Search Results (162)

Air-pollution source control is usually prioritised by emission mass, yet the health damage per tonne emitted varies widely in space. Using agricultural-residue open burning in Northern Thailand as a case study, we couple a GIS emission inventory with a province-resolved damage-function health model to quantify the health and economic burden, quantify how the health damage per tonne emitted varies across provinces, and apportion the co-benefits of diverting residue from open burning between air-quality and climate gains. In 2018, residue burning released about 21 kt of PM_2.5, 3.0 kt of black carbon and 0.84 Mt CO₂-eq of net non-biogenic greenhouse gases (methane and nitrous oxide), together with 6.2 Mt of biogenic CO₂ that is refixed by the following crop and is not a net climate source, with rice, sugarcane and maize contributing 39%, 35% and 20% of fine particles respectively, imposing costs of 59,600 disability-adjusted life years (DALYs; 97.5% from primary PM_2.5) and ~USD 1.07 billion per year. The damage caused per tonne emitted varied 4.8-fold among provinces (1.43–6.85 DALY per tonne of PM_2.5), so the largest emitter (Nakhon Sawan) was not the province whose emissions caused the largest attributable burden (Phetchabun); damage-weighted prioritisation therefore identifies where diversion yields the greatest benefit. Diverting rice and maize residue avoided 12 kt PM_2.5, 1.6 kt black carbon and 0.56 Mt CO₂-eq of net greenhouse gas, and 60% of the health and economic burden; extending diversion to sugarcane raised these to 20 kt, 2.9 kt, 0.79 Mt CO₂-eq and 95% (USD 1.02 billion per year), so a three-crop strategy is required. Rice-only and maize-only diversion were not clearly separable (rice-only was larger in 64% of the Monte Carlo draws). Full article

Coal self-heating in longwall goaf areas results from strongly coupled gas flow, heat transfer, mass transport, and chemical reactions occurring within a porous medium containing residual coal. This study presents a mathematical and numerical model for analysing these transient and non-isothermal processes with spatially variable permeability based on in-situ mining data. The model accounts for gas filtration through the porous goaf, heat and mass transfer between the gas and solid phases, heterogeneous coal oxidation, homogeneous gas-phase reactions, continuous methane emission, and the possibility of nitrogen inertisation. The governing equations form a strongly coupled non-linear system and are solved using the finite volume method. Numerical simulations were performed for U-type and Y-type ventilation layouts. The results provide spatial distributions of methane, oxygen, and carbon monoxide concentrations, gas temperature, solid-phase temperature, pressure, and gas velocity. The simulations demonstrate that ventilation configuration affects oxygen penetration, gas composition, and temperature development within the goaf. In particular, the Y-type ventilation system promotes deeper oxygen ingress into the porous zone, which may increase the extent of regions susceptible to coal self-heating. The proposed approach provides a framework for analysing coupled thermal and transport phenomena associated with spontaneous coal combustion and for assessing the influence of ventilation conditions on the development of thermal hazards in longwall goaf areas. Full article

