Search Results (10,426)

In this study, a Ag/ZrO₂ hybrid coating prepared by the sol–gel method on a β-type Ti45Nb alloy was applied by the spin coating technique, and the microstructural, mechanical, electrochemical, and tribological properties of the surface were evaluated in a multi-dimensional manner. The hybrid solution was prepared using zirconium propoxide and silver nitrate and stabilized through a low-temperature two-stage annealing protocol. The crystal structure of the coating was determined by XRD, and the presence of dense tetragonal ZrO₂ phase and crystalline Ag phases was confirmed. SEM-EDS analyses revealed a compact coating structure of approximately 1.8 µm thickness with homogeneously distributed Ag nanoparticles on the surface. As a result of the electrochemical corrosion tests, it was determined that the open circuit potential shifted to more noble values, the corrosion current density decreased, and the corrosion rate decreased by more than 70% on the surfaces where the Ag/ZrO₂ coating was applied. In the tribological tests, a decrease in the coefficient of friction, narrowing of wear marks, and significant reduction in surface damage were observed in dry and physiological (HBSS) environments. The findings revealed that the Ag/ZrO₂ hybrid coating significantly improved the surface performance of the Ti45Nb alloy both mechanically and electrochemically and offers high potential for biomedical implant applications. Full article

This study explored the potential of chitosan (CH)/bacterial cellulose (BC) complexes (0.5% w/v) as novel emulsifiers to stabilize oil-in-water (o/w) Pickering emulsions (20% v/v sunflower oil), with a focus on their gel-like behavior. Emulsions were prepared using CH combined with BNC derived via H₂SO₄ (BNC1) or H₂SO₄-HCl (BNC2) hydrolysis. Increasing BNC content improved stability by reducing phase separation and enhancing viscosity, while CH contributed interfacial activity and electrostatic stabilization. CH/BNC1_25:75 emulsions showed the highest stability, maintaining an emulsion stability index (ESI) of up to 100% after 3 days, with minimal change in droplet size (R_h ~8.5–8.8 μm) and a positive ζ-potential (15.1–29.8 mV), as confirmed by dynamic/electrophoretic light scattering. pH adjustment to 4 and 10 had little effect on their ESI, while ionic strength studies showed that 0.1 M NaCl caused only a slight increase in droplet size combined with the highest ζ-potential (−35.2 mV). Higher salt concentrations led to coalescence and disruption of their gel-like structure. Rheological analysis of CH/BNC1_25:75 emulsions revealed shear-thinning behavior and dominant elastic properties (G′ > G″), indicating a soft gel network. Incorporating sunflower-seed protein isolates into CH/BNC1 (25:75) emulsions led to coacervate formation (three-layer system), characterized by a decrease in droplet size and an increase in ζ-potential (up to 32.8 mV) over 7 days. These findings highlight CH/BNC complexes as sustainable stabilizers for food-grade Pickering emulsions, supporting the development of biopolymer-based emulsifiers aligned with bioeconomy principles. Full article

As a promising n-type semiconductor thermoelectric material, ZnO has great potential in the high-temperature working temperature range due to its advantages of abundant sources, low cost, high thermal stability, and good chemical stability, as well as being pollution-free. Sr-doped ZnO-based thermoelectric materials were prepared using the methods of room-temperature powder synthesis and high-temperature block synthesis. The phase composition, crystal structure, and thermoelectric performances of ZnO samples with different Sr doping levels were analyzed using XRD, material simulation software and thermoelectric testing devices, and the optimal doping concentrations were obtained. The results show that Sr doping could cause the Zn-O bond to become shorter; in addition, the hybridization between Zn and O atoms would become stronger, and the Sr atom would modify the density of states near the Fermi level, which could significantly increase the carrier concentration, electrical conductivity, and corresponding power factor. Sr doping could cause lattice distortion, enhance the phonon scattering effect, and decrease the lattice thermal conductivity and thermal conductivity. Sr doping can achieve the effect of improving electrical transport performance and decreasing thermal transport performance. The ZT value increased to ~0.418 at 873 K, which is ~4.2 times the highest ZT of the undoped ZnO sample. The Vickers hardness was increased to ~351.1 HV, which is 45% higher than the pristine ZnO. Full article

