Search Results (93)

In the context of a study on selected fragments of ancient architecture belonging to a collection of the archaeological museum “Luigi Bernabò Brea” in Lipari (Aeolian Islands, Messina, Italy), we analysed, using the non-destructive X-Ray Fluorescence (XRF) method, dozens of artefacts dating back to the sixth century BCE. The aim was to identify the origin of the raw materials used by craftsmen in the production of ceramic artefacts. The quantitative analyses, based on the composition and trace elements, suggest that the composition material used is consistent with local natural resources, given the presence of kaolinite–clay deposits in the northern part of Lipari. By comparing the ancient fragments with local raw kaolin powders still available today, this study aims to confirm the use of these materials in past ceramic production and decoration. These results support the hypothesis that the investigated fragments were locally manufactured, providing deeper insights into the production techniques of the time and the raw materials of the region. Full article

This article presents the results of an analysis of ceramics from archeological sites. The main goal of the study was to determine the elemental composition of ceramics using XRF. This study was conducted in two stages. The first stage involved the analysis of complete vessels from the museum exhibition. The second involved the interpretation of the results obtained from the first stage. In the second stage, 30 samples obtained by dividing a single fragment of a ceramic vessel were analyzed. The results (results scattered due to material heterogeneity) were compared with the results of analyses of a large group of ceramic samples from a similar period. To supplement the information about the ceramic material studied, destructive analyses were also performed (after grinding the aforementioned 30 samples), namely mineral composition using FTIR (to determine the raw materials) and iron speciation using UV-Vis and HPLC-ICP hrOES (to determine the firing method). The results obtained indicated that limiting the research to the most-used non-destructive procedures in archaeometry can lead to misinterpretation. Although the presented study concerned archaeological objects, it can be considered in the context of research on other materials. Full article

Dendrochronology, the study of tree-ring growth patterns, is a powerful tool for reconstructing past human–environment interactions. This review examines its role within archaeology, focusing on how tree-ring studies contribute to dating wooden artifacts, reconstructing past climates, and understanding timber use in historical buildings and cultural heritage. To explore these applications, we conducted a bibliometric analysis of studies indexed in Web of Science. Our results reveal a marked increase in dendrochronological research over the past 15 years, alongside a broadening of its impact across related fields such as anthropology and environmental sciences. We classify the literature into major thematic areas, including methodological developments, historical and environmental disruptions, art and architecture, mining history, and the ancient timber trade. By highlighting both the advantages and limitations of dendrochronology—such as issues of reference coverage, the need for non-destructive sampling, and the importance of interdisciplinary collaboration—we show how this approach extends beyond archaeology to illuminate wider cultural and environmental contexts. Ultimately, our findings demonstrate the significance of dendrochronology not only for understanding ancient civilizations and cultural heritage, but also for tracing the complex interactions between humans and natural resources across time. Full article

Background/Objectives: DNA analysis can be used to expand our understanding of extinct populations and the history of the world and humankind. Dental cavities often contain uncontaminated remains of ancient DNA (aDNA). Archaeological excavations are a convenient source for various samples; however, in almost all extraction methods, a piece of bone or tooth is powdered before extraction, thereby causing damage to archaeological samples that are often irreplaceable and unique. This study aimed to develop a method that enables the collection of DNA from teeth without causing significant damage. Methods: This study presents two methods of DNA extraction from teeth: destructive and non-destructive. Both contemporary and archaeological teeth were examined using both destructive and non-destructive approaches to compare their efficiency. To verify the results, methods such as quantitative RT-PCR, STR analysis, and Y-SNP analysis were employed. Results: Extraction efficiency plays a critical role in this field of research. The main steps of the DNA extraction method were compared and optimized based on purification and using quantitative PCR. Conclusions: The results demonstrate that a non-destructive method of DNA isolation from human teeth can be used successfully, especially when teeth are unique and cannot be destroyed during the examination process. This method yields an appropriate amount of DNA for sequencing. Full article

