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Search Results (1,202)

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25 pages, 5020 KiB  
Review
Research Progress on Tribological Properties of High-Entropy Alloys
by Shuai Zhang, Zhaofeng Wang, Wenqing Lin and Haoyu Guo
Lubricants 2025, 13(8), 342; https://doi.org/10.3390/lubricants13080342 - 1 Aug 2025
Viewed by 203
Abstract
As a new type of alloy system composed of five or more principal components, high-entropy alloys demonstrate outstanding comprehensive performance in the field of friction and wear through the synergistic effects of the high-entropy effect, lattice distortion effect, hysteresis diffusion effect and cocktail [...] Read more.
As a new type of alloy system composed of five or more principal components, high-entropy alloys demonstrate outstanding comprehensive performance in the field of friction and wear through the synergistic effects of the high-entropy effect, lattice distortion effect, hysteresis diffusion effect and cocktail effect. This paper systematically reviews the research progress on the friction and wear properties of high-entropy alloys. The mechanisms of metal elements such as Al, Ti, Cu and Nb through solid solution strengthening, second-phase precipitation and oxide film formation were analyzed emphatically. And non-metallic elements such as C, Si, and B form and strengthen the regulation laws of their tribological properties. The influence of working conditions, such as high temperature, ocean, and hydrogen peroxide on the friction and wear behavior of high-entropy alloys by altering the wear mechanism, was discussed. The influence of test conditions such as load, sliding velocity and friction pair matching on its friction coefficient and wear rate was expounded. It is pointed out that high-entropy alloys have significant application potential in key friction components, providing reference and guidance for the further development and application of high-entropy alloys. Full article
(This article belongs to the Special Issue Tribological Performance of High-Entropy Alloys)
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18 pages, 8192 KiB  
Article
Microstructure, Mechanical Properties, and Tribological Behavior of Friction Stir Lap-Welded Joints Between SiCp/Al–Fe–V–Si Composites and an Al–Si Alloy
by Shunfa Xiao, Pinming Feng, Xiangping Li, Yishan Sun, Haiyang Liu, Jie Teng and Fulin Jiang
Materials 2025, 18(15), 3589; https://doi.org/10.3390/ma18153589 - 30 Jul 2025
Viewed by 240
Abstract
Aluminum matrix composites provide an ideal solution for lightweight brake disks, but conventional casting processes are prone to crack initiation due to inhomogeneous reinforcement dispersion, gas porosity, and inadequate toughness. To break the conventional trade-off between high wear resistance and low toughness of [...] Read more.
Aluminum matrix composites provide an ideal solution for lightweight brake disks, but conventional casting processes are prone to crack initiation due to inhomogeneous reinforcement dispersion, gas porosity, and inadequate toughness. To break the conventional trade-off between high wear resistance and low toughness of brake disks, this study fabricated a bimetallic structure of SiCp/Al–Fe–V–Si aluminum matrix composite and cast ZL101 alloy using friction stir lap welding (FSLW). Then, the microstructural evolution, mechanical properties, and tribological behavior of the FSLW joints were studied by XRD, SEM, TEM, tensile testing, and tribological tests. The results showed that the FSLW process homogenized the distribution of SiC particle reinforcements in the SiCp/Al–Fe–V–Si composites. The Al12(Fe,V)3Si heat-resistant phase was not decomposed or coarsened, and the mechanical properties were maintained. The FSLW process refined the grains of the ZL101 aluminum alloy through recrystallization and fragmented eutectic silicon, improving elongation to 22%. A metallurgical bond formed at the joint interface. Tensile fracture occurred within the ZL101 matrix, demonstrating that the interfacial bond strength exceeded the alloy’s load-bearing capacity. In addition, the composites exhibited significantly enhanced wear resistance after FSLW, with their wear rate reduced by approximately 40% compared to the as-received materials, which was attributed to the homogenized SiC particle distribution and the activation of an oxidative wear mechanism. Full article
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30 pages, 3838 KiB  
Review
Advances in the Tribological Performance of Graphene Oxide and Its Composites
by Mayur B. Wakchaure and Pradeep L. Menezes
Materials 2025, 18(15), 3587; https://doi.org/10.3390/ma18153587 - 30 Jul 2025
Viewed by 299
Abstract
Graphene oxide (GO), a derivative of graphene, has attracted significant attention in tribological applications due to its unique structural, mechanical, and chemical properties. This review highlights the influence of GO and its composites on friction and wear performance across various engineering systems. The [...] Read more.
