings
by Shuo Wang, Lei Dai, Chao Lin, Long Wang, Zhenhua Ji, Yang Fu, Quyouyang Gao and Yuquan Zheng
Sensors 2024, 24(19), 6493; https://doi.org/10.3390/s24196493 - 9 Oct 2024
Cited by 3 | Viewed by 3963
Abstract
Volume-phase holographic gratings are suitable for use in greenhouse gas detection imaging spectrometers, enabling the detection instruments to achieve high spectral resolution, high signal-to-noise ratios, and high operational efficiency. However, when utilized in the infrared wavelength band with high dispersion requirements, gratings struggle [...] Read more.
Volume-phase holographic gratings are suitable for use in greenhouse gas detection imaging spectrometers, enabling the detection instruments to achieve high spectral resolution, high signal-to-noise ratios, and high operational efficiency. However, when utilized in the infrared wavelength band with high dispersion requirements, gratings struggle to meet the demands for low polarization sensitivity due to changes in diffraction performance caused by phase delays in the incidence of light waves with distinct polarization states, and current methods for designing bulk-phase holographic gratings require a large number of calculations that complicate the balance of diffraction properties. To overcome this problem, a design method for transmissive bulk-phase holographic gratings is proposed in this study. The proposed method combines two diffraction theories (namely, Kogelnik coupled-wave theory and rigorous coupled-wave theory) and establishes a parameter optimization sequence based on the influence of design parameters on diffraction characteristics. Kogelnik coupled-wave theory is employed to establish the initial Bragg angle range, ensuring that the diffraction efficiency and phase delay of the grating thickness curve meet the requirements for incident light waves in various polarization states. Utilizing rigorous coupled-wave theory, we optimize grating settings based on criteria such as a center wavelength diffraction efficiency greater than 95%, polarization sensitivity less than 10%, maximum bandwidth, and spectral diffraction efficiency exceeding 80%. The ideal grating parameters are ultimately determined, and the manufacturing tolerances for various grating parameters are analyzed. The design results show that the grating stripe frequency is 1067 lines per millimeter, and the diffraction efficiencies of TE and TM waves are 96% and 99.89%, respectively. The diffraction efficiency of unpolarized light is more than 88% over the whole spectral range with an average efficiency of 94.49%, an effective bandwidth of 32 nm, and a polarization sensitivity of less than 7%. These characteristics meet the performance requirements for dispersive elements based on greenhouse gas detection, the spectral resolution of the detection instrument is up to 0.1 nm, and the signal-to-noise ratio and working efficiency are improved by increasing the transmittance of the instrument. Full article
(This article belongs to the Section Optical Sensors)
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12 pages, 2430 KB  
Article
Higher-Dimensional Communications Using Multimode Fibers and Compact Components to Enable a Dense Set of Communicating Channels
by Daniel A. Nolan
Optics 2024, 5(3), 330-341; https://doi.org/10.3390/opt5030024 - 7 Aug 2024
Cited by 1 | Viewed by 3071
Abstract
Higher-dimensional communications are of interest for multiple reasons, including increasing the classical transmission capacity and, more recently, the quantum state transfer through fibers using the many modes within the fiber. For quantum communications, this enables an increase in the number of bits per [...] Read more.
Higher-dimensional communications are of interest for multiple reasons, including increasing the classical transmission capacity and, more recently, the quantum state transfer through fibers using the many modes within the fiber. For quantum communications, this enables an increase in the number of bits per photon, increasing quantum fidelity, increasing error thresholds and enabling hyperentanglement transfer, among other possibilities. A high-dimensional quantum state transfer can be transported through multimode fiber using the many modes available. However, this transfer of information through multimode optical fiber is limited by attenuation and mode coupling among the various spatial and polarization modes. Here, we consider how this mode coupling impacts the transfer process. We consider the fiber’s modal properties, including orbital angular momentum, modal group numbers, and principal modes. We also investigate and propose input and output optical components, as well as fiber properties, which better mitigate the deleterious effects of mode coupling. We use the WKB approximation to the scaler wave equation as a guidance to quantify this coupling and then implement corrections to this approximation using exact solutions to the scaler wave equation. We consider methods to circumvent this mode coupling using optical fiber designs, holographic optical components and devices that are commercially available today. Some of these components, such as the holographic gratings and lenses, could be implemented using flat optics. Full article
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12 pages, 2756 KB  
Article
Polarization Diffraction Gratings in PAZO Polymer Thin Films Recorded with Digital Polarization Holography: Polarization Properties and Surface Relief Formation
by Nataliya Berberova-Buhova, Lian Nedelchev, Georgi Mateev, Ludmila Nikolova, Elena Stoykova, Branimir Ivanov, Velichka Strijkova, Keehoon Hong and Dimana Nazarova
Photonics 2024, 11(5), 425; https://doi.org/10.3390/photonics11050425 - 3 May 2024
Cited by 8 | Viewed by 3241
Abstract
In this work, we study the polarization properties of diffraction gratings recorded in thin films of the azopolymer PAZO (poly[1-[4-(3-carboxy-4-hydroxyphenylazo)benzene sulfonamido]-1,2-ethanediyl, sodium salt]) using digital polarization holography. Using two quarter-wave plates, the phase retardation of each pixel of the SLM is converted into [...] Read more.