Small lakes are widespread, yet their biogeochemistry, particularly regarding greenhouse gases, remains insufficiently studied. This article presents the findings from an investigation of six small lakes in the Southern European part of Russia, conducted from September to October 2024. The primary aim was to examine the coupled distribution of methane (CH₄) and sulfide sulfur (a key metabolite of H₂S) in the lake sediments, in relation to geochemical parameters such as pH, Eh, sediment density, moisture, and the contents of sulfate ions (SO₄²⁻), organic matter, and granulometric composition. The studied sediment layers, reaching depths of up to 110 cm, consist primarily of silty clay. The lakes studied represent both freshwater (0.2–0.7 g/L) and brackish (1.3–24.2 g/L) systems. During the study period, the water column exhibited temperatures of 10.4–22.1 °C, pH values of 7.36–8.53, and dissolved O₂ concentrations ranging from 3.16 mg/L (34% saturation) to 11.79 mg/L (125% saturation). Methane concentrations in the water varied widely, from 1.6 µL/L to 37,380 µL/L. The lowest values were found in the highly mineralized Lake Bolshoy Tambukan (1.6–2.0 µL/L), while exceptionally high concentrations were detected in the bottom waters of the thermally stratified freshwater Lake Staroe. In the shallow, productive freshwater lakes, a significant portion of the organic matter undergoes limited mineralization in the water column and settles to the sediments as partially decomposed remains of sand- and coarse-silt-sized organisms. The subsequent degradation of this labile organic matter reduces bottom-water oxygen, triggering intense anaerobic processes in the upper sediment layer. In these freshwater sediments, where sulfate concentrations are relatively low, sulfate reduction is typically suppressed. Combined with an abundance of labile substrates, this condition fosters intensive methanogenesis, resulting in maximum CH₄ concentrations (33–179 µg/g). Under stable thermal stratification, such high CH₄ concentrations can also accumulate in the bottom water (e.g., up to 37. 4 mL/L in Lake Staroe), posing a risk of significant pulse emissions during autumn mixing. Conversely, the brackish Lake Bolshoy Tambukan exemplifies the crucial role of sulfate reduction, which is stimulated by sulfate-dependent anaerobic oxidation of CH₄. This process acts as a powerful natural biogeochemical barrier that curtails the emission of a major greenhouse gas. The sediments of this lake exhibited minimal CH₄ content (0.14–0.57 µg/g) alongside maximal sulfide sulfur concentrations (1.06–8.57 mg/g). Overall, this theoretical and experimental analysis demonstrates that sulfate reduction is a key determinant of redox potential, acid–base conditions, and the vertical distribution of CH₄ in the anaerobic sediments of small lakes in Southern Russia. Given the projected salinization of lakes in steppe and arid landscapes under climate change, a reduction in CH₄ emissions to the atmosphere is likely due to the enhanced sulfate-dependent anaerobic CH₄ oxidation associated with sulfate reduction in the sediments. Full article

Electrified steam methane reforming (eSMR) is emerging as a promising technology for the decarbonization of the chemical industry and low-carbon hydrogen production by coupling renewable electricity with renewable gaseous feedstocks such as biomethane. In this work, structured Ni-based catalysts washcoated on highly thermally conductive SiC open-cell foams (OCFs) were developed and evaluated for biomethane steam-reforming operating conditions. Two catalyst formulations, 30 wt.% Al₂O₃_30 wt.% CeO₂_20 wt.%Ni and SiC_30 wt.% Al₂O₃_30 wt.%Ce_0.25Zr0.75 O₂_20 wt.%Ni, were tested in a laboratory-scale indirectly electrically heated reformer. The high thermal conductivity of the SiC-structured support ensured efficient heat transfer throughout the reactor, limiting radial temperature gradients to below 10 °C. Both catalyst formulations exhibited excellent catalytic performance; however, the Ce_0.25Zr0.75O₂-promoted catalyst achieved the best results, maintaining equilibrium methane conversion at a gas hourly space velocity above 7000 h⁻¹ while reaching a specific electrical energy consumption of 2.06 kWh/Nm³ of produced H₂ projected for industrial-scale efficiency. Notably, these performances were obtained with a catalyst loading approximately 20–50% lower than that of conventional commercial alumina pellet catalysts. XRD characterization did not reveal the formation of crystalline graphitic carbon after catalytic operation. Furthermore, the structural evolution of the Ce–Zr–O highlights the active role of the mixed oxide in promoting redox processes and maintaining catalytic activity under reaction conditions. Overall, these results demonstrate that the combination of highly conductive SiC-structured supports and Ce–Zr-promoted Ni catalysts significantly enhances both the thermal and catalytic efficiency of eSMR. The proposed catalyst provides a promising route toward compact, energy-efficient, and decentralized hydrogen production from biomethane, supporting the electrification and decarbonization of future hydrogen generation technologies. Full article