Graphene oxide (GO), a derivative of graphene, has attracted significant attention in tribological applications due to its unique structural, mechanical, and chemical properties. This review highlights the influence of GO and its composites on friction and wear performance across various engineering systems. The paper explores GO’s key properties, such as its high surface area, layered morphology, and abundant functional groups. These features contribute to reduced shear resistance, tribofilm formation, and improved load-bearing capacity. A detailed analysis of GO-based composites, including polymer, metal, and ceramic matrices, reveals those small additions of GO (typically 0.1–2 wt%) result in substantial reductions in coefficient of friction and wear rate, with improvements ranging between 30–70%, depending on the application. The tribological mechanisms, including self-lubrication, dispersion, thermal stability, and interface interactions, are discussed to provide insights into performance enhancement. Furthermore, the effects of electrochemical environment, functional group modifications, and external loading conditions on GO’s tribological behavior are examined. Despite these advantages, challenges such as scalability, agglomeration, and material compatibility persist. Overall, the paper demonstrates that GO is a promising additive for advanced tribological systems, while also identifying key limitations and future research directions. Full article
(This article belongs to the Special Issue Tribology in Advanced Materials)
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23 pages, 3795 KiB  
Article
Structural Analysis of the Newly Prepared Ti55Al27Mo13 Alloy by Aluminothermic Reaction
by Štefan Michna, Jaroslava Svobodová, Anna Knaislová, Jan Novotný and Lenka Michnová
Materials 2025, 18(15), 3583; https://doi.org/10.3390/ma18153583 - 30 Jul 2025
Viewed by 169
Abstract
This study presents the structural and compositional characterisation of a newly developed Ti55Al27Mo13 alloy synthesised via aluminothermic reaction. The alloy was designed to overcome the limitations of conventional processing routes for high–melting–point elements such as Ti and Mo, enabling the formation of a [...] Read more.
This study presents the structural and compositional characterisation of a newly developed Ti55Al27Mo13 alloy synthesised via aluminothermic reaction. The alloy was designed to overcome the limitations of conventional processing routes for high–melting–point elements such as Ti and Mo, enabling the formation of a complex, multi–phase microstructure in a single high–temperature step. The aim was to develop and characterise a material with microstructural features expected to enhance wear resistance, oxidation behaviour, and thermal stability in future applications. The alloy is intended as a precursor for composite nanopowders and surface coatings applied to aluminium–, magnesium–, and iron–based substrates subjected to mechanical and thermal loading. Elemental analysis (XRF, EDS) confirmed the presence of Ti, Al, Mo, and minor elements such as Si, Fe, and C. Microstructural investigations using laser confocal and scanning electron microscopy revealed a heterogeneous structure comprising solid solutions, eutectic regions, and dispersed oxide and carbide phases. Notably, the alloy exhibits high hardness values, reaching >2400 HV in Al2O3 regions and ~1300 HV in Mo– and Si–enriched solid solutions. These results suggest the material’s substantial potential for protective surface engineering. Further tribological, thermal, and corrosion testing, conducted with meticulous attention to detail, will follow to validate its functional performance in target applications. Full article
(This article belongs to the Section Metals and Alloys)
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15 pages, 4423 KiB  
Article
Effect of B Element Doping on High-Temperature Tribological Properties of WS2-Based Composite Coatings
by Songmin Zhang, Xiaopeng Zhang, Haichao Cai, Zixuan Huang, Yujun Xue, Lulu Pei and Bowei Kang
Lubricants 2025, 13(8), 332; https://doi.org/10.3390/lubricants13080332 - 30 Jul 2025
Viewed by 195
Abstract
WS2 coating, as a solid lubricating material, plays a significant role in the lubrication of rotating components in spacecraft. During the launch process, however, spacecraft are exposed to high-temperature and humid atmospheric environments, which can lead to oxidative failure in the coating, [...] Read more.