A novel type of multifunctional hybrid membranes combining modified chitosan, functionalized multi-walled carbon nanotubes (MWCNTs), and rare earth element ion-imprinted polymers (REEIIPs) were designed and characterized. The synthesized materials were characterized by thermogravimetric analysis (TGA), scanning electron microscopy (SEM), vibrating sample magnetometry (VSM), X-ray diffraction (XRD), X-ray micro-tomography, and Fourier transform infrared spectroscopy (FTIR). The hybrid membranes were also studied in terms of their mechanical and rheological properties. The key element of the proper preparation of hybrid membranes using the casting method in an external magnetic field was to synthesize membrane components with appropriate magnetic properties. It was found that they showed tunable weak ferromagnetic properties, and the increase in modified nanotube addition caused the rise in the membrane’s saturation magnetization, which for Nd-selective hybrid membranes reached 0.44 emu/g. Also, the increase in thermooxidative stability was noted after introducing functionalized nanotubes into polymer matrices, which, in the case of Gd-selective membranes, were stable even up to 730 °C. The rise in the modified MWCNT addition and selection of appropriate REE ion-imprinted polymers improved mechanical (Rm and E values increase even twice) and rheological parameters (almost double growth of E′ and E″ values) of the tested membranes. Synthesized hybrid membranes showed a high rejection of matrix components and an increase in retention ratio with rising MWCNT-REEIIP addition, ultimately reaching 94.35%, 92.12%, and 90.11% for Nd, Pr, and Gd, respectively. The performed analysis confirmed homogeneous dispersion, phase compatibility, network integration, formation of a complex 3D microstructure, and improved operational stability of created hybrid membranes, which is significant for their future applications in Nd, Pr, and Gd recovery from coal fly ash extracts. Full article

This study presents a comprehensive evaluation and an equivalent circuit modeling of the skin–electrode impedance characteristics of three types of ultra-thin tattoo electrodes, all based on Parylene C nanofilms but with different active materials: Gold, Silver, and PEDOT:PSS. Their performance was compared to standard disposable Ag/AgCl electrodes. Impedance measurements were carried out on six human subjects under controlled conditions, assessing the frequency response in the range of 20 Hz to 1 kHz. For each subject, the impedance was recorded six times over one hour to investigate the stability and the temporal performance. The collected data were subsequently analyzed to model the electrical properties and interface behavior of each electrode type. The findings demonstrate that the tattoo electrodes offer impedance levels comparable to those of Ag/AgCl electrodes (in the order of tens of kΩ at 20 Hz), while providing additional benefits such as enhanced conformability, improved skin adhesion, and reduced skin irritation during use. Furthermore, the modeling of the skin–electrode interface through a more detailed equivalent circuit than the single time constant model enables a more detailed interface analysis and description, with fitting algorithm R² scores of about 0.999 and 0.979 for the impedance magnitude and impedance phase, respectively. The proposed equivalent circuit offers valuable insights for optimizing electrode design, supporting the potential of Parylene C-based tattoo electrodes as promising alternatives for next-generation wearable bioelectronic applications. Full article

This study investigates the effects of incorporating recycled concrete powder (RCP) as a supplementary cementitious material in Portland cement composites at replacement levels of 5–30% by weight. A comprehensive characterization using isothermal calorimetry, electrical conductivity measurements, thermogravimetric analysis, FT-IR spectroscopy, and scanning electron microscopy revealed that RCP modified the hydration behavior and microstructural development. The results showed a linear 16.5% reduction in the total heat of hydration (from 145.38 to 121.44 J/g) at 30% RCP content, accompanied by a 26.5% decrease in peak electrical conductivity (19.16 to 14.08 mS/cm) and delayed reaction kinetics. Thermal analysis demonstrated an increased stability of hydration products, with portlandite decomposition temperatures rising by up to 10.8 °C. Microstructural observations confirmed the formation of denser but more amorphous C–S–H phases alongside increased interfacial porosity at higher RCP contents. The study provides quantitative evidence of RCP’s dual functionality as both an inert filler and a nucleation agent, identifying an optimal 20–25% replacement range that balances performance and sustainability. These findings advance the understanding of construction waste utilization in cementitious materials and provide practical solutions for developing more sustainable building composites while addressing circular economy objectives in the construction sector. Full article