In this work, we study the polarization properties of diffraction gratings recorded in thin films of the azopolymer PAZO (poly[1-[4-(3-carboxy-4-hydroxyphenylazo)benzene sulfonamido]-1,2-ethanediyl, sodium salt]) using digital polarization holography. Using two quarter-wave plates, the phase retardation of each pixel of the SLM is converted into the azimuth rotation of linearly polarized light. When recording from the azopolymer side of the sample, significant surface relief amplitude is observed with atomic force microscopy. In contrast, recording from the substrate side of the sample allows the reduction of the surface relief modulation and the obtaining of polarization gratings with characteristics close to an ideal grating, recorded with two orthogonal circular polarizations. This can be achieved even with a four-pixel period of grating, as demonstrated by our results. Full article
(This article belongs to the Special Issue Technologies and Applications of Digital Holography)
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15 pages, 2991 KB  
Article
Analysis of Polarization Angle on Holographic Recording Based on PQ/PMMA
by Wanxiang He, Defa Liu, Hang Chen, Jundi Wang, Yaping Zhang and Bing Zhang
Polymers 2024, 16(6), 821; https://doi.org/10.3390/polym16060821 - 15 Mar 2024
Cited by 4 | Viewed by 2324
Abstract
The polarization state of light waves significantly affects the quality of holographic recordings. This paper quantitatively analyzes the impact of different polarization states of signal and reference beams on the quality of holographic recordings in PQ/PMMA photopolymer systems during the holography process. By [...] Read more.
The polarization state of light waves significantly affects the quality of holographic recordings. This paper quantitatively analyzes the impact of different polarization states of signal and reference beams on the quality of holographic recordings in PQ/PMMA photopolymer systems during the holography process. By deriving the light field distribution of the interference between two light waves of different polarization states and introducing the interference fringe contrast and the modulation of the refractive index of the photopolymer, we established the relationship between the diffraction efficiency of PQ/PMMA photopolymer holographic gratings and the angle between polarization directions. Based on this relationship, simulations and experiments were conducted. The experimental results demonstrated that as the angle between the polarization directions increased, the diffraction efficiency of the material decreased, with the efficiency dropping to 24.69% of its original value when the angle increased from 0° to 50°. When the angle increased to 60°, the influence of polarization characteristics became gradually significant, and at 90°, it was entirely dominated by polarization characteristics. The photoinduced birefringence properties of the PQ/PMMA prepared in the measurement experiment were studied, and the polarization characteristics of the reconstructed light under polarization direction angles of 0°, 60°, and 90° were investigated. The results indicated that at a polarization direction angle of 60 degrees, the material exhibited a significant response to the polarization information of the signal light. Finally, holographic recordings of objects at different polarization direction angles were conducted, and the reconstructed images were used to visually reflect the impact of the polarization direction angle on the quality of holographic recordings. Full article
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38 pages, 5421 KB  
Review
Nanocomposite Photoanisotropic Materials for Applications in Polarization Holography and Photonics
by Dimana Nazarova, Lian Nedelchev, Nataliya Berberova-Buhova and Georgi Mateev
Nanomaterials 2023, 13(22), 2946; https://doi.org/10.3390/nano13222946 - 14 Nov 2023
Cited by 18 | Viewed by 3303
Abstract
Photoanisotropic materials, in particular azodyes and azopolymers, have attracted significant research interest in the last decades. This is due to their applications in polarization holography and 4G optics, enabling polarization-selective diffractive optical elements with unique properties, including circular polarization beam-splitters, polarization-selective bifocal lenses, [...] Read more.