WS2 coating, as a solid lubricating material, plays a significant role in the lubrication of rotating components in spacecraft. During the launch process, however, spacecraft are exposed to high-temperature and humid atmospheric environments, which can lead to oxidative failure in the coating, thereby limiting its engineering applications. By doping with B elements, B/WS2 was successfully prepared as a composite coating. The results demonstrate that the fabricated coating exhibits excellent high-temperature tribological performance in atmospheric environments. The mechanism through which B doping improves the high-temperature friction and wear properties of the WS2 composite coating was revealed through high-temperature friction and wear tests. With the incorporation of B elements, the average friction coefficient of the coating was 0.071, and the wear rate was 7.63 × 10−7 mm3·N−1·m−1, with the wear mechanisms identified as abrasive wear and spalling. Due to high-temperature oxidation, thermal decomposition effects, and the formation of WB4 during sputtering, the wear resistance and anti-plastic deformation capability of the coating were further improved. Compared to room-temperature test conditions, the B/WS2 composite coating at different high temperatures exhibited superior friction coefficients and wear rates. Notably, at 150 °C, the average friction coefficient was as low as 0.015, and the wear forms were abrasive wear and adhesive wear. Full article
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16 pages, 14261 KiB  
Article
Effect of Er Microalloying and Zn/Mg Ratio on Dry Sliding Wear Properties of Al-Zn-Mg Alloy
by Hanyu Chen, Xiaolan Wu, Xuxu Ding, Shengping Wen, Liang Hong, Kunyuan Gao, Wu Wei, Li Rong, Hui Huang and Zuoren Nie
Materials 2025, 18(15), 3541; https://doi.org/10.3390/ma18153541 - 29 Jul 2025
Viewed by 266
Abstract
In this study, dry sliding wear tests were carried out on Er, Zr-microalloyed Al-Zn-Mg alloys with different Zn/Mg ratios under 30–70 N loads. The effects of the Zn/Mg content ratio and Er microalloying on the friction coefficient, wear volume loss, worn surface, and [...] Read more.
In this study, dry sliding wear tests were carried out on Er, Zr-microalloyed Al-Zn-Mg alloys with different Zn/Mg ratios under 30–70 N loads. The effects of the Zn/Mg content ratio and Er microalloying on the friction coefficient, wear volume loss, worn surface, and wear debris during the friction process of Al-Zn-Mg alloys were analyzed. At the load of 30 N, abrasive wear, fatigue wear, and adhesive wear were synergistically involved. At a load of 50 N, the abrasive wear dominated, accompanied by fatigue wear and adhesive wear. At a load of 70 N, the primary wear mechanisms transitioned to abrasive wear and fatigue wear, with additional adhesive wear and oxidative wear observed. Reducing the Zn/Mg ratio mitigated wear volume across all tested loads. For the Al4.5Zn1.5Mg alloy, Er microalloying significantly reduced wear volume under moderate-to-low loads (30 N, 50 N). Full article
(This article belongs to the Section Metals and Alloys)
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31 pages, 5261 KiB  
Review
Wear- and Corrosion-Resistant Coatings for Extreme Environments: Advances, Challenges, and Future Perspectives
by Subin Antony Jose, Zachary Lapierre, Tyler Williams, Colton Hope, Tryon Jardin, Roberto Rodriguez and Pradeep L. Menezes
Coatings 2025, 15(8), 878; https://doi.org/10.3390/coatings15080878 - 26 Jul 2025
Viewed by 735
Abstract
Tribological processes in extreme environments pose serious material challenges, requiring coatings that resist both wear and corrosion. This review summarizes recent advances in protective coatings engineered for extreme environments such as high temperatures, chemically aggressive media, and high-pressure and abrasive domains, as well [...] Read more.