Laminar counterflow multi-branch flames provide a canonical configuration for investigating interactions between oxidizer-rich and fuel-rich streams in liquid-oxygen/methane combustion systems. This study numerically investigates their flame structure and stability under transcritical conditions, with stability characterized by the extinction strain rate. Ideal-fluid (IF), partial real-fluid (PRF), and real-fluid (RF) models are compared to distinguish the effects of real-fluid thermodynamics and high-pressure transport corrections. The multi-branch flame comprises two premixed branches coupled with a central diffusion branch. Heat release from the premixed branches creates high-temperature plateaus that preheat the stagnation-region mixture and sustain the diffusion branch. Although the three models predict similar flame topologies, the IF model gives an extinction strain rate of $3.306\times {10}^6{\mathrm{s}}^{-1}$, whereas both PRF and RF predict $3.256\times {10}^6{\mathrm{s}}^{-1}$. Thus, the ideal-fluid treatment slightly overpredicts the extinction limit under the present reference condition, while high-pressure transport corrections influence the ignition location, peak temperature, and thermal diffusivity. Increasing pressure from 10 MPa to 40 MPa raises the extinction strain rate from $9.336\times {10}^5{\mathrm{s}}^{-1}$ to $4.867\times {10}^6{\mathrm{s}}^{-1}$ by strengthening heat release and reducing thermal diffusion from the high-temperature region. Oxidizer preheating markedly enhances flame stability, whereas fuel preheating has a weak effect. These findings establish the connection between real-fluid thermodynamics, branch interaction, and extinction stability, providing a physical basis for model selection, operating-condition optimization, and stability-margin assessment in transcritical liquid-oxygen/methane combustion systems. Full article

Methane is an abundant energy carrier and carbon resource. However, its efficient utilization remains challenging because the strong C-H bonds in methane hinder low-temperature activation, whereas high-temperature conversion often leads to undesired side reactions and reduced product selectivity. Solid oxide cells (SOCs) provide a promising platform for methane conversion by integrating high-temperature electrochemistry, catalytic reactions, and ion transport within a single system, enabling efficient energy and chemical production. This review summarizes recent advances in SOC-based methane conversion through three representative pathways: direct electricity generation in methane-fueled solid oxide fuel cell (SOFC), syngas production via SOC-assisted methane reforming, and value-added C₂ hydrocarbon synthesis through methane oxidative coupling in solid oxide electrolysis cell (SOEC). For methane-fueled SOFC, the relationships among fuel-electrode materials, microstructural characteristics, carbon deposition behavior, and electrochemical performance are discussed, together with current strategies for improving carbon resistance and operational stability. In methane reforming and upgrading processes, SOCs can regulate oxygen-ion transport, local reaction environments, and electrode reaction pathways, thereby enhancing methane conversion and product selectivity toward syngas, hydrogen, and C₂ hydrocarbons. The roles of electrode design, catalyst development, and operating conditions in determining reaction performance are also highlighted. Finally, the major challenges facing SOC-based methane conversion are critically discussed. Future research directions involving advanced electrode materials, microstructure engineering, and multiscale modeling are proposed to support the development of efficient and durable SOC technologies for methane utilization. Full article

Goaf gas drainage and residual-coal spontaneous-combustion prevention are often designed independently, even though both are controlled by the same leakage-flow, oxygen-transport and heat-release fields in a longwall goaf. This decoupled design may reduce methane accumulation while unintentionally enlarging the oxidation zone. Taking the No. 1217 fully mechanized working face of Zhongxing Coal Mine, Shanxi Province, China, as an engineering prototype, this study develops an integrated laboratory-field numerical framework to quantify the drainage-induced evolution of the three zones of spontaneous combustion. Programmed temperature-rise experiments on the No. 2 coal seam were used to determine the oxygen-consumption rate, heat-release intensity and apparent activation energy under oxygen concentrations of 3–21%, yielding a critical oxygen concentration of 5.9%. Bundle-tube monitoring and distributed optical-fiber temperature sensing delineated the in situ three-zone boundaries, and a three-dimensional CFD model coupling porous-media seepage, species transport and Arrhenius-type heat generation was validated against the field data, with most relative errors below 5%. Parametric simulations for buried-pipe depths of 20, 30 and 50 m and negative pressures of 15 and 20 kPa reveal a pronounced asymmetric response: drainage compresses and advances the return-side oxidation zone toward the working face, but drives the inlet-side oxidation zone deeper into the goaf by enhancing oxygen-bearing leakage. Within the investigated parameter space, a buried depth of 30 m and a negative pressure of 20 kPa provide the best compromise, reducing the return-side oxidation-zone width from 32 to 21 m and the upper-corner methane concentration from 6.80% to 0.58%. The results demonstrate that drainage design should be constrained simultaneously by methane dilution and oxidation-zone control, and provide a quantitative basis for coordinating gas extraction with fire prevention in gas-rich, oxidation-prone longwall panels. Full article