Carrier-based aircraft recovery is a critical and challenging phase in maritime operations due to the turbulent airwake generated by aircraft carriers, which significantly increases the workload of flight control systems and pilots. This study investigates the airwake effects of an aircraft carrier under varying wind direction conditions. A high-fidelity mathematical model combining delayed detached-eddy simulation (DDES) with the overset grid method was developed to analyze key flow characteristics, including upwash, downwash, and lateral recirculation. The model ensures precise control of aircraft speed and trajectory during landing while maintaining numerical stability through rigorous mesh optimization. The results indicate that the minimum lift occurs in the downwash region aft of the deck, marking it as the most hazardous zone during landing. Aircraft above the deck are primarily influenced by ground effects, causing a sudden increase in lift that complicates arresting wire engagement. Additionally, the side force on the aircraft undergoes an abrupt reversal during the approach phase. The dual overset mesh technique effectively captures the coupled motion of the hull and aircraft, revealing higher turbulence intensity along the glideslope and a wider range of lift fluctuations compared to stationary hull conditions. These findings provide valuable insights for optimizing carrier-based aircraft recovery procedures, offering more realistic data for simulation training and enhancing pilot preparedness for airwake-induced disturbances. Full article

Leeches hold significant medical and pharmaceutical value for antithrombotic treatments, yet their genetic diversity patterns remain poorly understood. We performed population genetic analyses on seven Hirudinaria manillensis populations from southern China using mitochondrial protein-coding genes (MitPCGs). Complete sequences of all 13 MitPCGs were obtained from 74 individuals. Haplotype diversity exhibited a logarithmic relationship with the gene length (R² = 0.858, p < 0.001), while nucleotide diversity showed a near-perfect alternating low-high pattern (Z = 2.938, p = 0.003). Concatenated sequence analyses indicated high haplotype diversity (>0.5) and low nucleotide diversity (<0.005) across all populations, suggesting a historical bottleneck followed by rapid expansion and mutation accumulation. The haplotype network, haplotype phylogenetics, and genetic structure analyses revealed moderate genetic differentiation across populations, dividing them into three clades: a basal Yunnan population (YNHH), sub-basal Guangxi populations (GXGG, GXLZ, and GXYL), and distal Guangdong/Hainan populations (GDMM, GDZJ, and HNDA). Analysis of historical population demography revealed five phases from ancient to recent times (P1–5): growth, prolonged stability, rapid decline, rapid growth, and secondary decline. These phases correlate strongly with past climatic events, demonstrating that glacial–interglacial cycles profoundly impacted the leech’s effective population size. This study provides a key scientific basis for H. manillensis resource conservation and utilization. Full article

Osteoarthritis and metastatic bone cancers create pathological oxidative environments characterized by elevated reactive oxygen species (ROS). ROS impair bone regeneration by degrading the scaffold and suppressing mineralization. To address these challenges, we fabricated thermoresponsive scaffolds based on poly(N-isopropylacrylamide) (PNIPAAm) incorporating in situ-grown nanohydroxyapatite on graphene oxide nanoscrolls (nHA-GONS) using stereolithography (SLA). Three scaffold formulations were studied: pure PNIPAAm (PNP), PNIPAAm with 5 wt.% nHA-GONS (P5G), and PNIPAAm with 5 wt.% nHA-GONS reinforced with polycaprolactone (PCL) microspheres (PN5GP). Each scaffold was evaluated for (i) swelling and lower critical solution temperature (LCST) using differential scanning calorimetry (DSC); (ii) oxidative degradation assessed using Fourier-transform infrared spectroscopy (FTIR), mass loss, and antioxidant assays; and (iii) mineralization and morphology via immersion in simulated body fluid followed by microscopy. The PN5GP and P5G scaffolds demonstrated reversible swelling, sustained antioxidant activity, and enhanced calcium deposition, which enable redox stability and mineralization under oxidative environments, critical for scaffold functionality in bone repair. PNP scaffolds exhibited copper accumulation, while PN5GP suffered from accelerated mass loss driven by the PCL phase. These findings identify the P5G formulation as a promising scaffold. This study introduces a quantitative framework that enables the predictive design of oxidation-resilient scaffolds. Full article