Tribological processes in extreme environments pose serious material challenges, requiring coatings that resist both wear and corrosion. This review summarizes recent advances in protective coatings engineered for extreme environments such as high temperatures, chemically aggressive media, and high-pressure and abrasive domains, as well as cryogenic and space applications. A comprehensive overview of promising coating materials is provided, including ceramic-based coatings, metallic and alloy coatings, and polymer and composite systems, as well as nanostructured and multilayered architectures. These materials are deployed using advanced coating technologies such as thermal spraying (plasma spray, high-velocity oxygen fuel (HVOF), and cold spray), chemical and physical vapor deposition (CVD and PVD), electrochemical methods (electrodeposition), additive manufacturing, and in situ coating approaches. Key degradation mechanisms such as adhesive and abrasive wear, oxidation, hot corrosion, stress corrosion cracking, and tribocorrosion are examined with coating performance. The review also explores application-specific needs in aerospace, marine, energy, biomedical, and mining sectors operating in aggressive physiological environments. Emerging trends in the field are highlighted, including self-healing and smart coatings, environmentally friendly coating technologies, functionally graded and nanostructured coatings, and the integration of machine learning in coating design and optimization. Finally, the review addresses broader considerations such as scalability, cost-effectiveness, long-term durability, maintenance requirements, and environmental regulations. This comprehensive analysis aims to synthesize current knowledge while identifying future directions for innovation in protective coatings for extreme environments. Full article
(This article belongs to the Special Issue Advanced Tribological Coatings: Fabrication and Application)
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12 pages, 7595 KiB  
Article
Reactive Sintering of Cemented Carbides
by Victor I. Stanciu, Alexandre Mégret, Anne Mouftiez, Véronique Vitry and Fabienne Delaunois
Alloys 2025, 4(3), 15; https://doi.org/10.3390/alloys4030015 - 25 Jul 2025
Viewed by 132
Abstract
Cemented carbides are among the primary materials for tools and wear parts. Today, energy prices and carbon emissions have become key concerns worldwide. Cemented carbides consist of tungsten carbide combined with a binder, typically cobalt, nickel, or more recently, various high-entropy alloys. Producing [...] Read more.
Cemented carbides are among the primary materials for tools and wear parts. Today, energy prices and carbon emissions have become key concerns worldwide. Cemented carbides consist of tungsten carbide combined with a binder, typically cobalt, nickel, or more recently, various high-entropy alloys. Producing tungsten carbide involves reducing tungsten oxide, followed by carburization of tungsten at 1400 °C under a hydrogen atmosphere. The tungsten carbide produced is then mixed with the binder, milled to achieve the desired particle size, and granulated to ensure proper flow for pressing and shaping. This study aims to bypass the tungsten carburizing step by mixing tungsten, carbon, and cobalt; shaping the mixture; and then applying reactive sintering, which will convert tungsten into carbide and consolidate the parts. The mixtures were prepared by planetary ball milling for 10 h under different conditions. Tests demonstrated that tungsten carburization successfully occurs during sintering at 1450 °C for 1 h. The samples exhibit a typical cemented carbide microstructure, characterized by prismatic grains with an average size of 0.32 μm. Densification reached 92%, hardness is approximately 1800 HV30, and toughness is 10.9 ± 1.15 MPa·m1/2. Full article
(This article belongs to the Special Issue New Alloys for Surface Engineered Coatings, Interfaces and Films)
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18 pages, 4701 KiB  
Article
Investigation of the Wear Resistance of Hard Anodic Al2O3/IF-WS2 Coatings Deposited on Aluminium Alloys
by Joanna Korzekwa, Adam Jarząbek, Marek Bara, Mateusz Niedźwiedź, Krzysztof Cwynar and Dariusz Oleszak
Materials 2025, 18(15), 3471; https://doi.org/10.3390/ma18153471 - 24 Jul 2025
Viewed by 268
Abstract
The anodic oxide layer’s porosity is considered a functional feature, acting as a reservoir of lubricants. This feature enables the design of self-lubricating systems that effectively reduce friction and wear. To improve the tribological performance of Al2O3 anodic coatings on [...] Read more.