A working-state model is proposed for the MnOx–Na₂WO₄/SiO₂ catalyst in oxidative coupling of methane (OCM), where a Na₂WO₄-rich surface environment forms an adaptive interphase that buffers the effective interfacial oxygen chemical potential and stabilizes cooperative MnO_x/Na–WO_x/Mn–O–W motifs. A thermodynamic-kinetic scheme is developed that relates (1) reaction-induced surface enrichment (structural stabilization), (2) oxygen spillover (damping of local oxygen gradients), and (3) Mn ↔ W redox exchange as an electron-oxygen buffer channel. Ex situ XPS/EDS/EPR data indicate a dynamically stratified near-surface region with chemically heterogeneous environments of Mn, W, and O. The W 4f region remains dominated by the W⁶⁺ contribution in the presence of a minor reduced component after OCM. In oxygen-deficient mixtures (CH₄/O₂ > 4), interfacial reconstruction becomes more pronounced: Mn-centered Mars–van Krevelen chemistry determines CH₄ activation and oxygen exchange, while the Na₂WO₄-rich phase ensures fast ion/oxygen transport. Observation of the EPR signal from W⁵⁺ ions in the tungstate matrix indicates the existence of reduced W intermediates at low oxygen potential. Optimization of C₂ selectivity and stability is suggested to require maintaining the catalyst within the selective window of effective interfacial μO by adjusting CH₂/O₂ and contact time, as well as controlling the architecture of the Na–W–O/MnO_x interfacial region. Full article

Tri-reforming of methane (TRM) has emerged as a promising pathway for low-carbon syngas production by integrating steam reforming, dry reforming, and partial oxidation within a single process. This coupling enables simultaneous CH₄ utilization and CO₂ valorization while enabling internal heat generation and flexible adjustment of the H₂/CO ratio for downstream synthesis. However, TRM performance cannot be adequately evaluated using conversion or energy efficiency alone, because the process involves complex interactions among competing reaction pathways, transport phenomena, catalyst stability, and thermodynamic irreversibility. This review provides a multiscale critical assessment of TRM from both first-law energy and second-law exergy perspectives, linking reaction-network fundamentals to reactor-level behavior and system-level performance. The literature evidence shows that although high temperatures and near-autothermal operation can enhance CH₄ conversion and reduce external heat demand, these conditions may simultaneously intensify deep oxidation, hotspot formation, carbon-forming tendencies, and exergy destruction. While equilibrium analyses help define feasible operating windows, they are insufficient without kinetic modeling and reactor-scale studies that capture spatial non-uniformities and pathway competition. Across reported TRM systems, exergy destruction is consistently concentrated within the reformer, identifying the reacting core as the dominant thermodynamic bottleneck. Accordingly, the key challenge in TRM is not simply to maximize conversion but to preserve chemical work potential while maintaining syngas quality and operational stability. Viewed from this perspective, TRM is better understood as an irreversibility-aware multiscale design problem in which optimal performance depends on the integrated optimization of catalyst functionality, reactor architecture, heat management, and system-level operation. Full article

There is increasing interest in structured layered double hydroxide (LDH)-based catalysts because they combine tunable acid–base/redox chemistry with reactor architectures that can reduce diffusion lengths, improve heat management, and lower pressure-drop penalties. This review evaluates LDH, LDH-derived oxide (LDO/MMO), reduced metal/LDO, reconstructed hydroxide-rich, and mixed dynamic states integrated into honeycomb monoliths, open-cell foams, meshes/felts, thin films, washcoats, coated plates, microchannels, capillaries, and additively manufactured lattices. To move beyond descriptive comparison, the literature is assessed using unified evaluation dimensions: operative active state, support architecture, coating/integration route, active-phase loading, coating thickness and uniformity, reactor-volume-normalized productivity or STY, ΔP/L, axial/radial thermal gradients, time-on-stream, coating loss, regeneration recovery, and pilot-readiness. Representative benchmarks illustrate both the promise and reporting gaps of the field: NiFe-LDH-derived monoliths for CO₂ methanation have reached ~70% CO₂ conversion at 300 °C with >90% CH₄ selectivity and only 0.7% post-test mass loss; NiFe-LDH/iron-foam monoliths retained 85% ozone conversion after 168 h; high-entropy LDH-derived oxides showed T50/T90 values of 246/254 °C for toluene oxidation; and Au/LDH capillary films achieved 31.9% glycerol carbonate yield and 3.78 g h⁻¹ g⁻¹ productivity. The strongest current cases are pollution abatement and CO₂ methanation, whereas biomass upgrading, fine-chemical flow, high-entropy coatings, and photo/electrocatalytic films require deeper module-level validation. Overall, structured LDH catalysts should be treated as coupled chemistry–coating–reactor systems whose performance must be judged simultaneously by activity, accessible catalyst inventory, transport efficiency, pressure drop, thermal profile, durability, regeneration, and manufacturability. Full article