An explorative study was conducted to evaluate the efficacy and safety of 5-aminolevulinic acid hydrochloride combined with sodium ferrous citrate (SPP-004) in 10 pediatric patients with Leigh syndrome (LS) aged 3–24 months in 10 institutions between December 2014 and July 2019. The patients were randomized and allocated to the SPP-004 or placebo group for a 12-week double-blind period, followed by a 12-week open-label period with SPP-004 and then a long-term study of up to 180 weeks. The efficacy and safety were evaluated using the Newcastle Pediatric Mitochondrial Disease Scale (NPMDS) and adverse events (AEs), respectively. No significant differences were found between groups in NPMDS scores, but prolonged SPP-004 treatment stabilized or improved scores. During the initial double-blind phase, the serum lactate levels increased in the placebo group but not in the SPP-004 group. Over the period of prolonged treatment with SPP-004, the average serum lactate level gradually decreased to a normal level. One patient died due to heart failure, presumably due to an underlying disease. Overall, 7 out of 10 patients received SPP-004 without developing severe AEs until the termination of the long-term study. Given the severe symptoms and poor prognosis of pediatric LS, NPMDS scores were indicative of stabilization in pediatric LS patients treated with SPP-004. Full article

The evaluation of the wave-induced seabed stability such as liquefaction and shear failure is one of the factors that must be considered in the design of marine infrastructures. Due to the transformation within the porous medium, the wave-induced soil response manifests itself as a phase delay in the dynamic wave pressure on the seabed surface, which is referred to as “phase-lag”. In this study, the analytical solutions of wave-induced soil response in an infinite porous seabed are further examined to clarify the effects of phase-lags. Based on the coefficient of relative rigidity of the soil skeleton to the pore fluid ($R_k$), a simplified approximation is derived. The expressions of the phase-lags for wave-induced soil response are presented for various cases. Moreover, the phase-lag effects on instantaneous liquefaction and shear failure are analysed. Based on the parametric study, it is concluded the extreme phase-lag for wave-induced pore pressure increases with increasing $R_k$, the extreme phase-lag for horizontal effective stress and shear stress decrease with increasing $R_k$. Furthermore, the liquefaction zone and shear failure zone increase with increasing $R_k$. Full article

Solid–liquid phase-change materials (PCMs) have attracted considerable attention in heat energy storage due to their appropriate phase-transition temperatures and high thermal storage density. The primary issues that need to be addressed in the wide application of traditional PCMs are easy leakage during solid–liquid phase transitions, low thermal conductivity, and poor energy conversion function. The heat transfer properties of PCMs can be improved by compounding with carbon materials. Carbon nanotubes (CNTs) are widely used in PCMs for heat storage because of their high thermal conductivity, strong electrical conductivity, and high chemical stability. This study investigates the thermal properties of 1-octadecanol (OD) modified with different diameters and amounts of CNTs using the melt blending method and the ultrasonic dispersion method. The aim is to enhance thermal conductivity while minimizing latent heat loss. The physical phase, microstructure, phase-change temperature, phase-transition enthalpy, thermal stability, and thermal conductivity of the OD/CNTs CPCMs were systematically studied using XRD, FTIR, SEM, DSC, and Hot Disk. Moreover, the heat charging and releasing performance of the OD/CNTs CPCMs was investigated through heat charging and releasing experiments, and the relationship among the composition–structure–performance of the CPCMs was established. Full article