A key goal when managing copper alloy heritage is preventing “bronze disease,” which damages surface detail and may disintegrate objects by oxidation and hydrolysis of nantokite (CuCl), forming voluminous copper trihydroxychlorides (Cu₂(OH)₃Cl). The success of mitigation strategies is difficult to evaluate due to the complexity of copper alloy corrosion profiles, limitations in non-destructive analytical methods and incomplete understanding of the corrosion mechanisms and reactions involved in bronze disease. Without better understanding, it is impossible to design truly effective solutions for the safe storage and display of archaeological copper alloys. Advancing current understanding, this paper examines oxidation and hydrolysis of CuCl using oxygen consumption, Fourier transform infrared spectroscopy and Raman spectroscopy, recognised as the basis of bronze disease. Variables potentially affecting bronze disease processes are evaluated, including relative humidity (RH) (15–80%RH at 20 °C) and the presence of metallic copper with CuCl and their respective ratios. Results confirm that these variables influence the reaction mechanisms and kinetics of bronze disease. The rate of oxidation and hydrolysis of CuCl accelerates with RH, and its effect is quantified. The presence of copper is shown to be important for producing bronze disease; it facilitates a cyclic reaction forming Cu₂(OH)₃Cl, increases its formation rate at lower RH than by hydrolysis of CuCl alone and prevents formation of soluble chloride compounds. The formation of Cu₂(OH)₃Cl without counteracting copper ions is shown to promote formation of CuCl₂ and CuCl₂·2H₂O, accelerating bronze disease. This new understanding is used to better quantify risk of bronze disease as a function of RH, providing a more quantitative tool for managing preservation of archaeological copper alloy collections. Full article

The preservation of archaeological bone is of great importance for both archaeological and conservation science studies. Traditional methods of preservation assessment, such as attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), are minimally invasive and destructive. Neutron and X-ray tomography offer a totally non-invasive novel analysis method for the state of preservation of archaeological bones. Seven archaeological animal bones were selected for analysis based on animal maturity, species, visual factors, and ATR-FTIR analysis results. Archaeological bone is a hierarchical composite material constructed from both organic and mineral components; therefore, neutron tomography and synchrotron X-ray tomography have been combined in this novel approach to assess the state of preservation of animal archaeological bone. The neutron data demonstrated that the organic distribution along the diaphysis of archaeological bones varied significantly both within bones and between different animal bones. There is minimal consistency between the samples, emphasizing the inhomogeneity in archaeological bone collections. X-ray tomography revealed unseen physical details, including cracks and substantial damage. The collection of this information via non-invasive methods is highly valuable for cultural heritage, providing a deeper understanding of the observed inhomogeneity in ATR-FTIR analysis data and revealing obscured physical details. Full article

During the processes of excavation, restoration, and conservation of archaeological sites, it is common practice to perform physical and chemical characterization of the site materials. This is carried out to determine the best methods and materials for conserving and preserving the site. For this reason, techniques such as infrared spectroscopy and elemental analysis by X-ray fluorescence (XRF) are primarily used for chemical characterization, while mechanical tests such as the uniaxial compression test and hardness tests are used for physical and mechanical characterization. However, a common limitation is obtaining samples for destructive physical tests, such as compression tests, due to their invaluable cultural value. To address this problem, this work proposes the mechanical characterization of the material through nanoindentation. This technique requires a smaller sample size and can be performed in a timely manner by observing the resistance of each mineralogical phase present in the material. Thus, a preliminary predictive model of mechanical resistance is proposed based on the composition observed in the samples from the archaeological site of Cerro de los Remedios, located in the municipality of Comonfort, Guanajuato, Mexico. The samples were characterized using infrared spectroscopy, XRF, XRD, and SEM-EDS. The results indicate that the stone (caliche) is formed from 95.6–93% micrite calcite; 2.51–0.42% aluminosilicate; 3.14–1.89% high-calcium aluminosilicate; and 3.43–2.39 quartz or amorphous SiO₂. The proposed correlation models were adjusted to a linear function, a second-order polynomial, and a logarithmic function. In the M2–linear model, the non-linear effects generated by variables such as texture, porosity, phase adhesion, cement type, and cracks or discontinuities were not considered. In this model the best prediction of the experimental data was obtained within a variation of ±15%. Full article