Photoanisotropic materials, in particular azodyes and azopolymers, have attracted significant research interest in the last decades. This is due to their applications in polarization holography and 4G optics, enabling polarization-selective diffractive optical elements with unique properties, including circular polarization beam-splitters, polarization-selective bifocal lenses, and many others. Numerous methods have been applied to increase the photoinduced birefringence of these materials, and as a result, to obtain polarization holographic elements with a high diffraction efficiency. Recently, a new approach has emerged that has been extensively studied by many research groups, namely doping azobenzene-containing materials with nanoparticles with various compositions, sizes, and morphologies. The resulting nanocomposites have shown significant enhancement in their photoanisotropic response, including increased photoinduced birefringence, leading to a higher diffraction efficiency and a larger surface relief modulation in the case of polarization holographic recordings. This review aims to cover the most important achievements in this new but fast-growing field of research and to present an extensive comparative analysis of the result, reported by many research groups during the last two decades. Different hypotheses to explain the mechanism of photoanisotropy enhancement in these nanocomposites are also discussed. Finally, we present our vision for the future development of this scientific field and outline its potential applications in advanced photonics technologies. Full article
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11 pages, 2153 KB  
Article
Two-Dimensional Polarization Holographic Gratings in Azopolymer Thin Films: Polarization Properties in the Presence or Absence of Surface Relief
by Georgi Mateev, Lian Nedelchev, Ludmila Nikolova, Branimir Ivanov, Velichka Strijkova, Elena Stoykova, Kihong Choi, Joongki Park and Dimana Nazarova
Photonics 2023, 10(7), 728; https://doi.org/10.3390/photonics10070728 - 26 Jun 2023
Cited by 11 | Viewed by 3180
Abstract
During polarization holographic recording in azopolymer thin films, usually together with the volume anisotropic grating, a surface relief grating (SRG) is also formed. By using two consecutive exposures, it is possible to obtain a two-dimensional (2D) grating. To the best of our knowledge, [...] Read more.
During polarization holographic recording in azopolymer thin films, usually together with the volume anisotropic grating, a surface relief grating (SRG) is also formed. By using two consecutive exposures, it is possible to obtain a two-dimensional (2D) grating. To the best of our knowledge, the polarization properties of such gratings have not been studied yet. To determine the influence of the surface relief on the polarization selectivity of the 2D gratings, we propose two methods to suppress the SRG formation: by varying the recording conditions or varying the sample structure. In these experiments we have used the commercially available azopolymer PAZO, poly[1-4-(3-carboxy-4-hydrophenylazo) benzene sulfonamido]-1,2-ethanediyl, sodium salt] to perform the polarization holographic recording using a 442 nm He-Cd laser. As indicated by our results, when the surface relief is present, it strongly dominates the response of the 2D grating and it behaves almost as a scalar polarization insensitive grating. Conversely, when the SRG formation is suppressed, the polarization properties of the 2D grating in all four diffracted orders are very well pronounced. In this way, we demonstrate that we can easily control SRG formation and, if desired, obtain 2D grating with high surface relief modulation, or alternatively record polarization-selective 2D gratings with virtually no surface relief. Full article
(This article belongs to the Special Issue Coherent and Polarization Optics)
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11 pages, 3055 KB  
Communication
Holographic Writing of Forked Diffraction Gratings on the Surface of a Chalcogenide Glass Semiconductor
by Nikolay A. Ivliev, Svetlana N. Khonina, Vladimir V. Podlipnov and Sergey V. Karpeev
Photonics 2023, 10(2), 125; https://doi.org/10.3390/photonics10020125 - 27 Jan 2023
Cited by 9 | Viewed by 3368
Abstract
We consider the formation of forked diffraction gratings on the surface of a multilayer structure based on chalcogenide glass semiconductors As2S3 and a-Se is. The distribution of electric field components upon interference of beams with different polarization states is analyzed [...] Read more.