TiVCr-based alloys are well-explored body-centered cubic (BCC) materials for hydrogen storage applications that can potentially store higher amounts of hydrogen at moderate temperatures. The challenge remains in optimizing the alloy-hydrogen stability, and several transition elements have been found to support the reduction in the hydride stability. In this study, Ni and Nb transition elements were incorporated into the TiVCr alloy system to thoroughly understand their influence on the (de)hydrogenation kinetics and thermodynamic properties. Three different compositions, (TiVCr)₉₅Ni₅, (TiVCr)₉₀ Ni₁₀, and (TiVCr)₉₅Ni₅Nb₅, were prepared via arc melting. The as-prepared samples showed the formation of a dual-phase BCC solid solution and secondary phase precipitates. The samples were characterized using hydrogen sorption studies. Among the studied compositions, (TiVCr)₉₀Ni₁₀ exhibited the highest hydrogen absorption capacity of 3 wt%, whereas both (TiVCr)₉₅Ni₅ and (TiVCr)₉₀Ni₅Nb₅ absorbed up to 2.5 wt% hydrogen. The kinetics of (de)hydrogenation were modeled using the JMAK and 3D Jander diffusion models. The kinetics results showed that the presence of Ni improved hydrogen adsorption at the interface level, whereas Nb substitution enhanced diffusion and hydrogen release at room temperature. Thus, the addition of Ni and Nb to Ti-V-Cr-based high-entropy alloys significantly improved the hydrogen absorption and desorption properties at room temperature for gas-phase hydrogen storage. Full article

Millimeter-wave frequencies are crucial for meeting the high-capacity, low-latency demands of 5G communication systems, thereby driving the need for compact, high-gain antenna arrays capable of efficient beamforming. This paper presents the design, simulation, fabrication, and experimental validation of a compact, high-efficiency 1 × 6 linear series-fed microstrip patch antenna array for 5G millimeter-wave communication operating at 28 GHz. The proposed antenna is fabricated on a low-loss Rogers RO3003 substrate and incorporates an integrated symmetric two-way microstrip power divider to ensure balanced feeding and phase uniformity across elements. The antenna achieves a simulated peak gain of 11.5 dBi and a broad simulated impedance bandwidth of 30.21%, with measured results confirming strong impedance matching and a return loss better than −20 dB. The far-field radiation patterns demonstrate a narrow, highly directive beam in the E-plane, and the H-plane results reveal beam tilting behavior, validating the antenna’s capability for passive beam steering through feedline geometry and element spacing (~0.5λ). Surface current distribution analysis confirms uniform excitation and efficient radiation, further validating the design’s stability. The fabricated prototype shows excellent agreement with the simulation, with minor discrepancies attributed to fabrication tolerances. These results establish the proposed antenna as a promising candidate for applications requiring compact, high-gain, and beam-steerable solutions, such as 5G mm-wave wireless communication systems, point-to-point wireless backhaul, and automotive radar sensing. Full article

Electrochromic (EC) devices are gaining increasing attention for next-generation smart windows and low-power displays due to their reversible color modulation, low operating voltage, and flexible form factors. Recently, electrochromic energy storage devices (EESDs) have emerged as a promising class of multifunctional systems, enabling simultaneous energy storage and real-time visual monitoring. In this study, we report a flexible dual-functional EESD constructed using polyaniline (PANI) films doped with anthraquinone-1-sulfonic acid sodium salt (AQS), coupled with a redox-active PVA-based gel electrolyte also incorporating AQS. The incorporation of AQS into both the polymer matrix and the gel electrolyte introduces synergistic redox activity, facilitating bidirectional Faradaic reactions at the film–electrolyte interface and within the bulk gel phase. The resulting vertically aligned PANI-AQS nanoneedle films provide high surface area and efficient ion pathways, while the AQS-doped gel electrolyte contributes to enhanced ionic conductivity and electrochemical stability. The device exhibits rapid and reversible color switching from light green to deep black (within 2 s), along with a high areal capacitance of 194.2 mF·cm⁻² at 1 mA·cm⁻² and 72.1% capacitance retention over 5000 cycles—representing a 31.5% improvement over undoped systems. These results highlight the critical role of redox-functionalized gel electrolytes in enhancing both the energy storage and optical performance of EESDs, offering a scalable strategy for multifunctional, gel-based electrochemical systems in wearable and smart electronics. Full article