Non-destructive tests are especially useful for the assessment of building stones and their deterioration in built cultural heritage. Gamma-ray spectrometry is a non-destructive test that has not been applied extensively in these types of constructions. Therefore, the purpose of this study is to show the results of gamma-ray spectrometry for limestone characterization and deterioration assessment. This study was conducted in the North Temple of the Archaeological Zone of Chichen Itza and several outcrops in the area. Gamma-ray spectrometry data were corrected for attenuation caused by the moisture content in rocks to calculate the real radioelements concentrations using linear regression, with interpretation based on their mobility resulting from chemical weathering processes. The results obtained with gamma-ray spectrometry were corroborated by laboratory analyses, demonstrating that stones from the North Temple are more weathered than rocks from the outcrops, and that some limestones have clasts derived from terrigenous sources, causing them to show slightly higher radiation, which can be distinguished easily with gamma-ray spectrometry, even when lithology cannot be recognized in plain sight. Gamma-ray spectrometry proved to be useful for limestone characterization, and data obtained can be correlated with parameters from other analyses. Full article

The Karnak Temples are considered one of Egypt’s most significant archaeological sites, dating back to the Middle Kingdom (c. 2000–1700 BC) and were continuously expanded until the Ptolemaic period (305–30 BC). As the second most visited UNESCO World Heritage archaeological site in Egypt after the Giza Pyramids, Karnak faces severe deterioration processes due to prolonged exposure to environmental impacts, mechanical damage, and historical interventions. This study employs a multidisciplinary approach integrating non-destructive testing (NDT) methods to assess the physical and mechanical condition and degradation mechanisms of scattered sandstone blocks at the site. Advanced documentation techniques, including Reflectance Transformation Imaging (RTI), photogrammetry, and Infrared Thermography (IRT), were used to analyze surface morphology, thermal stress effects, and weathering patterns. Ultrasonic Pulse Velocity (UPV) testing provided internal structural assessments, while spectral and gloss analysis quantified chromatic alterations and surface roughness. Additionally, the Karsten Tube test determined the water absorption behavior of the sandstone, highlighting variations in porosity and susceptibility to salt crystallization. In this sense, the results indicate that climatic factors such as extreme temperature fluctuations, wind erosion, and groundwater infiltration contributed to sandstone deterioration. Thermal cycling leads to microcracking and granular disintegration, while high capillary water absorption accelerates chemical weathering processes. UPV analyses showed substantial internal decay, with low-velocity zones correlating with fractures and differential cementation loss. Finally, an interventive conservation plan was proposed. Full article

Archaeological mollusk shells, such as those of Littorina obtusata/fabalis, hold valuable information about past human behavior and cultural practices. However, the original coloration of these shells, crucial for understanding their symbolic significance, is often lost due to taphonomic processes. Raman spectroscopy is a powerful technique for non-destructive analysis of archaeological samples, enabling the identification of pigments and mineralogical components. In this study, we present a methodology to predict, using Raman spectroscopy and k-means clustering, the original coloration of archaeological L. obtusata/fabalis shells which have lost their original coloration. Raman spectra were acquired from both modern shells, exhibiting a range of natural colors, and archaeological shell samples from La Chora cave (Cantabria, northern Spain). Spectral data were preprocessed to remove noise and baseline effects, and k-means clustering was applied to group the spectra based on their inherent spectral similarities. By comparing the spectral signatures of the archaeological samples with those of the modern shells within the generated clusters, we inferred the likely original coloration of the archaeological specimens. This approach provides a quantitative framework for predicting archaeological shell colors. Full article

A multiproxy methodology has been employed to characterise two granite anchors discovered on the seabed near the island of Nueva Tabarca (Alicante, Southeast Spain). According to the significant archaeological context where they were found, the studied anchors can be dated from the Roman ages (late Republican period). One of the most interesting aspects is the absence of regional geological outcrops with rocks compatible with the granite used in the production of the anchor, which shows a foreign origin consistent with the connection of the anchor to maritime transport across the Mediterranean Sea. The lack of precise information about the artifact’s origin underscores the interest and need for the application of petrological techniques to determine its provenance. The methodology utilised encompasses five distinct techniques: (1) non-destructive textural analysis using X-ray microcomputed tomography; (2) K–Ar dating; (3) petrological characterisation through optical microscopy; (4) geochemical characterisation using X-ray fluorescence and atomic absorption spectrometry. The results allow for a comparison of the anchor rock’s characteristics with various granite outcrops along the Mediterranean coasts (Eastern, Central, and Western sectors), suggesting potential source areas based on petrological compatibility with the material under study. The findings point to the origin of the Nueva Tabarca granite anchor being granite outcrops in Southern Italy (Calabria), reinforcing the connection between the Spanish southeastern coasts and Southern Italy. These results highlight the utility and significance of multiproxy petrological methodologies in the geoarchaeological study of decontextualised artifacts. Full article