We consider the formation of forked diffraction gratings on the surface of a multilayer structure based on chalcogenide glass semiconductors As2S3 and a-Se is. The distribution of electric field components upon interference of beams with different polarization states is analyzed theoretically. The possibility of direct holographic writing of diffraction gratings with a “forked” structure is demonstrated. The parameters of vortex laser beams generated by the microrelief formed are examined. Full article
(This article belongs to the Special Issue Vortex Beams: Fundamentals and Applications)
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10 pages, 2493 KB  
Communication
Vectorial Manipulation of High-Resolution Focusing Optical Field through a Scattering Medium
by Bote Qi, Lihua Shen, Khian-Hooi Chew and Rui-Pin Chen
Photonics 2022, 9(10), 737; https://doi.org/10.3390/photonics9100737 - 8 Oct 2022
Cited by 8 | Viewed by 6014
Abstract
The manipulation of the polarization states of the light transmitted through a scattering medium has become an emerging field due to the novel fundamental physics interest and potential applications. Here, the manipulation of the polarization states in the focusing high-resolution optical field (points [...] Read more.
The manipulation of the polarization states of the light transmitted through a scattering medium has become an emerging field due to the novel fundamental physics interest and potential applications. Here, the manipulation of the polarization states in the focusing high-resolution optical field (points and vector beams) after passing a scattering medium is theoretically and experimentally demonstrated. The vector transmission matrix (VTM) of a scattering medium is measured with the vector basis of orthogonally circular polarizations by the two-dimensional (2D) holographic grating combined with the four-step phase-shifting method. The incident wavefronts for the creation of desired high-resolution optical fields through a scattering medium are modulated according to the calculation with the VTM of the medium. The theoretical and experimental results show that the constructed high-resolution optical field with spatially variant states of polarization can be realized through frosted glass. These results provide a new way to vectorially manipulate the constructed high-resolution optical field by passing through a scattering medium. Full article
(This article belongs to the Special Issue Photorefractive Photonics and Beyond)
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10 pages, 2971 KB  
Article
Ferroelectric Liquid Crystal Compound Lens Based on Pancharatnam–Berry Phase
by Ying Ma, Mingkui Yin, Yuhang Shan, Vladimir G. Chigrinov, Hoi-Sing Kwok and Jianlin Zhao
Crystals 2022, 12(2), 231; https://doi.org/10.3390/cryst12020231 - 8 Feb 2022
Cited by 2 | Viewed by 4241
Abstract
We report a ferroelectric liquid crystal (FLC) compound lens based on the Pancharatnam–Berry (PB) phase. The phase of the FLC compound lens is an integration of polarization grating and a PB lens. Thus, when light passes through an FLC compound lens, the output [...] Read more.
We report a ferroelectric liquid crystal (FLC) compound lens based on the Pancharatnam–Berry (PB) phase. The phase of the FLC compound lens is an integration of polarization grating and a PB lens. Thus, when light passes through an FLC compound lens, the output light’s polarization handedness will be changed accordingly. In this case, FLC compound lenses can function as concave/convex lenses with spatially separated output light and rapid transmittance tunability. The FLC compound lenses were fabricated using a single-step holographic exposure system, based on a spatial light modulator working as numerous phase retarders. Photosensitive azo-dye material was used as the aligning layer. The output light transmittance of the FLC compound lens can be operated at 150 μs. Our results achieve the potential applications on various displays and augmented reality. Full article
(This article belongs to the Special Issue Liquid Crystals in China)
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16 pages, 8742 KB  
Review
A Review of Two-Dimensional Liquid Crystal Polarization Gratings
by Kai Zuo, Yue Shi and Dan Luo
Crystals 2021, 11(9), 1015; https://doi.org/10.3390/cryst11091015 - 25 Aug 2021
Cited by 20 | Viewed by 7138
Abstract
In the past two decades, polarization gratings (PGs) have attracted intensive attention due to the high-efficient diffraction and polarization selectivity properties. On one hand, the one-dimensional (1D) PGs have been investigated widely and adapted to various applications. On the other hand, optical signal [...] Read more.