The anodic oxide layer’s porosity is considered a functional feature, acting as a reservoir of lubricants. This feature enables the design of self-lubricating systems that effectively reduce friction and wear. To improve the tribological performance of Al2O3 anodic coatings on EN AW 5251 aluminium alloys, this paper presents a modification of the coating with tungsten disulfide (IF-WS2) nanopowder and its effect on coating resistance. The wear properties of Al2O3/IF-WS2 coatings in contact with a cast iron pin were investigated. The results include the analysis of the friction coefficient in the reciprocating motion without oil lubrication at two loads, the analysis of the wear intensity of the cast iron pin, the characterisation of wear scars, and the analysis of SGP parameters. Two-level factorial analysis showed that load and nanomodification significantly affected the load-bearing parameter Rk. Incorporation of the modifier, especially under higher loads, reduced the Rk value, thus improving the tribological durability of the contact pair. Both load and nanomodification had a notable impact on the coefficient of friction. The use of IF-WS2-modified coatings reduced the coefficient, and higher loads further enhanced this effect, by approximately 9% at a load of 0.3 MPa and 15% at a load of 0.6 MPa, indicating improved lubricating conditions under greater contact stress. Full article
(This article belongs to the Special Issue Surface Engineering in Materials (2nd Edition))
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14 pages, 6297 KiB  
Article
Enhancing the Elevated-Temperature Mechanical Properties of Levitation Melted NbMoTaW Refractory High-Entropy Alloys via Si Addition
by Yunzi Liu, Xiaoxiao Li, Shuaidan Lu, Jialiang Zhou, Shangkun Wu, Shengfeng Lin and Long Wang
Materials 2025, 18(15), 3465; https://doi.org/10.3390/ma18153465 - 24 Jul 2025
Viewed by 203
Abstract
To enhance the mechanical properties of NbMoTaW refractory high-entropy alloys (RHEAs), Si was added at varying concentrations (x = 0, 0.25, and 0.5) via vacuum induction levitation melting (re-melted six times for homogeneity). The microstructure and mechanical properties of NbMoTaWSix ( [...] Read more.
To enhance the mechanical properties of NbMoTaW refractory high-entropy alloys (RHEAs), Si was added at varying concentrations (x = 0, 0.25, and 0.5) via vacuum induction levitation melting (re-melted six times for homogeneity). The microstructure and mechanical properties of NbMoTaWSix (x = 0, 0.25, and 0.5) RHEAs were characterized using scanning electron microscopy (SEM), universal testing, microhardness testing, and tribological equipment. Experimental results manifested that Si addition induces the formation of the (Nb,Ta)5Si3 phase, and the volume fraction of the silicide phase increases with higher Si content, which significantly improves the alloy’s strength and hardness but deteriorates its plasticity. Enhanced wear resistance with Si addition is attributed to improved hardness and oxidation resistance. Tribological tests confirm that Si3N4 counterfaces are optimal for evaluating RHEA wear mechanisms. This work can provide guidance for the fabrication of RHEAs with excellent performance. Full article
(This article belongs to the Special Issue High-Entropy Alloys: Synthesis, Characterization, and Applications)
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30 pages, 2940 KiB  
Article
Chemical, Mechanical and Tribological Effects of Artificially Aging up to 6 Weeks on Virgin and Crosslinked UHMWPE Evaluated for a TKR Design
by Jens Schwiesau, Bernhard Fritz, Pierangiola Bracco, Georg Bergmann, Ana Laura Puente Reyna, Christoph Schilling and Thomas M. Grupp
Bioengineering 2025, 12(8), 793; https://doi.org/10.3390/bioengineering12080793 - 24 Jul 2025
Viewed by 488
Abstract
Patients undergo total knee arthroplasty (TKA) at younger ages with the expectation that the devices will perform well over two to three decades. During this time, the ultra-high molecular weight polyethylene (UHMWPE) bearing material properties of the implant may change due to aging [...] Read more.