This study investigates the subsurface remains of Jaundole Castle, a 14th-century medieval fortress located on Dole Island near Riga, Latvia. The castle, which has left no visible surface ruins, is known only from historical documents and maps. To assess whether its buried remains could be detected, a non-invasive ground penetrating radar (GPR) survey was carried out across five targeted grids. The results revealed multiple linear and circular anomalies consistent with historical records of the castle’s layout, including possible foundations of walls and towers. These findings demonstrate that GPR, when combined with historical map and image analysis, can effectively locate, and delineate lost architectural features. The integration of historical sources and geophysical data provides a replicable model for the investigation of other completely buried archaeological sites. This work contributes to the development of non-destructive prospection strategies and supports the planning of future archaeological excavations and conservation actions. Full article

Egyptian Blue was the first synthetic pigment by humankind. It contains of cuprorivaite, which is a calcium-copper-silicate (CaCuSi₄O₁₀). This study reports the results of a mineralogical and computer tomographic study of Egyptian Blue finds from Aguntum in East Tyrol along with Retznei and Wagna (formerly Flavia Solva) from southern Styria in Austria. The present work aims to extend our understanding of the processes involved in the production of the artificial pigment Egyptian Blue. The samples were investigated with respect to their elemental composition and spatial distribution of the calcium-copper-silicate cuprorivaite CaCuSi₄O₁₀ and then compared with data from previous studies. Thin sections of an Egyptian Blue sphere from Aguntum were examined using optical microscopy (OP), micro-X-ray fluorescence analysis (μ-XRF) and scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (SEM-EDX). The pigment’s initial mixture as well as the manufacturing process seem to be the decisive factor for the quality of the final product. A relationship between the presence of trace iron (Fe) and titanium (Ti) with the quartz and copper source of the initial mixture is discussed. SEM-EDX analysis revealed that cuprite (Cu₂O) was used as a copper source. In addition, micro-computed tomography (µCT) of the Egyptian Blue finds (Aguntum, Retznei, Wagna-Flavia Solva) was performed. Hence, revealing several concise differences between the samples. Texture and volumetric results show a distinctive difference in cuprorivaite content and particle size. To better analyse the spatial distribution, µCT-3D images of the individual mineral phases identified within each sample were obtained. The clear differences in the results may not only enable a differentiation of the production process but also show another potential of non-destructive µCT for assessment of archaeological findings. Full article

This review explores the applications of room temperature semiconductor detectors, with a focus on Cd(Zn)Te based detection systems, in non-destructive testing and evaluation (NDT&E). Cd(Zn)Te detectors, which operate efficiently at ambient temperatures, eliminate the need for cryogenic cooling systems and offer high energy and spatial resolution, making them ideal for a wide range of NDT&E applications. Key performance parameters such as energy resolution, spatial resolution, time resolution, detector efficiency, and form factor are discussed. The paper highlights the utilization of Cd(Zn)Te detectors in various imaging and spectroscopic applications, including nuclear threat detection and non-proliferation, archaeological NDT, and Unmanned Aerial Vehicle radiological surveying. Cd(Zn)Te detectors hold significant promise in NDT&E due to their high-resolution imaging, superior spectroscopic capabilities, versatility, and portability. Full article

In March 2022, an auction house in Zurich sold two female figurines made from mammoth ivory, along with other prehistoric artefacts. This is a rare occurrence because the scarcity and value of Paleolithic figurines have limited their presence in the international art market. Researchers from the Archaeological Museum Hamburg and the University of Tübingen subsequently undertook in situ and non-destructive investigations to illuminate the authenticity of the two figurines. We conducted a comprehensive analytical study that included detailed microscopic optical observations and spectroscopic investigations. This methodological approach, combined with a thorough comparison to contemporary ivory figurine replicas, proved effective and clearly demonstrated that the specimens were forgeries. Research efforts of this kind are crucial, as they significantly help reduce the spread of intentional fakes posing as genuine artefacts in the art market. By doing so, we foster collaboration between academic institutions and the art market to preserve and protect the integrity and value of authentic archaeological and cultural heritage. Full article