Greenhouse gas generated from wastewater treatment plants has attracted much attention as it has the potential to be recovered and used as an energy source. In this study, a membrane biofilm reactor was designed to simultaneously enhance nitrate removal and reduce methane (CH₄) emissions during methane oxidation coupled with the denitrification process. The enrichment of CH₄-driven denitrification microbes with a relatively short hydraulic retention time (HRT) and its effects on the stable operation of the reactor were studied within 250 d. With an increasing HRT from 8 to 20 h, a removal rate of up to approximately 0.51 mg/L·h⁻¹ was achieved, which also kept the effluent NO₂⁻-N below 0.5 mg/L. Microbial community analysis showed that the diversity and uniformity of microorganism communities decreased with the addition of CH₄ as a carbon source, and the microbial structure changed significantly. Compared with that of seed sludge at the phylum level, the relative abundance of Proteobacteria increased significantly, Alphaproteobacteria and Sphingobacteriia continued to become enriched, and the abundance of Methylocystis increased significantly. Neither denitrifying anaerobic methane oxidation (DAMO) archaea nor bacteria were found in the sequencing analysis. Methylocystis was the dominant CH₄ oxidizing bacteria, in synergy with the co-occurrence of autotrophic and heterotrophic denitrifying bacteria, which likely join up in nitrogen removal. Unlike the systems described in most methane-driven denitrification studies, our system achieved nitrate removal without detectable DAMO microbes. Full article

The circular valorization of biomass for sustainable energy recovery is a strategic priority in the transition toward low-carbon systems. In the last decade, anaerobic digestion (AD) has emerged as an efficient technology to produce an energetic vector to replace natural gas with biomethane and reduce waste; however, the hydrolysis of refractory fractions remains the main rate-limiting step. This study investigates an innovative electro-assisted pretreatment of biomass to promote the first rate-limiting hydrolysis step of refractory compounds in biomethane production. Lignocellulosic residues are employed not only as feedstock for the AD process but also as substrates in electrohydrolysis (EH) pretreatment using an Ir-Ta mixed metal oxide (MMO) anode coupled with advanced biomass-derived carbon felt cathodes. Two cathodes were functionalized with Phragmites Australis (PhA) hydrochars, untreated (PA) and KOH-activated (PA-KOH), to enhance the in situ generation of reactive oxygen species (ROS). Brassica napus (Bn) was chosen as the other biomass selected as a feedstock of AD, and was subjected to EH at varying energy inputs (500–5000 kJ kg⁻¹), evaluating structural and biochemical shifts. The results demonstrate that EH effectively modifies the biomass matrix; the PA-KOH-CF cathode exhibited good selectivity to degrade lignocellulosic structures, but higher biomethane production was achieved at 2500 kJ·kg⁻¹ TS using PA-CF, reaching an increase of 52% compared with untreated samples. Kinetic analysis of the biomethane potential was performed using the modified Gompertz model. The model accurately captured the asymmetric sigmoidal transitions of methane production with different electrode configurations, and finally, energy balance assessment identified 2500 kJ·kg⁻¹ TS as the optimal operational threshold. These findings suggest that an excess of applied energy is critical to the availability of soluble organic matter and the presence of refractory compounds that reduce efficiency. This electro-assisted approach offers a robust strategy for intensifying AD, aligning with circular bioenergy objectives. Full article