Patients undergo total knee arthroplasty (TKA) at younger ages with the expectation that the devices will perform well over two to three decades. During this time, the ultra-high molecular weight polyethylene (UHMWPE) bearing material properties of the implant may change due to aging induced by radiation and oxygen diffusion or other effects. Vitamin E or other antioxidants are promoted since several years to improve the oxidation resistance of UHMWPE. To compare the effectivity of these substances against established materials, a six weeks aging process was used and the chemical, mechanical and bio-tribological properties were analysed. Highly crosslinked and two weeks aged UHMWPE served as a reference for the currently established aging standards and virgin UHMWPE was aged for six weeks to separate the effects of crosslinking and vitamin E blending. Six weeks artificially aging changed the chemical, mechanical and bio-tribological properties of cross-linked UHMWPE significantly compared to only two weeks artificially aging, leading to cracks and delamination during the highly demanding activities wear test. The degradative effect of extended aging was also observed for virgin UHMWPE. These observations are in good accordance to retrieval findings. Minor changes on the chemical properties were observed for the cross-linked UHWMPE blended with vitamin E without impact on the mechanical and bio-tribological properties. Full article
(This article belongs to the Section Biomedical Engineering and Biomaterials)
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39 pages, 7688 KiB  
Review
Advances and Applications of Graphene-Enhanced Textiles: A 10-Year Review of Functionalization Strategies and Smart Fabric Technologies
by Patricia Rocio Durañona Aznar and Heitor Luiz Ornaghi Junior
Textiles 2025, 5(3), 28; https://doi.org/10.3390/textiles5030028 - 22 Jul 2025
Viewed by 410
Abstract
Graphene has emerged as a promising material for transforming conventional textiles into smart, multi-functional platforms due to its exceptional electrical, thermal, and mechanical properties. This review aims to provide a comprehensive overview of the latest advances in graphene-enhanced fabrics over the past ten [...] Read more.
Graphene has emerged as a promising material for transforming conventional textiles into smart, multi-functional platforms due to its exceptional electrical, thermal, and mechanical properties. This review aims to provide a comprehensive overview of the latest advances in graphene-enhanced fabrics over the past ten years, focusing on their functional properties and real-world applications. This article examines the main strategies used to incorporate graphene and its derivatives—such as graphene oxide and reduced graphene oxide—into textile substrates through coating, printing, or composite formation. The structural, electrical, thermal, mechanical, and electrochemical properties of these fabrics are discussed based on characterization techniques including microscopy, Raman spectroscopy, and cyclic voltammetry. Functional evaluations in wearable strain sensors, biosignal acquisition, electrothermal systems, and energy storage devices are highlighted to demonstrate the versatility of these materials. Although challenges remain in scalability, durability, and washability, recent developments in fabrication and encapsulation methods show significant potential to overcome these limitations. This review concludes by outlining the major opportunities and future directions for graphene-based textiles in areas such as personalized health monitoring, active thermal wear, and integrated wearable electronics. Full article
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24 pages, 15762 KiB  
Article
Performance of TiSiN/TiAlN-Coated Carbide Tools in Slot Milling of Hastelloy C276 with Various Cooling Strategies
by Ly Chanh Trung and Tran Thien Phuc
Lubricants 2025, 13(7), 316; https://doi.org/10.3390/lubricants13070316 - 19 Jul 2025
Viewed by 491
Abstract
Nickel-based superalloy Hastelloy C276 is widely used in high-performance industries due to its strength, corrosion resistance, and thermal stability. However, these same properties pose substantial challenges in machining, resulting in high tool wear, surface defects, and dimensional inaccuracies. This study investigates methods to [...] Read more.