In the past two decades, polarization gratings (PGs) have attracted intensive attention due to the high-efficient diffraction and polarization selectivity properties. On one hand, the one-dimensional (1D) PGs have been investigated widely and adapted to various applications. On the other hand, optical signal manipulation stimulates the development of multibeam optical devices. Therefore, the development of two-dimensional (2D) PGs is in demand. This review summarizes the research progress of 2D PGs. Different designs and fabrication methods are summarized, including assembling two 1D polarization patterns, a 2D holographic lithography by polarization interference and a micro-pixelated electric field stimulated 2D liquid crystal (LC) structure. Both experiments and analyses are included. The design strategy, diffraction property, merits and demerits are discussed and summarized for the different methods. Full article
(This article belongs to the Special Issue Liquid Crystals in China)
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12 pages, 3505 KB  
Article
Tunable Polarization and Surface Relief Holographic Gratings in Azopolymer Nanocomposites with Incorporated Goethite (α-FeOOH) Nanorods
by Lian Nedelchev, Georgi Mateev, Velichka Strijkova, Verónica Salgueiriño, David S. Schmool, Nataliya Berberova-Buhova, Elena Stoykova and Dimana Nazarova
Photonics 2021, 8(8), 306; https://doi.org/10.3390/photonics8080306 - 31 Jul 2021
Cited by 20 | Viewed by 3842
Abstract
We employ two approaches to tune the properties of concurrently inscribed volume polarization and surface relief gratings in nanocomposite thin films containing the azopolymer PAZO (poly[1-4-(3-carboxy-4-hydrophenylazo)benzensulfonamido]-1,2-ethanediyl, sodium salt]) and goethite (α-FeOOH) nanorods. The first one is applied on the stage of sample preparation [...] Read more.
We employ two approaches to tune the properties of concurrently inscribed volume polarization and surface relief gratings in nanocomposite thin films containing the azopolymer PAZO (poly[1-4-(3-carboxy-4-hydrophenylazo)benzensulfonamido]-1,2-ethanediyl, sodium salt]) and goethite (α-FeOOH) nanorods. The first one is applied on the stage of sample preparation by varying the concentration of the goethite nanorods from 0% to 15%. Then, different angles between the recording beams are set in the holographic scheme, which allow us to obtain gratings with spatial periods in the range from 0.86 to 2.51 µm. Surface relief modulation close to 300 nm is achieved as well as total diffraction efficiency in the ±1 diffracted orders of more than 50%. The influence of the incorporated goethite nanorods on the properties of both volume birefringence and the surface relief grating are discussed. Full article
(This article belongs to the Special Issue Materials, Methods and Models for Holographic Optical Elements)
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12 pages, 1271 KB  
Communication
Cicada Wing Inspired Template-Stripped SERS Active 3D Metallic Nanostructures for the Detection of Toxic Substances
by Srijit Nair, Juan Gomez-Cruz, Gabriel Ascanio, Aristides Docoslis, Ribal Georges Sabat and Carlos Escobedo
Sensors 2021, 21(5), 1699; https://doi.org/10.3390/s21051699 - 2 Mar 2021
Cited by 17 | Viewed by 5780
Abstract
This article introduces a bioinspired, cicada wing-like surface-enhanced Raman scattering (SERS) substrate based on template-stripped crossed surface relief grating (TS-CSRG). The substrate is polarization-independent, has tunable nanofeatures and can be fabricated in a cleanroom-free environment via holographic exposure followed by template-stripping using a [...] Read more.
This article introduces a bioinspired, cicada wing-like surface-enhanced Raman scattering (SERS) substrate based on template-stripped crossed surface relief grating (TS-CSRG). The substrate is polarization-independent, has tunable nanofeatures and can be fabricated in a cleanroom-free environment via holographic exposure followed by template-stripping using a UV-curable resin. The bioinspired nanostructures in the substrate are strategically designed to minimize the reflection of light for wavelengths shorter than their periodicity, promoting enhanced plasmonic regions for the Raman excitation wavelength at 632.8 nm over a large area. The grating pitch that enables an effective SERS signal is studied using Rhodamine 6G, with enhancement factors of the order of 1 × 104. Water contact angle measurements reveal that the TS-CSRGs are equally hydrophobic to cicada wings, providing them with potential self-cleaning and bactericidal properties. Finite-difference time-domain simulations are used to validate the nanofabrication parameters and to further confirm the polarization-independent electromagnetic field enhancement of the nanostructures. As a real-world application, label-free detection of melamine up to 1 ppm, the maximum concentration of the contaminant in food permitted by the World Health Organization, is demonstrated. The new bioinspired functional TS-CSRG SERS substrate holds great potential as a large-area, label-free SERS-active substrate for medical and biochemical sensing applications. Full article
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