The vision for global net-zero carbon emissions by 2050 has intensified the demand for sustainable and low-carbon energy resources. Within this context, recent discoveries of substantial methane (CH₄) reserves, coupled with the rapidly growing interest in hydrogen (H₂) as a clean energy carrier, have underscored the strategic importance of developing efficient and economically viable technologies for methane conversion. This current review investigates hydrogen production specifically from coalbed methane (CBM), a methane-rich unconventional gas resource embedded in coal seams. Both catalytic and non-catalytic pathways for hydrogen generation are reviewed, including steam methane reforming (SMR), partial oxidation (POX), autothermal reforming (ATR), direct methane decomposition (DMD), and plasma-assisted pyrolysis. Catalytic processes such as SMR remain the most mature and cost-effective, though they emit significant CO₂ unless integrated with carbon capture and storage (CCS) technologies. Non-catalytic routes, including thermal and plasma-based decomposition, offer CO₂-free hydrogen generation while producing solid carbon byproducts with potential commercial value. Hybrid coal–CBM systems are also discussed as integrated approaches for improving energy efficiency and resource utilization. The techno-economic assessment compares hydrogen yield, production cost, and environmental impact across methods, emphasizing the advantages of CBM as a high-purity methane source. Case studies, particularly from China, highlight the practical potential of CBM in supporting hydrogen infrastructure. The paper concludes that catalytic routes such as SMR are the most commercially mature and cost-effective but remain CO₂-intensive unless coupled with carbon capture and storage. Non-catalytic approaches, including direct methane decomposition and plasma pyrolysis, enable CO₂-free hydrogen generation while yielding solid carbon byproducts of potential commercial value, though they are less developed. Hybrid coal–CBM systems offer a balanced pathway to improve efficiency, resource utilization, and sustainability in future hydrogen production strategies. Full article

Global climate change poses escalating ecological challenges, with agriculture contributing approximately 30% of anthropogenic greenhouse gas emissions, primarily from nitrous oxide (N₂O) and methane (CH₄). The farmland carbon-nitrogen cycle represents a key nexus for coordinating pollution control and carbon mitigation. This study applies bibliometric methods, including co-occurrence analysis, clustering, and burst detection, to 1286 publications retrieved from the Web of Science Core Collection (1990–2025) and CiteSpace 6.2.R4. Results indicate that China (444 papers, centrality 0.42), the United States (211 papers), and Germany (151 papers) are leading contributors, with major institutions forming a multi-centered international collaboration network. Keyword analysis identified 11 core clusters (modularity Q = 0.82, silhouette S = 0.91), with nitrous oxide emerging as the central theme (frequency 670). The field has evolved through three stages: fundamental emission mechanism studies (1990–2005), agricultural management practices (2006–2015), and integrated mitigation strategies with microbial mechanism exploration (2016–2025). Current frontiers emphasize microbial-mediated carbon-nitrogen cycling and yield-scaled emission assessments bridging theory and practice. Future research should prioritize cross-scale coupling analysis, multi-objective management frameworks, smart agricultural technologies, and policy integration. This study provides a systematic bibliometric mapping of the evolution of synergistic carbon-nitrogen research in agricultural systems, offering a quantitative overview of development trends and research gaps. Full article

Ni coarsening is a primary degradation mechanism in Ni-based anodes, significantly contributing to performance decline and diminished lifespan of methane steam reforming solid oxide fuel cells (SOFCs) during long-term operation. In this study, a novel algorithm is introduced to reconstruct two-dimensional Ni-YSZ anode microstructures, complemented by the development of a multi-physics model that integrates phase-field modeling (PFM) with the Lattice Boltzmann Method (LBM). This coupled PFM-LBM framework is employed to investigate the effects of Ni agglomeration on microstructural evolution and methane-steam mass transport under diverse conditions. The results demonstrate that the initial Ni particle diameter exerts a significant influence on Ni agglomeration dynamics. Furthermore, the mass transport analysis reveals that the necking structures formed during Ni coarsening pose a substantial impediment to mass transfer efficiency. Finally, optimized structural parameters for Ni-YSZ are proposed to enhance anode performance in Ni-based electrodes. Full article