Nickel-based superalloy Hastelloy C276 is widely used in high-performance industries due to its strength, corrosion resistance, and thermal stability. However, these same properties pose substantial challenges in machining, resulting in high tool wear, surface defects, and dimensional inaccuracies. This study investigates methods to enhance machining performance and surface quality by evaluating the tribological behavior of TiSiN/TiAlN-coated carbide inserts under six cooling and lubrication conditions: dry, MQL with coconut oil, Cryo-LN2, Cryo-LCO2, MQL–Cryo-LN2, and MQL–Cryo-LCO2. Open-slot finishing was performed at constant cutting parameters, and key indicators such as cutting zone temperature, tool wear, surface roughness, chip morphology, and microhardness were analyzed. The hybrid MQL–Cryo-LN2 approach significantly outperformed other methods, reducing cutting zone temperature, tool wear, and surface roughness by 116.4%, 94.34%, and 76.11%, respectively, compared to dry machining. SEM and EDS analyses confirmed abrasive, oxidative, and adhesive wear as the dominant mechanisms. The MQL–Cryo-LN2 strategy also lowered microhardness, in contrast to a 39.7% increase observed under dry conditions. These findings highlight the superior performance of hybrid MQL–Cryo-LN2 in improving machinability, offering a promising solution for precision-driven applications. Full article
(This article belongs to the Special Issue High Performance Machining and Surface Tribology)
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53 pages, 7445 KiB  
Review
Research on the Application of Nano-Additives in Gel-like Lubricants
by Han Peng, Zihao Meng, Linjian Shangguan, Lei Liu, Can Yang and Lingxi Guo
Gels 2025, 11(7), 546; https://doi.org/10.3390/gels11070546 - 14 Jul 2025
Viewed by 398
Abstract
In the field of mechanical motion, friction loss and material wear are common problems. As one of the essential components for enhancing the lubricating performance of gel-like lubricants, nano-additives leverage their unique physical and chemical properties to form an efficient protective film on [...] Read more.
In the field of mechanical motion, friction loss and material wear are common problems. As one of the essential components for enhancing the lubricating performance of gel-like lubricants, nano-additives leverage their unique physical and chemical properties to form an efficient protective film on friction surfaces. This effectively reduces friction resistance and inhibits wear progression, thereby playing a significant role in promoting energy conservation, emissions reduction, and the implementation of green development principles. This study first introduces the physical and chemical preparation processes of gel-like lubricant nanoadditives. It then classifies them (mainly based on metal bases, metal oxides, nanocarbon materials, and other nanoadditives). Then, the performance of gel-like lubricant nano-additives is evaluated (mainly in terms of anti-wear, friction reduction, oxidation resistance, and load carrying capacity), and the surface analysis technology used is described. Finally, we summarize the application scenarios of gel-like lubricant nano-additives, identify the challenges faced, and discuss future prospects. This study provides new insights and directions for the design and synthesis of novel gel-like lubricants with significant lubricating and anti-wear properties in the future. Full article
(This article belongs to the Special Issue Physical and Mechanical Properties of Polymer Gels (3rd Edition))
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21 pages, 13173 KiB  
Article
Surface Modification by Plasma Electrolytic Oxidation of Friction Surfacing 4043 Aluminum-Based Alloys Deposited onto Structural S235 Steel Substrate
by Roxana Muntean and Ion-Dragoș Uțu
Materials 2025, 18(14), 3302; https://doi.org/10.3390/ma18143302 - 13 Jul 2025
Viewed by 460
Abstract
The friction surfacing (FS) process has emerged over the past few years as a method for joining both similar and dissimilar materials, for volume damage repair of defective components, and for corrosion protection. The possibility to produce a metallic coating by FS, without [...] Read more.
The friction surfacing (FS) process has emerged over the past few years as a method for joining both similar and dissimilar materials, for volume damage repair of defective components, and for corrosion protection. The possibility to produce a metallic coating by FS, without melting the material, classifies this technique as distinct from other standard methods. This unconventional deposition method is based on the severe plastic deformation that appears on a rotating metallic rod (consumable material) pressed against the substrate under an axial load. The present study aims to investigate the tribological properties and corrosion resistance provided by the aluminum-based FS coatings deposited onto a structural S235 steel substrate and further modified by plasma electrolytic oxidation (PEO). During the PEO treatment, the formation of a ceramic film is enabled, while the hardness, chemical stability, corrosion, and wear resistance of the modified surfaces are considerably increased. The morpho-structural characteristics and chemical composition of the PEO-modified FS coatings are further investigated using scanning electron microscopy combined with energy dispersive spectroscopy analysis and X-ray diffraction. Dry sliding wear testing of the PEO-modified aluminum-based coatings was carried out using a ball-on-disc configuration, while the corrosion resistance was electrochemically evaluated in a 3.5 wt.% NaCl solution. The corrosion rates of the aluminum-based coatings decreased significantly when the PEO treatment was applied, while the wear rate was substantially reduced compared to the untreated aluminum-based coating and steel substrate, respectively. Full article
(This article belongs to the Section Metals and Alloys)
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